块体金属玻璃的剪切带行为

0 引言 玻璃态物质以纷繁多样的形式广泛存在于自然与科技技术领域[1-3].除了人们熟知的门窗上的硅酸盐无机玻璃、各种塑料制品的高聚物玻璃外,玻璃态还与光纤通讯、生物制品和生化药剂的保鲜存储、极端干燥条件下昆虫活性的保持等这些鲜为人知的方面密切相关.     

统计细观损伤力学和损伤演化诱致突变（Ⅱ）

材料的损伤和破坏是固体力学中一个十分复杂的基本问题，近年来在这方面的研究从不同的角度取得一系列新的进展。本文较系统地介绍了统计细观损伤力学和损伤演化诱致突变理论，这是把力学与统计物理学及非线性科学结合起来研究材料损伤和破坏问题的一种探索。     

统计细观损伤力学和损伤演化诱致突变（Ⅱ）

材料的损伤和破坏是固体力学中一个十分复杂的基本问题，近年来在这方面的研究从不同的角度取得一系列新的进展。本文较系统地介绍了统计细观损伤力学和损伤演化诱致突变理论，这是把力学与统计物理学及非线性科学结合起来研究材料损伤和破坏问题的一种探索。     

统计细观损伤力学和损伤演化诱致突变

材料的损伤和破坏是固体力学中一个十分复杂的基本问题，近年来在这方面的研究从不同的角度取得一系列新的进展。本文较系统地介绍了统计细观损伤力学和损伤演化诱致突变理论，这是把力学与统计物理学及非线性科学结合起来研究材料损伤和破坏问题的一种探索。     

混凝土单轴压缩下细观损伤特性的CT研究

混凝土是一种非均质的材料,在细观层次上将混凝土看作由骨料、砂浆和两者之间的界面组成的三相复合材料.本文利用CT技术对混凝土的细观损伤过程进行实时扫描观测,获得了混凝土试件实时静力压缩CT图像,提取出图像上各点的CT数并根据分区理论定义了一个基于CT数的统计损伤变量.通过对图像和CT数以及损伤变量的分析表明混凝土试件在静力压缩条件下经历了压密阶段、扩容阶段,损伤急剧增大到破坏的细观损伤演化全过程,以此反映了混凝土细观损伤演化的特性.进而通过细观损伤对混凝土材料裂纹的扩展、贯通以及最后失稳破坏的破坏实质进行了有益的探索.     

动态延性损伤的细观力学研究现状

本文从细观理论、率相关弹塑性本构、层裂实验及数值模拟等几个方面综述、评价了延性动态损伤的细观力学研究现状，结合以上工作，指出了今后材料动态延性损伤、断裂的细观力学研究应进一步开展工作的７个研究方向。     

统计细观损伤力学和损伤演化诱致突变

材料的损伤和破坏是固体力学中一个十分复杂的基本问题,近年来在这方面的研究从不同的角度取得一系列新的进展。本文较系统地介绍了统计细观损伤力学和损伤演化诱致突变理论,这是把力学与统计物理学及非线性科学结合起来研究材料损伤和破坏问题的一种探索。      

玻璃态高分子材料银纹力学研究进展

银纹是玻璃态高分子材料所特有的一种现象, 它既是高分子材料的塑性变形和增韧机理, 又是高分子材料的损伤机理, 还是连接高分子材料微观损伤与宏观破坏的桥梁. 银纹的萌生、长大与断裂是高分子科学和固体力学所共同关注的难题. 过去几十年在试验、理论和数值模诸方面也取得了显著进展, 但较为系统的理论框架尚未建立, 人们试图把细观力学的基本知识与高分子系统银纹化现象联系起来的设想才刚刚开始,且尚未在指导高分子合金设计方面起到关键作用. 本文试图对近10多年来, 高分子银纹化的研究进展予以介绍和评述. 首先简要介绍银纹的基本形貌、萌生判据与生长规律, 然后分别介绍银纹断裂力学、银纹损伤力学和银纹细观力学的研究进展和成果, 最后概要介绍银纹分子动力学研究的最新进展.      

各向同性弹性损伤的双标量描述

损伤状态的描述是损伤力学中仍未完善解决的基本问题．我们旨在对此问题就最简单的一种情形——各向同性弹性损伤，进行较为全面的研究．首先，指出了古典各向同性损伤理论中，基于应变等效假设，用单个标量损伤变量描述损伤状态的局限性．然后，建立了一个用两个标量损伤变量描述的各向同性弹性损伤模型．此模型解除了古典理论的局限，能完全描述各向同性弹性损伤，并且得到本文数值实验的验证．最后，将本文模型与现有细观力学结果连接，给出了宏细观损伤变量之间的关系，使得细观量可以通过宏观量来反映，建立了一个用细观损伤材料常数描述细观缺陷特征的损伤本构模型     

高聚物玻璃化的不平衡性及流变行为

高聚物在玻璃化转变前后表现出截然不同的力学、物理及流变特性,并在玻璃态下继续松弛。本文介绍了有关经典理论的形成和发展,最后从热力学、统计力学、动理学(kinetics)3方面联合考虑提出了3维空间(PVT/PST)数学表象,这是目前处理这方面问题较完善的理论。      

Micromechanics, macromechanics and constitutive modeling of the elasto-viscoplastic deformation of rubber-toughened glassy polymers

Under certain conditions, such as sufficiently low temperatures, high loading rates and/or highly triaxial stress states, glassy polymers display an unfavorable characteristic—brittleness. A technique used for reducing the brittleness (increasing the fracture toughness) of these materials is rubber toughening. While there is significant qualitative understanding of the mechanical behavior of rubber-toughened polymers, quantitative modeling tools for the large-strain deformation of rubber-toughened glassy polymers are largely lacking.In this paper, we develop a suite of numerical tools to investigate the mechanical behavior of rubber-toughened glassy polymers, with emphasis on rubber-toughened polycarbonate. The rubber particles are modeled as voids in view of their deformation-induced cavitation early during deformation. A three-dimensional micromechanical model of the heterogeneous microstructure is developed to study the effects of initial rubber particle (void) volume fraction on the underlying elasto-viscoplastic deformation mechanisms in the material, and how these mechanisms influence the macroscopic response of the material. A continuum-level constitutive model is developed for the large-strain elasto-viscoplastic deformation of porous glassy polymers, and it is calibrated against micromechanical modeling results for porous polycarbonate. The constitutive model can be used to study various boundary value problems involving rubber-toughened (porous) glassy polymers. As an example, the case of an axisymmetric notched bar is simulated for the case of polycarbonate with varying levels of initial porosity. The quality of the constitutive model calibration is assessed using a multi-scale modeling approach.     

Plastic flow in oriented glassy polymers

A manufactured product often possesses residual texture which was either incidentally or deliberately acquired during its processing history. This is particularly true for the case of polymers, where the ability to easily preferentially preorient the material in specific directions is exploited in order to obtain a higher strength product. Specific examples include synthetic fibers, and biaxially-oriented films and containers. The response of the preoriented/textured product to normal service life loading conditions will differ considerably from that of a product composed of isotropic material. This paper addresses the issue of the effects of texture on the deformation behavior of glassy polymers. Here, the physically-based constitutive model of Boyce, Parks, and Argon describing the rate, temperature, and pressure dependent inelastic deformation of initially isotropic glassy polymers is used to model the effects of preorientation (i.e., initial texture), via the use of appropriate initial conditions on internal state variables. The model is then utilized in an analysis of the effects of texture on the yield of glassy polymers and the shear localization which normally follows yielding in oriented polymers. These results are compared with trends found in experiments as reported in the literature. The effectiveness of the proposed model for the present application is also compared with earlier models of yielding of anisotropic materials such as Hill's criterion.     

玻璃态聚合物银纹化过程的数值模拟

银纹化是玻璃态聚合物材料所特有的一种现象。本文在代表体积单元中嵌入能够刻划银纹萌生与生长的银纹单元，运用有限元方法对银纹化过程进行了数值模拟。银纹化过程中的最大主应力矢量图说明计算模型以及计算方法是比较合理的。而且，本文所揭示出来的银纹化过程的规律与实验中观察到的现象是吻合的。     

Effect of crack-tip shape on the near-tip field in glassy polymer

The physical nature of a crack tip is not absolutely sharp but blunt with finite curvature. In this paper, the effects of crack-tip shape on the stress and deformation fields ahead of blunted cracks in glassy polymers are numerically investigated under Mode I loading and small scale yielding conditions. An elastic–viscoplastic constitutive model accounting for the strain softening upon yield and then the subsequently strain hardening is adopted and two typical glassy polymers, one with strain hardening and the other with strain softening–rehardening are considered in analysis. It is shown that the profile of crack tip has obvious effect on the near-tip plastic field. The size of near-tip plastic zone reduces with the increase of curvature radius of crack tip, while the plastic strain rate and the stresses near crack tip enhance obviously for two typical polymers. Also, the plastic energy dissipation behavior near cracks with different curvatures is discussed for both materials.     

预延伸非晶聚合物材料各向异性变形局部化

给出一种可描述预延伸各向异性特性的背应力张量三维表达式，引入大变形弹塑性有限元驱动应力法，结合ＢＰＡ８ 链细观分子网络模型，模拟了预延伸各向异性非晶聚合物材料平面应变拉伸变形局部化力学行为．详细讨论了预延伸比（ＩｎｉｔｉａｌＤｒａｗｉｎｇＲａｔｉｏ；ＩＤＲ）和预延伸方向（ＩｎｉｔｉａｌＤｒａｗｉｎｇＤｉｒｅｃｔｉｏｎ；ＩＤＤ）对变形抗力、颈缩规律、剪切带方向以及试件中心部位链延伸比的影响．     

A generalized coupled viscoplastic-viscodamage-viscohealing theory for glassy polymers

A thermodynamic consistent, small-strain, non-unified model is developed to capture the irregular rate dependency included in the strain controlled inelastic responses of polymers at the glassy state. The model is considered as a generalized Frederick-Armstrong-Philips-Chaboche (FAPC) theory proposed by [Voyiadjis and Basuroychowdhury, 1998] and [Voyiadjis and Abu Al-Rub, 2003] which is based on a von Mises and Chaboche isotropic hardening type viscoplasticity formulation. Using the proposed model, different experimental results are simulated and the range of viscoplastic related material constants are obtained through a parametric study. The thermodynamic framework is used to incorporate the effect of coupling between viscodamage and viscohealing phenomena into the inelastic deformation of glassy polymers. This coupling effect is crucial for polymeric based self healing systems in which different damage mechanisms are active and the efficiency of the healing processes are highly dependent on the damage. The computational aspect for general coupled inelastic-damage-healing processes together with the required solution algorithms are elaborated and the inelastic-damage-healing response of a polymeric based self-healing system is simulated. The proposed viscoplasticity theory constitutes a physically consistent approach to model the irregular mechanical responses of glassy polymers and the viscodamage model provides an exquisite predicting tool to evaluate the ductile damage associated with the large inelastic deformation and low cycle fatigue in polymeric based material systems. In conclusion, a well structured viscohealing theory is formulated for polymeric based self healing systems.     

Modelling of the elasto-viscoplastic damage behaviour of glassy polymers

Constitutive equations are proposed in order to describe the elasto-viscoplastic damage behaviour of polymers. The behaviour is well accounted for by a modified Bodner–Partom model comprising hydrostatic and void evolution terms. The true stress–strain and volumetric strain behaviour of typical rubber-toughened glassy polymers (RTPMMA and HIPS) were experimentally determined at constant local true strain rate by using a video-controlled technique. Successful agreement is obtained between experimental results and the proposed model.     

A variational framework for the modeling of glassy polymers under finite strains

Continuum Mechanics and Thermodynamics - In this paper, a viscoelastic model able to capture important mechanical features of a wide class of glassy polymers is presented. Among them, the ability...