共查询到20条相似文献,搜索用时 250 毫秒
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国际职前化学教师教育研究的热点对我国职前化学教师教育发展具有借鉴意义。以47篇《化学教育研究与实践》上职前化学教师教育研究的论文作为研究对象,通过内容分析法和文献计量法分析,并与国内的研究现状进行对比,发现在发文量上,本领域文献产量都不高,国外相关研究成果也是近5年来才开始蓬勃,但在作者分布、研究主题、研究范式上存在较大差距。具体表现:国外学者注重跨专业、跨校、跨国合作研究职前化学教师教育;国外学者倾向于从学生的视角展开调查或测试,基于证据为学生的学习乃至教师教学改革提供策略;国外学者擅长实证研究,和国内经验总结的研究范式差别很大。 相似文献
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开展多媒体课堂教学的尝试与体会 总被引:3,自引:0,他引:3
随着计算机技术的迅速发展,人类已进入信息时代,信息的承载媒体的多元化、集成化。交互性的特征对教育的改革将产生深远的影响,并且对传统的教学提出了挑战。我校领导班子敏锐地认识到将现代媒体技术应用于课堂教学、对于发展学生智力、增强教师的现代化意识、推动学校整体教学改革具有十分重要的意义,及时提出把多媒体课堂教学作为学校办学的重要特色和教育改革的突破口,我们的具体做法主要是:一、勇于探索、积极开展多媒体课堂教学活动多媒体课堂教学是根据教学目的和教育对象的特点,通过对教学策略设计,合理选择和应用教学媒体,… 相似文献
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应用化学专业考试及考核体系的改革与探索 总被引:3,自引:0,他引:3
考试是促进学生全面发展 ,提高素质的重要手段 ,也是检查教学效果、巩固学生所学知识、改进教学工作和督促实现教育目标的必要教学环节。应用化学专业是一个应用理科专业 ,强调学生应既有扎实的化学理论基础 ,又有一定的工程基础和工程实践能力。在应用化学专业开设的课程中既有理科特点的深层次基础课程 ,又有大量锻炼实践能力的实验课程 (包括工程实验 )。因此 ,针对应用化学专业特点 ,建立科学、合理的考试、考核体系具有重要意义。1 传统考试模式的反思与现状分析 传统教育注重知识的传授 ,强调对知识的记忆、模仿和重复练习 ,通常… 相似文献
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Charles H. Langley Diwakar M. Pawar Eric A. Noe 《Journal of Molecular Structure》2005,732(1-3):99-111
The optimized geometries, relative free energies and related thermodynamic properties, harmonic frequencies, and dipole moments have been calculated at the HF and MP2 levels for ethynyl formate (1a), ethynyl acetate (1b), cyano formate, HCO2CN (1c), cyano acetate (1d), S-ethynyl thioformate (2a), S-ethynyl thioacetate (2b), S-cyano thioformate (2c), S-cyano thioacetate (2d), N-ethynylformamide (3a), N-ethynylacetamide (3b), N-cyanoformamide (3c), and N-cyanoacetamide (3d) with the gaussian 98 program. For ethynyl formate, the calculation for 25 °C at the MP2/6-311++G(df,pd) level predicts that the Z isomer is more stable by 1.23 kcal/mol. For S-ethynyl thioformate, calculations at the MP2/6-311++G(2d,2p) level predict that the E isomer is favored by 0.71 kcal/mol at 25 °C. The E isomers of N-ethynylformamide and N-ethynylacetamide were found at all levels to be more stable than the Z isomers at 25 °C. For cyano formate and cyano acetate, calculations at the MP2/6-311++G(df,pd) level predict that the Z isomers are more stable at 25 °C by 1.50 and 2.72 kcal/mol, respectively. At this level and temperature, the Z isomers of 2c, 2d, 3c, and 3d are predicted to have free energies of 0.46, −0.07, 1.22, and 2.28 kcal/mol, respectively, relative to the E conformations. Z to E free-energy barriers at 25 °C of 8.63, 10.64, 17.63, 7.39, and 14.03 kcal/mol were calculated for 1a, 2a, 3a, 1c, and 3c at the HF/6-311G(d,p) level, and at the HF/6-311+G(d,p) level, the free-energy barrier for 2c was 7.08 kcal/mol. 相似文献
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黎志明 《广东微量元素科学》2010,17(7):49-70
从心脑血管疾病的流行率、心脑血管疾病的元素病因、心脑血管疾病的元素诊断和心脑血管疾病的元素治疗等4个方面讨论了元素医学防治心脑血管疾病的临床意义。 相似文献
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Iwona A. Rutkowska Anna Wadas Ewelina Szaniawska Anna Chmielnicka Agnieszka Zlotorowicz Pawel J. Kulesza 《Current Opinion in Electrochemistry》2020
Copper- and copper oxide–based materials are, in principle, promising components (supports, reactive sites, and visible light–absorbing semiconductors) of electrocatalysts and photocathodes for reduction of carbon dioxide. Electrochemical and photoelectrochemical approaches are generally suitable for the low-temperature CO2-conversion to carbon-based simple organic fuels or utility chemicals.Different concepts of utilization, including nanostructuring, doping, admixing, preconditioning, modification, or functionalization of various copper- and copper oxide–based systems for catalytic electroreduction and photoelectrochemical reduction of CO2 are elucidated, as well as important strategies to enhance the systems' overall activity and stability are discussed. 相似文献
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C. K. Kim M. Aguilar-vega D. R. Paul 《Journal of Polymer Science.Polymer Physics》1992,30(10):1131-1142
Dynamic mechanical and gas transport properties for homogeneous homopolymer blends and random copolymers of bisphenol-A and tetramethyl bisphenol-A polycarbonates (PC-TMPC) were determined. The gas transport measurements were performed at 35°C for the gases He, H2, O2, Ar, N2, CH4, and CO2. The results show that the copolymers have lower permeability, apparent diffusion, and solubility coefficients than the blends. Permeability coefficients for blends follow a semilogarithmic ideal mixing rule while copolymers exhibit negative deviations from this. Specific volume measurements show that the free volume available for gas transport is slightly larger in copolymers than in blends of the same composition. These apparently contradictory results may relate to the differences in local mode chain motions observed for the copolymer and blend series. The γ relaxation processes in PC and TMPC seem to operate independently in the blends (no intermolecular coupling) while there is clear evidence for intramolecular coupling in the copolymers. © 1992 John Wiley & Sons, Inc. 相似文献
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M. G. Voronkov O. M. Trofimova Yu. I. Bolgova L. V. Klyba L. I. Larina A. I. Albanov V. A. Pestunovich N. F. Chernov K. B. Petrushenko 《Chemistry of Heterocyclic Compounds》2003,39(12):1639-1644
We have synthesized 1- and 2-(trimethylsilylmethyl)- and 1- and 2-(trimethoxysilylmethyl)benzotriazoles by reaction of 1,2,3-benzotriazolylsodium with trimethyl- or trimethoxy(chloromethyl)silane. We obtained 1- and 2-(silatranylmethyl)benzotriazoles by transesterification of the latter with triethanolamine. 相似文献
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Manfred Spiekermann Daniel Bougeard Hans -Joachim Oelichmann Bernhard Schrader 《Theoretical chemistry accounts》1980,54(4):301-313
The combination of normal coordinate analysis with intensity calculations gives quantitative information about molecular force fields and the assignments of vibrational frequencies. Calculations of vibrational intensities by means of a standard CNDO/2 version give rise to satisfactory results for the IR intensities. However, the calculated Raman intensities often differ strongly from the experimental data. Inclusion of 2p-polarization functions on hydrogen in the usually used valence basis set is quite successful to obtain improved molecular polarizabilities as well as Raman intensities. 相似文献
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The high-resolution (1)H, (13)C, (1)H-(1)H COSY and (1)H-(13)C COSY NMR spectra have been recorded in CDCl(3) for arylacetonitriles 1-12 and analyzed. The arylacetonitriles 3-7 exist in two isomeric forms E (methyl group is anti to cyano group) and Z (the methyl group is syn to cyano group) in solution. Normal chair conformation with equatorial orientations of phenyl rings at C-2 and C-6 for monocyclic nitriles 1 and 2, epimeric chair structure EC (axial configuration of methyl group at C-3) for both the E and Z isomers of arylacetonitrile derivatives (3-7) and a distorted boat form, B(3), for the N-acylacetonitrile derivatives (8-10) have been proposed based on NMR data. The bicyclic nitriles 11 and 12 exist in twin chair conformations in solution. DFT calculations and chemical shifts also support these conformations. Geometry optimizations for 1-12 were carried out according to density functional theory using B3LYP/6-31G(d,p) basis set and for 1 and 8 the theoretical geometrical parameters have been compared with those of single crystal measurements. 相似文献
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V. D. Ignatiev 《Journal of Structural Chemistry》2005,46(4):744-751
A new system of atomic radii for the elements up to barium inclusive is constructed. Values of the radii are chosen so as the dependence between the dissociation energy of diatomic homonuclear molecules and a depth of atom overlapping is monotonous, and the scatter of data is minimal. The depth of overlapping is calculated as a difference between the sum of atomic radii and an experimental interatomic distance. Conclusions are made that: the radii of free atoms and ions are determined by the value of the electron density equal to 0.01 au; they considerably change in molecules and crystals only as a result of the charge transfer from cation to anion; covalent bonding is well described by the overlapping of free atoms (ions), confined by the surface of the given radius, and its energy depends upon the depth of overlapping of valence electron densities of atoms. A method of overlapping atoms is proposed for the approximate estimation of ionic sizes and charges in bound systems. 相似文献
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Several kinds of tea, camomile and herbal tea were analysed to determine natural and artificial radioactivity. The radionuclides were determined by alpha (210Po) and gamma (228Ac, 214Pb, 214Bi, 210Pb, 40K and 137Cs) spectrometry. 228Ac ranged between 0.6 and 9.0 Bq kg−1dry; 210Po between 1.90 and 36.1 Bq kg−1dry; 214Pb and 214Bi between 0.7 and 4.9 Bq kg−1dry; 210Pb between < 10.0 and 58.9 Bq kg−1dry; 40K between 463 and 936 Bq kg−1dry; 137Cs between < 0.3 and 2.6 Bq kg−1dry. The percentage of 210Po extraction in infusion was also determined; the arithmetical mean value of percentage of 210Po extraction resulted 20.7 ± 7.50. 相似文献