On the boundary conditions at the macroscopic level

We study the problem of the boundary conditions specified at the boundary of a porous domain in order to solve the macroscopic transfer equations obtained by means of the volume-averaging method. The analysis is limited to the case of conductive transport but the method can be extended to other cases. A numerical study enables us to illustrate the theoretical results in the case of a model porous medium. Roman Letters _sf interfacial area of the s-f interface contained within the macroscopic system m² - A _sf interfacial area of the s-f interface contained within the averaging volume m² - C _p mass fraction weighted heat capacity, kcal/kg/K - d _s , d _f microscopic characteristic length m - g vector that maps to _s, m - h vector that maps to _f , m - K _eff effective thermal conductivity tensor, kcal/m s K - l REV characteristic length, m - L macroscopic characteristic length, m - n _fs outwardly directed unit normal vector for the f-phase at the f-s interface - n _e outwardly directed unit normal vector at the dividing surface - T ^* macroscopic temperature field obtained by solving the macroscopic equation (3), K - V averaging volume, m³ - V _s , V _f volume of the considered phase within the averaging volume, m³ - volume of the macroscopic system, m³ - _s , _f volume of the considered phase within the volume of the macroscopic system, m³ - dividing surface, m² Greek Letters _s , _f volume fraction - ratio of thermal conductivities - _s , _f thermal conductivities, kcal/m s K - spatial average density, kg/m³ - microscopic temperature, K - ^* microscopic temperature corresponding to T ^* , K - spatial deviation temperature K - error on the temperature due to the macroscopic boundary conditions, K - spatial average - ^s , ^f intrinsic phase average     

Optical co-ordinates in general relativity 2 — the problem of distance

Summary Let denote the congruence of null geodesics associated with a given optical observer inV ₄. We prove that determines a unique collection of vector fieldsM₍₎ ( =1, 2, 3) and ₍₀₎ overV ₄, satisfying a weak version of Killing's conditions.This allows a natural interpretation of these fields as the infinitesimal generators of spatial rotations and temporal translation relative to the given observer. We prove also that the definition of the fieldsM₍₎ and ₍₀₎ is mathematically equivalent to the choice of a distinguished affine parameter f along the curves of, playing the role of a retarded distance from the observer.The relation between f and other possible definitions of distance is discussed.

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Sommario Sia la congruenza di geodetiche nulle associata ad un osservatore ottico assegnato nello spazio-tempoV ₄. Dimostriamo che determina un'unica collezione di campi vettorialiM₍₎ ( =1, 2, 3) e ₍₀₎ inV ₄ che soddisfano una versione in forma debole delle equazioni di Killing. Ciò suggerisce una naturale interpretazione di questi campi come generatori infinitesimi di rotazioni spaziali e traslazioni temporali relative all'osservatore assegnato. Dimostriamo anche che la definizione dei campiM₍₎, ₍₀₎ è matematicamente equivalente alla scelta di un parametro affine privilegiato f lungo le curve di, che gioca il ruolo di distanza ritardata dall'osservatore. Successivamente si esaminano i legami tra f ed altre possibili definizioni di distanza in grande.

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Work performed in the sphere of activity of: Gruppo Nazionale per la Fisica Matematica del CNR.     

Flow in porous media II: The governing equations for immiscible,two-phase flow

The Stokes flow of two immiscible fluids through a rigid porous medium is analyzed using the method of volume averaging. The volume-averaged momentum equations, in terms of averaged quantities and spatial deviations, are identical in form to that obtained for single phase flow; however, the solution of the closure problem gives rise to additional terms not found in the traditional treatment of two-phase flow. Qualitative arguments suggest that the nontraditional terms may be important when / is of order one, and order of magnitude analysis indicates that they may be significant in terms of the motion of a fluid at very low volume fractions. The theory contains features that could give rise to hysteresis effects, but in the present form it is restricted to static contact line phenomena.Roman Letters (, = , , and ) A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - g gravity vector, m²/s - H mean curvature of the- interface, m^–1 - H area average of the mean curvature, m^–1 - H – H , deviation of the mean curvature, m^–1 - I unit tensor - K Darcy's law permeability tensor, m² - K permeability tensor for the-phase, m² - K viscous drag tensor for the-phase equation of motion - K viscous drag tensor for the-phase equation of motion - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - n unit normal vector pointing from the-phase toward the-phase (n = –n ) - p _c p – P , capillary pressure, N/m² - p pressure in the-phase, N/m² - p intrinsic phase average pressure for the-phase, N/m² - p – p , spatial deviation of the pressure in the-phase, N/m² - r ₀ radius of the averaging volume, m - t time, s - v velocity vector for the-phase, m/s - v phase average velocity vector for the-phase, m/s - v intrinsic phase average velocity vector for the-phase, m/s - v – v , spatial deviation of the velocity vector for the-phase, m/s - V averaging volume, m³ - V volume of the-phase contained within the averaging volume, m³ Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m² - surface tension of the- interface, N/m - viscous stress tensor for the-phase, N/m² - / kinematic viscosity, m²/s     

Laser velocimetry measurements in a horizontal gas-solid pipe flow

This paper presents laser measurements of particle velocities in a horizontal turbulent two-phase pipe flow. A phase Doppler particle analyzer, (PDPA), was used to obtain particle size, velocity, and rms values of velocity fluctuations. The particulate phase consisted of glass spheres 50 m in diameter with the volume fraction of the suspension in the range _p=10^-4 to _p=10^-3. The results show that the turbulence increases with particle loading.List of symbols a particle diameter - C _va velocity diameter cross-correlation - d pipe diameter - Fr ² Froude number - g gravitational constant - p(a) Probability density of the particle diameter - Re pipe Reynolds number based on the friction velocity - T characteristic time scale of the energy containing eddies - T _L integral scale of the turbulence sampled along the particle path - u, U, u characteristic fluid velocities: fluctuating, mean and friction - v characteristic velocity of the paricle fluctuations - f expected value of any random variable f - f¦g expected value of f given a value of the random variable g - _p particle volume fraction - _p particle response time - absolute fluid viscosity - v kinematic fluid viscosity - _p, _f densities, particle and fluid - _a ² particle diameter variance - _va ² velocity variance due to the particle diameter variance - _vT ² total particle velocity variance - _vt ² particle velocity variance due to the response to the turbulent field     

A noninvasive method for the measurement of flow-induced surface displacement of a compliant surface

A noninvasive optical method is described which allows the measurement of the vertical component of the instantaneous displacement of a surface at one or more points. The method has been used to study the motion of a passive compliant layer responding to the random forcing of a fully developed turbulent boundary layer. However, in principle, the measurement technique described here can be used equally well with any surface capable of scattering light and to which optical access can be gained. The technique relies on the use of electro-optic position-sensitive detectors; this type of transducer produces changes in current which are linearly proportional to the displacement of a spot of light imaged onto the active area of the detector. The system can resolve displacements as small as 2 m for a point 1.8 mm in diameter; the final output signal of the system is found to be linear for displacements up to 200 m, and the overall frequency response is from DC to greater than 1 kHz. As an example of the use of the system, results detailing measurements obtained at both one and two points simultaneously are presented.List of symbols C _t elastic transverse wave speed = (G/)^1/2 - d ⁺ spot diameter normalized by viscous length scale - G frequency average of G() - G() shear storage modulus - G() shear loss modulus - l. viscous length scale = v/u _* - N total number of sampled data values - r separation vector for 2-point measurements = (, ) - rms root-mean-square value - R momentum thickness Reynolds number = U _t8/v - t time - u (y) mean streamwise component of velocity in boundary layer - u _* friction velocity = (t _w/)^1/2 - U free-stream velocity - x, y, z longitudinal, normal and spanwise directions - y _o undisturbed surface position - vertical component of compliant surface displacement - ₉₉ boundary layer thickness for which u(y) = 0.99 U _t8 - _l viscous sublayer thickness 5 l _* - frequency average of G()/ - boundary layer momentum thicknes = - fluid dynamic viscosity - v fluid kinematic viscosity = / - , longitudinal, spanwise components of separation vector r - fluid density - time delay - _w wall shear stress     

Hydrodynamic models as applied to the investigation of magnetic plasma stability

In the present paper magnetohydrodynamic models are employed to investigate the stability of an inhomogeneous magnetic plasma with respect to perturbations in which the electric field may be regarded as a potential field (rot E 0). A hydrodynamic model, actually an extension of the well-known Chew-Goldberg er-Low model [1], is used to investigate motions transverse to a strong magnetic field in a collisionless plasma. The total viscous stress tensor is given; this includes, together with magnetic viscosity, the so-called inertial viscosity.Ordinary two-fluid hydrodynamics is used in the case of strong collisions=. It is shown that the collisional viscosity leads to flute-type instability in the case when, collisions being neglected, the flute mode is stabilized by a finite Larmor radius. A treatment is also given of the case when epithermal high-frequency oscillations (not leading immediately to anomalous diffusion) cause instability in the low-frequency (drift) oscillations in a manner similar to the collisional electron viscosity, leading to anomalous diffusion.Notation f particle distribution function - E electric field component - H₀ magnetic field - density - V particle velocity - e charge - m, M electron and ion mass - _i, _e ion and electron cyclotron frequencies - viscous stress tensor - P pressure - r_i Larmor radius - P pressure tensor - t time - frequency - T temperature - collision frequency - collision time - j current density - _i, _e ion and electron drift frequencies - k_x, k_y, k_z wave-vector components - n₀ particle density - g acceleration due to gravity. The authors are grateful to A. A. Galeev for valuable discussion.     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Two-phase flow in heterogeneous porous media II: Numerical experiments for flow perpendicular to a stratified system

In this work, we make use of numerical experiments to explore our original theoretical analysis of two-phase flow in heterogeneous porous media (Quintard and Whitaker, 1988). The calculations were carried out with a two-region model of a stratified system, and the parameters were chosen be consistent with practical problems associated with groundwater flows and petroleum reservoir recovery processes. The comparison between theory (the large-scaled averaged equations) and experiment (numerical solution of the local volume averaged equations) has allowed us to identify conditions for which the quasi-static theory is acceptable and conditions for which a dynamic theory must be used. Byquasi-static we mean the following: (1) The local capillary pressure,everywhere in the averaging volume, can be set equal to the large-scale capillary pressure evaluated at the centroid of the averaging volume and (2) the large-scale capillary pressure is given by the difference between the large-scale pressures in the two immiscible phases, and is therefore independent of gravitational effects, flow effects and transient effects. Bydynamic, we simply mean a significant departure from the quasi-static condition, thus dynamic effects can be associated with gravitational effects, flow effects and transient effects. To be more precise about the quasi-static condition we need to refer to the relation between the local capillary pressure and the large-scale capillary pressure derived in Part I (Quintard and Whitaker, 1990). Herep _c ¦_y represents the local capillary pressure evaluated at a positiony relative to the centroid of the large-scale averaging volume, and {p _c }¦_x represents the large-scale capillary pressure evaluated at the centroid.In addition to{p _c } ^c being evaluated at the centroid, all averaged terms on the right-hand side of Equation (1) are evaluated at the centroid. We can now write the equations describing the quasi-static condition as , , This means that the fluids within an averaging volume are distributed according to the capillary pressure-saturation relationwith the capillary pressure held constant. It also means that the large-scale capillary pressure is devoid of any dynamic effects. Both of these conditions represent approximations (see Section 6 in Part I) and one of our main objectives in this paper is to learn something about the efficacy of these approximations. As a secondary objective we want to explore the influence of dynamic effects in terms of our original theory. In that development only the first four terms on the right hand side of Equation (1) appeared in the representation for the local capillary pressure. However, those terms will provide an indication of the influence of dynamic effects on the large-scale capillary pressure and the large-scale permeability tensor, and that information provides valuable guidance for future studies based on the theory presented in Part I.Roman Letters A scalar that maps {}*/t onto - A scalar that maps {}*/t onto - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - a vector that maps ({}*/t) onto , m - a vector that maps ({}*/t) onto , m - b vector that maps ({p}– g) onto , m - b vector that maps ({p}– g) onto , m - B second order tensor that maps ({p}– g) onto , m² - B second order tensor that maps ({p}– g) onto , m² - c vector that maps ({}*/t) onto , m - c vector that maps ({}*/t) onto , m - C second order tensor that maps ({}*/t) onto , m² - C second order tensor that maps ({}*/t) onto . m² - D third order tensor that maps ( ) onto , m - D third order tensor that maps ( ) onto , m - D second order tensor that maps ( ) onto , m² - D second order tensor that maps ( ) onto , m² - E third order tensor that maps () onto , m - E third order tensor that maps () onto , m - E second order tensor that maps () onto - E second order tensor that maps () onto - p _c =(), capillary pressure relationship in the-region - p _c =(), capillary pressure relationship in the-region - g gravitational vector, m/s² - largest of either or - - - i unit base vector in thex-direction - I unit tensor - K local volume-averaged-phase permeability, m² - K local volume-averaged-phase permeability in the-region, m² - K local volume-averaged-phase permeability in the-region, m² - {K } large-scale intrinsic phase average permeability for the-phase, m² - K –{K }, large-scale spatial deviation for the-phase permeability, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K ^* large-scale permeability for the-phase, m² - L characteristic length associated with local volume-averaged quantities, m - characteristic length associated with large-scale averaged quantities, m - I _i i = 1, 2, 3, lattice vectors for a unit cell, m - l characteristic length associated with the-region, m - ; characteristic length associated with the-region, m - l _H characteristic length associated with a local heterogeneity, m - - n unit normal vector pointing from the-region toward the-region (n =–n ) - n unit normal vector pointing from the-region toward the-region (n =–n ) - p pressure in the-phase, N/m² - p local volume-averaged intrinsic phase average pressure in the-phase, N/m² - {p } large-scale intrinsic phase average pressure in the capillary region of the-phase, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - P _c p –{p }, capillary pressure, N/m² - {p_c}^c large-scale capillary pressure, N/m² - r ₀ radius of the local averaging volume, m - R ₀ radius of the large-scale averaging volume, m - r position vector, m - , m - S /, local volume-averaged saturation for the-phase - S ^* {}*{}*, large-scale average saturation for the-phaset time, s - t time, s - u , m - U , m² - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - {v } large-scale intrinsic phase average velocity for the-phase in the capillary region of the-phase, m/s - {v } large-scale phase average velocity for the-phase in the capillary region of the-phase, m/s - v –{v }, large-scale spatial deviation for the-phase velocity, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - V local averaging volume, m³ - V volume of the-phase in, m³ - V large-scale averaging volume, m³ - V capillary region for the-phase within, m³ - V capillary region for the-phase within, m³ - V _c intersection of m³ - V volume of the-region within, m³ - V volume of the-region within, m³ - V () capillary region for the-phase within the-region, m³ - V () capillary region for the-phase within the-region, m³ - V () , region in which the-phase is trapped at the irreducible saturation, m³ - y position vector relative to the centroid of the large-scale averaging volume, m Greek Letters local volume-averaged porosity - local volume-averaged volume fraction for the-phase - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region (This is directly related to the irreducible saturation.) - {} large-scale intrinsic phase average volume fraction for the-phase - {} large-scale phase average volume fraction for the-phase - {}* large-scale spatial average volume fraction for the-phase - –{}, large-scale spatial deviation for the-phase volume fraction - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - a generic local volume-averaged quantity associated with the-phase - mass density of the-phase, kg/m³ - mass density of the-phase, kg/m³ - viscosity of the-phase, N s/m² - viscosity of the-phase, N s/m² - interfacial tension of the - phase system, N/m - , N/m - , volume fraction of the-phase capillary (active) region - , volume fraction of the-phase capillary (active) region - , volume fraction of the-region ( + =1) - , volume fraction of the-region ( + =1) - {p }– g, N/m³ - {p }– g, N/m³     

New calculations on the Faraday effect in wave guides

Summary The propagation of electromagnetic waves is investigated theoretically for a round wave guide, containing a gyroelectrie-gyromagnetic medium with gyroaxis parallel to the guide in the form of a cylindrical shell of thickness, adjacent to the wall of the guide. An equation is set up, permitting to compute the change in the propagation constant due to the presence of the shell, including terms proportional to ². Assuming only the presence of gyromagnetism, the change ₁ of first order in for TE-waves is determined and is found to be the same fpr right- and left-circular polarization. The second order difference ₂ ⁺ — ₂ ^- for the two senses of polarization, however, appears to have a non-vanishing value which, just like ₁ can be expressed in terms of the radius of the guide, the frequency, the dielectric constant and the elements of the gyromagnetic permeability tensor which characterize the medium of the shell.     

Shear viscosity behavior of highly concentrated suspensions at low and high shear-rates

A method is proposed for determining the shear viscosity behavior of highly concentrated suspensions at low and high shear-rates through the use of a formulation that is a function of three parameters signifying the effects of particle size distribution. These parameters are the intrinsic viscosity [], a parametern that reflects the level of particle association at the initiation of motion and the maximum packing concentration _m. The formulation reduces to the modified Eilers equation withn = 2 for high shear rates. An analytical method was used for the calculation of maximum packing concentration which was subsequently correlated with the experimental values to account for the surface induced interaction of particles with the fluid. The calculated values of viscosities at low and high shear-rates were found to be in good agreement with various experimental data reported in literature. A brief discussion is also offered on the reliability of the methods of measuring the maximum packing concentration. _r = /₀ relative viscosity of the suspension - volumetric concentration of solids - k _n coefficient which characterizes a specific effect of particle interactions - _m maximum packing concentration - _r,0 relative viscosity at low shear-rates - [] intrinsic viscosity - n, n parameter that reflects the level of particle interactions at low and high shear-rates, respectively - _r, relative viscosity at high shear-rates - (_m)_s, (_m)_i, (_m)_l packing factors for small, intermediate and large diameter classes - v _s, v_i, v_l volume fractions of small, intermediate and large diameter classes, respectively - _si, _sl coefficient to be used in relating a smaller to an intermediate and larger particle group, respectively - _is, _il coefficient to be used in relating an intermediate to a smaller and larger particle group, respectively - _ls, _li coefficient to be used in relating a larger to a smaller and intermediate particle group, respectively - _m0 maximum packing concentration for binary mixtures - _m,e measured maximum packing concentration - _m,c calculated maximum packing concentration     

Chaos and integrability in a nonlinear wave equation

We consider the parametrized family of equations _tt ,u- _xx u-au+u ₂ ² u=O,x(0,L), with Dirichlet boundary conditions. This equation has finite-dimensional invariant manifolds of solutions. Studying the reduced equation to a four-dimensional manifold, we prove the existence of transversal homoclinic orbits to periodic solutions and of invariant sets with chaotic dynamics, provided that =2, 3, 4,.... For =1 we prove the existence of infinitely many first integrals pairwise in involution.     

Image processing of hydrogen bubble flow visualization for determination of turbulence statistics and bursting characteristics

A technique is described which employs automated image processing of hydrogen-bubble flow visualization pictures to establish local, instantaneous velocity profile information. Hydrogen bubble flow visualization sequences are recorded using a high-speed video system and then digitized, stored, and evaluated by a VAX 11/780 computer. Employing special smoothing and gradient detection algorithms, individual bubble-lines are computer identified, which allows local velocity profiles to be constructed using time-of-flight techniques. It is demonstrated how this techniques may be used to 1) determine local velocity behavior as a function of position and time, 2) evaluate time-averaged turbulence properties, and 3) correlate probe-type turbulent burst detection techniques with the corresponding visualization data.List of symbols Re Reynolds number based on momentum thickness, u / - t ⁺ nondimensional time tu ² / - T VITA variance averaging time period - u shear velocity = - u local instantaneous streamwise velocity,x-direction - u local fluctuating streamwise velocity,x-direction - u ⁺ nondimensional streamwise velocity, /u - local normal velocity,y-direction - w local spanwise velocity,z-direction - x ⁺ nondimensional coordinate in streamwise direction xu /v - y ⁺ nondimensional coordinate normal to wall, yu /v Greek momentum thickness, - kinematic viscosity - _w wall shear stress This paper was presented at the Ninth Symposium on Turbulence, University of Missouri-Rolla, October 1–3, 1984     

Peristaltic pumping of a second-order fluid in a planar channel

The peristaltic motion of a non-Newtonian fluid represented by the constitutive equation for a second-order fluid was studied for the case of a planar channel with harmonically undulating extensible walls. A perturbation series for the parameter ( half-width of channel/wave length) obtained explicit terms of 0(²), 0(²Re²) and 0(₁Re²) respectively representing curvature, inertia and the non-Newtonian character of the fluid. Numerical computations were performed and compared to the perturbation analysis in order to determine the range of validity of the terms.Presented at the second conference Recent Developments in Structured Continua, May 23–25, 1990, in Sherbrooke, Québec, Canada     

Untersuchung des lokalen Stoffüberganges am laminaren und turbulenten Rieselfilm

Zusammenfassung Der lokale Stoffübergang wurde in Abhängigkeit von der Meßlänge, dem Startort und der Zulaufhöhe gemessen. Der Gültigkeitsbereich der Theorie von Nusselt wird ermittelt. Die Reynolds-Zahl nahm Werte zwischen 3,86 und 2496 an. Die örtlich wirkende Hydrodynamik ist entscheidend für das Anwachsen der örtlichen Sherwood-Zahl. Die Genauigkeit aller Versuchsergebnisse kann auf ± 5% abgeschätzt werden.

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Investigation of the local mass transfer of a laminar and turbulent falling liquid film

The local mass transfer was measured as a function of the measuring length, the starting point and the liquid height above the ring-slot. The range of the Reynolds number was 3,86 Re 2496. The validity of the Nusselt theory and the range of it is shown. The local hydrodynamic is the most important factor of the increase of the local Sherwood number. The accuracy of the measurements is ± 5%.

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Bezeichnungen a Temperaturleitfähigkeit m²/s=/(c_p) - c Konzentration, c=¯c + c kmol/m³ - c_i0 Konzentration im Flüssigkeitskern kmol/m³ - D Diffusionskoeffizient m²/s - EL-NR Elektrodennummer - Fa Faraday-Konstante A s/kgäq=96,5·10⁶ - g Erdbeschleunigung m/s² - i_G Grenzstromdichte A/m² - u Geschwindigkeit in x-Richtung, u= + u - U Umfang des Rohres m - v Geschwindigkeit in y-Rich- m/stung, v=¯v + v - V^* Volumenstrom m³/s - x Lauflänge, Koordinate in m Strömungsrichtung - x_M Meßlänge für den Stoff-Übergang m - x_ST Startort für den Stoff-Übergang m - y Wegkoordinate senkrecht zur Rohroberfläche m - z Wertigkeit der Elektro-denreaktion kgäq/kmol - ZH Zulaufhöhe m - Wärmeübergangskoeffizient W/m²C - Stoffübergangskoeffizient m/s - Filmdicke m - Wärmeleitfähigkeit W/(mC) - kinematische Viskosität m²/s - Re=u/=V^*/U Reynolds-Zahl - Pr=/a=c_p/ Prandtl-Zahl - Sc=/D Schmidt-Zahl - Nu= / Nusselt-Zahl - Sh= /D Sherwood-Zahl - SHL lokale Sherwood-Zahl - SHM mittlere Sherwood-Zahl - - zeitlich gemittelt - örtlich gemittelt Die Durchführung der Arbeit am Institut für Verfahrens — und Kältetechnik der ETH Zürich bei Prof. Dr. P. Grassmann wurde ermöglicht durch Zuschüsse der Kommission zur Förderung der wissenschaftlichen Forschung und meiner Eltern.     

Deformation to breaking of deep water gravity waves

The results of laboratory observations of the deformation of deep water gravity waves leading to wave breaking are reported. The specially developed visualization technique which was used is described. A preliminary analysis of the results has led to similar conclusions than recently developed theories. As a main fact, the observed wave breaking appears as the result of, first, a modulational instability which causes the local wave steepness to approach a maximum and, second, a rapidly growing instability leading directly to the breaking.List of symbols L total wave length - H total wave height - crest elevation above still water level - trough depression below still water level - wave steepness =H/L - crest steepness =/L - trough steepness =/L - F ₁ forward horizontal length from zero-upcross point (A) to wave crest - F ₂ backward horizontal length from wave crest to zero-downcross point (B) - crest front steepness =/F ₁ - crest rear steepness =/F ₂ - vertical asymmetry factor=F ₂/F ₁ (describing the wave asymmetry with respect to a vertical axis through the wave crest) - µ horizontal asymmetry factor=/H (describing the wave asymmetry with respect to a horizontal axis: SWL) - T ₀ wavemaker period - L ₀ theoretical wave length of a small amplitude sinusoïdal wave generated at T _inf0 ^sup–1 frequency - ₀ average wave height     

Flow in porous media I: A theoretical derivation of Darcy's law

Stokes flow through a rigid porous medium is analyzed in terms of the method of volume averaging. The traditional averaging procedure leads to an equation of motion and a continuity equation expressed in terms of the volume-averaged pressure and velocity. The equation of motion contains integrals involving spatial deviations of the pressure and velocity, the Brinkman correction, and other lower-order terms. The analysis clearly indicates why the Brinkman correction should not be used to accommodate ano slip condition at an interface between a porous medium and a bounding solid surface.The presence of spatial deviations of the pressure and velocity in the volume-averaged equations of motion gives rise to aclosure problem, and representations for the spatial deviations are derived that lead to Darcy's law. The theoretical development is not restricted to either homogeneous or spatially periodic porous media; however, the problem ofabrupt changes in the structure of a porous medium is not considered.Roman Letters A interfacial area of the - interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the - interface contained within the averaging volume, m² - A ^* interfacial area of the - interface contained within a unit cell, m² - Ae area of entrances and exits for the -phase contained within a unit cell, m² - B second order tensor used to represent the velocity deviation (see Equation (3.30)) - b vector used to represent the pressure deviation (see Equation (3.31)), m^–1 - d distance between two points at which the pressure is measured, m - g gravity vector, m/s² - K Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the -phase (see Figure 2), m - characteristic length scale for the -phase (see Figure 2), m - n unit normal vector pointing from the -phase toward the -phase (n =–n ) - n _e unit normal vector for the entrances and exits of the -phase contained within a unit cell - p pressure in the -phase, N/m² - p intrinsic phase average pressure for the -phase, N/m² - p –p , spatial deviation of the pressure in the -phase, N/m² - r ₀ radius of the averaging volume and radius of a capillary tube, m - v velocity vector for the -phase, m/s - v phase average velocity vector for the -phase, m/s - v intrinsic phase average velocity vector for the -phase, m/s - v –v , spatial deviation of the velocity vector for the -phase, m/s - V averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ Greek Letters V/V, volume fraction of the -phase - mass density of the -phase, kg/m³ - viscosity of the -phase, Nt/m² - arbitrary function used in the representation of the velocity deviation (see Equations (3.11) and (B1)), m/s - arbitrary function used in the representation of the pressure deviation (see Equations (3.12) and (B2)), s^–1     

Method of mass-average quantities for the boundary layer in an outer flow with transverse nonuniformity

An engineering method is proposed for calculating the friction and heat transfer through a boundary layer in which a nonuniform distribution of the velocity, total enthalpy, and static enthalpy is specified across the streamlines at the initial section x₀. Such problems arise in the vortical interaction of the boundary layer with the high-entropy layer on slender blunt bodies, with sudden change of the boundary conditions for an already developed boundary layer (temperature jump, surface discontinuity), and in wake flow past a body, etc.Notation x, y longitudinal and transverse coordinates - u,, H, h gas velocity, stream function, total and static enthalpy - p,,, pressure, density, viscosity, Prandtl number - , q friction and thermal flux at the body surface - r(x), (x) body surface shape and boundary layer thickness - V, M freestream velocity and Mach number - u⁽⁰⁾(x₀,), H⁽⁰⁾(x₀,), h⁽⁰⁾(x₀,) parameter distributions at initial section - u⁽⁰⁾(x,), h⁽⁰⁾(x,), h⁽⁰⁾(x,) profiles of quantities in outer flow in absence of friction and heat transfer at the surface of the body The indices v=0, 1 relate to plane and axisymmetric flows - , w, b, relate to quantities at the outer edge of the inner boundary layer, at the body surface in viscid and nonviscous flows, and in the freestream, respectively. The author wishes to thank O. I. Gubanov, V. A. Kaprov, I. N. Murzinov, and A. N, Rumynskii for discussions and assistance in this study.     

Transport in ordered and disordered porous media IV: Computer generated porous media for three-dimensional systems

In the method of volume averaging, the difference between ordered and disordered porous media appears at two distinct points in the analysis, i.e. in the process of spatial smoothing and in the closure problem. In theclosure problem, the use of spatially periodic boundary conditions isconsistent with ordered porous media and the fields under consideration when the length-scale constraint,r ₀L is satisfied. For disordered porous media, spatially periodic boundary conditions are an approximation in need of further study.In theprocess of spatial smoothing, average quantities must be removed from area and volume integrals in order to extractlocal transport equations fromnonlocal equations. This leads to a series of geometrical integrals that need to be evaluated. In Part II we indicated that these integrals were constants for ordered porous media provided that the weighting function used in the averaging process contained thecellular average. We also indicated that these integrals were constrained by certain order of magnitude estimates for disordered porous media. In this paper we verify these characteristics of the geometrical integrals, and we examine their values for pseudo-periodic and uniformly random systems through the use of computer generated porous media.

Nomenclature

Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - a _i i=1, 2, 3 gaussian probability distribution used to locate the position of particles - I unit tensor - L general characteristic length for volume averaged quantities, m - L characteristic length for , m - L characteristic length for , m - characteristic length for the -phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1, 2, 3 lattice vectors, m - m convolution product weighting function - m _v special convolution product weighting function associated with the traditional volume average - n _i i=1, 2, 3 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - r position vector, m - r _m support of the weighting functionm, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume,, m³ - x positional vector locating the centroid of an averaging volume, m - x ₀ reference position vector associated with the centroid of an averaging volume, m - y position vector locating points relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - /L, small parameter in the method of spatial homogenization - standard deviation ofa _i - _r standard deviation ofr - _r intrinsic phase average of      

Asymptotic analysis of equilibrium states for rotating turbulent flows

The equilibrium states of homogeneous turbulence simultaneously subjected to a mean velocity gradient and a rotation are examined by using asymptotic analysis. The present work is concerned with the asymptotic behavior of quantities such as the turbulent kinetic energy and its dissipation rate associated with the fixed point (/kS)=0, whereS is the shear rate. The classical form of the model transport equation for (Hanjalic and Launder, 1972) is used. The present analysis shows that, asymptotically, the turbulent kinetic energy (a) undergoes a power-law decay with time for (P/)<1, (b) is independent of time for (P/)=1, (c) undergoes a power-law growth with time for 1<(P/)<(C ₂–1), and (d) is represented by an exponential law versus time for (P/)=(C ₂–1)/(C ₁–1) and (/kS)>0 whereP is the production rate. For the commonly used second-order models the equilibrium solutions forP/,II, andIII (whereII andIII are respectively the second and third invariants of the anisotropy tensor) depend on the rotation number when (P/kS)=(/kS)=0. The variation of (P/kS) andII versusR given by the second-order model of Yakhot and Orzag are compared with results of Rapid Distortion Theory corrected for decay (Townsend, 1970).     

Eine analytische Näherungslösung für die eingefrorene laminare Grenzschichtströmung eines binären Gemisches

Zusammenfassung Für die eingefrorene laminare Grenzschichtströmung eines teilweise dissoziierten binären Gemisches entlang einer stark gekühlten ebenen Platte wird eine analytische Näherungslösung angegeben. Danach läßt sich die Wandkonzentration als universelle Funktion der Damköhler-Zahl der Oberflächenreaktion angeben. Für das analytisch darstellbare Konzentrationsprofil stellt die Damköhler-Zahl den Formparameter dar. Die Wärmestromdichte an der Wand bestehend aus einem Wärmeleitungs- und einem Diffusionsanteil wird angegeben und diskutiert. Das Verhältnis beider Anteile läßt sich bei gegebenen Randbedingungen als Funktion der Damköhler-Zahl ausdrücken.

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An analytical approximation for the frozen laminar boundary layer flow of a binary mixture

An analytical approximation is derived for the frozen laminar boundary layer flow of a partially dissociated binary mixture along a strongly cooled flat plate. The concentration at the wall is shown to be a universal function of the Damkohler-number for the wall reaction. The Damkohlernumber also serves as a parameter of shape for the concentration profile which is presented in analytical form. The heat transfer at the wall depending on a conduction and a diffusion flux is derived and discussed. The ratio of these fluxes is expressed as a function of the Damkohler-number if the boundary conditions are known.

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Formelzeichen A Atom - A₂ Molekül - C Konstante in Gl. (20) - c₁=1/(2C) Konstante in Gl. (35) - c_p spezifische Wärme bei konstantem Druck - D binärer Diffusionskoeffizient - Ec=u ² /(2h_f) Eckert-Zahl - h spezifische Enthalpie - h_t=h+u²/2 totale spezifische Enthalpie - h _A ⁰ spezifische Dissoziationsenthalpie - K_w Reaktionsgeschwindigkeitskonstante der heterogenen Wandreaktion - 1= /( ) Champman-Rubesin-Parameter - Le=Pr/Sc Lewis-Zahl - M Molmasse - p statischer Druck - Pr= c_pf/ Prandtl-Zahl - q_w Wärmestromdichte an der Wand - q_cw, q_dw Wärmeleitungsbzw. Diffusionsanteil der Wärmestromdichte an der Wand - universelle Gaskonstante - R=/(2M_a) individuelle Gaskonstante der molekularen Komponente - Re_x= u x/ Reynolds-Zahl - Sc=/( D) Schmidt-Zahl - T absolute Temperatur - T_d=h _A ⁰ /R charakteristische Dissoziationstemperatur - u, v x- und y-Komponenten der Geschwindigkeit - U=u/u normierte x-Komponente der Geschwindigkeit - x, y Koordinaten parallel und senkrecht zur Platte Griechische Symbole - =A/ Dissoziationsgrad - Grenzschichtdicke - ₂ Impulsverlustdicke - Damköhler-Zahl der Oberflächenreaktion - =T/T normierte Temperatur - =y/ normierter Wandabstand - Wärmeleitfähigkeit - dynamische Viskosität - , ^* Ähnlichkeitskoordinaten - Dichte - Schubspannung Indizes A auf ein Atom bezogen - M auf ein Molekül bezogen - f auf den eingefrorenen Zustand bezogen - w auf die Wand bezogen - auf den Außenrand der Grenzschicht bezogen