Na‐site energy of P2‐type NaxM O2 (M = Mn and Co)

P2‐type Na_xM O₂ (M = Mn and Co) is a promising cathode material for low‐cost sodium ion secondary batteries. In this structure, there are two different crystallographic Nai (i = 1 and 2) sites with different Coulomb potential $ (\varphi _i)$ provided by M^4–x and O^2–. Here, we experimentally determine a difference ${(\rm \Delta }\varepsilon \equiv \varepsilon _1 - \varepsilon _2)$ of Na‐site energies ${(}\varepsilon _i \equiv e\varphi {\kern 1pt} _i)$ based on the temperature dependence of the site occupancies. We find that ${\rm \Delta }\varepsilon \;{=}\;56\;{K}$ for Na_0.52MnO₂ is significantly smaller than 190 K for Na_0.59CoO₂. We interpret the suppressed ${\rm \Delta }\varepsilon $ in Na_0.52MnO₂ in terms of the screening effect of the Na⁺ charge. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

One-and-a-Half Quantum de Finetti Theorems

When n − k systems of an n-partite permutation-invariant state are traced out, the resulting state can be approximated by a convex combination of tensor product states. This is the quantum de Finetti theorem. In this paper, we show that an upper bound on the trace distance of this approximation is given by , where d is the dimension of the individual system, thereby improving previously known bounds. Our result follows from a more general approximation theorem for representations of the unitary group. Consider a pure state that lies in the irreducible representation of the unitary group U(d), for highest weights μ, ν and μ + ν. Let ξ_μ be the state obtained by tracing out U _ν. Then ξ_μ is close to a convex combination of the coherent states , where and is the highest weight vector in U _μ. For the class of symmetric Werner states, which are invariant under both the permutation and unitary groups, we give a second de Finetti-style theorem (our “half” theorem). It arises from a combinatorial formula for the distance of certain special symmetric Werner states to states of fixed spectrum, making a connection to the recently defined shifted Schur functions [1]. This formula also provides us with useful examples that allow us to conclude that finite quantum de Finetti theorems (unlike their classical counterparts) must depend on the dimension d. The last part of this paper analyses the structure of the set of symmetric Werner states and shows that the product states in this set do not form a polytope in general.     

Coordinates of the quantum plane as q-tensor operators in (\mathfrak{s}\mathfrak{u}(2)*\mathfrak{s}\mathfrak{u}(2))

The relation between the set of transformations of the quantum plane and the quantum universal enveloping algebra U _q (u(2)) is investigated by constructing representations of the factor algebra U _q (u(2))* . The noncommuting coordinates of , on which U _q (2) * U _q (2) acts, are realized as q-spinors with respect to each U _q (u(2)) algebra. The representation matrices of U _q (2) are constructed as polynomials in these spinor components. This construction allows a derivation of the commutation relations of the noncommuting coordinates of directly from properties of U _q (u(2)). The generalization of these results to U _q (u(n)) and is also discussed.     

Role of Fe,Mn, and Zn ions as dopants on the electrical conductivity behavior of sodium phosphate glass

Sodium phosphate glass undoped and doped with different concentrations of chlorides of iron, manganese, and zinc were prepared by melt quenching. The synthesized glasses were characterized by elemental analysis, X-ray diffraction, infrared (IR) spectroscopy, differential scanning calorimetry, and electrical conductivity studies. The undoped sodium phosphate glass (Na₂O–P₂O₅) has low electrical conductivity σ compared to all doped glasses except for 10% FeCl₃-doped samples for which σ is found to be the lowest, and the trend is

New quantum groups by double-bosonisation

We obtain new family of quasitriangular Hopf algebras via the author's recent double-bosonisation construction for new quantum groups. They are versions of U _q(su _n+1) with a fermionic rather than bosonic quantum plane of roots adjoined to U _q(su _n). We give the n = 2 case in detail. We also consider the anyonic-double of an anyonic ( ) braided group and the double-bosonisation of the free braided group in n variables.     

PJLZ gauge-fixing approach in SU(2) lattice gauge theory

We study the SU(2) gauge theory with the interpolating gauge a la Parrinello-Jona-Lasinio-Zwanziger (PJLZ) with the gauge-fixing functional $F = \sum {_{x\mu } \frac{1}{2}} Tr\left( {U_{x\mu } \sigma _3 U_{x\mu }^\dag \sigma _3 } \right)$ . We find a strong indication of the nonanaliticity with respect to the interpolating parameter λ at c～0.8.     

Quantum Marginal Inequalities and the Conjectured Entropic Inequalities

A conjecture – the modified super-additivity inequality of relative entropy – was proposed in Zhang et al. (Phys. Lett. A 377:1794–1796, 2013): There exist three unitary operators \(U_{A}\in \mathrm {U}(\mathcal {H}_{A}), U_{B}\in \mathrm {U}(\mathcal {H}_{B})\) , and \(U_{AB}\in \mathrm {U}(\mathcal {H}_{A}\otimes \mathcal {H}_{B})\) such that $$\mathrm{S}\left(U_{AB}\rho_{AB}U^{\dagger}_{AB}||\sigma_{AB}\right)\geqslant \mathrm{S}\left(U_{A}\rho_{A}U^{\dagger}_{A}||\sigma_{A}\right) + \mathrm{S}\left(U_{B}\rho_{B}U^{\dagger}_{B}||\sigma_{B}\right), $$ where the reference state σ is required to be full-ranked. A numerical study on the conjectured inequality is conducted in this note. The results obtained indicate that the modified super-additivity inequality of relative entropy seems to hold for all qubit pairs.     

Laser-diode-excited Blue Upconversion in Tm3+/Yb3+-codoped TeO2-Ga2O3-R2O (R=Li, Na, K) Glasses

This paper reports on intense blue upconversion in Tm³⁺/Yb³⁺ codoped TeO₂-Ga₂O₃-R₂O(R=Li, Na, K) glasses upon excitation with commercial available laser diode (LD). Effects of alkali ions on the Raman spectra, thermal stability and spectroscopic properties of the tellurite-gallium glasses have also been investigated. Energy transfer and the involved upconversion mechanisms have been discussed. Intense blue upconversion emission centered at 476 nm along with a weak red emission at 650 nm has been observed upon excitation of 977 nm LD, assigned to the transitions of , and and/or of Tm³⁺, respectively. The blue upconversion intensity has a cubelike dependence on incident pump laser power, indicating a three-photon process. However, a quadratic dependence of the 476 nm upconversion intensity on the incident pump laser power has been observed when samples under excitation of 808 nm LD due to a two-photon absorption process. Enhanced upconversion luminescence have been observed with replacing K⁺ for Na⁺ and Li⁺.     

Mixed conductivity of glasses in the P2O5-V2O5-Na2O system

The conductivity of glasses in the P₂O₅−[(1−x) V₂O₅−x Na₂O] system is studied as a function of temperature and composition. For all compositions, the conductivity variations as a function of temperature follow an Arrhenius type relationship: . The activation energies and pre-exponential factors corresponding to the V₂O₅ richest compositions are lower than that corresponding to the ionic ones. Isothermal variations of the conductivity as a function of composition show a deep minimum for a molar ratio x near 0.65. On either side of this minimum, the conductivity is mainly electronic (x<0.7) or ionic (x>0.8). The variations are interpreted assuming a prevailing diluting effect of the non predominantly present oxide without any interactions between the electronic and ionic charge carriers. Paper presented at the 5th Euroconference on Solid State Ionics, Benalmádena, Spain, Sept. 13–20, 1998.     

Asymptotic behaviour of particle motion under repulsive forces

The asymptotic nature of motions, as time tends to infinity, is investigated for classical point particles interacting by repulsive two-body potentialsU _ij . It is found that the conditions are necessary and sufficient for asymptotically straight line uniform motion. In the case of equal asymptotic velocities the proof depends only on a certain property of the motion (partial center of mass convexity) implied by the repulsivity of the potentials.The original version of this paper was edited and re-written by A. Lenard from Indiana University. The author expresses his gratitude to Professor Lenard for his work which has significantly improved both the mathematical presentation and the style of the paper     

Minimal affinizations of representations of quantum groups: the irregular case

Let be a finite-dimensional complex simple Lie algebra and U_q( ) the associated quantum group (q is a nonzero complex number which we assume is transcendental). IfV is a finitedimensional irreducible representation of U_q( ), an affinization ofV is an irreducible representationVV of the quantum affine algebra U_q( ) which containsV with multiplicity one and is such that all other irreducible U_q( )-components ofV have highest weight strictly smaller than the highest weight ofV. There is a natural partial order on the set of U_q( ) classes of affinizations, and we look for the minimal one(s). In earlier papers, we showed that (i) if is of typeA, B, C, F orG, the minimal affinization is unique up to U_q( )-isomorphism; (ii) if is of typeD orE and is not orthogonal to the triple node of the Dynkin diagram of , there are either one or three minimal affinizations (depending on ). In this paper, we show, in contrast to the regular case, that if U_q( ) is of typeD ₄ and is orthogonal to the triple node, the number of minimal affinizations has no upper bound independent of .As a by-product of our methods, we disprove a conjecture according to which, if is of typeA _n,every affinization is isomorphic to a tensor product of representations of U_q( ) which are irreducible under U_q( ) (in an earlier paper, we proved this conjecture whenn=1).Both authors were partially supported by the NSF, DMS-9207701.     

Quantum conformal superspace

For a compact connected orientablen-manifoldM, n 3, we study the structure ofclassical superspace ,quantum superspace ,classical conformal superspace , andquantum conformal superspace . The study of the structure of these spaces is motivated by questions involving reduction of the usual canonical Hamiltonian formulation of general relativity to a non-degenerate Hamiltonian formulation, and to questions involving the quantization of the gravitational field. We show that if the degree of symmetry ofM is zero, thenS,S ₀,C, andC ₀ areilh orbifolds. The case of most importance for general relativity is dimensionn=3. In this case, assuming that the extended Poincaré conjecture is true, we show that quantum superspaceS ₀ and quantum conformal superspaceC ₀ are in factilh-manifolds. If, moreover,M is a Haken manifold, then quantum superspace and quantum conformal superspace arecontractible ilh-manifolds. In this case, there are no Gribov ambiguities for the configuration spacesS ₀ andC ₀. Our results are applicable to questions involving the problem of thereduction of Einstein's vacuum equations and to problems involving quantization of the gravitational field. For the problem of reduction, one searches for a way to reduce the canonical Hamiltonian formulation together with its constraint equations to an unconstrained Hamiltonian system on a reduced phase space. For the problem of quantum gravity, the spaceC ₀ will play a natural role in any quantization procedure based on the use of conformal methods and the reduced Hamiltonian formulation.     

<Emphasis Type="Italic">U</Emphasis>(2) and minimal flavour violation in supersymmetry

Rather than sticking to the full U(3)³ approximate symmetry normally invoked in Minimal Flavour Violation, we analyze the consequences on the current flavour data of a suitably broken U(2)³ symmetry acting on the first two generations of quarks and squarks. A definite correlation emerges between the ΔF=2 amplitudes \(\mathcal{M}( K^{0} \to \bar{K}^{0} )\), \(\mathcal{M}( B_{d} \to \bar{B}_{d} )\) and \(\mathcal{M}( B_{s} \to \bar{B}_{s} )\), which can resolve the current tension between \(\mathcal{M}( K^{0} \to \bar{K}^{0} )\) and \(\mathcal{M}( B_{d} \to \bar{B}_{d} )\), while predicting \(\mathcal{M}( B_{s}\to \bar{B}_{s} )\). In particular, the CP violating asymmetry in B _s →ψφ is predicted to be positive S _ψφ =0.12±0.05 and above its Standard Model value (S _ψφ =0.041±0.002). The preferred region for the gluino and the left-handed sbottom masses is below about 1÷1.5 TeV. An existence proof of a dynamical model realizing the U(2)³ picture is outlined.     

The electrochemical properties of LaAl12O18N

The ceramic material LaAl₁₂O₁₈N which adopts the magnetoplumbite type structure was prepared by a high temperature sintering technique from La₂O₃, α-Al₂O₃ and AlN powders under a controlled atmosphere. Phase purity was confirmed by powder XRD and IR spectroscopy. Impedance spectroscopy data from a ceramic disc of LaAl₁₂O₁₈N revealed an intra-granular ionic (La³⁺) conductivity (≈3×10^?5 Scm^?1 at 1540 K) with an activation energy E_a=1.6 eV and a dielectric constant ?=56. The ionic conductivity at 1540 K is comparable to an extrapolated value for the divalent material; Sr-Li-β-alumina. Since LaAl₁₂O₁₈N can be considered as a quasi-binary compound (LaN·6Al₂O₃), it was shown to act simultaneously as an electrolyte and a nitrogen-sensing phase at high temperature. The key electrochemical reaction in terms of dinitrogen gas is: $$La^{3 + } \left( {LaAl_{12} O_{18} N} \right) + 3e^ - + {1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}N_2 \left( g \right) + 6\alpha - Al_2 O_3 \to LaAl_{12} O_{18} N.$$ . Positive e.m.f. measurements at high temperature across the following cell: $$Nb,Nb_2 N,\alpha - Al_2 O_3 \left| {LaAl_{12} O_{18} N} \right|\alpha - AL_2 O_3 ,Nb_2 N,Nb_4 N_3 ,$$ , were in agreement withP _N2(Nb₂N,Nb₄N₃)>P _N2(Nb, Nb₂N) for the idealised cell reaction; Nb₄N₃+ 2Nb → 3Nb₂N, thus demonstrating the nitrogen-sensing property of this cell. The e.m.f. for a variety of cells with electrodes containing the sub-nitrides of vanadium, niobium, tantalum and titanium were consistent with the predicted equilibrium nitrogen partial pressures.     

High scale perturbative gauge coupling in R-parity conserving SUSY <Emphasis Type="Italic">SO</Emphasis>(10) with longer proton lifetime

It is well known that in single step breaking of R-parity conserving SUSY SO(10) that needs the Higgs representations , the GUT gauge coupling violates the perturbative constraint at mass scales a few times larger than the GUT scale. Therefore, if the SO(10) gauge coupling is to remain perturbative up to the Planck scale ( GeV), the scale M_U of the GUT symmetry breaking is to be bounded from below. The bound depends upon specific Higgs representations used for SO(10) symmetry breaking but, as we find, cannot be lower than $1.5 \times 10$¹⁷ GeV. In order to obtain such a high unification scale we propose a two-step SO(10) breaking through SU(2)_L $\times$ SU(2)_R $\times$ U(1)_B-L $\times$SU(3)_C ( ) intermediate gauge symmetry. We estimate the potential threshold and gravitational corrections to the gauge coupling running and show that they can make the picture of perturbative gauge coupling running consistent at least up to the Planck scale. We also show that when by the Higgs representations , gravitational corrections alone with negligible threshold effects may guarantee such perturbative gauge coupling. The lifetime of the proton is found to increase by nearly 6 orders over the present experimental limit for . For the proton decay mediated by a dim = 5 operator a wide range of lifetimes is possible, extending from the current experimental limit up to values 2-3 orders longer. Received: 1 July 2005, Revised: 21 August 2005, Published online: 11 October 2005     

Pyroxene inclusions in paleo-Christian mosaic tesserae: a new tool for constraining the glass manufacturing temperature

The mineral inclusions of two orange glass tesserae from paleo-Christian mosaics were investigated in order to derive the melting temperature reached during their production (sourced from Padua and Vicenza, Veneto region, Italy). In particular, clinopyroxene crystals were studied by single-crystal X-ray diffraction and electron microprobe WDS analysis. The crystals show C2/c symmetry, typical of disordered Ca/Na and Mg/Al distributions indicating high-temperature of formation (>700°C). The cation site populations were obtained by combining results from the two experimental techniques enabled us to derive the following stoichiometric formula:

Update of electroweak parameters fromZ decays

Based on 520 000 fermion pairs accumulated during the first three years of data collection by the ALEPH detector at LEP, updated values of the resonance parameters of theZ are determined to beM _Z =(91.187±0.009) GeV, _Z =(2.501±0.012) GeV, _had ⁰ =(41.60±0.27) nb, andR =20.78±0.13. The corresponding number of light neutrino species isN =2.97±0.05. The forward-backward asymmetry in lepton-pair decays is used to determine the ratio of vector to axial-vector couplings of leptons:g _V ² (M _Z ² )/g _A ² (M _Z ² )=0.0052±0.0016. Combining this with ALEPH measurements of theb andc quark asymmetries and polarization gives sin² _W ^eff =0.2326±0.0013. Assuming the minimal Standard Model, and including measurements ofM _W /M _Z fromp colliders and neutrino-nucleon scattering, the mass of the top quark is GeV.Deceased     

Paramagnetische Resonanz an Einkristallen einiger Selten-Erd-Oxide

The paramagnetic resonance of Nd³⁺ in Y₂O₃ has been measured at 4.2°K and 9.25 kMe/s. The values of theg-tensors are: ions onC _3i -sites:g _∥=2.434±0.007;g _⊥=0.702±0.005; ions onC ₂-sites:g _x =4.395±0.012;g _y =0.433±0.009;g _z =1.648±0.006. Further measurements have been performed on La₂O₃ crystals doped with Ce³⁺, Dy³⁺, and Er³⁺; the results are (C _3v -sites only): .      

Uncertainty Relation on Generalized Skew Information with aMonotone Pair

In this paper, we first define a generalized (f,g)-skew information \(\left |I_{ \rho }^{(f, g)}\right |(A)\) and two related quantity \(\left |J_{ \rho }^{(f, g)}\right |(A)\) and \(\left |U_{ \rho }^{(f, g)}\right |(A)\) for any non-Hermitian Hilbert-Schmidt operator A and a density operator ρ on a Hilbert space H and discuss some properties of them. And then, we obtain the following uncertainty relation in terms of \(\left |U_{ \rho }^{(f, g)}\right |(A)\):

$$\begin{array}{@{}rcl@{}} \left|U_{ \rho}^{(f, g)}\right|(A)\left|U_{ \rho}^{(f, g)}\right|(B)\geq \beta_{(f, g)}\left|Tr\left( f(\rho)g(\rho)[A, B]^{0}\right)\right|^{2}, \end{array} $$

which is a generalization of a known uncertainty relation in Ko and Yoo (J. Math. Anal. Appl. 383, 208–214, 11).

     

A Note on Quantum Coherence

In this paper, we discuss the coherence of the reduced state in system H _A ?H _B under taking different quantum operations acting on subsystem H _B . Firstly, we show that for a pure bipartite state, the coherence of the final subsystem H _A under the sum of two orthonormal rank 1 projections acting on H _B is less than or equal to the sum of the coherence of the state after two orthonormal projections acting on H _B , respectively. Secondly, we obtain that the coherence of reduced state in subsystem H _A under random unitary channel \({\Phi }(\rho )={\sum }_{s}\lambda _{s}U_{s}\rho U_{s}^{\ast }\) acting on H _B , is equal to the coherence of the state after each operation \({\Phi }_{s}(\rho )=\lambda _{s}U_{s}\rho U_{s}^{\ast }\) acting on H _B for every s. In addition, for general quantum operation \({\Phi }(\rho )={\sum }_{s}F_{s}\rho F_{s}^{\ast }\) on H _B , we get the relation

$$ C\left (\left ((I\otimes {\Phi })\rho ^{AB}\right )^{A}\right )\leq \sum \limits _{s}C\left (\left ((I\otimes {\Phi }_{s})\rho ^{AB}\right )^{A}\right ). $$