热辐射对热团簇衰变率和丰度的影响

本文量化了辐射冷却对单分子衰变速率、热簇以及非特定激发能量的分子的影响.检测出两种不同的区域,可以通过发射光子的能量大小进行定义,并根据光子发射速率常数和颗粒的热性质确定它们之间的边界.此外,通过丰度光谱计算了相当于小光子能量的连续冷却情况.两种不同区域分别是连续性冷却和单分子衰变的单光子猝灭.辐射效应通过重新定义每个单独的团簇用于进行蒸发的时间进行参数化,可用有效辐射时间常数来表示.     

Ion spectrum under excitation of a cluster beam by a laser pulse

A model describing the decay dynamics of large charged clusters formed during the interaction of a short laser pulse with a cluster beam is constructed. It is shown that the dynamics of the evolution of the cluster plasma and the energy spectrum of ions are affected by the presence of the decay products from neighboring clusters and the electron background due to ionization. The parameters of the plasma being formed are determined as functions of the cluster beam and laser pulse parameters.     

Electron emission from laser-irradiated atomic clusters

The mechanism of fast-electron emission from laser-irradiated clusters is studied by model calculations. Rescattering of electrons at the charged cluster is shown to be an important process. In contrast to rescattering at atoms, the structure, that is the size and strength, of the scattering potential determines final kinetic energies of the electrons. This becomes evident in a strong cluster-size dependence of the electron spectra.     

EICO measurements of inner-core excited mixed rare-gas clusters

The spectra of deep inner-core excited mixed rare-gas clusters were recorded by using electron ion coincidence (EICO) and multi-hit momentum imaging (MHMI) techniques. The EICO spectra for Ar₉₉Kr₁ clusters reveal that singly charged ions are emitted from the inner-core excited clusters in addition to the multiple charged ions. The dependence of the EICO spectra on photon energy and cluster size suggests that the holes created through vacancy cascade on the krypton atoms are transferred to the surrounding atoms, and that the singly charged ions are the primary product of the krypton photoabsorption. Charge localization is suggested for the inner-core excited mixed rare-gas clusters from the analysis of the EICO peak width. The MHMI measurements give us direct evidence for the strong charge migration from X-ray absorbing atoms to surrounding atoms. The photon energy dependence of the PSD image for fragment ions suggests that the momentum of the fragment ions depends on the number of charges generated by the vacancy cascade.     

Yields and ionization probabilities of sputtered Inn particles under atomic and polyatomic Aum ion bombardment

The emission of neutral and charged atoms and clusters from a polycrystalline indium surface under bombardment with 5 and 10 keV Au, Au₂, Au₃ and Au₅ projectiles was investigated. Single photon laser postionization was utilized for the detection of sputtered neutral particles. Secondary ions were detected without the laser under otherwise exactly the same experimental conditions. The relative cluster yields were found to be enhanced under polyatomic projectile bombardment, more so the larger the number of atoms in the sputtered cluster. The ionization probability strongly increases with increasing cluster size, but is essentially independent of the projectile impact energy. At a fixed impact energy, the ionization probability of sputtered monomers was found to decrease with increasing number of constituent gold atoms per projectile, but there was no detectable effect for sputtered dimers and larger clusters.     

Multi-Cluster Decay of Atomic Nuclei

The decay of unstable nuclei which disintegrate with simultaneous emission of few charged fragments is studied. The decay scenario is determined by means of consideration of the Coulomb-correlated quasi-classical motion of outgoing clusters in the sub-barrier region. It is shown that the special solutions which describe the self-similar expansion are particularly important to describe penetration through a multi-dimensional potential barrier. The correlated motion of outgoing particles at the final stage of sub-barrier penetration leads to the energy and angular correlations of emitted particles.     

Magic clusters Na57 - and Na59 +

The electronic structure of positively charged sodium cluster with 59 atoms and negatively charged sodium cluster with 57 atoms (both having 58 electrons) have been studied using an ab initio molecular dynamics method. Although the geometries of both clusters are nearly spherical, the results show differences in the electronic shells.     

Rescattering for extended atomic systems

Laser-driven rescattering of electrons is the basis of many strong-field phenomena in atoms and molecules. Here, we will show how this mechanism operates in extended atomic systems, giving rise to effective energy absorption. Rescattering from extended systems can also lead to energy loss, which in its extreme form results in nonlinear light-induced trapping. Intense-laser interaction with atomic clusters is discussed as an example. We explain fast electron emission, seen in experimental and numerically obtained spectra, by rescattering of electrons at the highly charged cluster.     

Possible Realization of Cluster States and Quantum Information Transfer in Cavity QED via Raman Transition

We present a scheme to generate cluster states with many scheme, no transfer of quantum information between the atoms in cavity QED via Raman transition. In this atoms and cavities is required, the cavity fields are only virtually excited and thus the cavity decay is suppressed during the generation of cluster states. The atoms are always populated in the two ground states. Therefore, the scheme is insensitive to the atomic spontaneous emission and cavity decay. We also show how to transfer quantum information from one atom to another.     

Emission of charged clusters during metal sputtering by ions

A method for simulating processes of metal sputtering by ion bombardment in the form of large neutral and charged clusters with a number of atoms N≥5 based on simple physical assumptions and in fair agreement with experiment is suggested. As an example, the ionization degrees and ionization coefficients, as well as the relative cluster yields, are calculated as a function of the number of atoms in clusters of different metals (Ag, Nb, and Ta) bombarded by singly charged Ar⁺¹ and Au⁻¹ ions. A fluctuation mechanism of charge state formation for large clusters, which describes the dependence of the charge state distributions on cluster size and target temperature, is developed.     

Radiative relaxation in 2p-excited argon clusters

The emission of ultraviolet fluorescence radiation from variable size argon clusters is investigated with high spectral resolution in the Ar 2p-excitation regime. The fluorescence excitation spectra reveal strong fluorescence intensity in the Ar 2p-continuum, but no evidence for the occurrence of discrete low-lying core-exciton states in the near-edge regime. This finding is different from the absorption and photoionization cross section of argon clusters and the solid. The dispersed fluorescence shows a broad molecular band centered near 280 nm. The present work indicates that double and triple ionization via the LMM-Auger decay are required to initiate the fluorescence processes in the Ar 2p-continuum. The present results are consistent with the formation of singly charged, excited moieties within the clusters, which are assigned as sources of the radiative emission in the 280 nm regime. A fast energy transfer process (interatomic Coulombic decay (ICD)), which has been proposed by recent theoretical work, is assigned to be primarily the origin of these singly charged, excited cations besides intra-cluster electron impact ionization by the Auger electrons. Our findings give first possible experimental evidence for ICD in the core level regime.     

Coulombic energy transfer and triple ionization in clusters

Using neon and its dimer as a specific example, it is shown that excited Auger decay channels that are electronically stable in the isolated monomer can relax in a cluster by electron emission. The decay mechanism, leading to the formation of a tricationic cluster, is based on an efficient energy-transfer process from the excited, dicationic monomer to a neighbor. The decay is ultrafast and expected to be relevant to numerous physical phenomena involving core holes in clusters and other forms of spatially extended atomic and molecular matter.     

Core-electron binding energies in free and supported metal clusters

Core-electron binding energy shifts in free and supported clusters are discussed using the Born-Haber formalism. For grounded clusters this approach shows that the shift reflects the decrease in the average atomic cohesive energy of the cluster relative to that of the bulk metal. This shift is closely related to the surface-atom core level shift. For free clusters there is a second term reflecting the unit charge left on the cluster by the emission of the photoelectron. In small clusters this term results in the suppression of conduction electron screening. Clusters supported on amorphous carbon remain charged in the final-state, and are similar to free clusters, but have smaller shifts because the substrate reduces the energy of the final state by forming an image charge. The shift in monolayer islands on metallic substrates is determined largely by the adsorption enthalpy of the adatoms.     

II. The intermediate velocity source in the 40Ca + 40Ca reaction at Elab = 35AMeV

The shape of the velocity distributions of charged particles projected on the beam direction can be explained if emissions from the hot projectile-like fragment and the target-like fragment are supplemented by an emission from an intermediate velocity source located between them. The creation of this source is predicted by a two-stage reaction model where, in the second stage, some of the nucleons identified in the first stage as participants form a group of clusters located in the region between the colliding nuclei. The cluster coalescence process is governed on the average by the maximum value of entropy, although its fluctuations are also significant. The properties of the intermediate velocity source are precisely described, including the isotopic composition of the emitted particles. Received: 12 March 2001 / Accepted: 20 June 2001     

Femtosecond interatomic Coulombic decay in free neon clusters: large lifetime differences between surface and bulk

A quantitative determination of 2s vacancy lifetimes in surface and bulk atoms of free Ne clusters has been made. While for free atoms the 2s inner-valence hole has a ps lifetime, it reduces to 6+/-1 fs for cluster bulk atoms. For surface atoms, the lifetime is on average longer than 30 fs. The lifetime estimate was obtained from fits of high-resolution photoelectron spectra of Ne clusters. The shortening of the lifetime is attributed to the coordination dependent interatomic Coulombic decay, which is extremely sensitive to internuclear distances.     

Influence of kinematical constraints on multiplicity distributions and neutral charged correlations in the independent cluster emission model

Energy-momentum conservation in the cluster production process is introduced in the independent cluster emission model using the generating functional formalism. In a simple version of the model clusters are produced which decay into a fixed number of pions. The ?? model and a model with isospin conservation in the cluster decay are used to calculate the charge distribution among the secondaries of cluster decay. Multiplicity characteristics like average multiplicity, second moments and associated average neutral multiplicities and second moments are calculated. The results are compared with experimental data.     

Production and investigation of multiply charged metal clusters in a Penning trap

Singly charged gold cluster ions from a laser-vaporization source are transferred into a Penning trap and subjected to electron bombardment. The charged reaction products are analyzed by time-of-flight mass spectrometry after axial ejection from the trap. They include singly charged cluster fragments, multiply charged clusters of the initial size and multiply charged cluster fragments. The multiply charged clusters are selected and further investigated by collision induced dissociation. Two types of reactions can be distinguished: Dissociation into several charged fragments and evaporation of neutrals. Several features of multiply charged clusters relevant for future investigations are reviewed.This work comprises part of the dissertation of J. Ziegler.     

Charged particle correlations in\bar pp collisions at c.m. energies of 200, 546 and 900 GeV

We present data on two-particle pseudorapidity and multiplicity correlations of charged particles for non single-diffractive \(p\bar p - collisions\) at c.m. energies of 200, 546 and 900 GeV. Pseudorapidity correlations interpreted in terms of a cluster model, which has been motivated by this and other experiments, require on average about two charged particles per cluster. The decay width of the clusters in pseudorapidity is approximately independent of multiplicity and of c.m. energy. The investigations of correlations in terms of pseudorapidity gaps confirm the picture of cluster production. The strength of forward-backward multiplicity correlations increases linearly with ins and depends strongly on position and size of the pseudorapidity gap separating the forward and backward interval. All our correlation studies can be understood in terms of a cluster model in which clusters contain on average about two charged particles, i.e. are of similar magnitude to earlier estimates from the ISR.