Damping of Magnetorheological Elastomers

利用改装后的力磁耦合动态测试系统实验研究了磁流变弹性体在磁场下的阻尼性能. 实验得出了外加磁场的磁感应强度、基体的本征阻尼、铁粉含量、动态应变以及激励频率对磁流变弹性体阻尼的影响规律. 发现了磁流变弹性体的阻尼在很大程度上是由基体和颗粒之间的界面滑移所决定的. 而且该界面滑移不同于一般复合材料,它会受到外加磁场的影响..     

Effect of Cyclic Deformation on Magnetorheological Elastomers

采制备了铁颗粒含量分别是60%,70%和80%的三种材料,在应变幅值为50%,75%和100%的循环加载条件下,利用改进后的动态力学分析仪测试了循环加载后材料的储能模量和损耗模量. 结果显示铁颗粒含量为70%和80%的样品,其储能模量和损耗模量都和循环加载的幅值以及循环加载的次数有关,铁颗粒含量为80%样品受加载条件的影响尤其明显. 但铁颗粒含量为60%的样品,其性能却与循环加载的幅值和次数无关. 为了更好的研究磁流变弹性体受循环加载后的性能,样品还进行了准静态拉伸测试,并用扫描电镜对测试的样品进行了原位观察.     

A Gaussian distribution model of anisotropic magnetorheological elastomers

A Gaussian distribution model was developed to examine the field-induced performance of anisotropic magnetorheological elastomers. The developed model was based on the assumption that the iron particles in magnetorheological elastomers aggregate into a large number of parallel body-centered tetragonal structure columns whose length obeys the Gaussian distribution. By using multi-pole approximation with local field effect and taking into account the nonlinearity and saturation of particle magnetization, the field-induced shear modulus was calculated as a function of distribution and dimension of the particle structures, the external magnetic field and the dynamic shear strain. Compared with other modes as well as the published experimental results, this model shows a remarkable improvement in accurately predicting the behavior of the magnetorheological elastomers.     

Radiation Vulcanization of Magnetorheological Elastomers Based on Silicone Rubber

介绍了两种制备磁流变弹性体的硫化方法即高温硫化和辐射硫化. 研究中采用动态力学分析仪(DMA)测量了样品的动态力学特性.特别是对样品的磁流变效应和耐久性进行了详细的测试. 实验结果表明,经过辐射硫化的样品具有更大的零场模量和磁致模量,以及更好的磁流变效应和耐久性. 为了解释这些结果,文章对样品的体积形变和增塑剂渗出都作了详细的分析. 在硫化过程中样品的体积保持稳定是辐射硫化样品具有大磁致模量的重要原因,而增塑剂渗透性小也是辐射硫化样品具有高磁流变效应和耐久性的重要因素.     

基于多链模型的磁流变弹性体剪切模量的数值分析

从颗粒间的磁相互作用能出发,利用磁能密度的变化,计算了磁流变弹性体的磁致剪切模量.考虑了链内颗粒和相邻链中颗粒的影响,修正了磁流变弹性体的磁偶极子模型.构建了 BCT 结构计算模型,对含柱状结构的磁流变弹性体进行了计算.计算结果表明,传统的点偶极子模型高估了磁流变弹性体的磁致剪切模量；在提高磁流变弹性体的磁致剪切模量方面,颗粒体积比浓度较小时,链状结构比柱状结构要好；而当颗粒体积比浓度较大时,柱状结构优于链状结构.     

Influence of composition of carbonyl iron particles on dynamic mechanical properties of magnetorheological elastomers

Magnetorheological elastomers (MRE) are known as smart materials. However, the magnetorheological (MR) effect of MRE is not high enough at present, which limits its engineering applications. Prior studies have shown that magneto-induced shear storage modulus and MR effect were mainly determined by the performance of the ferromagnetic particles. In this paper, MRE samples were prepared by carbonyl iron particles (CIP) of different compositions based on silicon rubber under external magnetic field. Their microstructures were observed using an optical digital microscope and a scanning electron microscope. The dynamic mechanical properties of MRE samples were measured using a modified dynamic mechanical analyzer under varying magnetic field strength and frequency. The results show that the carbon content of CIP have a greater impact on the dynamic mechanical properties of MRE. The magneto-induced shear storage modulus and MR effect can be increased by selecting CIP of low carbon content. In addition, the damping property is also significantly influenced by the carbon content of the CIP. This study is expected to provide guidance for fabrication of high performance MRE.     

超细金属铁颗粒的高分子修饰及其悬浮液的磁流变性能

报道了γ射线辐照方法合成具有良好分散性的高分子复合金属铁粒子,分别选择十二烷基硫酸钠、溴化十六锘三甲基胺、Ｔｗｅｅｎ－８０、ＴｒｉｔｏｎＸ－２００和ＯＰ－１０表面活必睡有机单体、无机铁颗粒一起制备乳状液,通过对这种含有超细金属铁颗粒乳状液稳定性的比较,以寻求合适的乳化剂,并对以ＴｒｉｔｏｎＸ－２００为乳化剂时合成出的高聚物复合铁颗进行了ＸＲＤ、ＴＥＭ和ＩＲ表征,还将实验中所获得的高聚物复合铁粒子与     

起落架磁流变减摆器模糊PID控制算法的研究

为了减小飞机机轮的摆振,提高飞机乘坐的舒适性和驾驶的安全性,将磁流变控制技术应用于飞机起落架减摆器,实现减摆器阻尼力的实时智能控制。针对磁流变减摆器,建立了飞机起落架摆振的半主动控制非线性动力学模型,设计了模糊PID控制算法,并使用Matlab/Simulink建立了半主动控制仿真模型。通过调节流过磁感线圈的电流大小改变磁流变减摆器的阻尼力,从而减小机轮摆动实现半主动控制。通过动力学仿真,在给定速度下分别对比未安装减摆器、被动控制下以及半主动控制下机轮摆角、侧向位移、侧滑角随时间变化的曲线,结果表明了模糊PID控制算法的正确性和可行性,该控制策略可以较好的抑制机轮的摆振,同时也表明模糊PID控制算法具有良好的可控性,减摆效果也明显优于传统的被动控制。     

轻质磁性材料的制备及在磁流变液中的应用

研究了使用化学镀的方法在轻质载体上包覆具有磁性的镍、钴等物质。该材料具有密度低的优点（有效密度为2-3g/cm^3）。对比于几种羰基镍粉制备的磁流变液的沉降稳定性,使用该轻质磁性材料制备的磁流变液不用加防沉剂,其稳定性类似于加入较多防沉剂的羟基镍粉磁流变液。其在磁场下表观粘度比零磁场下的粘度有几十倍的变化。因此,使用该轻质磁性材料有望解决磁流变液普遍存在的沉降问题,得到综合性能良好的产品。     

磁流变液动态屈服行为的随机多尺度建模

根据能量保守原理,将微观粒子运动的动能等效成宏观动态屈服的应变能,建立内秉悬浮粒子运动涨落的磁流变液剪切应力的随机多尺度模型.分析表明,悬浮粒子初始随机条件和Brownian运动,以及剪切应变加载过程中,链簇反复断裂、重组的先后次序和数目不均匀,导致系统宏观屈服性态的非线性涨落和随机涨落;同时,微观运动涨落在体积平均过程中被严重弱化,宏观随机涨落相对不明显.拟合Bingham剪变率本构模型则进一步表明,外加场强对宏观屈服性态的变异性有一定程度的影响,磁流变液装置设计中应该考虑物理参数的随机性.     

Surfactants in Mechanical Alloying/Milling: A Catch-22 Situation

Mechanical alloying/milling technique is characterized by the repeated welding and fracturing of powder particles in a high-energy ball mill, which often results in excessive cold welding and agglomeration of ductile particles. To achieve the critical balance between cold welding and fracturing, the surface of the deforming particles is modified by introducing a suitable organic material, called surfactant or process control agent (PCA). However, the use of surfactants is self-contradictory by nature and requires further consideration of the milling variables and type/amount of surfactant. The current article provides a practical approach to the promises and challenges associated with surfactants in mechanical alloying/milling. An attempt has been made to address the most crucial aspects correlated with surfactants, including contamination, the morphology and size of powder particles, formation of alloy and microstructural evolution, and powder yield, as well as the physico-mechanical properties, such as magnetism, density, hardness, and compressive strength. An overview is also given on the adsorption mechanism of surfactants onto the surface of powder particles, with a special emphasis on type, amount, and the addition time of surfactants in the mechanical alloying process.     

Magnetorheological characteristics of nanoparticle-added carbonyl iron system

Magnetorheological (MR) fluid, suspension of magnetic carbonyl iron (CI) and magnetic additives in mineral oil, were prepared. The novel core–shell structured additives, comprising monodisperse polystyrene (PS) spheres as cores and magnetite as shells, were fabricated by surfactant-free emulsion polymerization. This MR fluid with bimodal particles was suspended in mineral oil and their MR characteristics were examined via a rotational rheometer in a parallel plate geometry equipped with a magnetic field supplier. MR properties of the bimodal MR fluid with magnetic additive exhibit similar magnetic and MR properties compared to MR fluid consisting of pristine CI, but with much improved dispersion stability.     

大口径非球面元件磁流变加工稳定性研究

重点分析了非球面元件磁流变加工的动态稳定性影响因素。设计了非球面元件的自动装调定位系统,提高了装调精度。采用一种拟合光栅式加工的新方法来验证其效果,通过测量元件表面形成的直线沟壑深度、宽度波动比例来评价去除的动态稳定性。在400 mm×400 mm口径的方形非球面元件上进行面形收敛验证实验,波长λ为632.8 nm时,加工后的透射波前误差PV值达到0.331λ,低频透射波前梯度误差GRMS值达到了0.008λ/cm。     

磁流变减振系统参数辨识

在对磁流变体的力学性能、减振系统设计和实验建模方法深入研究的基础上,提出了采用非线性顺序滤波来辨识磁流变化减振装置粘弹性模型参数的实验建模方法。研究表明,基于粘塑性假设,可用于该辨识算法获得库仑摩擦力和粘性摩擦系数。     

磁流变液阻尼器在转子振动控制中的应用

设计了一种转子振动控制用的剪切式磁流变液阻尼器,建立了磁流变液阻尼器－悬臂转子系统的分析模型,理论和实验研究了转子系统的不平衡响应特性。研究表明,随着施加磁场强度的增加,磁流变液阻尼和刚度增大,转子系统的临界振幅明显下降,系统的临界转速也明显提高。通过简单的开关控制,可抑止转子通过临界转速过程中的振动。     

Chemical modification of the surface of Fe<Subscript>75</Subscript>Si<Subscript>25</Subscript> alloy particles with stearic acid under high-energy ball-milling conditions

The morphology, phase composition and surface structure of Fe₇₅Si₂₅-alloy particles are studied by electron microscopy, X-ray diffraction analysis, and Mössbauer, Auger, IR (infrared) and X-ray photoelectron spectroscopy. The alloy particles used as fillers for the polyethylene matrix are produced by high-energy ball milling in an organic medium with the addition of stearic acid. The addition of stearic acid is shown to promote plasticization of the brittle Fe₇₅Si₂₅ alloy and the formation of a surface layer of no more than 1.5 nm thick, consisting of oxides based on iron and silicon, responsible for the chemisorption of stearic acid on the surface. Chemical modification of the surface of filler particles with an amphiphilic surfactant is carried out to enhance their adhesion in the polymer matrix.     

基于链化分析的磁流变液剪切屈服应力模型

基于磁性颗粒在磁场作用下的链化分析和统计分析方法,建立了磁流变液的宏观屈服剪应力的分析模型.模型考虑了磁感应强度、颗粒尺寸、体积分数、剪应变率以及饱和磁化强度等因素,能描述不同剪切应变率下剪切应力的变化及在高应变率下可能出现的剪切稀化效应.分析了不同因素对剪切屈服应力的影响,讨论了提高磁流变液剪切屈服应力的途径.分析表明,该模型的计算结果能较好地描述有关实验现象,并可用于高性能磁流变液的设计分析.     

Novel magnetorheological figuring of KDP crystal

A new process of magnetorheological figuring(MRF) based on the deliquescence theory is proposed to finish KDP crystals.A novel,non-aqueous,and abrasive-free magnetorheological(MR) fluid is explored,and polishing experiments are performed on a self-developed MRF machine.The removal mechanism is reckoned to be the result of a combination of dominant chemical etching and accessorial mechanical drag.The results indicate that the surface roughness of I plate KDP of 80 × 80(mm) polished by MRF is 1.2 nm(root mean square(RMS)),and the tool marks are completely removed.The surface accuracy by MRF is 0.035λ(RMS),and the low/middle-frequency errors are significantly corrected after MRF.     

Magnetorheological and deformation properties of magnetically controlled elastomers with hard magnetic filler

Viscoelastic and deformational behavior of soft magnetic elastomers with hard magnetic fillers under the influence of a magnetic field is studied by different experimental techniques. The magnetic elastomers used in this work were synthesized on the basis of silicone rubber filled with FeNdB particles and were magnetized in a field of 3 and 15 kOe. We have shown that due to high residual magnetization the materials demonstrate well pronounced non-elastic behavior already in the absence of any external magnetic field. In particular, in contrast to magnetic elastomers based on soft magnetic fillers their elastic modulus is strain-dependent. Under the influence of external magnetic field the storage and loss moduli of magnetic elastomers with hard magnetic filler can both increase and decrease tremendously.     

微米级高聚物包埋型金属铁复合粒子的球磨法制备及其磁流变效应

采用球磨法,能成功地直接从高聚物与金属铁的混合研磨中,获得微米级由聚苯乙烯和 甲基丙烯酸甲酯等高聚物包埋型金属羰基铁复合粒子。详细讨论制备条件包括不同高聚物比例、球磨时间对复合粒子形貌和粒径的影响及其复合粒子的热稳定性,还简要研究了由这些粒子组成的浓有机悬浮溶液的磁流变效应及其粒子的沉降稳定性。