Optical Properties of a New Two-photon Absorption Dye DEASPI

1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｔｗｏ ｐｈｏｔｏｎａｂｓｏｒｐｔｉｏｎ (ＴＰＡ)ｉｓａｐｒｏｃｅｓｓｉｎｗｈｉｃｈｔｗｏｐｈｏｔｏｎｓａｒｅｓｉｍｕｌｔａｎｅｏｕｓｌｙａｂｓｏｒｂｅｄｔｏａｎｅｘｃｉｔｅｄｓｔａｔｅｉｎａｍｅｄｉｕｍｖｉａａｖｉｒｔｕａｌｓｔａｔｅ .ＴＰＡｉｎｔｅｎｓｉｔｙｉｓｃｈａｒａｃｔｅｒｉｚｅｄｂｙＴＰＡｃｒｏｓｓｓｅｃｔｉｏｎ .ＳｕｃｈｍａｔｅｒｉａｌｓｗｉｔｈｌａｒｇｅＴＰＡｃｒｏｓｓｓｅｃｔｉｏｎｈａｖｅｒｅｃｅｉｖｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｔｅｎｔｉｏｎｉ…     

Introduction to Authors

ＡｉｍｓａｎｄｓｃｏｐｅＨＩＧＨＥＮＥＲＧＹＰＨＹＳＩＣＳＡＮＤＮＵＣＬＥＡＲＰＨＹＳＩＣＳｃｏｖｅｒｓｔｈｅｆｉｅｌｄｓｏｆＨｉｇｈＥｎｅｒｇｙＰｈｙｓｉｃｓ,Ｃｏｓｍｉｃ ＲａｙＰｈｙｓｉｃｓ,ＨｉｇｈＥｎｅｒｇｙＡｓｔｒｏｐｈｙｓｉｃｓ,ＩｎｔｅｒｍｅｄｉａｔｅＥｎｅｒｇｙＰｈｙｓｉｃｓ,ＮｕｃｌｅａｒＰｈｙｓｉｃｓ,ＨｅａｖｙＩｏｎＰｈｙｓｉｃｓ,Ａｃｃｅｌｅｒａｔｏｒ,Ｄｅｔｅｃ ｔｏｒａｎｄＳｙｎｃｈｒｏｔｒｏｎｒａｄｉａｔｉｏｎｉｎｔｈｅａｓｐｅｃｔｓｏｆｅｘｐｅｒｉｍｅｎｔｓ,ｔｈｅｏｒｉ…     

Observation of Single-slope Quasistatic Wings of Laser Induced Collision Energy Transfer

1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｌａｓｅｒ ｉｎｄｕｃｅｄｃｏｌｌｉｓｉｏｎｅｎｅｒｇｙｔｒａｎｓｆｅｒ(ＬＩＣＥＴ)ｉｓａｎｏｐｔｉｃａｌｐｈｅｎｏｍｅｎｏｎｉｎｖｏｌｖｉｎｇｔｈｅｓｉｍｕｌｔａｎｅｏｕｓｉｎｔｅｒａｃｔｉｏｎｓｏｆｂｏｔｈｔｈｅｌａｓｅｒｆｉｅｌｄａｎｄｃｏｌｌｉｓｉｏｎ[1～ 3 ] .ＴｈｉｓＬＩＣＥＴｒｅａｃｔｉｏｎｃａｎｂｅｗｒｉｔｔｅｎａｓ:Ａ Ｂ ｈΩ →Ａ Ｂ (1)Ｄｕｒｉｎｇｔｈｅｃｏｌｌｉｓｉｏｎｏｆａｔｏｍ Ａｗｉｔｈａｔｏｍ Ｂ ,ａｔｏｍＡｇｏｅｓｂａｃｋｔｏｇｒ…     

Wavefront match simulation on receiver surfaces in coherent lidar

ＷａｖｅｆｒｏｎｔｍａｔｃｈｓｉｍｕｌａｔｉｏｎｏｎｒｅｃｅｉｖｅｒｓｕｒｆａｃｅｓｉｎｃｏｈｅｒｅｎｔｌｉｄａｒＺＨＡＯＹｕａｎＳＵＮＤｏｎｇｓｏｎｇＱＩＡＯＬｉｊｉｅＮＡＮＪｉｎｇｄａ（ＤｅｐａｒｔｍｅｎｔｏｆＡｐｐｌｉｅｄＰｈｙｓｉｃｓ，Ｈａ...     

杨振宁对称与物理

杨振宁对称与物理Ａｂｓｔｒａｃｔ：Ｔｈｅｃｏｎｃｅｐｔｏｆｓｙｍｅｔｒｙｉｎｐｈｙｓｉｃｓａｎｄｍａｔｈｅｍａｔｉｓｉｓｉｎｔｒｏｄｕｃｅｄｂａｓｅｄｏｎｔｈｅｃｏｍｍｏｎｉｄｅａａｂｏｕｔｓｙｍｍｅｔｒｙ．Ｉｔｉｓｓｈｏｗｎｔｈａｔｔｈｅｅｆｆｅｃ...     

Novel All Digital Scheme for Open Loop Fiber Optic Gyroscopes

ＮｏｖｅｌＡｌＤｉｇｉｔａｌＳｃｈｅｍｅｆｏｒＯｐｅｎＬｏｏｐＦｉｂｅｒＯｐｔｉｃＧｙｒｏｓｃｏｐｅｓＹＡＮＧＹｕａｎｈｏｎｇ（Ｔｈｅ５ｔｈＲｅｓｅａｒｃｈＤｉｖｉｓｉｏｎｏｆＢｅｉｊｉｎｇＵｎｉｖｅｒｓｉｔｙｏｆＡｅｒｏｎａｕｔｓ＆Ａｓｔｒｏｎａｕ...     

Enhancement of Axial Trapping Force in a Single-beam Gradient Optical Trap by a Pair of Axicons

1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　　ＴｈｅｆｉｒｓｔｗｏｒｋｗｉｔｈｏｐｔｉｃａｌｔｒａｐｐｉｎｇｏｎｓｍａｌｌｐａｒｔｉｃｌｅｓｗｅｒｅｄｏｎｅｂｙＡｓｈｋｉｎｅｔａｌ.ｉｎ1 985ａｎｄ 1 986 [1,2 ] ,Ｗｈｏｓｕｃｃｅｓｓｆｕｌｌｙｄｅｍｏｎｓｔｒａｔｅｄｔｈａｔｍｉｃｒｏｓｃｏｐｉｃｐａｒｔｉｃｌｅｓｃｏｕｌｄｂｅｔｒａｐｐｅｄｂｙａｓｉｎｇｌｅｆｏｃｕｓｓｅｄｌａｓｅｒｂｅａｍ .Ａｎｕｍｂｅｒｏｆｄｅｍｏｎｓｔｒａｔｉｏｎｓｏｆｔｒａｐｐｉｎｇａｎｄｍａｎｉｐｕｌａｔｉｏｎｏｆｂｉｏｌｏｇｉｃａｌ…     

评述文章扫描

1Ｐｈｙｓｉｃｓｉｎｔｈｅｗｈｉｒｌｗｉｎｄｏｆｏｐｔｉｃａｌｃｏｍｍｕｎｉｃａ ｔｉｏｎｓ (ＧｏｒｄｏｎＡ .Ｔｈｏｍａｓ ,ＤａｖｉｄＡ .Ａｃｋｅｒｍａｎ ,ＰａｕｌＲ .Ｐｒｕｃｎａｌｅｔａｌ .Ｐｈｙｓ .Ｔｏｄａｙ ,2 0 0 0 ,Ｎｏ .9)2ＤＮＡ ｉｎｓｐｉｒｅｄｅｌｅｃｔｒｏｓｔａｔｉｃｓ (ＷｉｌｌｉａｍＭ .Ｇｅｌｂａｒｔ ,ＲｏｂｉｊｎＦ .Ｂｒｕｉｎｓｍａ ,ＰｈｉｌｉｐＡ .Ｐｉｎｃｕｓｅｔａｌ .Ｐｈｙｓ .Ｔｏｄａｙ ,2 0 0 0 ,Ｎｏ .9)3Ｈｏｔ ｐｒｏｓｐｅｃｔｓｆｏｒｕｌｔｒａｃｏｌｄｍｏｌｅｃｕｌｅｓ (Ｂ…     

Birefringence of (Al)GaAs/AlGaAs multiplequantum well optical waveguides

Ｂｉｒｅｆｒｉｎｇｅｎｃｅｏｆ（Ａｌ）ＧａＡｓ／ＡｌＧａＡｓｍｕｌｔｉｐｌｅｑｕａｎｔｕｍｗｅｌｌｏｐｔｉｃａｌｗａｖｅｇｕｉｄｅｓ￥ＭＡＣｈｕｎｓｈｅｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＥｌｅｃｔｒｏｎｉｃＥｎｇｉｎｅｅｒｉｎｇ，ＮａｔｉｏｎａｌＩｎｔｅ...     

A Novel OADM Based on Fiber Gratings

1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｏｐｔｉｃａｌａｄｄ/ｄｒｏｐｍｕｌｔｉｐｌｅｘｅｒ (ＯＡＤＭ)ｉｓｔｈｅｋｅｙｃｏｍｐｏｎｅｎｔｏｆｏｐｔｉｃａｌｔｒａｎｓｐｏｒｔｎｅｔｗｏｒｋｓ(ＯＴＮ) .ＭａｎｙＯＡＤＭａｒｃｈｉｔｅｃｔｕｒｅｓｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄ ,ｓｕｃｈａｓｔｈｏｓｅｂａｓｅｄｏｎｗａｖｅｌｅｎｇｔｈｍｕｌｔｉｐｌｅｘｅｒｓ,ａｒｒａｙｅｄｗａｖｅｇｕｉｄｇｒａｔｉｎｇｓ(ＡＷＧ ) ,ａｃｏｕｓｔｏ ｏｐｔｉｃｔｕｎａｂｌｅｆｉｌｔｅｒｓ (ＡＯＴＦ) ,ｆｉｂｅｒＢｒａｇｇ ｇｒａｔｉ…     

金纳米粒子自组装薄膜的光谱学研究

采用柠檬酸钠还原氯金酸制备了金胶体，通过静电自组装制备了金纳米粒子薄膜，利用紫外-可见光吸收光谱等对金纳米粒子薄膜进行了光谱学研究，紫外-可见光吸收光谱表明所制备的金溶胶为单分散体系，根据自组装薄膜的X-射线衍射谱，由谢乐公式估算金纳米粒子的粒径约为21nm；X-射线光电子能谱显示氯金酸的还原反应比较完全，金主要以Au^0的价态存在，金胶体粒子通过静电吸引机制组装到PDDA改性的衬底表面；紫外-可见光吸收光谱和表面增强拉曼光谱显示，由于粒子间的电磁耦合，自组装金纳米粒子薄膜表现出协同等离子体共振吸收行为和表面增强拉曼散射效应。     

An improved self‐assembly gold colloid film as surface‐enhanced Raman substrate for detection of trace‐level polycyclic aromatic hydrocarbons in aqueous solution

To detect trace‐level polycyclic aromatic hydrocarbons, some investigations of an improved self‐assembly method are carried out using gold colloid films for the preparation of the surface‐enhanced Raman scattering (SERS)‐active substrate. Extinction spectra and scanning electron microscopy images reveal that controllable surface plasmonic metal substrates can be obtained by increasing the temperature of (3‐aminopropyl)trimethoxysilane solution up to 64.5 °C. The SERS‐active substrates have a high enhancement factor, and they can be both easily prepared and reproducible. With the use of these substrates, different concentrations of pyrene and anthracene in aqueous solutions were detected by SERS. A further enhancement can be supported by shifted excitation Raman difference spectroscopy. Raman signals of pyrene and anthracene adsorbed on gold colloid substrates up to limits of detection at 5 and 1 nmol/l, respectively, can be obtained. The quantitative analysis shows the possibility of in situ detection of polycyclic aromatic hydrocarbons while such gold colloid film serves as a SERS‐active substrate. Copyright © 2012 John Wiley & Sons, Ltd.     

An acoustically enhanced gold film Raman sensor on a lithium niobate substrate

The surface enhanced Raman scattering effect has shown immense potential for detecting trace amounts of explosive vapor molecules. To date, efforts to produce a commercially available, reliable SERS sensor have been impeded by an inability to separate the electromagnetic enhancement produced by the metallic nanostructure from other signal enhancing effects. Here, we show a new Raman sensor that uses surface acoustic waves (SAWs) to produce controllable surface structures on gold films deposited on LiNbO₃ substrates that modulate the Raman signal of a target compound (thiophenol) adsorbed on the films. We demonstrate that this sensor can dynamically control the Raman signal simply by changing the SAW's amplitude, allowing the Raman signal enhancement factor to be directly measured with no variation in the concentration of the target compound. The physically adsorbed molecules can be removed from the sensor without physical cleaning or damage, making it possible to reuse it for real‐time Raman detection. Copyright © 2014 John Wiley & Sons, Ltd.     

金纳米空心半球壳膜的可调谐光学性质研究

以单层聚苯乙烯微球阵列为模板,通过控制其表面金膜蒸镀时间,制备了具有不同厚度的空心半球壳结构的金纳米膜.利用扫描电子显微镜和自制光谱仪分别测量了金膜表面形貌和其透射光谱,并分析了金膜形貌与其光学性质间的关系,同时以4-巯基苯胺为探针分子测定了金膜的表面增强喇曼散射效应.结果表明,该金纳米膜的表面等离子体共振波长随膜厚度增大而发生红移,在可见与近红外波段较宽范围内可调谐,并且,当金膜共振波长与入射激发光波长较近时,探针分子可产生出较强的表面增强喇曼信号.同时,对该现象的产生机制也进行了理论解释.     

Multiscale electromagnetic SERS enhancement on self‐assembled micropatterned gold nanoparticle films

In this work, we demonstrate a cascaded, multiplicative electromagnetic enhancement effect in surface‐enhanced Raman scattering (SERS) on periodically micropatterned films made of colloidal gold nanoparticles, prepared by a self‐assembly approach, without implying lithography procedures. The multiplicative enhancement effect is obtained by combining surface plasmon near‐field enhancement due to nanoscale features with far‐field photonic coupling by periodic microscale features. The effect is observed for both internal Raman reporters (molecules attached to the Au colloids before their assembly) and external Raman probes (molecules adsorbed on the samples after film assembly). The ability of the patterned films for far‐field light coupling is supported by reflectivity spectra, which present minima/maxima in the visible spectral range. Finite‐difference time‐domain computer simulations of the electric field distribution also support this interpretation. The fabricated dual‐scale SERS substrates exhibit a good spot‐to‐spot reproducibility and time stability, as proved by the SERS response over a time scale longer than 1 month. The experimental demonstration of this cascaded electromagnetic enhancement effect contributes to a better understanding of SERS and can affect future design of SERS substrates. Moreover, such dual‐scale colloidal films prepared by convective self‐assembly can be of general interest for the broader field of nanoparticle‐based devices. Copyright © 2014 John Wiley & Sons, Ltd.     

碳化硅薄膜脉冲激光晶化特性研究

采用XeCl准分子激光对非晶碳化硅(a-SiC)薄膜的脉冲激光晶化特性进行了研究.通过原子力显微镜（AFM）和Raman光谱技术对退火前后薄膜样品的形貌、结构及物相特性进行了分析.结果表明，选用合适的激光能量采用激光退火技术能够实现a-SiC薄膜的纳米晶化.退火薄膜中的纳米颗粒大小随着激光能量密度的增加而增大；Raman谱分析结果显示了退火后的薄膜的晶态结构特性并给出了伴随退火过程存在的物相分凝现象.根据以上结果并结合激光退火特性，对a-SiC的脉冲激光晶化机理进行了讨论. 关键词： 激光退火 晶化 碳化硅     

Selective excitation of surface-enhanced secondary emission from biomolecules by substrates based on thin golden films

Thin (5–30 nm) golden films have been derived by vacuum deposition of gold onto dielectric substrates and subsequent annealing at temperatures of 200–350°C. These films allow selective detection of the desired component (fluorescence or Raman scattering) of the surface-enhanced secondary emission from the same resonantly driven molecule.     

Using surface enhanced Raman scattering to study vibrations of adsorbates on thin metallic overlayers on silver

We have studied the surface enhanced Raman scattering from molecules adsorbed on thin gold overlayers on silver island films. The Raman scattering of gold cyanide species adsorbed on gold overlayers decreases in intensity with gold overlayer thickness between 0.5 – 10 Å . This intensity decrease is consistent with a simple model which takes into account the damping of the electromagnetic resonances of the silver islands by the absorbing gold overlayer. Implications of these findings for the enhancement of Raman scattering from adsorbates on other metals deposited as overlayers on silver will be discussed.     

The role of direct surface interaction in surface enhanced Raman scattering by pyridine and CO on silver

The surface enhanced Raman scattering (SERS) phenomenon due to pyridine on silver and CO on silver in ultra-high vacuum (UHV) has been compared. The study was carried out for two different kinds of silver surfaces, island films and “cold” films on island films. We have reported earlier that it was necessary to warm the samples to about 70K in order to observe the full surface enhanced Raman spectrum when the pyridine was deposited on silver island films on sapphire substrates at liquid He temperatures. We call this the effect of a “low temperature anneal” and the present work indicates that this effect is more general than we originally thought. It has also been found that island films exhibit enhanced Raman scattering for pyridine but not for CO, although “cold” films enhance the Raman scattering of both CO and pyridine. This is the first clear indication that molecular specificity may be a part of the SERS phenomenon. The interpretation of these observations depends critically on our understanding of the SERS phenomenon.     

Au/TiN复合薄膜制备及其表面增强拉曼光谱研究

表面增强拉曼散射光谱(SERS)已用于环境监测、生物医药、食品卫生等领域,而高活性SERS基底是表面增强拉曼散射光谱技术应用的关键。TiN作为新型等离子材料具有较强的SERS性能,同时化学稳定性及生物相容性较好,但其SERS性能不如贵金属金强。该研究采用氨气还原氮化法和电化学沉积法,在TiN薄膜表面沉积贵金属Au纳米颗粒制备出Au/TiN复合薄膜。在Au/TiN复合薄膜中单质Au和TiN两种物相共存;随着电化学沉积时间延长,TiN薄膜表面单质金纳米颗粒数量逐渐增多,金纳米颗粒尺寸增大,颗粒间距减小。由于金与TiN两者的本征表面等离子共振耦合作用,Au/TiN复合薄膜的共振吸收峰发生了偏移。利用罗丹明6G为拉曼探针分子,对Au/TiN复合薄膜进行SERS性能分析,发现Au/TiN复合薄膜上的R6G探针分子的拉曼峰信号强度随沉积时间延长呈现先增大后减小的规律;当电化学沉积时间为5 min时,R6G拉曼信号峰较高,复合薄膜样品的SERS活性最大。将Au/TiN复合薄膜和Au薄膜分别浸泡在10-3,10-5,10-7,10-8及10-9 mol·L-1 R6G溶液5 min,进行检测限分析,发现Au/TiN复合薄膜检测极限达10-8 mol·L-1,增强因子达到8.82×105,与Au薄膜和TiN薄膜相比,Au/TiN复合薄膜上对R6G探针分子SERS活性最高。这得益于Au/TiN复合膜中表面等离子体产生的耦合效应,使得局域电磁场强度增强,从而引起R6G探针分子拉曼信号增强。通过2D-FDTD模拟电场分布发现Au/TiN,Au及TiN薄膜具有电场增强作用,其中Au/TiN复合薄膜的增强作用尤为显著,这也证实了氮化钛与金纳米颗粒之间存在耦合效应。另外发现TiN与Au之间可能存在电荷转移,促进了4-氨基苯硫酚氧化反应,进而证实了TiN与Au薄膜的协同作用。此外,Au/TiN复合薄膜均匀性较好,相对平均偏差仅为7.58%。由此可见,采用电化学沉积制备的Au/TiN复合薄膜具有作为SERS基底材料的应用潜力。