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A super-molecular complex, [Na(DB18C6)(CH3CN)]2W6O19·(CH3CN)2, was obtained by solvothermal reaction and characterized by IR , 1H NMR, gumbc spectrum single crystal and X-ray diffraction. The compou- nd crystallizes in monoclinic space group P21/c with a=1.185 22(4) nm, b=2.091 51(8) nm, c=1.487 19(5) nm, β=117.467(2)° and Z=2. The complex contains four basic units: Na+, CH3CN, DB18C6 and W6O192-. Sodium ions located in the cavity of dibenzo-18-crown-6 with 6 Na-O bonds and the crown ether-sodium ion complex is supported on the terminal oxygen atoms of the typical Lindqvist isopolyanion W6O192- via the coordinative interactions. W6O192- located between two DB18C6 and led to the formation of the “hamburger” structure. Two isolated CH3CN are included in the complex. The whole title crystal is stabilized by van der waals force. CCDC: 292369. 相似文献
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Synthesis,Crystal Structure of Cis—dioxo—catecholatotungsten(VI) Complex and Its NMR Studies on the Interaction with ATP 总被引:1,自引:0,他引:1
Cis-dioxo-catecholatotungsten(VI) complex anion[W^(VI)O2-(OC6H4O)2]^2- was obtained with discrete protonated ethylenediamine (NH2CH2CH2NH3)^ cations by the reaction of tetrabutyl ammonium decatungstate with catechol in the mixed solvent of CH3OH,CH3CN and ethylenediamine,and compared with its molybdenum anaogue [Mo^(V) O2(OC6H4O)2]^3- by crystal structure,UV,EPR,The results of the UV and EPR spectra show that tungsten is less redox active than molybdenum since the molybdenum is reduced from Mo(VI) to Mo(V) but tungsten stays in the original highest oxidized state Mo(VI) when they are crystallized from the solution above.It is worthy to note that [W^(VI)O2(OC6H4O)]^2- shows the same coordination structure as its molybdenum analogue in which the metal center exhibits distorted octahedral coordination geometry with two cis-dioxocatecholate ligands and might have the related coordination structure feature with the cofactor of flavoenzyme because [Mo^(V)O2(OC6H4O)2]^3- presented essentially the same EPR spectra as flavoenzyme.The NMR studies on the interaction of the title complex with ATP reveal that the reduction of W(VI) to W(V) occurs when the title complex is dissolved in D2O and the W(V) is oxidized again when ATP solution is mixed with original solution and the hydrolysis of the catecholato ligand take places at mean time being monitored by ^1H NMR and ^13C NMR spectra. 相似文献
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Cis-dioxo-tungsten(Ⅵ) complex, (NH2CH2CH2NH2)[(NH2CH2CH2NH3)2WⅥO2(NHC6H4NH)2]2·H2O is synthesized at room temperature by the reaction of sodium tungstate with o-phenylenediamine. The crystal structure of complex was determined by X-ray diffraction structural analysis. The results show that complex belongs to monoclinic system with space group P21/ c, a=0.712 8(2) nm, b=3.081 1(10) nm, c=0.981 9(3) nm, β=102.615(4)°, V=2.104 4(11) nm3, Z=2, μ=55.26 cm-1, F(000)=1 176. Compared the complex with its analogous biomimetic complexes of the cofactor of molybdoenzymes and tungstoenzymses, it is found that the variance of the coordination atoms and the metal ions center have no influence on the coordination feature, and exhibits distored octahedral coordination with cis-dioxo o-phenylenediamine. CCDC: 252834. 相似文献
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以苯并15冠5和钼多酸为原料, 用水热法合成了两个新颖的超分子配合物[Na(B30C10)][Mo6O19] (1)和[NaL(CH3CN)][NaL][α-PMo12O40][NaL2] (L=B15C5) (2), 并用单晶X射线衍射测定了它们的晶体结构. 配合物1属单斜晶系, 空间群为C2/m, 它包含三个基本单元: Na+, B15C5和Mo6O , 冠醚分子和Na+配位, 并通过静电作用力和多酸分子相连. 配合物2属三斜晶系, 空间群为P-1, 它包含一个[α-PMo12O40]3-离子和三个钠离子配合物. [Na(B15C5)]+通过Mo-O-Na-O键和多酸阴离子相连. 相似文献
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回顾了钨多酸抗艾滋病研究的历史;简要介绍了钨多酸的药物动力学、抗HIV作用机理和选择性;总结了研究过程中的检测手段;预测了未来钨多酸抗HIV研究工作的方向。 相似文献
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苯基氮杂—15—冠—5对钼同多酸以及钨钼杂多酸阴离子的选择 总被引:1,自引:1,他引:1
合成了两种氮杂大环八聚多酸超分子配合物[Na(N-Ph)aza-15C5(Et2O)]2Na2MO8O26(Ⅰ)和[Na(N-Ph)aza-15C5(Et2O)]2Na2Wo25Mo7.75O26(Ⅱ),用元素分析、IR、1HNMR和H,H-COSY谱进行了表征,并用X射线测定了配合物(Ⅱ)的晶体结构.配合物(Ⅱ)属单斜晶系,空间群为P21/c,晶胞参数为:a=1.7644(4)nm,b=1.3702(3)nm,c=1.4507(3)nm,β=114.02(3)°,Z=2.该类晶体由大环金属销配位阳离子和二维阴离子网络[Na2WxMo8-xO26」2-组成,阴、阳离子分层堆积.研究了苯基氮杂-15-冠-5和与之键合的多酸阴离子的结构及相互关系.发现在苯基氮杂-15-冠-5分别与八错多酸和六聚钨错杂多酸反应所得的产物中,多酸阴离子的聚合度均为8.表明大环化合物的结构与阴离子的结构有一定的对应关系. 相似文献