Loss of real characteristics for models of three-phase flow in a porous medium

In this paper we examine the generalized Buckley-Leverett equations governing threephase immiscible, incompressible flow in a porous medium, in the absence of gravitational and diffusive/dispersive effects. We consider the effect of the relative permeability models on the characteristic speeds in the flow. Using a simple idea from projective geometry, we show that under reasonable assumptions on the relative permeabilities there must be at least one point in the saturation triangle at which the characteristic speeds are equal. In general, there is a small region in the saturation triangle where the characteristic speeds are complex. This is demonstrated with the numerical results at the end of the paper.Symbols and Notation a, b, c, d entries of Jacobian matrix - A, B, C, D coefficients in Taylor expansion of _t, _v, _a - det J determinant of matrix J - dev J deviator of matrix J - J Jacobian matrix - L linear term in Taylor expansion for J near (s _v, s_a) = (0, 1) - m slope of r ₊ - p pressure - r± eigenvectors of Jacobian matrix - R real line - S intersection of saturation triangle with circle of radius centered at (1, 0) - S intersection of saturation triangle with circle of radius centered at (0, 1) - s _l, s_v, s_a saturations of phases (liquid, vapor, aqua) - tr J trace of matrix J - v _l , v _v , v _a phase flow rates (Darcy velocities) - v _T total flow rate - X, Y, Z entries of dev J - smooth closed curve inside saturation triangle - saturation triangle - _l, _v, _a phase density times gravitational acceleration times resevoir dip angle - K total permeability - _l, _v, _a three-phase relative permeabilities - _lv>, _la liquid phase relative permeabilities from two-phase data - _l, _v, _a mobilities of phases - _T total mobility - _l Corey mobility - _l, _v, _a phase viscosities - _± eigenvalues of Jacobian matrix - porosity Supported in part by National Science Foundation grant No. DMS-8701348, by Air Force Office of Scientific Research grant No. AFOSR-87-0283, and by Army Research Office grant No. DAAL03-88-K-0080.This work was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under contract No. W-7405-Eng-48.     

Finite element simulation of solidification problems

The modelling of liquid-solid phase change phenomena is extremely important in many areas of science and engineering. In particular, the solidification of molten metals during various casting methods in the foundry, provides a source of important practical problems which may be resolved economically with the aid of computational models of the heat transfer processes involved. Experimental design analysis is often prohibitively expensive, and the geometries and complex boundary conditions encountered preclude any analytical solutions to the problems posed. Thus the motivation for numerical simulation and computer aided design (CAD) systems is clear, and several mathematical/computational modelling techniques have been brought to bear in this area during recent years.This paper reports on the application of the finite element method to solidification problems, principally concerning industrial casting processes. Although convective heat transfer has been modelled, the work herein considers only heat conduction, for clarity. The heat transfer model has also been coupled with thermal stress analysis packages to predict mechanical behaviour including cracking and eventual failure, but this is reported elsewhere.Following the introduction, the mathematical and computational modelling tools are described in detail, for completeness. A discussion on the handling of the phase change interface and latent heat effects is then presented. Some aspects of the solution procedures are examined next, together with special techniques for dealing with the mold-metal interface. Finally, some numerical examples are presented which substantiate the capabilities of the finite element model, in both two and three dimensions.Nomenclature c heat capacity - C capacitance matrix - f time function - F loading term - h heat convection coefficient - H specific enthalpy - |J| Jacobian determinant - || patch approximation to |J| - k thermal conductivity - K conductance matrix - L latent heat - unit outward normal - N _i nodal shape function - q known heat flux - R _i nodal heat capacity - S phase change interface - t time - T temperature - known boundary temperature - T vector of nodal temperatures - T _a ambient temperature - T _c solidification temperature - T _L liquidus temperature - T ₀ initial temperature - T _s solidus temperature - x space coordinates - interface heat transfer coefficient - iteration parameter - boundary of domain - T solidification range - t timestep magnitude - vector gradient operator - convergence tolerance - timestepping parameter - t known vector in alternating-direction formulation - Laplace modifying parameter - (, ) local space coordinates - density - time limit - () shape function factor - () shape function factor - domain of interest     

On natural convection from a vertical plate with a prescribed surface heat flux in porous media

This paper presents a theoretical and numerical investigation of the natural convection boundary-layer along a vertical surface, which is embedded in a porous medium, when the surface heat flux varies as (1 +x ²)), where is a constant andx is the distance along the surface. It is shown that for > -1/2 the solution develops from a similarity solution which is valid for small values ofx to one which is valid for large values ofx. However, when -1/2 no similarity solutions exist for large values ofx and it is found that there are two cases to consider, namely < -1/2 and = -1/2. The wall temperature and the velocity at large distances along the plate are determined for a range of values of .Notation g Gravitational acceleration - k Thermal conductivity of the saturated porous medium - K Permeability of the porous medium - l Typical streamwise length - q _w Uniform heat flux on the wall - Ra Rayleigh number, =gK(q _w /k)l/(v) - T Temperature - Too Temperature far from the plate - u, v Components of seepage velocity in the x and y directions - x, y Cartesian coordinates - Thermal diffusivity of the fluid saturated porous medium - The coefficient of thermal expansion - An undetermined constant - Porosity of the porous medium - Similarity variable, =y(1+x ) ^/3/x ^1/3 - A preassigned constant - Kinematic viscosity - Nondimensional temperature, =(T – T )Ra^1/3 k/qw - Similarity variable, = =y(log_e x)^1/3/x ^2/3 - Similarity variable, =y/x ^2/3 - Stream function     

Chaos and integrability in a nonlinear wave equation

We consider the parametrized family of equations _tt ,u- _xx u-au+u ₂ ² u=O,x(0,L), with Dirichlet boundary conditions. This equation has finite-dimensional invariant manifolds of solutions. Studying the reduced equation to a four-dimensional manifold, we prove the existence of transversal homoclinic orbits to periodic solutions and of invariant sets with chaotic dynamics, provided that =2, 3, 4,.... For =1 we prove the existence of infinitely many first integrals pairwise in involution.     

Investigations of mean and turbulent flow characteristics of a two dimensional plane diffuser

This paper reports the investigation of mean and turbulent flow characteristics of a two-dimensional plane diffuser. Both experimental and theoretical details are considered. The experimental investigation consists of the measurement of mean velocity profiles, wall static pressure and turbulence stresses. Theoretical study involves the prediction of downstream velocity profiles and the distribution of turbulence kinetic energy using a well tested finite difference procedure. Two models, viz., Prandtl's mixing length hypothesis and k- model of turbulence, have been used and compared. The nondimensional static pressure distribution, the longitudinal pressure gradient, the pressure recovery coefficient, percentage recovery of static pressure, the variation of U _max/U _bar along the length of the diffuser and the blockage factor have been valuated from the predicted results and compared with the experimental data. Further, the predicted and the measured value of kinetic energy of turbulence have also been compared. It is seen that for the prediction of mean flow characteristics and to evaluate the performance of the diffuser, a simple turbulence model like Prandtl's mixing length hypothesis is quite adequate.List of symbols C ₁ , C ₂ ,C turbulence model constants - F _x body force - k kinetic energy of turbulence - l _m mixing length - L length of the diffuser - u, v, w rms value of the fluctuating velocity - u, v, w turbulent component of the velocity - mean velocity in the x direction - _A average velocity at inlet - U _bar average velocity in any cross section - U _max maximum velocity in any cross section - V mean velocity in the y direction - W local width of the diffuser at any cross section - x, y coordinates - dissipation rate of turbulence - _m eddy diffusivity - Von Karman constant - mixing length constant - _l laminar viscosity - _eff effective viscosity - v kinematic viscosity - density - _k effective Schmidt number for k - effective Schmidt number for - stream function - non dimensional stream function     

Eine analytische Näherungslösung für die eingefrorene laminare Grenzschichtströmung eines binären Gemisches

Zusammenfassung Für die eingefrorene laminare Grenzschichtströmung eines teilweise dissoziierten binären Gemisches entlang einer stark gekühlten ebenen Platte wird eine analytische Näherungslösung angegeben. Danach läßt sich die Wandkonzentration als universelle Funktion der Damköhler-Zahl der Oberflächenreaktion angeben. Für das analytisch darstellbare Konzentrationsprofil stellt die Damköhler-Zahl den Formparameter dar. Die Wärmestromdichte an der Wand bestehend aus einem Wärmeleitungs- und einem Diffusionsanteil wird angegeben und diskutiert. Das Verhältnis beider Anteile läßt sich bei gegebenen Randbedingungen als Funktion der Damköhler-Zahl ausdrücken.

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An analytical approximation for the frozen laminar boundary layer flow of a binary mixture

An analytical approximation is derived for the frozen laminar boundary layer flow of a partially dissociated binary mixture along a strongly cooled flat plate. The concentration at the wall is shown to be a universal function of the Damkohler-number for the wall reaction. The Damkohlernumber also serves as a parameter of shape for the concentration profile which is presented in analytical form. The heat transfer at the wall depending on a conduction and a diffusion flux is derived and discussed. The ratio of these fluxes is expressed as a function of the Damkohler-number if the boundary conditions are known.

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Formelzeichen A Atom - A₂ Molekül - C Konstante in Gl. (20) - c₁=1/(2C) Konstante in Gl. (35) - c_p spezifische Wärme bei konstantem Druck - D binärer Diffusionskoeffizient - Ec=u ² /(2h_f) Eckert-Zahl - h spezifische Enthalpie - h_t=h+u²/2 totale spezifische Enthalpie - h _A ⁰ spezifische Dissoziationsenthalpie - K_w Reaktionsgeschwindigkeitskonstante der heterogenen Wandreaktion - 1= /( ) Champman-Rubesin-Parameter - Le=Pr/Sc Lewis-Zahl - M Molmasse - p statischer Druck - Pr= c_pf/ Prandtl-Zahl - q_w Wärmestromdichte an der Wand - q_cw, q_dw Wärmeleitungsbzw. Diffusionsanteil der Wärmestromdichte an der Wand - universelle Gaskonstante - R=/(2M_a) individuelle Gaskonstante der molekularen Komponente - Re_x= u x/ Reynolds-Zahl - Sc=/( D) Schmidt-Zahl - T absolute Temperatur - T_d=h _A ⁰ /R charakteristische Dissoziationstemperatur - u, v x- und y-Komponenten der Geschwindigkeit - U=u/u normierte x-Komponente der Geschwindigkeit - x, y Koordinaten parallel und senkrecht zur Platte Griechische Symbole - =A/ Dissoziationsgrad - Grenzschichtdicke - ₂ Impulsverlustdicke - Damköhler-Zahl der Oberflächenreaktion - =T/T normierte Temperatur - =y/ normierter Wandabstand - Wärmeleitfähigkeit - dynamische Viskosität - , ^* Ähnlichkeitskoordinaten - Dichte - Schubspannung Indizes A auf ein Atom bezogen - M auf ein Molekül bezogen - f auf den eingefrorenen Zustand bezogen - w auf die Wand bezogen - auf den Außenrand der Grenzschicht bezogen     

Flow through a helically coiled annulus

In this paper the flow is studied of an incompressible viscous fluid through a helically coiled annulus, the torsion of its centre line taken into account. It has been shown that the torsion affects the secondary flow and contributes to the azimuthal component of velocity around the centre line. The symmetry of the secondary flow streamlines in the absence of torsion, is destroyed in its presence. Some stream lines penetrate from the upper half to the lower half, and if is further increased, a complete circulation around the centre line is obtained at low values of for all Reynolds numbers for which the analysis of this paper is valid, being the ratio of the torsion of the centre line to its curvature.Nomenclature A =constant - a outer radius of the annulus - b unit binormal vector to C - C helical centre line of the pipe - D rL - g 1000 - K Dean number=Re² - L 1+r sin - M (L ²+ ² r ²)^1/2 - n unit normal vector to C - P, P pressure and nondimensional pressure - p ₀, p pressures of O(1) and O() - Re Reynolds number=aW ₀/ - (r, , s), (r, , s) coordinates and nondimensional coordinates - nonorthogonal unit vectors along the coordinate directions - r ₀ radius of the projection of C - t unit tangent vector to C - V _r, V , V _s velocity components along the nonorthogonal directions - V_r, V, V _s nondimensional velocity components along - W ₀ average velocity in a straight annulus Greek symbols , curvature and nondimensional curvature of C - U, V, W lowest order terms for small in the velocity components along the orthogonal directions t - _r, , _s first approximations to V _r , V, V _s for small - =/=/ - kinematic viscosity - density of the fluid - , torsion and nondimensional torsion of C - , stream function and nondimensional stream function - nondimensional streamfunction for U, V - a inner radius of the annulus After this paper was accepted for publication, a paper entitled On the low-Reynolds number flow in a helical pipe, by C.Y. Wang, has appeared in J. Fluid. Mech., Vol 108, 1981, pp. 185–194. The results in Wangs paper are particular cases of this paper for =0, and are also contained in [9].     

Some remarks on differential equations of quadratic type

In this paper we study differential equations of the formx(t) + x(t)=f(x(t)), x(0)=x ₀ C HereC is a closed, bounded convex subset of a Banach spaceX,f(C) C, and it is often assumed thatf(x) is a quadratic map. We study the differential equation by using the general theory of nonexpansive maps and nonexpansive, non-linear semigroups, and we obtain sharp results in a number of cases of interest. We give a formula for the Lipschitz constant off: C C, and we derive a precise explicit formula for the Lipschitz constant whenf is quadratic,C is the unit simplex inR ⁿ, and thel ₁ norm is used. We give a new proof of a theorem about nonexpansive semigroups; and we show that if the Lipschitz constant off: CC is less than or equal to one, then lim_tf(x(t))–x(t)=0 and, if {x(t):t 0} is precompact, then lim_tx(t) exists. Iff¦C=L¦C, whereL is a bounded linear operator, we apply the nonlinear theory to prove that (under mild further conditions on C) lim_t f(x(t))–x(t)=0 and that lim_t x(t) exists if {x(t):t 0} is precompact. However, forn 3 we give examples of quadratic mapsf of the unit simplex ofR ⁿ into itself such that lim_t x(t) fails to exist for mostx ₀ C andx(t) may be periodic. Our theorems answer several questions recently raised by J. Herod in connection with so-called model Boltzmann equations.     

A delta-function method for the n-th approximation of relaxation or retardation time spectrum from dynamic data

A function series g(x; n, m) is presented that converges in the limiting case n and m = constant to the delta-function located at x = = 1. For every finite n, there exists 2n+1(–nmn) approximations of the delta-function _(n)(x–x _n,m ). x _n,m is the argument where the function reaches its maximum. A formula for the calculation is given.The delta-function approximation is the starting point for the approximative determination of the logarithmic density function of the relaxation or retardation time spectrum. The n-th approximation of density functions based on components of the complex modulus (G*) or the complex compliance (J*) is given. It represents an easy differential operator of order n.This approach generalizes the results obtained by Schwarzl and Staverman, and Tschoegl. The symmetry properties of the approximations are explained by the symmetry properties of the function g(x; n, m). Therefore, the separate equations for each approximation given by Tschoegl can be subsumed in a single equation for G and G, and in another for J and J.     

Heat transfer in laminar flow in a uniformly porous channel with an applied transverse magnetic field

Summary The steady laminar flow of an incompressible, viscous, and electrically conducting fluid between two parallel porous plates with equal permeability has been discussed by Terrill and Shrestha [6]. In this paper, using the solution of [6] for the velocity field, the heat transfer problems of (i) uniform wall temperature and (ii) uniform heat flux at wall are solved.For small suction Reynolds numbers we find that the Nusselt number, with increasing Reynolds number, increases for case (i) and decreases for (ii).Nomenclature stream function - 2h channel width - x, y distances measured parallel, perpendicular to the channel walls - U velocity of fluid in the x direction at x=0 - V constant velocity of suction at the wall - nondimensional distance, y/h - nondimensional distance, x/h - f() function defined in (1) - density - coefficient of kinematic viscosity - R suction Reynolds number, V h/ - Re channel Reynolds number, 4U h/ - B ₀ magnetic induction - electrical conductivity - M Hartmann number, B ₀ h(/)^1/2 - K constant defined in (3) - A constant defined in (5) - 4R/Re - q local heat flux per unit area at the wall - k thermal conductivity - T temperature of the fluid - X –1/ ln(1–) - C _p specific heat at constant pressure - j current density - Pr Prandtl number, C _p/k - P mass transfer Péclet number, R Pr - Pe mass transfer Péclet number, P/ - T ₀ temperature at x=0 - T _H() temperature in the fully developed region - T _h(X, ) temperature in the entrance region - Y _n () eigenfunctions, uniform wall temperature - _n eigenvalues - e() function defined by (24) - B _n 2/3 _n ² - A _n constants defined by (28) - a _2m constants defined by (30) - F _n () eigenfunctions, uniform wall heat flux - a _n , b _n , c _n , d _n , e _n constants defined by (45) and (48) - S a parameter, U ²/q - h ₁ heat transfer coefficient - T _m mean temperature - Nu Nusselt number - Nu _T Nusselt number, uniform wall temperature - Nu _q Nusselt number, uniform wall heat flux     

Oscillatory free convection heat transfer along a semi-infinite vertical plate

Summary The fluctuating free convection flow along a semi-infinite vertical plate is considered when the plate temperature is of the form T _p –T =(T ₀ –T ) where 0 < 1, denotes the frequency of oscillation and the mean temperature T ₀–T is proportional to ⁿ (0 n < 1). Flow and temperature fields have been obtained by means of two asymptotic expansions. For small values of the frequency parameter , a regular expansion is obtained while for large the method of matched asymptotic expansion is used. It is found that the skin friction and the rate of heat transfer obtained from two expansions overlap satisfactorily for a certain value of . For n=1 the flow governing equations to a semisimilar form, and have been solved by finite difference method. The results obtained from the series and the finite difference methods are in good agreement.

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Oszillierender Wärmeübergang an einer halbunendlichen senkrechten Platte bei freier Konvektion

Übersicht Betrachtet wird die fluktuierende freie Konvektionsströmung längs einer halbunendlichen senkrechten Platte, deren Temperatur dem Gesetz T _p –T =(T ₀–T ) [1+ sin {ie1-03}] folgt, wobei 0 < 1 gelte, {ie1-04} die Frequenz ist und der Temperatur-Mittelwert T ₀–T proportional zu ⁿ (0 n < 1) ist. Mit Hilfe zweier asymptotischer Entwicklungen werden die Strömungs- und Temperaturfelder gewonnen. Für kleine Werte des Frequenzparameters wird eine gewöhnliche Entwicklung benutzt, für große die Methode angepaßter asymptotischer Entwicklungen. Es stellt sich heraus, daß die Oberflächenreibung und die Wärmeübergangsrate aus zwei Entwicklungen für ein bestimmtes zufriedenstellend aufeinander fallen. Für n=1 werden die Grundgleichungen zueinander ähnlich und werden nach der Finite-Differenzen-Methode gelöst. Die Ergebnisse nach den Reihenentwicklungen und der Finite-Differenzen-Methode stimmen gut überein.

     

Diffusion in anisotropic porous media

An experimental system was constructed in order to measure the two distinct components of the effective diffusivity tensor in transversely isotropic, unconsolidated porous media. Measurements were made for porous media consisting of glass spheres, mica particles, and disks made from mylar sheets. Both the particle geometry and the void fraction of the porous media were determined experimentally, and theoretical calculations for the two components of the effective diffusivity tensor were carried out. The comparison between theory and experiment clearly indicates that the void fraction and particle geometry are insufficient to characterize the process of diffusion in anisotropic porous media. Roman Letters A interfacial area between - and -phases for the macroscopic system, m² - A _e area of entrances and exits of the -phase for the macroscopic system, m² - A interfacial area contained within the averaging volume, m² - a characteristic length of a particle, m - b average thickness of a particle, m - c _A concentration of species A, moles/m³ - c _o reference concentration of species A, moles/m³ - c _A intrinsic phase average concentration of species A, moles/m³ - c _a c _A–c _A, spatial deviation concentration of species A, moles/m³ - C c _A/c ₀, dimensionless concentration of species A - binary molecular diffusion coefficient, m²/s - D _eff effective diffusivity tensor, m²/s - D _xx component of the effective diffusivity tensor associated with diffusion parallel to the bedding plane, m²/s - D _yy component of the effective diffusivity tensor associated with diffusion perpendicular to the bedding plane, m²/s - D _eff effective diffusivity for isotropic systems, m₂/s - f vector field that maps c _A on to c _a , m - h depth of the mixing chamber, m     

Flow of soft solids squeezed between planar and spherical surfaces

The force to squeeze a Herschel–Bulkley material without slip between two approaching surfaces of various curvature is calculated. The Herschel–Bulkley yield stress requires an infinite force to make plane–plane and plane–concave surfaces touch. However, for plane–convex surfaces this force is finite, which suggests experiments to access the mesoscopic thickness region (1–100 m) of non-Newtonian materials using squeeze flow between a plate and a convex lens. Compared to the plane–parallel surfaces that are used most often for squeeze flow, the dependence of the separation h and approach speed V on the squeezing-time is more complicated. However, when the surfaces become close, a simplification occurs and the near-contact approach speed is found to vary as V h⁰ if the Herschel–Bulkley index is n<1/3, and V h^(3n-1)/(2n) if n 1/3. Using both plane–plane and plane–convex surfaces, concordant measurements are made of the Herschel–Bulkley index n and yield stress ₀ for two soft solids. Good agreement is also found between ₀ measured by the vane and by each squeeze-flow method. However, one of the materials shows a limiting separation and a V(h) behaviour not predicted by theory for h<10 m, possibly owing to an interparticle structure of similar lengthscale.     

Der Spannungs- und Verschiebungszustand drehsymmetrischer Membrane mit beliebig gekrümmter Meridiankurve

Zusammenfassung Die Einführung von Zylinderkoordinaten (x, r, ) in die Gleichgewichtsbedingungen der Schnittkräfte bzw. in die Beziehungen zwischen Verzerrung und Verschiebungen am differentialen Schalenabschnitt ermöglicht die Berechnung des Spannungs- und Verschiebungszustandes von drehsymmetrischen Membranen mit beliebig gekrümmter Meridiankurve auf die Integration einer einfachen, linearen partiellen Differentialgleichung zweiter Ordnung für eine charakteristische FunktionF bzw. zurückzuführen. Eine geschlossene Lösung und damit eine Darstellung der Schnittkräfte und Verschiebungen durch explizite Formeln ist bei harmonischer Belastung cosn für zwei Funktionsgruppen=x ² und=x ^–3 möglich. Im Sonderfall der drehsymmetrischen und der antimetrischen Belastung mitn=0 undn=1 gelten die Gleichungen der Schnitt- und Verschiebungsgrößen für eine beliebige Meridianfunktion=(). Die Betrachtungen der Randbedingungen offener Schalen bei harmonischer Belastung geben über die infinitesimalen Deformationen einer drehsymmetrischen Membran mit überall negativer Krümmung Aufschluß.     

A visualization study of the interaction of a free vortex with the wake behind an airfoil

The two-dimensional interaction of a single vortex with a thin symmetrical airfoil and its vortex wake has been investigated in a low turbulence wind tunnel having velocity of about 2 m/s in the measuring section. The flow Reynolds number based on the airfoil chord length was 4.5 × 10³. The investigation was carried out using a smoke-wire visualization technique with some support of standard hot-wire measurements. The experiment has proved that under certain conditions the vortex-airfoil-wake interaction leads to the formation of new vortices from the part of the wake positioned closely to the vortex. After the formation, the vortices rotate in the direction opposite to that of the incident vortex.List of symbols c test airfoil chord - C vortex generator airfoil chord - TA test airfoil - TE test airfoil trailing edge - TE _G vortex generator airfoil trailing edge - t dimensionless time-interval measured from the vortex passage by the test airfoil trailing edge: gDt=(T-T- _TE)·U/c - T time-interval measured from the start of VGA rotation - U free stream velocity - U vortex induced velocity fluctuation - VGA vortex generator airfoil - y distance in which the vortex passes the test airfoil - Z vortex circulation coefficient: Z=/(U · c/2) - vortex generator airfoil inclination angle - vortex circulation - vortex strength: =/2     

The wedge subjected to tractions: a paradox resolved

The classical two-dimensional solution provided by Lévy for the stress distribution in an elastic wedge, loaded by a uniform pressure on one face, becomes infinite when the opening angle 2 of the wedge satisfies the equation tan 2 = 2. Such pathological behavior prompted the investigation in this paper of the stresses and displacements that are induced by tractions of O(r ^–) as r0. The key point is to choose an Airy stress function which generates stresses capable of accommodating unrestricted loading. Fortunately conditions can be derived which pre-determine the form of the necessary Airy stress function. The results show that inhomogeneous boundary conditions can induce stresses of O(r ^–), O(r ^– ln r), or O(r ^– ln² r) as r0, depending on which conditions are satisfied. The stress function used by Williams is sufficient only if the induced stress and displacement behavior is of the power type. The wedge loaded by uniform antisymmetric shear tractions is shown in this paper to exhibit stresses of O(ln r) as r0 for the half-plane or crack geometry. At the critical opening angle 2, uniform antisymmetric normal and symmetric shear tractions also induce the above type of stress singularity. No anticipating such stresses, Lévy used an insufficiently general Airy stress function that led to the observed pathological behavior at 2.     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Supersonic air flow past a sphere with account for vibrational relaxation

A numerical solution is obtained for the problem of air flow past a sphere under conditions when nonequilibrium excitation of the vibrational degrees of freedom of the molecular components takes place in the shock layer. The problem is solved using the method of [1]. In calculating the relaxation rates account was taken of two processes: 1) transition of the molecular translational energy into vibrational energy during collision; 2) exchange of vibrational energy between the air components. Expressions for the relaxation rates were computed in [2]. The solution indicates that in the state far from equilibrium a relaxation layer is formed near the sphere surface. A comparison is made of the calculated values of the shock standoff with the experimental data of [3].Notation uV_max, vV_max velocity components normal and tangential to the sphere surface - V_max maximal velocity - P V _max ² pressure - density - TT temperature - e_viRT vibrational energy of the i-th component per mole (i=–O₂, N₂) - =rb–1 shock wave shape - a _f the frozen speed of sound - HRT/m gas total enthalpy     

The rheology of polymeric liquid crystals

The molecular theory of Doi has been used as a framework to characterize the rheological behavior of polymeric liquid crystals at the low deformation rates for which it was derived, and an appropriate extension for high deformation rates is presented. The essential physics behind the Doi formulation has, however, been retained in its entirety. The resulting four-parameter equation enables prediction of the shearing behavior at low and high deformation rates, of the stress in extensional flows, of the isotropic-anisotropic phase transition and of the molecular orientation. Extensional data over nearly three decades of elongation rate (10^–2–10¹) and shearing data over six decades of shear rate (10^–2–10⁴) have been correlated using this analysis. Experimental data are presented for both homogeneous and inhomogeneous shearing stress fields. For the latter, a 20-fold range of capillary tube diameters has been employed and no effects of system geometry or the inhomogeneity of the flow-field are observed. Such an independence of the rheological properties from these effects does not occur for low molecular weight liquid crystals and this is, perhaps, the first time this has been reported for polymeric lyotropic liquid crystals; the physical basis for this major difference is discussed briefly. A Semi-empirical constant in eq. (18), N/m² - c rod concentration, rods/m³ - c ^* critical rod concentration at which the isotropic phase becomes unstable, rods/m³ - C interaction potential in the Doi theory defined in eq. (3) - d rod diameter, m - D semi-empirical constant in eq. (19), s^–1 - D _r lumped rotational diffusivity defined in eq. (4), s^–1 - rotational diffusivity of rods in a concentrated (liquid crystalline) system, s^–1 - D _ro rotational diffusivity of a dilute solution of rods, s^–1 - f distribution function defining rod orientation - F tensorial term in the Doi theory defined in eq. (7) (or eq. (19)), s^–1 - G tensorial term in the Doi theory defined in eq. (8) - K _B Boltzmann constant, 1.38 × 10^–23 J/K-molecule - L rod length, m - S scalar order parameter - S tensor order parameter defined in eq. (5) - t time, s - T absolute temperature, K - u unit vector describing the orientation of an individual rod - rate of change ofu due to macroscopic flow, s^–1 - v fluid velocity vector, m/s - v velocity gradient tensor defined in eq. (9), s^–1 - V mean field (aligning) potential defined in eq. (2) - x coordinate direction, m - Kronecker delta (= 0 if = 1 if = ) - _r ratio of viscosity of suspension to that of the solvent at the same shear stress - _s solvent viscosity, Pa · s - ^* viscosity at the critical concentrationc ^*, Pa · s - v ₁, v₂ numerical factors in eqs. (3) and (4), respectively - deviatoric stress tensor, N/m² - volume fraction of rods - ⁰ constant in eq. (16) - ^* volume fraction of rods at the critical concentrationc ^* - average over the distribution functionf(u, t) (= d ²u f(u, t)) - gradient operator - d ²u integral over the surface of the sphere (|u| = 1)     

Measurement of dynamic surface tension by the oscillating droplet method

An optical measuring method has been applied to determine the dynamic surface tension of aqueous solutions of heptanol. The method uses the frequency of an oscillating liquid droplet as an indicator of the surface tension of the liquid. Droplets with diameters in the range between 100 and 200 m are produced by the controlled break-up of a liquid jet. The temporal development of the dynamic surface tension of heptanol-water solutions is interpreted by a diffusion controlled adsorption mechanism, based on the three-layer model of Ward and Tordai. Measured values of the surface tension of bi-distilled water, and the pure dynamic and static (asymptotic) surface tensions of the surfactant solutions are in very good agreement with values obtained by classical methods.List of symbols a coefficient of intermolecular forces, Nm^-1 - B adsorption constant - c _o bulk concentration, mol m^-3 - D apparent diffusion coefficient, m²s^-1 - t time, s - T absolute temperature, K - R universal gas constant=8.314, J mol^-1 K^-1 - (, t) droplet contour function - _o droplet equilibrium radius, m Greek symbols maximum surface excess concentration, mol m^-2 - (t) droplet volume normalization function - azimuth of the polar coordinate system - density, kgm^-3 - surface tension, N m^-1 - (t) concentration in the subsurface, molm^-3 - droplet oscillation frequency Daimler-Benz AG, Produktion & Umwelt, D-89081 UlmOn leave of absence from the Institute of Fundamental Technological Research, Polish Academy of Sciences, PL-00-049 Warszawa