"一锅法"合成N-乙基咔唑乙酰化衍生物

以N-乙基咔唑为原料,通过“一锅法”合成了未见文献报道的单乙酰化衍生物3-乙酰基-9-乙基咔唑和双乙酰化衍生物3,6-二乙酰基-9-乙基咔唑,其结构经1H NMR,IR,MS和元素分析表征。     

水热法制备核-壳结构的α-ZnS纳米晶

以氯化锌和氨基硫脲为原料，采用配合物低温水热分解法，制备了具有核．壳结构的α-ZnS半导体纳米晶。X射线粉末衍射(XRD)和X射线光电子能谱(XPS)确定所制备样品为纯ZnS，透射电镜(TEM)表明产品的形貌是核．壳结构小球，电子衍射图案进一步证实核和壳均是由几个到十几个纳米的ZnS纳米晶组成的聚集体。荧光(FL)性质表明该样品有一定的量子尺寸效应。     

Multi-Electron Processes in 4.15-11.08 keV/u^13C^6＋ on Argon Collisions

The relative partial cross sections for ^13C^6＋ -Ar collisions at 4.15-11.08 ke V/u incident energy are measured. The cross-section ratios σ^2E/σ^SC, σ^3E/σ^SC, σ^4E/σ^SC and σ^SE/σ^SC are approximately the constants of 0.514-0.05, 0.204-0.03, 0.064-0.03 and 0.024-0.01 in this region. The significance of the multi-electron process in highly charged ions （HCIs） with argon collisions is demonstrated （σ^ME/σ^SC as high as 0.794-0.06）. In multi-electron processes, it is shown that transfer ionization is dominant while pure electron capture is weak and negligible. For all reaction channels, the cross-sections are independent of the incident energy in the present energy region, which is in agreement with the static characteristic of classic models, i.e. the molecular Coulomb over-the-barrier model （MCBM）, the extended classical over-the-barrier model （ECBM） and the semiempirical scaling laws （SL）. The result is compared with these classical models and with our previous work of ^13C^6＋ -Ne collisions [Chin. Phys. Lett. 23 （2006） 95].     

具有双光子活性的蓝色发光材料的合成

具有双光子活性的蓝色发光材料的合成;双光子;荧光;蓝色发光材料     

A control method for congested traffic in the coupled map car-following model

Based on the pioneer work of Konishi et al, a new control method is presented to suppress the traffic congestion in the coupled map (CM) car-following model under an open boundary. A control signal concluding the velocity differences of the two vehicles in front is put forward. The condition under which the traffic jam can be contained is analyzed. The results are compared with that presented by Konishi et al [Phys. Rev. 1999 E 60 4000--4007]. The simulation results show that the temporal behavior obtained by our method is better than that by the Konishi's et al. method, although both the methods could suppress the traffic jam. The simulation results are consistent with the theoretical analysis.     

改进的有自由面非稳定渗流分析复合单元渗透矩阵调整法

应用连续的罚函数,提出了一种改进的自由面边界条件渗流分析复合单元渗透矩阵调整法,优化了此类算法的稳定性,提高了收敛速度和精度,并将此改进算法编制成相应的有限元分析程序,应用于上海地铁4号线董家渡隧道修复基坑降水工程的优化设计,解决了基坑降水过程中复杂三维渗流场的高效精细模拟问题,同时预测了基坑中心水位降至地面以下40 m,位于承压含水层顶面以下,基坑内外自由面落差很大时基坑周边渗流场以及地面沉降的分布特征.     

高导热聚合物复合材料结构与性能研究进展

由于电子信息、通信、航空航天、汽车等技术领域中元器件的功率密度迅速增大,导致设备因局部过热产生性能、稳定性和寿命降低的问题日益严重.因此,运用高导热材料将电子设备中产生的热量尽可能快速且有效地移除,以维持设备的操作温度十分必要.聚合物材料具有轻质、柔性、易加工成型、良好的力学性能、耐化学腐蚀、电绝缘、低成本等优势,在各类电子器件中获得广泛应用.然而大多数聚合物热导率低,难以满足现代电子设备中散热的要求.本文针对导热聚合物复合材料的最新研究进展进行系统介绍,着重探讨填料结构、尺寸、无序性、几何结构,聚合物基体化学结构、链运动、取向、结晶、分子间作用力,以及填料-基体界面热阻对复合材料热导率、导热机制以及函数(线性/非线性)等诸多方面因素对导热性能的影响.     

北京谱仪—ⅡKS^0、∧粒子衰变顶点位置的确定

阐述了北京谱仪（BES）中KS^0、∧衰变顶点（次级顶点）寻找、径迹参数确定及误差矩阵修正程序的原理。采用BES-Ⅱ的dE/dx和多重库仑散射修正，并考虑谱仪内磁场并非常数而是位置的函数等因素，对用于BES－I的寻找次级顶点的程序进行了修改，使之能应用于BES－Ⅱ的数据处理。进而，通过对北京谱仪J／φ衰变道的蒙特卡罗模拟和数据分析结果，验证了程序的可靠性。     

北京谱仪-ⅡK0S、Λ粒子衰变顶点位置的确定

阐述了北京谱仪(BES)中K0S、Λ衰变顶点(次级顶点)寻找、径迹参数确定及误差矩阵修正程序的原理.采用BES-Ⅱ的dE/dx和多重库仑散射修正,并考虑谱仪内磁场并非常数而是位置的函数等因素,对用于BES-Ⅰ的寻找次级顶点的程序进行了修改,使之能应用于BES-Ⅱ的数据处理. 进而,通过对北京谱仪J/ψ衰变道的蒙特卡罗模拟和数据分析结果,验证了程序的可靠性.     

简捷微波合成多角星形氧化锌

Using Zn(acac)₂ as precursor, ethylenediamine as base, distilled water as solvent, multigonal(octagonal and above) star-shaped ZnO microcrystals with high purity and even particle size have been prepared in domestic microwave oven by low heating for 8 min. The obtained powder was characterized by XRD, FESEM and TEM. The individual star-shaped ZnO microcrystal was composed of some hexagonal nanocones with diameters of 100～500 nm and lengths of 0.6～1 μm growing along c axis. The room temperature PL spectrum showed a strong broad yellow emission with peak located at 564 nm. The deep-level involved in the yellow luminescence is attributed to interstitial oxygen.