局部域上谱测度的纯型性

众所周知、一个σ-有限测度μ可以唯一地分解成离散、奇异连续和绝对连续部分.考虑局部域上的谱测度的纯型性质、即若μ是局部域上的谱测度、则它只能属于上述三种类型的一种.     

弹性力学问题的一种新解法

弹性力学问题的一种新解法邹广德，沈玉凤（山东工程学院，淄博２５５０１２）对于弹性力学问题，常常采用边界积分方程的间接解法，将假想作用在边界上的虚拟力作为未知量，故也称虚拟力法。这种方法与边界积分方程的直接解法一样，存在奇异积分，且边界附近精度较低。为...     

Al2O3负载Cu,Fe或Ni掺杂氧化钼催化乙苯氧化脱氢（英文）

Molybdenum-based catalysts supported on Al2O3 doped with Ni, Cu, or Fe oxide were synthesized and used in ethylbenzene dehydrogenation to produce styrene. The molybdenum oxide was sup-ported using an unconventional route that combined the polymeric precursor method (Pechini) and wet impregnation on commercial alumina. The samples were characterized by X-ray diffraction (XRD), N2 adsorption-desorption isotherms, temperature-programmed reduction of H2 (H2-TPR), and thermogravimetric (TG) analysis. XRD results showed that the added metals were well dis-persed on the alumina support. The addition of the metal oxide (Ni, Cu, or Fe) of 2 wt% by wet im-pregnation did not affect the texture of the support. TPR results indicated a synergistic effect be-tween the dopant and molybdenum oxide. The catalytic tests showed ethylbenzene conversion of 28%–53% and styrene selectivity of 94%–97%, indicating that the addition of the dopant improved the catalytic performance, which was related to the redox mechanism. Molybdenum oxides play a fundamental role in the oxidative dehydrogenation of ethylbenzene to styrene by its redox and acid–base properties. The sample containing Cu showed an atypical result with increasing conver-sion during the reaction, which was due to metal reduction. The Ni-containing solid exhibited the highest amount of carbon deposited, shown by TG analysis after the catalytic test, which explained its lower catalytic stability and selectivity.     

教学札记

<正> 关于速度合成定理的几何证明方法文章[1]指出证明速度合成定理的几何法存在两个问题,笔者对此表示异议.图1中的 M_1 M′正是动点的相对位移,相对位移的绝对导数     

第十三届国际等离子体化学会议总结

第十三届国际等离子体化学会议总结＠吴承康￥ＩＳＰＣ－１３组委会第十三届国际等离子体化学会议总结国际等离子体化学会议（ＩｎｔｅｒｎａｔｉｏｎａｌＳｙｍｐｏ ｓｉｕｍｏｎＰｌａｓｍａＣｈｅｍｉｓｔｒｙ）是低温等离子体领域最有影响的国际系列会议．其内容包括低温等...     

用紫外光谱法测定共轭亚油酸乙酯的含量

在226-240nm波长范围内，采用紫外可见分光光度法测定了不同浓度的共轭亚油酸乙酯的吸光度，绘制出样品在不同浓度时的吸光度曲线，找出适宜的浓度范围，作线性回归分析，得到样品浓度和吸光度的线性关系。利用PE Autosystem XL-TurboMass测得样品中共轭亚油酸乙酯的准确浓度，结合回归系数给出了测定共轭亚油酸乙酯含量的经验公式。     

Existence and Global Asymptotic Behavior of Positive Solutions for Sublinear and Superlinear Fractional Boundary Value Problems

In this paper, the authors aim at proving two existence results of fractional differential boundary value problems of the form(P_(a,b)){D~αu(x) + f(x, u(x)) = 0, x ∈(0, 1),u(0) = u(1) = 0, D~(α-3)u(0) = a, u(1) =-b,where 3 α≤ 4, Dαis the standard Riemann-Liouville fractional derivative and a, b are nonnegative constants. First the authors suppose that f(x, t) =-p(x)t~σ, with σ∈(-1, 1)and p being a nonnegative continuous function that may be singular at x = 0 or x = 1and satisfies some conditions related to the Karamata regular variation theory. Combining sharp estimates on some potential functions and the Sch¨auder fixed point theorem, the authors prove the existence of a unique positive continuous solution to problem(P_(0,0)).Global estimates on such a solution are also obtained. To state the second existence result, the authors assume that a, b are nonnegative constants such that a + b 0 and f(x, t) = tφ(x, t), with φ(x, t) being a nonnegative continuous function in(0, 1)×[0, ∞) that is required to satisfy some suitable integrability condition. Using estimates on the Green's function and a perturbation argument, the authors prove the existence and uniqueness of a positive continuous solution u to problem(P_(a,b)), which behaves like the unique solution of the homogeneous problem corresponding to(P_(a,b)). Some examples are given to illustrate the existence results.     

钾改性对Au/ZSM-5催化剂上正丁烷裂解性能的影响

采用负压沉积沉淀法制备了负载型Au/HZSM-5催化剂,采用X射线衍射（XRD）、透射电镜（TEM）、Ｘ射线光电子能谱（XPS）、NH3-TPD、紫外可见漫反射（UV-vis）等技术对催化剂进行了表征分析,并考察了催化剂对正丁烷裂解性能的影响。结果表明,Au金属成功负载到HZSM-5催化剂上,并且金颗粒的尺寸受负载量的影响,其中1.0%Au/HZSM-5催化剂中的金颗粒粒径最小,约为5～10nm。钾离子作为一种碱性离子可以调节载体酸性,随着K离子的引入xK-Au/HZSM-5催化剂的酸性逐渐降低,使Au0的电子结合能更高。相对于HZSM-5,2.0Au/HZSM-5催化剂对于正丁烷的转化率从13.1%提升到了37.5%,对丙烯的选择性从17.2%提升到了52.5%。随着K离子的引入,催化剂对于丁烯以及异丁烷的选择性有所提高,当K离子负荷为0.08%时,对丁烯的选择性从3.8%提高到36.9%,负荷为0.1%时,对异丁烷的选择性由2.8%提升到51.8%。但原料转化率低于2.0Au/HZSM-5,这可能与K的加入降低催化剂酸改性有关。此外通过研究Au/HZSM-5用K+修饰得知Au+离子是Au/HZSM-5催化剂转化正丁烷主要活性中心。     

小样本字典学习的兰姆波模态识别方法*

针对兰姆波多模态识别问题,提出了基于小样本字典学习的模态识别方法。将多层复合板的频散特性看作一个线性时不变系统,首先,根据频散知识模拟各个模态传播特定距离后的信号,提取走时和能量特征创建字典;其次,获取待测信号的走时特征,通过查询字典来识别兰姆波模态;最后,根据能量参数估计结果,实现待测信号中各模态信号的分离和重构。通过对三层粘接的AAA板(铝板-亚克力板-铝板,每层厚度为2mm)中传播距离为0.3m、0.5m的直达波和反射波的实验验证,结果显示该方法对A0、S0模态的有效识别和各个波包信号的准确重建。     

Development and validation of a sensitive and fast solid-phase spectrophotometric procedure for phenol determination in pharmaceuticals

A very sensitive, simple, and fast solid-phase spectrophotometric procedure for the determination of phenol using the p-nitrobenzenediazonium reagent (DAR reagent) was developed. This procedure is based on the simultaneous concentration of the orange product on a Dowex 1-X2 anion exchanger within 15 min, and a direct absorbance measurement of the sorbed species at both 530 nm (the absorption maximum of the phenol-DAR in the resin phase) and 700 nm (the range where only the resin absorbs light). Quality control and evaluation of the analytical parameters was carried out using a comprehensive prevalidation strategy. The linearity of the method was confirmed within an analyte working range from 0.01 to 0.10 μmol (0.2 to 2.0 nmol mL(-1)). The precision ranged from ±1.17 to ±9.61%; the accuracy ranged from -17.50 to +17.81%. The evaluated limiting values were L(D) = 0.0013 μmol and L(Q) = 0.0082 μmol. The DAR-SPS method was successfully applied to the determination of phenol in a pharmaceutical sample of salicylic acid (98.0-100.0%) and vaccines (98.0-103.4%).