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以羟基铝低聚物与其交联制得柱撑皂石,并在偏三甲苯歧化反应中考察了它们的催化性能.结果表明,催化活性随柱撑皂石表面酸量增加而增加;四甲苯中均四甲苯和二甲苯中邻二甲苯的百分含量皆高于热力学平衡值.催化特性与柱撑皂石的柱密度相关. 相似文献
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酒类饮料中含有一定量乙醇,与水溶液相比,当其引入ICP时会产生许多差异。Gree-nfield等曾报道了将甲醇及其他有机酸引入ICP时,发射强度与溶液粘度、表面张力、密度等物理特性的相关关系;伊藤等研究了将0~5%乙醇引入ICP时,某些谱线强度的变化;王小如等研究了不同浓度乙醇对某些元素的离子线和原子线强度、溶液粘度、提取率、雾化效率、ICP电学参数、激发温度等的影响;孙雅如等据此提出了一种分析酒样中微量元素的方法,就是根据酒样喷入ICP时,自激式R.F.发生器阳流、栅流变化情况, 相似文献
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在283.15-333.15 K温度范围内, 测量了质子型离子液体N,N-二甲基乙醇胺丙酸盐(DMEOAP)的密度、粘度及电导率. 讨论了温度对密度、粘度和电导率等物理化学参数的影响. 通过经验和半经验方程得到了该离子液体的热膨胀系数、分子体积、标准摩尔熵及晶格能等热力学性质参数. 由电导率和密度计算出了该离子液体的摩尔电导率. 利用Vogel-Fulcher-Tamman (VFT)方程, 将测量的动力粘度和电导率对温度拟合, 得到了动力粘度和电导率随温度变化方程式.并通过Walden规则, 建立了粘度与摩尔电导率之间的联系. 相似文献
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含氰基离子液体的合成、表征及流变性质研究 总被引:1,自引:1,他引:0
摘要合成、 表征了一系列新的含氰基咪唑类离子液体. 测定了该离子液体的密度、 熔点及溶解性等物理性质, 研究了其在稳态、 瞬态和动态条件下的流变行为. 结果表明, 当剪切速率在0.1~50 s-1范围内时, 其粘度不随剪切速率的变化而变化, 但随温度升高而降低, 粘流活化能随取代基长度变化呈现规律性变化. 对于1-丁基-3-氰乙基咪唑六氟磷酸盐离子液体, 维持剪切速率不变时, 其剪切应力和粘度均不随时间变化, 且随着温度的升高而降低; 在动态条件下, 在线性粘弹区, 复合粘度和损耗模量G″ 随温度升高而降低.
关键词 相似文献
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通过功能化聚对苯撑乙炔(含羟基与氨基)和聚丙烯酸之间的非共价键自组装制备了一系列含共轭聚合物的水溶性荧光纳米粒子, 并进行了相关结构和光学性质表征. 研究表明, 纳米粒子的大小和聚丙烯酸/聚对苯撑乙炔质量比直接相关. 光物理性质研究表明, 形成水溶性纳米粒子后, 疏水的聚苯撑乙炔链在纳米粒子中易于形成π-链间聚集, 其光物理性质与其在薄膜态时相似. 相似文献
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关于非晶态高分子化合物的本体粘度依赖于分子量的关系,过去曾有不少工作,但对天然橡胶的数据尚付缺如。 本工作的目的,卽在阐明了天然橡胶本体的非牛顿粘流特性贝及粘流与塑流的互相转变之后,对天然橡胶的本体粘度与粘均分子量之间的关系进行了研究,借所订定的关系式卽可应用机械方法来测定天然橡胶本体的粘均分子量。 相似文献
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二氧化硅负载胺丙基硅烷电流变流体 总被引:1,自引:0,他引:1
研究用二氧化硅负载胺丙基三乙氧基硅烷[NH2(CH2)3Si(OEt)3]作为分散颗粒,制备无水型的电流变(ER)流体.考察电场强度(E)、剪切速率(γ·)、分散颗粒含量、分散介质种类以及极性小分子等因素对ER流体流变性能的影响.结果发现,以硅油为分散介质,含分散颗粒为15%(g/ml)的流体,不添加任何活化剂,在γ·为8066s-1时,E从0升至1666kV/mm,流体的表现粘度(ηa)从0396Pa.s增大到16668Pa.s.γ·提高,ηa降低.分散颗粒含量增加,ηa增大.用硅油作分散介质,ER效应比用矿物油或石蜡油显著.加入极性小分子苯胺,可以增强流体的ER效应,但随着苯胺含量增多,漏电流密度也增大. 相似文献
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对聚苯胺、及聚苯胺/聚丙烯酸盐复合粒子的稳态剪切流动行为进行了综合考察.结果表明, 在交流电场下,电流变体的剪切应力和剪切速率的关系符合Bingham流体形为.并对此现象进行了分析,提出用非理想塑性体的新模型来描述交流电场下聚苯胺类电流变体的稳态剪切流动. 相似文献
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《Liquid crystals》1999,26(3):383-387
The effect of an electric field on the viscosity, the electrorheological (ER) effect, is studied as a function of the frequency of the electric field for the nematic phase of 4-n-pentyl-4'- cyanobiphenyl (5CB). In the frequency region between 10Hz and 1kHz, a gradual change of the ER effect is observed, with its behaviour depending on the shear rate and the amplitude of the electric field. On the basis of a calculation of the orientational motion of the director and its effect on the viscosity, the observed frequency dependence is suggested to occur as a result of an orientational relaxation of the director. 相似文献
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稀土掺杂PMMA包裹硅铝氧烷凝胶的ER效应 总被引:3,自引:2,他引:1
以二氧化硅微粒制备电流变液是研究者使用较多的一种方法[1] ,但由于二氧化硅的密度相对于分散相硅油来说太大 ,所以制成的电流变液稳定性较差。而用导电高分子微粒制成的电流变液则有在高电场时漏电流密度较大的问题[2 ] 。有研究者用直接聚合法在二氧化硅纳米微粒外包裹一层有机共聚物 ,生成一种微囊复合颗粒 ,可以使其相对密度减小 ,提高了电流变液的稳定性[3] 。我们以廉价水玻璃为原料制取硅铝氧烷溶胶 ,在其表面包裹聚甲基丙烯酸甲酯 (PMMA)后 ,得到PMMA包裹的硅铝氧烷凝胶具有相当的稳定性和易极化性 ,易形成较稳定的悬浮液 … 相似文献
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Biocompatible chitosan particle suspensions in host oils of corn, soybean, and silicone were prepared and their electrorheological
(ER) characteristics were examined under the imposition of electric fields. The effects of the weight concentration of particulate
chitosan and the strength of the applied electric field on ER response in the various chitosan particle suspensions were investigated
via measurements of rheological properties including flow curve, shear viscosity, and yield stress. The yield stresses of
the three different chitosan–oil systems showed different values of slope in the electric field, but all data were found to
fit well with our previously proposed universal scaling function. 相似文献
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Kubra Koyuncu H. Ibrahim Unal O. Yunus Gumus Ozlem Erol Bekir Sari Turgay Ergin 《先进技术聚合物》2012,23(11):1464-1472
In this study, poly(vinyl chloride) (PVC), polyindole (PIN), and PVC/PIN conducting composites having five different compositions were used. Particle sizes, densities, dielectric constants, and sedimentation ratios of the materials were determined. The zeta‐potentials of the samples were measured in aqueous and nonaqueous (silicone oil [SO]) media. The dispersions prepared in SO were subjected to external electric field strength, and their electrorheological properties were investigated. Then the effects of dispersed particle volume fraction, shear rate, external electric field strength, frequency, and temperature onto electrorheological activities of the dispersions were examined. Further, creep and creep‐recovery tests were applied to the PIN/SO and PVC/PIN/SO dispersions, and reversible viscoelastic deformations were observed. Finally, the vibration damping capacity of PVC (66%)/PIN (34%)/SO dispersion system was tested by using an automobile shock absorber. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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In this paper, we present a newly developed rare earth modified amorphous barium strontium titanate (Ba(x)Sr(1-x)TiO3) gel/silicone oil electrorheological (ER) fluid. The ER behaviors of suspensions of pure and rare earth modified amorphous Ba(x)Sr(1-x)TiO3 particles in silicone oil have been investigated under a dc electric field. The shear yield stress of the rare earth modified amorphous BaTiO3 gel/silicone oil ER fluid could reach 14.9 kPa at E=3.5 kV/mm while the leaking current density was very low, about 7.64 microA/cm2. The ER fluids with a higher volume fraction had a higher current density and a higher shear yield stress under the same electric field. The ER fluid has a long-term stability against sedimentation. The problem of caking was not serious and the agglomerated particles could be easily broken up by strongly stirring. 相似文献
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Simone Less Andreas Hannisdal Johan Sjöblom 《Journal of Dispersion Science and Technology》2013,34(1):106-114
The influence of an applied DC electric field on viscosity and droplet size distribution of different water‐in‐crude oil emulsions was monitored in order to investigate the induction of coalescence of the water droplets. The effects caused by the voltage imposition were studied by rheological analysis and the validity of the obtained results was discussed, comparing with the features of real electrocoalcscer systems. A low field NMR technique (CPMG NMR) and digital video microscopy (DVM) were used to elucidate the behavior of the emulsions. Experiments performed at low shear rate with increasing electric field magnitude showed an increase in viscosity until a critical value. ECRIT was reached. Thereafter coalescence occurred and viscosity decreased irreversibly below its initial value. The electrorheological behavior of the emulsions can be attributed to the organization (flocculation) of water droplets induced by the electric field, accompanied by an increase in viscosity. The structure breaks down as the shear rate is increased, leading to a decrease in viscosity. Experiments performed at high shear showed only a small decline in the viscosity. Although it was evident that coalescence took place, it did not involve the whole sample, because the electrodes were uncoated. As a direct consequence, the mean value of the droplet size within the emulsion did not change noticeably. Nonetheless this mean value was less recurrent and the formation of droplets of very large diameter occurred. 相似文献
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Polyaniline (PANI) was synthesized via oxidative coupling polymerization in acid conditions and de-doped in solution of ammonia. The electrorheological (ER) properties of the PANI/silicone oil suspensions were investigated in oscillatory shear as functions of electric field strength, particle concentration, and host fluid viscosity. Consistent with literature, the PANI ER fluid exhibits viscoelastic behavior under the applied electric field and the ER response is strongly enhanced with increasing electric field strength and particle concentration. The dynamic moduli, G' and G' increase dramatically, by 5 orders of magnitude, as the electric field strength is increased to 2 kV/mm. A viscoelastic liquid to solid transition occurs at a critical electric field strength, in the range Ec = 50-200 V/mm, whose value depends on particle concentration and host fluid viscosity. The fibrillar structure formed in the presence of the applied field has a static yield strength tau(y), whose value scales with electric field strength as tau(y) approximately E(1.88). When the field is switched off a residual structure remains, whose yield stress increases with the strength of the applied field and particle concentration. When the applied stress exceeds the yield stress of the residual structure, fast, fully reversible switching of the ER response is obtained. 相似文献