Fe掺杂ZnSe团簇结构和磁性质

采用密度泛函理论研究了Fe原子单掺杂和双掺杂(ZnSe)12团簇的结构、电子性质和磁性质.我们考虑了三种掺杂方式:替代掺杂,外掺杂和内掺杂.单掺杂时,外掺杂团簇是最稳定结构;而双掺杂时,内掺杂团簇是最稳定结构.团簇磁矩主要来自Fe-3d态的贡献,4s和4p态也贡献了一小部分磁矩.由于轨道杂化,相邻的Zn和Se原子上也产生少量自旋.不同掺杂团簇的总磁矩不同,在可调磁矩的磁性材料领域有潜在应用价值.     

Scalability of dark current in silicon PIN photodiode

The mechanism for electrical conduction is investigated by the dark temperature-dependent current–voltage characteristics of Si PIN photodiodes with different photosensitive areas.The characteristic tunneling energy E_(00) can be obtained to be 1.40 me V,1.53 me V,1.74 me V,1.87 me V,and 2.01 me V,respectively,for the photodiodes with L = 0.25 mm,0.5 mm,1 mm,1.5 mm,and 2 mm by fitting the ideality factor n versus temperature curves according to the tunneling-enhanced recombination mechanism.The trap-assisted tunneling-enhanced recombination in the i-layer plays an important role in our device,which is consistent with the experimental result that area-dependent leakage current is dominant with the side length larger than 1 mm of the photosensitive area.Our results reveal that the quality of the bulk material plays an important role in the electrical conduction mechanism of the devices with the side length larger than 1 mm of the photosensitive area.     

Theoretical derivation of the crystallographic parameters of polytypes of long-period stacking ordered structures with the period of 13 and 14 in hexagonal close-packed system

Based on crystallographic theory, there are 63 kinds of polytypes of 13H long-period stacking order(LPSO) structure,126 kinds of polytypes of 14H LPSO structure, 120 kinds of polytypes of 39R LPSO structure, and 223 kinds of polytypes of 42R LPSO structure in a hexagonal close-packed(HCP) system, and their stacking sequences and space groups have been derived in detail. The result provides a theoretical explanation for the various polytypes of the LPSO structure.     

16 keV C–离子在锥形玻璃管中的输运过程

鉴于经锥形玻璃管聚焦的离子束在微纳加工、微区分析以及辐照生物医学等领域具有广阔的应用前景,本文研究了16 keV C^–在不同倾斜角度的锥形玻璃管中输运过程.实验发现当处于0°倾斜角度时,出射粒子由核区和晕区构成,核区是从锥形管后锥孔中直接出射,未与锥形管内壁之间发生电荷交换,主要成分为C^–离子.晕区是C^–与锥形管内壁发生部分电荷交换作用,由C^–和C⁰构成.当倾斜角度为1°时,出射离子由两部分组成:C⁰原子束斑和C^–离子束斑,未出现核区.出射核区的离子方向始终保持在入射粒子方向,与锥形管倾斜角度无关.随着锥形管不断倾斜,相对透射率不断减小, C⁰束斑占比增加, C^–束斑占比减小.锥形管对入射离子有聚焦效应.本实验弥补了低能负离子在锥形管运输过程研究的欠缺,有助于聚焦离子束的后续开发应用.     

近期热点文章

正Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries H.-R.Yao,P.-F.Wang,Y.Gong,J.Zhang,X.Yu,L.Gu,C.Ou Yang,Y.-X.Yin,E.Hu,X.-Q.Yang,E.Stavitski,Y.-G.Guo,L.-J.Wan J.Am.Chem.Soc.DOI:10.1021/jacs.7b05176通过减小储钠层的层间距并同时提高过渡金属离     

近期热点文章

<正>Coulometry and Calorimetry of Electric Double Layer Formation in Porous Electrodes M.Janssen,E.Griffioen,P.M.Biesheuvel,R.van Roij,B.ErnéPhys.Rev.Lett.119(2017)166002.电量测定与量热相结合,发现电势固定的多孔碳电极/Na Cl溶液双电层的电量随温度上升而下降.首次测出双电层形成中熵变对巨热力学势的贡献约25%,不同于点电荷模型预测的100%.     

光纤陀螺随机漂移补偿中的数据融合方法（英文）

为提高光电平台的控制性能和稳定性,以平台反馈回路所用的光纤陀螺传感器为研究对象,对光纤陀螺角速率的历史输出、当前量测以及随机漂移进行融合补偿。采用双自回归模型确定了光纤陀螺时间序列输出的自回归多项式和光纤陀螺随机漂移的自回归关系。以陀螺当前输出为量测量,结合卡尔曼滤波算法将陀螺历史输出和历史随机漂移融合进状态方程,并进行随机漂移在线估计补偿。实验结果表明,光纤陀螺随机漂移的AR模型能达到90%拟合效果,经卡尔曼滤波补偿后随机漂移能降到1/10。该方法能很好地抑制光电平台三个框架轴光纤陀螺的随机漂移,补偿率为80%~90%。     

测定自来水中双氯芬酸的两种免疫分析方法对比研究北大核心CSCD

将双氯芬酸（Diclofenac,DCF）与牛血清白蛋白（BsA）通过活化酯法偶联制备人工免疫原,并免疫新西兰大白兔制得抗双氯芬酸的多克隆抗体。使用该抗体建立了测定环境水样中的双氯芬酸的间接竞争酶联免疫吸附分析（ic—ELISA）法;用生物素一亲和素（Biotin-Avidin,BA）标记抗体,建立测定双氯芬酸的BA—ELISA方法。ic-ELISA、BA-ELISA两种方法的线性范围分别为10～10。ng／L和1～10。ng／L;检测限分别为27．0ng／L与2．6ng／L;用于环境水样中双氯芬酸的测定,回收率分别为96．3％～106．7％与93．5％～118．4％。     

Observation and analysis of halo current in EAST

Plasma in a typically elongated cross-section tokamak （for example, EAST） is inherently unstable against vertical displacement. When plasma loses the vertical position control, it moves downward or upward, leading to disruption, and a large halo current is generated helically in EAST typically in the scrape-off layer. When flowing into the vacuum vessel through in-vessel components, the halo current will give rise to a large J × B force acting on the vessel and the in-vessel components. In EAST VDE experiment, part of the eddy current is measured in halo sensors, due to the large loop voltage. Primary experimental data demonstrate that the halo current first lands on the outer plate and then flows clockwise, and the analysis of the information indicates that the maximum halo current estimated in EAST is about 0.4 times the plasma current and the maximum value of TPF × Ih/Ip0 is 0.65, furthermore Ih/Ipo and TPF × Ih/Ipo tend to increase with the increase of Ip0. The test of the strong gas injection system shows good success in increasing the radiated power, which may be effective in reducing the halo current.     

非线性光学晶体YCOB的性能表征

采用显微硬度计、差热扫描仪等表征手段开展了非线性光学晶体YCOB的硬度及热学等相关性能的测量。结果表明YCOB晶体在(100)、(010)及(001)三个方向上的硬度的各向异性较小,有利于YCOB晶体的后期加工。其在330K时的比热容为0.74J·g-1·K-1,经过计算,其在主轴化方向上的热导率分别为1.74,2.16及3.08W·m-1·K-1,具有比较适中的热导率。