Carrier-envelope phase dependence of the duration of generated solitons for few-cycle rectangular laser pulses propagation

We investigate the nonlinear propagation of few-cycle rectangular laser pulses on resonant intersubband transitions in semiconductor quantum wells using an iterative predictor–corrector finite-difference time-domain method. An initial 2π rectangular pulse will split into Sommerfeld–Brillouin precursors and a self-induced transparency soliton during the course of propagation. The duration of generated soliton depends on the carrier-envelope phase of the incident pulse. In our case, not only the near-resonant frequency components but also the low frequency components could contribute to the generation of the soliton pulse when the condition of multi-photon resonance is satisfied. The phase-sensitive property of the solitons results from the phase-dependent distribution of high and low frequency sidebands of few-cycle rectangular pulses.     

Phase-dependent loss due to nonadiabatic ionization by sub-10-fs pulses

For the first time to the author's knowledge, the effect of phase-dependent loss that can be used to stabilize the phase of a sub-10-fs laser pulse with respect to the envelope is shown. This loss is caused by the nonadiabatic response of an atom illuminated by a short pulse, which leads to the dependence of the tunneling ionization on the absolute phase of the pulse. The phase selectivity can be employed as a phase-dependent filter within the laser cavity with important applications in nonlinear optics in the single-cycle regime.     

Carrier-envelope phase dependence of few-cycle ultrashort laser pulse propagation in a polar molecule medium

We theoretically investigate carrier-envelope phase dependence of few-cycle ultrashort laser pulse propagation in a polar molecule medium. Our results show that a soliton pulse can be generated during the two-photon resonant propagation of few-cycle pulse in the polar molecule medium. Moreover, the main features of the soliton pulse, such as pulse duration and intensity, depend crucially on the carrier-envelope phase of the incident pulse, which could be utilized to determine the carrier-envelope phase of a few-cycle ultrashort laser pulse from a mode-locked oscillator.     

Accurate determination of the absolute phase and temporal-pulse phase of few-cycle laser pulses

A Fourier analysis method is used to accurately determine not only the absolute phase but also the temporal-pulse phase of an isolated few-cycle (chirped) laser pulse. This method is independent of the pulse shape and can fully characterize the light wave even though only a few samples per optical cycle are available. It paves the way for investigating the absolute phase-dependent extreme nonlinear optics, and the evolutions of the absolute phase and the temporal-pulse phase of few-cycle laser pulses.     

Effective dipolar couplings determined by dipolar dephasing of double-quantum coherences

It is shown how homonuclear distances and homonuclear dipolar lattice sums between spin-1/2 nuclei can be measured by a pulsed solid-state NMR experiment under magic-angle spinning conditions. The presented technique is based on double-quantum coherence filtering. Instead of measuring a build-up of double-quantum coherence the pulse sequence is designed to dephase double-quantum coherence. This is achieved by exciting double-quantum coherence either with the help of the through-space dipolar coupling or the through-bond dipolar coupling while the dephasing relies on the through-space dipolar coupling as selected by a gamma-encoded pulse sequence from the C/R symmetry class. Since dephasing curves can be normalized on zero dephasing, it is possible to analyze the initial dephasing regime and hence determine dipolar lattice sums (effective dipolar couplings) in multiple-spin systems. A formula for the effective dipolar coupling is derived theoretically and validated by numerical calculations and experiments on crystalline model compounds for (13)C and (31)P spin systems. The double-quantum dephasing experiment can be combined with constant-time data sampling to compensate for relaxation effects, consequently only two experimental data points are necessary for a single distance measurement. The phase cycling overhead for the constant-time experiment is minimal because a short cogwheel phase cycle exists. A 2D implementation is demonstrated on [(13)C(3)]alanine.     

Two Simple NMR Experiments for Measuring Dipolar Couplings in Asparagine and Glutamine Side Chains

Residual dipolar couplings are now widely used for structure determination of biological macromolecules. Until recently, the main focus has been on measurement of dipolar couplings in the protein main chain. However, with the aim of more complete protein structure, it is also essential to have information on the orientation of protein side chains. In addition, residual dipolar couplings can potentially be employed to study molecular dynamics. In this Communication, two simple NH(2) and spin-state edited experiments are presented for rapid and convenient determination of five residual dipolar couplings from (15)N, (1)H correlation spectrum in asparagine and glutamine side chains. The pulse sequences are demonstrated on two proteins, 30.4-kDa Cel6A in diluted liquid crystal phase and 18-kDa human cardiac troponin C in water.     

Molecular rotation in liquid crystals selective deuterium spin-lattice relaxation times in the nematic mesophase of 4-cyano-4′-d17-n-octylbiphenyl

The Gibbs ensemble is used to simulate the liquid–liquid equilibria of binary mixtures containing dipolar and non-polar components.The interactions of the dipolar fluid are calculated using the Keesom intermolecular potential. The liquid–liquid coexistence properties are reported for different pressures and different combinations of dipolar/non-polar molecules. The critical properties of the mixtures are estimated. The ability of a dipole to induce phase separation is influenced by the dispersion energy of the molecule. Phase separation is enhanced if the dipolar molecule is also the component with the greatest dispersion energy.     

超短脉冲激光在有机分子材料中的动力学过程研究

利用从头计算方法，在密度泛函理论上，计算了分子的电子结构和电偶极矩.通过求解麦克斯韦-布洛赫方程，研究了超短脉冲激光与硝基苯胺分子材料的相互作用，着重分析了分子的固有偶极矩对脉冲激光波形、频谱成分以及分子能级占有率产生的影响.研究结果表明，慢变幅近似和旋波近似不能很好地描述超短脉冲在PNA分子介质中传播.分子的固有偶极矩进一步使脉冲传播背离面积定理，引起了脉冲更快地分裂.当脉冲激光在PNA分子介质中以电荷转移态的激发能共振传播时，脉冲激光频谱中明显地出现了二次谐波成分，显示了该分子具有较强的双光子吸收性质. 关键词： 超短脉冲激光 硝基苯胺分子 麦克斯韦-布洛赫方程     

超短激光脉冲驱动的Thomson散射空间分布特性

研究了超短激光脉冲驱动的Thomson散射的辐射空间分布. 发现辐射的空间分布对称性显著地依赖于超短脉冲的载波相位η₀，在η₀＝0，π时，辐射的空间分布呈现出二重或一重对称性；而在其他载波相位时，这些空间分布对称性遭到破坏. 辐射光的准直性也依赖于驱动脉冲的载波相位，在η₀＝±π/2时辐射光的准直性最好. 这些结果表明可以通过改变驱动激光脉冲的载波相位来控制辐射光的空间分布，也可以利用辐射空间分布对相位的依赖特性来测量超短激光脉冲的载波相位. 关键词： Thomson散射 空间分布 载波相位     

Pulse chirping effect on controlling the transverse cavity oscillations in nonlinear bubble regime

The propagation of an intense laser pulse in an under-dense plasma induces a plasma wake that is suitable for the acceleration of electrons to relativistic energies. For an ultra-intense laser pulse which has a longitudinal size shorter than the plasma wavelength, λp, instead of a periodic plasma wave, a cavity free from cold plasma electrons, called a bubble, is formed behind the laser pulse. An intense charge separation electric field inside the moving bubble can capture the electrons at the base of the bubble and accelerate them with a narrow energy spread. In the nonlinear bubble regime, due to localized depletion at the front of the pulse during its propagation through the plasma, the phase shift between carrier waves and pulse envelope plays an important role in plasma response. The carrier–envelope phase(CEP) breaks down the symmetric transverse ponderomotive force of the laser pulse that makes the bubble structure unstable. Our studies using a series of two-dimensional(2D) particle-in-cell(PIC) simulations show that the frequency-chirped laser pulses are more effective in controlling the pulse depletion rate and consequently the effect of the CEP in the bubble regime. The results indicate that the utilization of a positively chirped laser pulse leads to an increase in rate of erosion of the leading edge of the pulse that rapidly results in the formation of a steep intensity gradient at the front of the pulse. A more unstable bubble structure, the self-injections in different positions, and high dark current are the results of using a positively chirped laser pulse. For a negatively chirped laser pulse, the pulse depletion process is compensated during the propagation of the pulse in plasma in such a way that results in a more stable bubble shape and therefore, a localized electron bunch is produced during the acceleration process. As a result, by the proper choice of chirping, one can tune the number of self-injected electrons, the size of accelerated bunch and its energy spectrum to the values required for practical applications.     

周期量级飞秒脉冲电场在非线性克尔介质中的传输

采用时间转换法研究了周期量级飞秒脉冲电场在非线性克尔介质中的传输.由于周期量级飞秒脉冲电场的脉宽小于介质拉曼响应的特征时间,在传输过程中脉冲电场会发生剧烈的变形和分裂,并在频谱上观察到了强烈的拉曼感应频移和色散波.由于周期量级脉冲电场依赖于载波包络相位,发现在脉冲电场传输过程中,主脉冲电场和色散波电场的相位线性地依赖于初始脉冲的载波包络相位.     

Spin-State-Selective TPPI: A New Method for Suppression of Heteronuclear Coupling Constants in Multidimensional NMR Experiments

A novel multidimensional NMR pulse sequence tool, spin-state-selective time-proportional phase incrementation (S(3) TPPI), is introduced. It amounts to application of different TPPIs on the two components of doublets so that their frequencies can be manipulated independently. The chief application is for suppression of large heteronuclear one-bond coupling constants in indirect dimensions of multidimensional experiments without interchanging the two transverse magnetization components of doublets as conventional decoupling does, which is advantageous when they relax at different rates such as by partial compensation of dipolar and CSA relaxation contributions. For experimental confirmation we use a sample of (15)N-labeled neural cell adhesion molecule modules 1 and 2, a protein with a molecular weight of about 20 kDa. The new tool is general and can be combined with many multidimensional NMR experiments for proteins.     

Modeling interaction of ultrashort pulses with ENZ materials

In this work, the split-step Fourier method for beam propagation is used to investigate the interaction of ultra-short pulses with epsilon-near-zero materials. The propagation of pulses is governed by the nonlinear Schrödinger equation (NLSE) containing dispersion, gain-bandwidth, self-phase modulation, self-steepening, and absorption parameters. It is found that the intensity profile of the pulse is broadened and the phase of the pulse is shifted by dispersion phenomena. The gain/loss related to the imaginary part of the refractive index causes an increase or decrease in intensity and pulse edge effects. These effects do not favor the steady propagation of the pulse. The self-phase modulation is not noted to appreciably affect the intensity pulse profile. The self-steepening modifies the phase and energy of the pulse during propagation, as well as absorption, which influences the losses by both the linear and nonlinear effects.     

Phase-dependent ionization in the barrier suppression regime

Here the dependence of atomic ionization on the absolute phase of sub-10-fs pulses in the barrier suppression regime is investigated. The results obtained show that it is possible to find a parameter range for the laser pulse where the phase dependence of the ionization after the pulse is a nonoscillating curve with a well defined minimum (or maximum). This effect is explained by a simple model based on the assumption that in this regime the ionization is dominated by the electrons ejected when the field exceeds the critical value for suppression of the Coulomb barrier. These findings can be used to design phase-dependent absorbers with a potential application to stabilize the absolute phase into the cavity of a femtosecond laser, which is of major importance for extreme nonlinear optics.     

Ionization Dynamics of 1D Model Atom in Ultra-Strong lω-2ω Laser Fields

We investigate the ionization dynamics of 1D model atom in ultra-strong dichromatic lω-2ω laser fields with a constant phase difference. We find numerically that both the total ionization and the distribution between forward and backward rates show clear phasedependent character. This phenomenon can be explained by the first-order high frequency Floquet theory. Finally, this phase-dependent character is testified u;ith pulsed laser fields provided the pulse is smoothly (adiabatically) turned on.     

Programming scale-free optics in disordered ferroelectrics

Using the history dependence of a dipolar glass hosted in a compositionally disordered lithium-enriched potassium tantalate niobate (KTN:Li) crystal, we demonstrate scale-free optical propagation at tunable temperatures. The operating equilibration temperature is determined by previous crystal spiralling in the temperature/cooling-rate phase space.     

Homonuclear zero-quantum recoupling in fast magic-angle spinning nuclear magnetic resonance

Solid-state magic-angle-spinning NMR pulse sequences which implement zero-quantum homonuclear dipolar recoupling are designed with the assistance of symmetry theory. The pulse sequences are compensated on a short time scale by the use of composite pulses and on a longer time scale by the use of supercycles. (13)C dipolar recoupling is demonstrated in powdered organic solids at high spinning frequencies. The new sequences are compared to existing pulse sequences by means of numerical simulations. Experimental two-dimensional magnetization exchange spectra are shown for [U-(13)C]-L-tyrosine.     

在采用集总放大器的光孤子优越传输中啁啾的作用

讨论了光孤子传输中，由脉冲包络的相位变化产生的啁啾与孤子传输的关系。数值计算表明，当孤子脉冲收缩、展宽时，啁啾总是改变符号，利用啁啾也可以定出孤子传输的光纤临界长度（即孤子传输中集总放大器的间隔），其效果比用脉宽恢复定出的临界长度要好     

Gouy phase shift for few-cycle laser pulses

We measured for the first time the influence of the Gouy effect on focused few-cycle laser pulses. The carrier-envelope phase is shown to undergo a smooth variation over a few Rayleigh distances. This result is of critical importance for any application of ultrashort laser pulses, including high-harmonic and attosecond pulse generation, as well as phase-dependent effects.     

The role of internal reflection in transskull phase distortion

Phase distortion due to reflection in transcranial ultrasound propagation is investigated. Understanding of these phase-dependent properties is motivated by efforts to construct a reliable prediction model for noninvasive ultrasound therapy in the brain. The present study measures the phase of an ultrasound wave after propagation through an ex vivo human skull and considers the dependence of this phase on reflections between the transducer and the skull surface in addition to reflections within the skull. Experiments are performed using a human calvarium fragment placed between an underwater ultrasonic transducer and a polyvinylidene difluoride hydrophone. Data are presented indicating the ultrasound phase dependence as a function of burst length and the distance of the transducer element from the skull at a driving frequency of 0.5 MHz. Experimental results are compared with predictions obtained from a propagation model which considers transmission at the skull interfaces as well as multiple reflections within the skull. It is concluded that by using short ultrasound bursts a distance may be indicated that beyond which the contributions of transducer reflections on the phase of the propagating wave may be neglected. Additionally, a comparison of the measurements with simulated data supports the contention that for reasonably small incident angles, reflection within the skull causes minimal phase shift.