配合物[Fe_2(BPMPP)_2](BPh_4)_2的合成与晶体结构

合成了含不对称双核配体BPMPP的配合物[Fe2(BPMPP)2](BPh4)2;利用元素分析仪、红外光谱仪和X射线衍射仪分析了其组成和晶体结构.结果表明,标题配合物属单斜晶系,空间群为P21/c;晶胞参数:a=1.406 5(3)nm,b=1.990 4(4)nm,c=1.712 2(3)nm,β=112.511(3)°,V=4.428 0(14)nm3,Z=2,Dc=1.349 Mg/m3,μ=1.288 mm-1,F(000)=1 872,GOF=0.967,最终偏差因子R1=0.059 6,wR2=0.111 3.在阳离子[Fe(BPMPP)]2+中,两个铁(Ⅱ)离子处于对称位置,均具有变形的三角双锥几何构型.     

含柔性间隔基的扩链脲增韧环氧树脂性能研究——环氧树脂／扩链脲／双氰双胺体系性能研究

合成了含不同分子量柔性间隔基的扩链脲（Ｕｉ），并对其与双氰双胺共同固化环氧树脂体系的反应活性、抗冲击性能、动态力学性能、形态结构及贮存性能进行了考察。结果表明：含分子量为４００的聚乙二醇柔性链的扩链脲／双氰双胺／环氧树脂固化体系的抗冲击强度较单纯双氰双胺／环氧树脂固化体系提高了７倍左右，其冲击试样断面电镜照片呈韧性断裂的特征。扩链脲的反应活性基本不受分子中聚乙二醇链段分子量的影响。环氧树脂／扩链脲／双氰双胺体系在５０℃下贮存期可达１～２天。     

锥形脊结构半导体光放大器的有限元分析

为提高半导体光放大器与单模光纤耦合效率，建立了半导体放大器的锥形脊结构模型。在该模型下利用有限元数值模拟方法分析，计算了波导区折射率、锥尖宽度、条形波导尺寸、渐变折射率波导层对锥形脊结构模式扩展的影响。通过完善锥形脊结构参量的设计，获得了锥形脊结构半导体光放大器与单模光纤95％的耦合效率。     

反应堆高阶κ本征方程数值计算方法的改进

针对反应堆高阶κ-本征方程数值计算问题，提出了提高计算效率和计算精度的改进方法，并以一维问题为例，对该方法进行了验证。The solution methods for the higher order oped yet in the nuclear reactor engineering. Based on harmonics and higher order eigenvalues are not well develthe analysis of the convergence process of power iteration, a new approach for setting the starting values of higher order harmonic flux has been proposed. The results of numerical tests demonstrate that the proposed method could effectively improve the efficiency of calculations of higher order harmonics. In addition, a new type of criterion that judges the convergence of higher order harmonics dynamically has been proposed, it has been verified that the new convergence criterion could effectively prevent the buildup of numerical errors introduced in the solution of lower order harmonics in the solution of higher order harmonics.     

高频金融时序的密度函数肥尾度量

本文在分析高频金融时序的基本特征的基础上,应用极值理论和相关性质估计和检验了肥尾指数。     

环焦改进型双镜天线

本文导出了环焦改进型天线主副镜轮廓的计算公式,天线各种极化辐射场的计算公式,并扼要介绍这种新型天线的性能和设计方法。     

二价硅离子高于3s3p态能级间自旋允许跃迁的理论计算

在最弱受约束电子势模型理论中，电子被分成最弱受约束电子和非最弱受约束电子，而假定最弱受约束电子在核和非最弱受约束电子形成的势场中运动，这样许多多电子体系的问题可以简化成最弱受约束电子的单电子问题来解决．最弱受约束电子势模型理论已经被成功地应用于跃迁几率，振子强度和原子能级的计算．应用一组方程计算了Si III的离子自旋允许跃迁的跃迁几率，计算结果与标准值比较是相当令人满意的，误差均在15%以下．而且表明最弱受约束电子势模型理论可以非常简便并准确地应用于计算高激发态间的跃迁几率．     

部分相干涡旋光束在湍流大气中的传输特性

根据广义的惠更斯-菲涅耳原理,推导了部分相干涡旋光束在湍流介质中传输时光强分布情况的理论公式,详细研究了部分相干涡旋光束在湍流介质中的传输变化规律。研究结果表明,湍流介质的强弱,光源的相干性以及光束所带拓扑电荷数大小均会影响光束传输特性。     

Laser induced damage of multi-layer dielectric used in pulse compressor gratings

Laser induced damage threshold (LIDT) of multi-layer dielectric used in pulse compressor gratings (PCG) was investigated. The sample was prepared by e-beam evaporation (EBE). LIDT was detected following ISO standard 11254-1.2. It was found that LIDTs of normal and 51.2°incidence (transverse electric (TE) mode) were 14.14 and 9.31 J/cm2, respectively. A Nomarski microscope was employed to map the damage morphology, and it was found that the damage behavior was pit-concave-plat structure for normal incidence, while it was pit structure for 51.2°incidence with TE mode. The electric field distribution was calculated to illuminate the difference of LIDT between the two incident cases.     

Damage on HfO_2/SiO_2 high-reflecting coatings under single and multiple Nd:YAG laser pulse irradiation

The single- and multi-shot damage behaviors of HfO2/SiO2 high-reflecting (HR) coatings under Nd:YAG laser exposure were investigated. Fundamental aspects of multi-shot laser damage, such as the instability due to pulse-to-pulse accumulation of absorption defect and structural defect effect, and the mechanism of laser induced defect generation, are considered. It was found in multi-shot damage, the main factors influencing laser-induced damage threshold (LIDT) are accumulation of irreversible changes of structural defects and thermal stress that induced by thermal density fluctuations.