Trend of extreme precipitation events over China in last 40 years

Using the daily precipitation data of 740 stations in China from 1960 to 2000, the analysis on the variations and distributions of the frequency and the percentage of extreme precipitation to the annual rainfall have been performed in this paper. Results indicate that the percentage of heavy rains （above 25mm/day） in the annual rainfall has increased, while on average the day number of heavy rains has slightly reduced during the past 40 years. In the end of 1970s and the beginning of 1980s, both the number of days with extreme precipitation and the percentage of extreme precipitation abruptly changed over China, especially in the northern China. By moving t test, the abrupt change year of extreme precipitation for each station and its spatial distribution over the whole country are also obtained. The abrupt change years concentrated in 1978-1982 for most regions of northern China while occurred at various stations in southern China in greatly different/diverse years. Besides the abrupt change years of extreme precipitation at part stations of Northwest China happened about 5 years later in comparison with that of the country＇s average.     

Cubic potential models for cluster radioactivity

Cluster radioactivity is a process by which nuclei equal and heavier than the α-particle is emitted spontaneously. The clusters usually emitted in this process are the α-particle, carbon, oxygen, neon, magnesium, silicon etc. When the mass of the cluster becomes comparable with the mass of the daughter, symmetric fission takes place. Thus the cluster radioactivity is an intermediate process between the well known α-decay and the spontaneous fission. In earlier years such cluster radioactivity was found mostly in actinide nuclei like radium, uranium etc. Very recently it has been predicted that such decays are possible in a new region around ¹¹¹Ba. There has been an exciting experimental detection of the emission of ¹²C from ¹¹¹Ba leading to ¹⁰²Sn, which is attracting a lot of attention recently. To study the phenomenon of cluster radioactivity there are various theoretical models in vogue. The existing models generally fall under two categories: the unified fission model (UFM) and the preformed cluster model (PCM). The physics of the UFM and the PCM are completely different. The UFM considers cluster radioactivity simply as a barrier penetration phenomenon in between the fission and the α-decay without worrying about the cluster being or not being preformed in the parent nucleus. In the PCM clusters are assumed to be preborn in a parent nucleus before they could penetrate the potential barrier with a given Q-value. The basic assumption of the UFM is that heavy clusters as well as the α-particle have equal probability of being preformed. In PCM, clusters of different sizes have different probabilities of their being preformed in the parent nucleus. We have developed three fission models during the last decade using the cubic potential for the pre-scission region. The use of these models in the study of cluster radioactivity in both the actinide and barium regions will be discussed in this talk in comparison with the other existing theories.     

中国近1000年旱涝的持续性特征研究

应用中国近531年旱涝指数和近1041年干湿指数,定义干旱(湿润)等级,滑动计算原指数序列各干旱(湿润)等级的出现次数,发现各等级出现的次数与其窗口长度之间均遵循指数分布P_i(x)=Ae^-γx.结合指数分布的数理意义,定义指数特征值γ的倒数λ为描述旱(涝)持续性的尺度因子并对华北和江淮流域旱(涝)发生的持续性特征进行研究.结果表明：旱尺度因子的空间分布表现为由北向南呈带状式波动分布,我国北方地区干旱的持续性相对长江流域要长一些,由北向南三个区的旱尺度因子的均值分别为187,162,182.旱涝指数序列中旱或偏旱(涝或偏涝)相对集中的时段对旱(涝)持续性影响较显著,12世纪末期、13世纪早期、17世纪早期和20世纪末期华北和江淮流域发生时间上同步、空间上尺度较大的极端干旱事件的概率较高,这也从侧面验证了旱涝指数序列中群发现象的存在;华北地区1260—1280年(对应的气候背景为中世纪暖期的末期)的旱涝指数对旱尺度因子的影响较1980—2000年(对应的气候背景为20世纪全球增暖)的情况更显著;1260—1280年这一时段旱或偏旱年数较1980—2000年也要多一些.因此,在气候较暖的时期可能易发生强度大、范围广的同步干旱事件,而近30年的中国北方干旱化可能是自然变率起主导作用下人为变率和自然变率共同作用的结果. 关键词： 旱(涝)尺度因子 持续性 群发性 指数分布     

Interface structure in colored DLA model

We propose a model for the simultaneous diffusion-limited growth of two clusters A and B, where the growth of one cluster screens the growth of the other one. We consider the possibility that the A and B clusters can penetrate into each other in course of their growth in different spatial dimensions and express the conjecture that the A-B boundary is flat in all dimensions. Using an electrostatic analogy, we compute some spatial characteristics of the clusters. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 7, 504–509 (10 October 1996) Published in English in the original Russian journal. Edited by Steve Torstveit.     

中国近58年温度极端事件的区域特征及其与气候突变的联系

运用动力学自相关因子指数Q分析中国温度的时空变化特征,得到8个不同的动力学温度变化特征区：准噶尔区、 东北区、西北区、西南东区、西南西区、华北区、东南区和中南区.初步讨论了这些特征区的年均温度变化和极端温度年出现天数及其与温度突变的关系,以及不同温度段对中国近58年增暖的可能影响.研究结果表明：（1）准噶尔区、东北区等7个温度特征区近58年的年均温和极端高温的年出现天数均表现为增长趋势,极端低温天数则为降低趋势,极端高温的变化与温度增暖呈正相关,与极端低温则呈负相关.同时,北方涛动、南方涛动 关键词： Q指数')" href="#">Q指数 温度段 极端温度 温度突变     

Molecular simulation of LiCl aqueous solutions

Non-primitive LiCl aqueous electrolyte solutions were studied at 1.0, 5.0 and 10.0 M concentrations by molecular dynamics simulations. It was observed that the ion hydration structure is progressively lost with increasing concentration. The ions are aggregated in small clusters at C = 1.0 M. However, at this concentration, two large clusters were detected that are an initial step in an aggregation process. At C = 5.0 M, the highly unstable ion clustering seems to correspond to an intermediary state between low concentration states with poor aggregation and states where the ions are highly aggregated, as observed at C = 10.0 M where almost all the ions are clustered in one cluster. This cluster does not present a crystal-like structure. The high solubility of LiCl in aqueous solutions can consequently be explained as a result of the large radii difference between the anion and the cation that results in the instability of the ionic aggregates, which makes the formation of crystal seeds difficult.     

Structure of small hydrogen nanoclusters containing ortho-molecules

Using the quantum mechanical path integral Monte Carlo method, we simulated parahydrogen clusters (j = 0) and clusters doped with several (up to 6) orthohydrogen molecules (j = 1), with the total number of molecules ranging from 4 to 40 at temperatures of 1.5, 3, and 4.5 K. Some energy parameters (including the chemical potentials) and spatial characteristics of the clusters are found. At a temperature of 1.5 K, as the total number N of molecules in the cluster increases, the chemical potential and the rotational energy of the clusters attain local minima at the same geometrically determined values of N (the magic numbers). The ortho-molecules exhibit a larger probability (compared to the para-molecules) to reside in the central region of the cluster and a smaller probability to be located near its surface. This effect is enhanced as the number of orthohydrogen molecules in the cluster increases, the total number N of molecules grows, or the temperature is lowered.     

小尺寸铜团簇冷却与并合过程中结构变化的原子尺度研究

研究Cu_N（N=57,58,59）熔融铜团簇在冷却过程以及300 K时两个具有二十面体结构Cu₅₅团簇在并合过程中的结构变化.对这些小尺寸团簇的结构变化采用基于嵌入原子方法的正则系综分子动力学进行计算机模拟.通过对模拟结果的分析表明,小团簇的冷却和并合过程存在阶段变化的特点.降温过程中Cu_N（N=57,58,59）团簇的原子运动及其微观结构变化表现出较大差异,由此导致这三类团簇内原子排布的不同,其中Cu₅₉团簇结构的有序程度最低.在两个Cu₅₅团簇并合早期阶段,这两个团簇相接触后发生变形导致原子位置出现较大改变,在随后的并合过程中,原子扩散引起原子局部位置调整导致所并合体系的结构发生变化.远离两个团簇接触区的原子仍保持其并合前的结构. 关键词： 团簇 分子动力学 计算机模拟 表面     

One-dimensional atomic transport by clusters of self-interstitial atoms in iron and copper

Atomic-scale computer simulation has been used to study the thermally activated atomic transport of self-interstitial atoms (SIAs) in the form of planar clusters in pure Cu and f-Fe. There is strong evidence that such clusters are commonly formed in metals during irradiation with high-energy particles and play an important role in accumulation and spatial distribution of surviving defects. An extensive study of the mobility of SIA clusters containing two to 331 interstitials has been carried out using the molecular dynamics simulation technique for the temperature range from 180 to 1200 K. The results obtained show that clusters larger than three to four SIAs are one-dimensionally mobile in both Cu and Fe. Large clusters of more than 100 SIAs in Cu and 300 SIAs in Fe have significantly reduced mobility. The problem of describing one-dimensional (1D) motion in three-dimensional space is discussed. An attempt is made to describe the mobility of SIA clusters within the approximation of 1D diffusion. For clusters in both metals the effective migration energy of 1D diffusion as estimated via the jump frequency of the cluster centre of mass is found to be independent of the number of SIAs in the clusters, although the cluster jump frequency decreases with increasing cluster size. Mechanisms of 1D mobility of interstitial clusters are discussed.     

Cluster Structure of Liquid Alcohols,Water, and <Emphasis Type="Italic">n</Emphasis>-Hexane

The processes of cluster formation in liquid alcohols, water, methanol, n-hexanol, and n-hexane have been investigated by the method of flicker-noise spectroscopy. Two types of clusters — clusters with a close-packed structure and clusters with a loose structure — have been detected. The energy of formation of different clusters in methanol and n-hexane ranges, respectively, from −250 to +250 J/mole and from −50 to +50 J/mole. The smallest clusters of methanol, n-hexanol, water, and n-hexane consist, respectively, of six, two, eleven, and two molecules, and their largest clusters represent oscillators consisting, respectively, of 50,400, 17,200, 93,500, and 33,150 molecules at 274 K. In methanol at 271 K, more than 44 types of clusters consisting of 6, 97, 152, 219, 297, 492, 1029, 1368, 1560, etc. molecules were detected. In n-hexanol at 273 K, 57 types of clusters were detected. Models of small clusters are proposed. In water, the content of close-packed clusters is maximum at 277 K. The energy of formation/decomposition of small clusters in water ranges from −0.4 to +0.4 kJ/mole and increases with increase in the water temperature. The hysteresis of transformation of the (H₂O)₂₈₀ cluster in the process of heating and cooling of water in the temperature range 273–280 K was detected. Series of energy spectra of clusters in liquids at different temperatures are presented and discussed. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 3, pp. 305–312, May–June, 2005.     

Mass spectrometer for measuring the mass distributions of cluster ions in the range 105–107 amu

The mass analysis of heavy cluster ions in the range m/q=10⁵–10⁷ amu is investigated. A dynamic mass spectrometer is described for measurements of the mass distributions of charged particles generated in pulsed sources of polyatomic clusters in the given range. The main parameters and characteristics of the instrument are given. The distribution of cluster ions with respect to the ratio m/q is determined for a specific source of gold cluster ions formed in the inelastic sputtering of gold island films with fission fragments of ²⁵²Cf nuclei. Zh. Tekh. Fiz. 67, 107–112 (April 1997) The reported investigations have been performed under the auspices of International Science Foundation Grant No. R1S000, ISF Grant No. R1S300, ant the Government of the Russian Federation, 1994–1995.     

Energy Characteristics of Small Metal Clusters Containing Vacancies

Self-consistent calculations of spatial distributions of electrons, potentials, and energies of dissociation, cohesion, vacancy formation, and electron attachment, as well as the ionization potential of solid Al _N , Na _N clusters (N ≥ 254), and clusters containing a vacancy (N ≥ 12) have been performed using a model of stable jellium. The contribution of a monovacancy to the energy of the cluster, the size dependences of the characteristics, and their asymptotic forms have been considered. The calculations have been performed on the SKIT-3 cluster at the Glushkov Institute of Cybernetics, National Academy of Sciences of Ukraine (Rpeak = 7.4 Tflops).     

A revised many-body potential energy function for the description of the H3O+(H2O)n clusters

A revised potential energy function that has been fitted to the latest set of Kebarle and coworkers [1982, J. Am. chem. Soc, 104, 1462] entropy and enthalpy measurements at T = 300 K is presented. The model assumes a rigid hydronium unit and accounts for all orders of many-body interactions explicitly. The difference with the older function that had been based on earlier measurements by Kebarle and co-workers [1972, J. Am. chem. Soc, 94, 7627; 1967, J. Am. chem. Soc, 89, 6393] is that more compact clusters are generated. We have studied the structural properties of water clusters in the size range 5–80 at T = 250 K within the framework of the (μPT) Grand Canonical ensemble. Clusters with sizes less than about 10 water molecules consist of a four-coordinated first shell, where the fourth water molecule is hydrogen bonded to the oxygen atom of the hydronium ion. The hydration number goes through a minimum value ～1.6, for a cluster size around 50, and it starts increasing again with further cluster growth, to ～2.5 for a cluster size of 250 water molecules, which is the largest cluster examined. On the other hand the water molecule coordination number shows a monotonic increase with cluster size. In small clusters, less than 10, water molecules prefer to be arranged in a chain-like fashion; at sizes around 50, tri-coordinated clathrate-like structures dominate whereas with further size increase the coordination number eventually levels off to the experimental bulk value, at 4.6.     

Stability of <Superscript>244–260</Superscript>Fm isotopes against alpha and cluster radioactivity

Taking Coulomb and proximity potentials as the interacting barrier we have studied the cold valley in the radioactive decay of ^244–260Fm isotopes. It is found that in addition to alpha particle minima, other minima occur at S, Ar and Ca clusters. We have computed the half-lives and other characteristics of different clusters emitted from these parents treating parent, daughter and emitted cluster as spheres. Our study reveals that most of these parents are unstable against alpha and heavy cluster (⁴⁶Ar, ^48,50Ca) emissions and stable against light cluster emission, except ⁸Be from ^244–248Fm isotopes. The most probable clusters from these parents are predicted to be ⁴⁶Ar, ^48,50Ca which indicate the role of doubly or near doubly magic clusters (Z = 20, N = 28) and also stress the role of doubly magic ²⁰⁸Pb daughter. The computed half-lives for alpha decay are in good agreement with the experimental data. It is found that the presence of neutron excess in the parent nuclei slows down the cluster decay process. The effect of quadrupole (β ₂) and hexadecapole (β ₄) deformations of parent and fragments on half-lives are also studied. It is found that inclusion of β ₂ and β ₄ reduces the height and shape of the barrier (increases barrier penetrability) and hence the half-life decreases.     

Symmetry-breaking transitions and dissociation of two-dimensional Plateau borders

We have experimentally studied the dissociation/coalescence of internal Plateau borders (PBs) in simple monolayer bubble clusters, as a result of changing the liquid fraction. At large liquid content, the clusters consist of n bubbles of the same size, symmetrically placed around an internal n-sided PB (n-PB). On decreasing the liquid fraction we observed symmetry-breaking transitions in the 4- and 5-bubble clusters (but not in the 3-bubble cluster), followed by dissociation of the PBs. We used the Surface Evolver to determine the various equilibrium configurations of the corresponding two-dimensional wet clusters and their surface energies. The sequence of 4-bubble cluster configurations observed on varying the liquid fraction correlates qualitatively with that predicted on the basis of Surface Evolver calculations. The same is not true of the 5-bubble cluster.     

Simulation of doping and primary radiation damage to the SiC(111) surface under bombardment by Si<Subscript><Emphasis Type="Italic">N</Emphasis></Subscript> atomic and cluster ions (<Emphasis Type="Italic">N</Emphasis> = 1, 5, and 60) using classical molecular dynamics

The features of the cascade of atomic collisions, the spatial distribution of dopes, and primary radiation damage in a near-surface region of cubic silicon carbide under bombardment by Si _N ions and clusters (N = 1, 5, and 60) in the case of the same energy per one atom of the particle-projectile (200 and 1000 eV/atom) are studied in this paper. The study is carried out using classical molecular dynamics. As a result, several features of the low-energy implantation of polyatomic clusters in SiC(111) are revealed, namely, a relatively weak effect of the size of the implanted cluster on the distribution of ranges of incorporated atoms, a low degree of nonlinear effects at the cascade and postcascade stages, and formation of amorphous regions in the target during cluster implantation.     

Charge transfer between alkali cluster ions and atoms in the 1 to 10 keV collisional energy range

The cross-sections for collisional charge transfer between singly charged free clusters M _n ⁺ (M = Li, Na; n=1...50) and atomic targets A (cesium, potassium) have been measured as a function of collisional relative velocity in laboratory energy range 1–10 keV. For each cluster size, the experimental values of the charge transfer cross-section are fitted with an universal parametric curve with two independent parameters and v_m, the maximum cross-section and the corresponding velocity. For small size clusters (), the characteristic parameters show strong variations with the number of atoms in the cluster. Abrupt dips observed for n=10 and n=22 are attributed to electronic properties. Charge transfer patterns observed for various collisional systems present similarities, which appear more sensitive to cluster quantum size effects than to collision energy defects. In their whole, the and v_m parameters show differences in both their size evolution and their absolute values discussed in term of projectile and target electronic structures. Received 13 April 2000 and Received in final form 29 June 2000     

季风与极涡的异常配置下中国夏季大尺度旱涝分布

从冷暖系统配置的角度,选取东亚夏季风(EASM)和7月亚洲区极涡面积(APVA),分析了二者的气候特征与中国夏季降水分布之间的关系.在此基础上,将1951—2010年EASM和APVA的异常配置分为四种类型:A:季风强、极涡大;B:季风强、极涡小;C:季风弱、极涡大;D:季风弱、极涡小.研究发现,二者的异常配置下,中国夏季大尺度旱涝分布在季尺度上表现出多面性特征:A型年,夏季整体偏旱;B型年,夏季南涝北旱;C型年,夏季北涝南旱;D型年,夏季整体偏涝.由此可见,中国夏季旱涝总体分布除了与EASM有关外还与APVA密切相关,二者异常的不同配置下,夏季降水多寡和旱涝分布表现出了显著的差异和规律性,这对夏季降水总体趋势预测有一定的指示意义.此外,通过研究不同配置关系对应大气环流异常特征,并分析不同要素在夏季风和极涡关系变化中的作用,发现不同配置类型下夏季降水表现出的差异和规律性直接取决于环流场的整体配置,其中西太副高和中高纬阻塞形势起主导作用.     

Coulomb explosion of a cluster with a complex ion composition

The problem of the Coulomb explosion of a homogeneous cluster with light and heavy ions has been analytically solved. The space-time and spectral distributions of accelerated ions have been obtained. The characteristics of scattered light ions are determined as functions of the atomic composition of the cluster. It has been shown that sources of monoenergetic ions can be created using the interaction of high-power ultrashort laser pulses with molecular clusters.