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IntroductionImidazolehasattractedconsiderableinterestasalig andinmanybiologicalsystemsinwhichitprovidesapo tentialbindingsiteformetalions .1Imidazoleitselfisanunidentateligandandformscomplexeswithmetalionsthroughitstertiarynitrogenatom .Somecomplexesofi… 相似文献
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INTRODUCTIONThesynthesisofpolynuclearcopper lanthanoidcomplexesisofspecialinterestforsev eralreasons〔1-4〕.Thesecomplexesareim... 相似文献
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SynthesisandStructureof 1-Cyclopentylindenyl Lanthanide(II) Complexes and Their Catalytic Behavior for Polymerization of Acrylonitrile 总被引:3,自引:0,他引:3
IntroductionGreatprogresshasbeenmadeinthechemistryofdi valentorganolanthanidecomplexes .Avarietyofnewclassesofcomplexeshavebeensynthesizedandwidelyusedinorganicsynthesisandpolymerchemistry .1 6 Itwasnoticedthatmostoftheworkpublishedisfocusedonthecomplexe… 相似文献
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1 INTRODUCTIONThemixedchaletNi(Ⅱ)complexescontainingpyridineshavebeenofgreatinterestforinorganicandbioinorganicchemists[1~5].VanillinisoneofthenormalusedcompoundswhichhavetwooxygenatomsandareeasytoformanumberofcomplexeswithCu(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Zn(Ⅱ)andetal[6].Inth… 相似文献
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IntroductionOrganometallicandcoordinationcomplexeshavere centlyemergedaspotentialbuildingblocksfornonlinearoptical (NLO )materials .1 6Comparedwithorganicmolecules ,metalcomplexescanhavealargervarietyofstructuresandamuchgreaterdiversityoftunableelec tronic… 相似文献
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《高等学校化学研究》1999,(3)
IntroductionSchiffbase-transitionmetalcomplexescanbeusedashomogeneouscatalystsinasymmetricorganicsynthesis,suchasthesynthesisofchiralα-cyanohydrin,cyclopropaneorepoxidescompounds[1—3],furthermore,ithasbeenfoundthatthesecomplexeswerefoundtobeassociate… 相似文献
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IntroductionPolynuclearmixed-metalcomplexescontainingbothtransitionandlanthanoidmetalionsareofspecialcurentinterestinrelation... 相似文献
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IntroductionTheabilityofdithiocarbamate(dtc)bindingtometalshasbeenknownformanyyears .Itformschelateswithvirtu allyalltransitionmetals.1Thebidentateanionisalsowellknownasabridgebetweentwotransitionmetalcenters.2 Wa ter solubledialkyldithiocarbamatecomplexes… 相似文献
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IntroductionOrganotin(IV)complexeswerewidelyusedasbio cides,fungicidesandinindustryashomogeneouscata lysts.1 6 Morerecently ,pharmaceuticalpropertiesofalkyltin(IV)complexeswithN ,N dialkyldithiocarba mateligandshavebeeninvestigatedfortheirantitumouractivity.7,8… 相似文献
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1INTRODUCTIONRecentresearchonaseriesofdinuclearmolybdenum(0)carbonylcomplexescontain ingthiolato bridgeshasledtotheconclusion... 相似文献
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1INTRODUCTIONInrecentyears,aseriesoflanthanide aluminiumcomplexeswhichareactiveforpoly merizationofolfins〔1〕havebeenreported.... 相似文献
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1INTRODUCTIONRecently,thechemistryofcomplexescontaininglow valencemetalatomshasincreas inglyatractedtheatentionfromchemistsan... 相似文献
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IntroductionTheinteractionofbisphosphineswith (transition)metalsisafascinatingfieldfromthecoordinationchemist’spointofview .Awidearrayofmono andmulti metalliccis η2 P ,P′coordinatedcomplexesareformedinwhichavarietyofcoordinationmodesisen countered .Thechela… 相似文献
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IntroductionMolecularmagnetismofpolynuclearcomplexesisofconsiderableinterestfordesigningnewmagneticmaterialsandforinvestigatingtherelationshipbetweenthestructureandtheroleofthepolymetallicactivesitesinbiologicalsystems.1 4 Journauxetal .5haverecentlyprop… 相似文献
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0IntroductionNumerousuniqueframeworkshavebeenreportedbyassemblyofrationaldesignedorganiclig-andswithmetalionsoverthepastdecade1~3.Itisknownthatbothimidazoleandcarboxylatearefunctionalgroupsforcoordinationtotransitionmetalionstoformcomplexes4~6.Howeve… 相似文献
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IntroductionTheorganometallicchemistryoflanthanidemetalsinlowoxidationstatesiscurrentlyun dergoingarapiddevelopment.Thestudiesondivalentmetal complexchemistryhaveledtoavarietyofnewclassesofcomplexesandreactivitypatterns[14 ] .Theimportanceofstericfactorsc… 相似文献
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GONG Meng-lian WU Wei-ning SHI Hua-hong LEI Heng-yi MENG Jian-xin YANG Yan-sheng 《高等学校化学研究》1998,14(4):359-364
IntroductionAvarietyofnewpolyaminopolycarboxylateligandsandtheirlanthanidecomplexeshavebeensynthesizedinrecentyearsbecauseoft... 相似文献
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1 INTRODUCTIONSulfoxideisknowntoformcoordinationcompoundswithLanthanide(Ⅲ)andtheirsyntheses,propertiesandvariousphysicalcharacteristicshavebeenreport-ed〔1~9〕.However,therearesomanydifficultyinpreparingthekindoflanthanidecomplexesbecausetheanionsuseda… 相似文献
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IntroductionOwingtotheformationofstableanddeeplycoloredcomplexeswithheavymetalions(suchaslead(Ⅱ)etc),theferrocenylaroylhydrazonesarenotonlypotentiallyusefulasspe-cificreagentsinanalyticalandextractivechemistry[1]butalsostronglyactivebiologically,andc… 相似文献
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IntroductionCopper(Ⅱ)complexeswithorganicacidsandotherdonorligandsexistextensivelywithinhumanbodies,andplayanimportantroleinavastrangeofchemicalandbiochemicalcatalyticsystems[1].Muchattentionhasbeenpaidtowhattheymayrevealtothestructuresandtheprobable… 相似文献