共查询到19条相似文献,搜索用时 93 毫秒
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介绍了碳纳米管的发展历史、结构、制备方法,并重点介绍了碳纳米管在纤维材料、复合材料、电子器件、催化、储氢等领域的应用. 相似文献
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碳纳米管纤维是一种碳纳米管的宏观聚集体,是由碳纳米管及管束组装而成的连续纱线,具有高强、高韧、高导电等特性,在结构功能一体化复合材料、纤维状能源器件、人工肌肉以及轻质导电线缆等领域具有非常广泛的应用前景。经过近二十年的发展,碳纳米管纤维材料在连续制备技术、高性能化以及应用探索等方面相继取得了突破性的研究进展。本文总结了碳纳米管纤维材料的发展历程,对比介绍了碳纳米管纤维的不同连续制备与组装技术,重点讨论了碳纳米管纤维结构与性能之间的关联规律,并对目前碳纳米管纤维的高性能化方法进行了综述。在此基础上,对碳纳米管纤维材料的发展思路以及未来的应用方向进行了展望。 相似文献
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近年来,柔性电子器件的发展日新月异。以碳纳米管为代表的碳纳米材料,尤其是其组装成的宏观结构碳纳米管薄膜具有良好的柔性和优异的导电性,且具有化学稳定、热稳定、光学透明性等优点,在柔性电子领域展现了极大的应用潜力。本文简要综述了近年来碳纳米管薄膜在柔性电子器件领域的研究进展。首先详细介绍了碳纳米管薄膜的两类主要制备方法,分别为干法制备和湿法制备;继而介绍了碳纳米管薄膜在多种柔性电子器件的组装、性能与应用方面的最新研究进展;最后总结了碳纳米管薄膜基柔性电子领域的发展现状,并讨论了该领域所面临的挑战及其未来前景。 相似文献
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以"碳的结构与性能及其应用"为例说明元素化学课堂教学中的方法,引导学生在复习碳元素的结构与性质的基础上,组织学生开展课堂讨论,引导学生对不断涌现的新型碳材料的关注和兴趣。同时,分组讨论碳氧化物的结构与化学性质之间关系及其有效利用,即模拟光合作用实现CO2的光催化还原和基于费托合成实现CO为原料制备燃料,鼓励和推进学生开展碳材料及其应用的本科生科研训练,实现课堂知识与科学研究衔接。 相似文献
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含茂基稀土金属有机络合物催化剂在有机合成中的应用 总被引:2,自引:0,他引:2
综述了含茂基稀土金属有机络合物催化下的不饱和烃(或其取取衍生物)转化反应及其在有机合成中的作用。重点阐述了含茂基稀土金属有机络合物催化的烯烃氧化,氢化环化;烯烃和炔烃的氢化硅化,1,5-或1,6-二烯或烯炔的氢化硅化/环化,氨基取代烯烃,炔烃,丙二烯等的氢化胺化/环化等反应在有机合成中的主要用途,这些反应在形成碳-杂原子键,碳-碳键,碳环和杂环等方面具有广泛的应用前景。讨论了这些反应的催化循环机制,区域稳定性,对映选择性,非对映选择性及其影响因素。 相似文献
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This article summarizes the preparation and applications of carbon derived from jute sticks and fibers that are low‐cost, widely available, renewable, and environmentally friendly. Both the fibers and sticks are considered ideal candidates of carbon preparation because they are composed of cellulose, hemicelluloses, and lignin, and contain negligible ash content. Various carbon preparation methods including simple pyrolysis, pyrolysis with chemical and physical activations are discussed. The impacts of several parameters including types of activating agents, impregnation ratio, and temperature on their morphology, surface area, pore size, crystallinity, and surface functional groups are also emphasized. Various treatments to endow functionalization for increasing the practical applicability, such as chemical, physical, and physico‐chemical methods, are discussed. In addition, applications of jute‐derived carbon in various practical areas, including energy storage, water treatment, and sensors, are also highlighted in this report. Due to the porous fine structure and a large specific surface area, the jute‐derived carbon could be considered as a powerful candidate material for various industrial applications. Finally, possible future prospects of jute‐derived carbon for various applications are pointed out. 相似文献
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Saito N Aoki K Usui Y Shimizu M Hara K Narita N Ogihara N Nakamura K Ishigaki N Kato H Haniu H Taruta S Kim YA Endo M 《Chemical Society reviews》2011,40(7):3824-3834
Carbon fibers are state-of-the-art materials with properties that include being light weight, high strength, and chemically stable, and are applied in various fields including aeronautical science and space science. Investigation of applications of carbon fibers to biomaterials was started 30 or more years ago, and various products have been developed. Because the latest technological progress has realized nano-level control of carbon fibers, applications to biomaterials have also progressed to the age of nano-size. Carbon fibers with diameters in the nano-scale (carbon nanofibers) dramatically improve the functions of conventional biomaterials and make the development of new composite materials possible. Carbon nanofibers also open possibilities for new applications in regenerative medicine and cancer treatment. The first three-dimensional constructions with carbon nanofibers have been realized, and it has been found that the materials could be used as excellent scaffolding for bone tissue regeneration. In this critical review, we summarize the history of carbon fiber application to the biomaterials and describe future perspectives in the new age of nano-level control of carbon fibers (122 references). 相似文献
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A tremendous growth in the field of carbon nanomaterials has led to the emergence of carbon nanotubes, fullerenes, mesoporous carbon and more recently graphene. Some of these materials have found applications in electronics, sensors, catalysis, drug delivery, composites, and so forth. The high temperatures and hydrocarbon precursors involved in their synthesis usually yield highly inert graphitic surfaces. As some of the applications require functionalization of their inert graphitic surface with groups like ? COOH, ? OH, and ? NH2, treatment of these materials in oxidizing agents and concentrated acids become inevitable. More recent works have involved using precursors like carbohydrates to produce carbon nanostructures rich in functional groups in a single‐step under hydrothermal conditions. These carbon nanostructures have already found many applications in composites, drug delivery, materials synthesis, and Li ion batteries. The review aims to highlight some of the recent developments in the application of carbohydrate derived carbon nanostructures and also provide an outlook of their future prospects. 相似文献