On Thermodynamic Consistency of Turbulent Closures

The problem of the implementation of the second law of thermodynamics for the determination of the thermodynamic consistency of solutions determined by turbulent closures is considered for incompressible fluids. The possibility of the application of the methods of thermodynamics to constraining constitutive laws describing turbulent flow features, but not material behaviour, is discussed. It is shown that the ordinary realizability conditions requiring non-negative values of the averaged squared fluctuations are necessary and sufficient conditions determining the thermodynamic consistency of a process governed by a closure model. Because turbulent closures are not universal, using the second law of thermodynamics to constrain them can impose unnecessary restrictions on the models, when the turbulent entropy is considered as a constitutive quantity. The notion and validity of different forms of the turbulent entropy is discussed. It is found that the form of the turbulent entropy originating from the analogy between the turbulent kinetic energy and absolute temperature contradicts the principle of irreversibility. In a particular case of small temperature fluctuations, the second law yields correct constraints, if the turbulent entropy is assumed not to be a constitutive quantity, but a variable governed by an evolution equation of special form generated by the balance equation for internal energy. Received 14 October 2000 and accepted 30 May 2001     

Theoretical derivation of the conservation equations for single phase flow in porous media: a continuum approach

This paper deals with the theoretical derivation of the conservation equations for single phase flow in a porous medium. The derivation is obtained within the framework of the continuum mechanics and classical thermodynamics. The adopted procedure provides the conservation equations of mass, momentum, mechanical energy, total energy, internal energy, entropy, temperature, enthalpy, Gibbs free energy and Helmholtz free energy. The obtained results highlight the connection between the basic equations of fluid mechanics and of fluid flow in porous media, as well as the restrictions and the limitations of Darcy’s law and Richards’ equation.     

Nonlinear Fluctuations of Weakly Asymmetric Interacting Particle Systems

We introduce what we call the second-order Boltzmann–Gibbs principle, which allows one to replace local functionals of a conservative, one-dimensional stochastic process by a possibly nonlinear function of the conserved quantity. This replacement opens the way to obtain nonlinear stochastic evolutions as the limit of the fluctuations of the conserved quantity around stationary states. As an application of this second-order Boltzmann–Gibbs principle, we introduce the notion of energy solutions of the KPZ and stochastic Burgers equations. Under minimal assumptions, we prove that the density fluctuations of one-dimensional, stationary, weakly asymmetric, conservative particle systems are sequentially compact and that any limit point is given by energy solutions of the stochastic Burgers equation. We also show that the fluctuations of the height function associated to these models are given by energy solutions of the KPZ equation in this sense. Unfortunately, we lack a uniqueness result for these energy solutions. We conjecture these solutions to be unique, and we show some regularity results for energy solutions of the KPZ/Burgers equation, supporting this conjecture.     

Theoretical framework and experimental procedure for modelling mesoscopic volume fraction stochastic fluctuations in fiber reinforced composites

Many engineering materials exhibit fluctuations and uncertainties on their macroscopic mechanical properties. This randomness results from random fluctuations observed at a lower scale, especially at the meso-scale where microstructural uncertainties generally occur. In the present paper, we first propose a complete theoretical stochastic framework (that is, a relevant probabilistic model as well as a non-intrusive stochastic solver) in which the volume fraction at the microscale is modelled as a random field whose statistical reduction is performed using a Karhunen–Loeve expansion. Then, an experimental procedure dedicated to the identification of the parameters involved in the probabilistic model is presented and relies on a non-destructive ultrasonic method. The combination of the experimental results with a micromechanical analysis provides realizations of the volume fraction random field. In particular, it is shown that the volume fraction can be modelled by a homogeneous random field whose spatial correlation lengths are determined and may provide conditions on the size of the meso-volumes to be considered.     

A thermodynamic model of turbulent motions in a granular material

This paper is devoted to a thermodynamic theory of granular materials subjected to slow frictional as well as rapid flows with strong collisional interactions. The microstructure of the material is taken into account by considering the solid volume fraction as a basic field. This variable is of a kinematic nature and enters the formulation via the balance law of the configurational momentum, including corresponding contributions to the energy balance, as originally proposed by Goodman and Cowin [1], but modified here. Complemented by constitutive equations, the emerging field equations are postulated to be adequate for motions, be they laminar or turbulent, if the resolved length scales are sufficiently small. On large length scales the sub-grid motion may be interpreted as fluctuations, which manifest themselves in correspondingly filtered equations as correlation products, like in the turbulence theory. We apply an ergodic (Reynolds) filter to these equations and thus deduce averaged equations for the mean motions. The averaged equations comprise balances of mass, linear and configurational momenta, energy, and turbulent kinetic energy as well as turbulent configurational kinetic energy. They are complemented by balance laws for two internal fields, the dissipation rates of the turbulent kinetic energy and of the turbulent configurational kinetic energy. We formulate closure relations for the averages of the laminar constitutive quantities and for the correlation terms by using the rules of material and turbulent objectivity, including equipresence. Many versions of the second law of thermodynamics are known in the literature. We follow the Müller-Liu theory and extend Müllers entropy principle to allow the satisfaction of the second law of thermodynamics for both laminar and turbulent motions. Its exploitation, performed in the spirit of the Müller-Liu theory, delivers restrictions on the dependent constitutive quantities (through the Liu equations) and a residual inequality, from which thermodynamic equilibrium properties are deduced. Finally, linear relationships are proposed for the nonequilibrium closure relations.Received: 21 March 2003, Accepted: 1 September 2003, Published online: 11 February 2004PACS: 05.70.Ln, 61.25.Hq, 61.30.-vCorrespondence to: I. Luca     

Synchronization of networked multibody systems using fundamental equation of mechanics

From the analytical dynamics point of view, this paper develops an optimal control framework to synchronize networked multibody systems using the fundamental equation of mechanics. A novel robust control law derived from the framework is then used to achieve complete synchronization of networked identical or non-identical multibody systems formulated with Lagrangian dynamics. A distinctive feature of the developed control strategy is the introduction of network structures into the control requirement. The control law consists of two components, the first describing the architecture of the network and the second denoting an active feedback control strategy. A corresponding stability analysis is performed by the algebraic graph theory. A representative network composed of ten identical or non-identical gyroscopes is used as an illustrative example. Numerical simulation of the systems with three kinds of network structures, including global coupling, nearest-neighbour, and small-world networks, is given to demonstrate effectiveness of the proposed control methodology.     

基于蒙特卡罗随机有限元方法的随机多孔介质内流体自然对流不确定性研究

为分析孔隙率不确定性对多孔介质方腔内自然对流换热的影响,发展了一种基于KL（Karhunen-Loeve展开）-蒙特卡罗随机有限元算法的随机多孔介质内自然对流不确定性分析数理模型及有限元数值模拟程序框架。通过K-L展开及基于拉丁抽样法生成多孔介质孔隙率随机实现,并耦合多孔介质自然对流有限元程序,进行随机多孔介质内自然对流传热数值模拟,得出了多孔介质内流场与温度场平均值与标准偏差,并分析了孔隙率不确定性条件下Da数对Nu数的影响。结果表明,孔隙率不确定性对多孔介质方腔内自然对流有重要影响。随机多孔介质内流场及温度场与确定性条件下的流场及温度场存在一定偏差,Nu数标准偏差随着Da的增大先增大后减小。     

A nonlocal phase-field model of Ginzburg–Landau–Korteweg fluids

A thermodynamic model of Korteweg fluids undergoing phase transition and/or phase separation is developed within the framework of weakly nonlocal thermodynamics. Compatibility with second law of thermodynamics is investigated by applying a generalized Liu procedure recently introduced in the literature. Possible forms of the free energy and of the stress tensor, which generalize some earlier ones proposed by several authors in the last decades, are carried out. Owing to the new procedure applied for exploiting the entropy principle, the thermodynamic potentials are allowed to depend on the whole set of variables spanning the state space, including the gradients of the unknown fields, without postulating neither the presence of an energy or entropy extra-flux, nor an additional balance law for microforce.     

Computation of functionals over discontinuous sample paths of a stochastic van der pol oscillator

This paper deals with a random van der Pol oscillator. It is assumed that the oscillator is subjected to two different kinds of perturbation. The first kind of perturbation is represented by the standard Wiener process and the second kind by a homogeneous process with independent increments, finite second order moments, mean zero and no continuous sample functions. In order to measure quantitatively the stochastic stability of the oscillator, two functionals are defined over its phase plane sample paths. It is shown that each of these functionals is a solution to a corresponding partial integro-differential equation. A numerical procedure for the solution of these equations, is suggested, and its efficiency and applicability are demonstrated with examples.     

Nonconventional thermodynamics,indeterminate couple stress elasticity and heat conduction

We present a phenomenological thermodynamic framework for continuum systems exhibiting responses which may be nonlocal in space and for which short time scales may be important. Nonlocality in space is engendered by state variables of gradient type, while nonlocalities over time can be modelled, e.g. by assuming the rate of the heat flux vector to enter into the heat conduction law. The central idea is to restate the energy budget of the system by postulating further balance laws of energy, besides the classical one. This allows for the proposed theory to deal with nonequilibrium state variables, which are excluded by the second law in conventional thermodynamics. The main features of our approach are explained by discussing micropolar indeterminate couple stress elasticity and heat conduction theories.     

Damage and self-similarity in fracture

Consider applications of damage mechanics to material failure. The damage variable introduced in damage mechanics quantifies the deviation of a brittle solid from linear elasticity. An analogy between the metastable behavior of a stressed brittle solid and the metastable behavior of a superheated liquid is established. The nucleation of microcracks is analogous to the nucleation of bubbles in the superheated liquid. In this paper we have applied damage mechanics to four problems. The first is the instantaneous application of a constant stress to a brittle solid. The results are verified by applying them to studies of the rupture of chipboard and fiberglass panels. We then obtain a solution for the evolution of damage after the instantaneous application of a constant strain. It is shown that the subsequent stress relaxation can reproduce the modified Omori’s law for the temporal decay of aftershocks following an earthquake. Obtained also are the solutions for application of constant rates of stress and strain. A fundamental question is the cause of the time delay associated with damage and microcracks. It is argued that the microcracks themselves cause random fluctuations similar to the thermal fluctuations associated with phase changes.     

Volume-weighted mixture theory for granular materials

In the present work we treat granular materials as mixtures composed of a solid and a surrounding void continuum, proposing then a continuum thermodynamic theory for it. In contrast to the common mass-weighted balance equations of mass, momentum, energy and entropy for mixtures, the volume-weighted balance equations and the associated jump conditions of the corresponding physical quantities are derived in terms of volume-weighted field quantities here. The evolution equations of volume fractions, volume-weighted velocity, energy, and entropy are presented and explained in detail. By virtue of the second law of thermodynamics, three dissipative mechanisms are considered which are specialized for a simple set of linear constitutive equations. The derived theory is applied to the analysis of reversible and irreversible compaction of cohesionless granular particles when a vertical oscillation is exerted on the system. In this analysis, a hypothesis for the existence of a characteristic depth within the granular material in its closely compacted state is proposed to model the reversible compaction.     

Integral Representation Results for Energies Defined on Stochastic Lattices and Application to Nonlinear Elasticity

This article is devoted to the study of the asymptotic behavior of a class of energies defined on stochastic lattices. Under polynomial growth assumptions, we prove that the energy functionals F_e{F_\varepsilon} stored in the deformation of an e{{\varepsilon}}-scaling of a stochastic lattice Γ-converge to a continuous energy functional when e{{\varepsilon}} goes to zero. In particular, the limiting energy functional is of integral type, and deterministic if the lattice is ergodic. We also generalize, to systems and nonlinear settings, well-known results on stochastic homogenization of discrete elliptic equations. As an application of the main result, we prove the convergence of a discrete model for rubber towards the nonlinear theory of continuum mechanics. We finally address some mechanical properties of the limiting models, such as frame-invariance, isotropy and natural states.     

Entropy of microstructure

Two points are made in this paper: first, energy of random structures is not determined uniquely by any finite set of the characteristics of microstructure. The information lost is characterized by entropy of microstructure; it describes the scattering of the values of energy. Therefore, entropy of microstructure is a key thermodynamic parameter in phenomenological modeling of the behavior of random structures. Second, mathematical modeling of a random structure is based on the construction of its probabilistic measure; a way to select the probabilistic measure from the experimental data is outlined. The corresponding probabilistic measure is remarkably similar to that of classical statistical mechanics, though the underlying physics is quite different. After the probabilistic measure is chosen, the entropy of microstructure can be found from the analysis of the homogenization problem. Entropy of microstructure is computed in two example problems. Applications to phenomenological modeling of work hardening are discussed.     

A multi-scale simulation of tungsten film delamination from silicon substrate

To bridge the different spatial scales involved in the process of tungsten (W) film delaminating from silicon (Si) substrate, a multi-scale simulation procedure is proposed via a sequential approach. In the proposed procedure, a bifurcation-based decohesion model, which represents the link between molecular and continuum scales, is first formulated within the framework of continuum mechanics. Molecular dynamics (MD) simulation of a single crystal W block under tension is conducted to investigate the effect of specimen size and loading rate on the material properties. The proposed decohesion model is then calibrated by using MD simulation of a single crystal W block under tension and using available experimental data, with a power scaling law to account for the size effect. A multi-scale model-based simulation of W film delamination from Si substrate is performed by using the proposed procedure within the framework of the material point method. The simulated results provide new insights into the mechanisms of the film delamination process.     

RENEWAL OF BASIC LAWS AND PRINCIPLES FOR POLAR CONTINUUM THEORIES(Ⅸ)—THERMOMECHANICS

The existing fundamental laws of thermodynamics for micropolar continuum field theories are restudied and their incompleteness is pointed out. New first and second fundamental laws for thermostatics and thermodynamics for micropolar continua are postulated. From them all equilibrium equations and the entropy inequality of thermostatics as well as all balance equations and the entropy rate inequalities are naturally and simultaneously deduced. The comparisons between the new results presented here and the corresponding results demonstrated in existing monographs and textbooks concerning micropolar continuum mechanics are made at any time. It should be emphasized to note that, the problem of why the local balance equation of energy and the local entropy inequality could not be obtained from the existing fundamental laws of thermodynamics for micropolar continua, is believed to be clarified.     

RENEWAL OF BASIC LAWS AND PRINCIPLES FOR POLAR CONTINUUM THEORIES (Ⅸ)-THERMOMECHANICS

The existing fundamental laws of thermodynamics for micropolar continuum field theories are restudied and their incompleteness is pointed out. New first and second fundamental laws for thermostatics and thermodynamics for micropolar continua are postulated. From them all equilibrium equations and the entropy inequality of thermostatics as well as all balance equations and the entropy rate inequalities are naturally and simultaneously deduced. The comparisons between the new results presented here and the corresponding results demonstrated in existing monographs and textbooks concerning micropolar continuum mechanics are made at any time. It should be emphasized to note that, the problem of why the local balance equation of energy and the local entropy inequality could not be obtained from the existing fundamental laws of thermodynamics for micropolar continua, is believed to be clarified.     

On the stochastic interpretation of gradient-dependent constitutive equations

The paper elaborates on the statistical interpretation of a class of gradient models by resorting to both microscopic and macroscopic considerations. The microscopic stochastic representation of stress and strain fields reflects the heterogeneity inherently present in engineering materials at small scales. A physical argument is advanced to conjecture that stress shows small fluctuations and strong spatial correlations when compared to those of strain; then, a series expansion in the respective constitutive equations renders unimportant stress gradient terms, in contrast to strain gradient terms, which should be retained. Each higher-order strain gradient term is given a physically clear interpretation. The formulation also allows for the underlying microstrain field to be statistically non-stationary, e.g., of fractal character. The paper concludes with a comparison between surface effects predicted by gradient and stochastic formulations.     

Nonlinear response of SDOF systems under combined deterministic and random excitations

Dynamical systems subjected to random excitations exhibit non-linear behavior for sufficiently large motion. The multiple time scale method has been extensively utilized in the framework of non-linear deterministic analysis to obtain two averaged first-order differential equations describing the slow time scale modulation of amplitude and phase response. In this paper the multiple time scale method, opportunely modified to take properly into account the correlation structure of the stochastic input process, is adopted to derive a stochastic frequency-response relationship involving the response amplitude statistics and the input power spectral density. A low-intensity noise is assumed to separate the strong mean motion from its weak fluctuations. The moment differential equations of phase and amplitude are derived and a linearization technique applied to evaluate the second order statistics. The theory is validated through digital simulations on a nonlinear single degree of freedom model for the transversal oscillation of a cantilever beam with tip force and to a Duffing-Rayleigh oscillator, to analyze non-linear damping effects.     

THE EXTREMITY LAWS OF HYDRO-THERMODYNAMICS

This paper presents the law of maximum rate of energy dissipa-tion in hydrodynamics and also in general continuum dynamicsas an addition to the classical conservation laws expressed inthe equation of continuity and the equations of motion.Thecorollary of the law is B(?)langer-B(?)ss theorem of minimum reser-ved specific energy in applied hydraulics.The mechanical energy dissipated is transformed into heatreserved in the substance.The rate of energy dissipation ata time at a given temperature gives rise to the increase in en-tropy production.Hence the maximum rate of energy dissipationsuggests itself the idea of reformulation of the second law ofthermodynamics that the rate of entropy production in mech-anical motion is always the maximum possible.The proposed extremity law in continuum dynamics has beenderived from the variational principle and the reformulatedsecond law of thermodynamics analyzed microscopically in thepaper.The two laws together form the extremity laws of hydro-thermodynamics.