共查询到20条相似文献,搜索用时 812 毫秒
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我们合成了一类多苯基取代的烯丙基锗烷类化合物,并测量了这三种化合物的拉曼光谱和红外光谱。经光谱分析,指认了主要波数所对应的分子振动。在这三种化合物的拉曼光谱中,Ge-Ph均在1000cm-1附近出现非常强的振动峰;烯丙基中的C=C键在1615 cm-1和1595 cm-1附近出现强的振动峰;在1585 cm-1附近出现芳香环的多重振动峰;在3050 cm-1(m)1、025 cm-1(m)、615 cm-1(m)附近出现芳香环的C-H伸缩振动,C-H面内弯曲振动和C-H面外弯曲振动峰;与饱和碳原子相连接的Ge-C振动峰分别出现在595 cm-1、592 cm-1和597 cm-1。在红外光谱中,这类化合物的Ge-C振动和饱和Ge-C振动较为明显,分别出现在1090 cm-1(s)附近和625 cm-1~577 cm-1(w)之间。 相似文献
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采用紫外薄层色谱法在硅胶GF254板上分离N-{2-[(2,2-二氰基-乙烯基)-甲基-氨基]-丙基}-4-甲基-苯磺酰胺(C_(15)H_(18)N_4SO_2)和4-甲基-N-{2-[甲基-(2-硝基-乙烯基)-氨基]-丙基}-苯磺酰胺(C_(13)H_(19)N_3SO_4)二种有机物的方法。硅胶GF254板由0.27mol/L,pH=7的EDTA溶液修饰,避免了这两种样品与板上少量无机金属离子发生络合作用;展开剂为乙酸乙酯-石油醚-乙醇-37.5%氨水(体积比为10∶10∶1∶1)。C_(15)H_(18)N_4SO_2和C_(13)H_(19)N_3SO_4的Rf值分别为0.64和0.48。用紫外薄层色谱法分离C_(15)H_(18)N_4SO_2和C_(13)H_(19)N_3SO_4具有操作简单,灵敏,准确的特点。 相似文献
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7-(苯并噻唑-2-偶氮)-8-羟基喹啉-5-磺酸与镉显色反应的研究和应用 总被引:1,自引:1,他引:0
在 p H4 .8的邻苯二甲酸氢钾 - Na OH介质中 ,非离子表面活性剂 Tween- 80存在下 ,7- (苯并噻唑 - 2 -偶氮 ) - 8-羟基喹啉 - 5 -磺酸 (BTAQS)与镉形成 2∶ 1的紫红色配合物 ,其最大吸收波长 λmax=5 6 0 nm,表观摩尔吸光系数为 8.71× 10 4L· mol-1·cm-1,镉含量在 0— 6 μg/ 10 m L范围内服从比耳定律。用于矿样中镉的测定 ,相对误差小于 3% ,相对标准偏差小于 2 .5 % (n=5 )。 相似文献
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徐友辉 《原子与分子物理学报》2016,33(6)
采用密度泛函理论B3LYP/6-31++G**方法对2-胺基苯基丙烷(a)、2-甲胺-1-苯基丙烷(b)、7-甲氧基- a -甲基-1,3-苯骈二氧杂环戊烯-5-乙胺(c)、2,5-二甲氧基- a -甲基苯乙酰胺(d)四个新型胺类毒品分子进行结构优化,并进行频率和热容、熵、焓、自由能等气态热力学性质计算,获得它们的红外光谱、电子光谱和分子轨道图,模拟出标准摩尔热容Cθpm、标准摩尔熵Sθm、标准摩尔焓Hθm等气态热力学性质与温度之间的函数关系式. 相似文献
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采用密度泛函理论B3LYP/6-31++G**方法对2-胺基苯基丙烷(a)、2-甲胺-1-苯基丙烷(b)、7-甲氧基-a-甲基-1,3-苯骈二氧杂环戊烯-5-乙胺(c)、2,5-二甲氧基-a-甲基苯乙酰胺(d)四个新型胺类毒品分子进行结构优化,并进行频率和热容、熵、焓、自由能等气态热力学性质计算,获得它们的红外光谱、电子光谱和分子轨道图,模拟出标准摩尔热容Cpm、标准摩尔熵Sm、标准摩尔焓Hm等气态热力学性质与温度之间的函数关系式. 相似文献
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合成了新显色剂1-偶氮苯-3-(3-硝基-5-氯-2-吡啶)-三氮烯(ABNCPDT)。研究了它与铜的显色反应。在pH10.5的Na2B4O7-NaOH缓冲溶液中,Triton X-100表面活性剂存在下,试剂与铜生成4∶1型红色配合物。配合物的最大吸收峰位于540nm,表观摩尔吸光系数为1.48×105L·mol-1·cm-1。Cu2 浓度在0—480μg/L范围内符合比耳定律,用于测定铝合金中微量铜,结果满意。 相似文献
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H. T. C. Stoof 《Journal of statistical physics》1997,87(5-6):1353-1366
We study, by means of a variational method, the stability of a condensate in a magnetically trapped atomic Bose gas with a negative scattering length and find that the condensate is unstable in general. However, for temperatures sufficiently close to the critical temperature the condensate turns out to be metastable. For that case we determine in the usual WKB approximation the decay rate of the condensate due to macroscopic quantum fluctuations. When appropriate, we also calculate the decay rate due to thermal fluctuations. An important feature of our approach is that (nonsingular) phase fluctuations of the condensate are taken into account exactly. 相似文献
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P. Horak H. Ritsch 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,13(2):279-287
We propose a method to create macroscopic superpositions, so-called Schr?dinger cat states, of different motional states of
an ideal Bose-Einstein condensate. The scheme is based on the scattering of a freely expanding condensate by the light field
of a high-finesse optical cavity in a quantum superposition state of different photon numbers. The atom-photon interaction
creates an entangled state of the motional state of the condensate and the photon number, which can be converted into a pure
atomic Schr?dinger cat state by operations only acting on the cavity field. We discuss in detail the fully quantised theory
and propose an experimental procedure to implement the scheme using short coherent light pulses.
Received 26 June 2000 and Received in final form 2nd October 2000 相似文献
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We consider the formation of entangled quantum states for an atomic Bose condensate interacting with an external electromagnetic field in a single-particle state under conditions of change in various regimes for exchange interaction processes. These states of the Bose system have high phase coherence and are accompanied by the generation of squeezed states of a new type in terms of the parameters defined by a combination of transition operators for the condensate atoms and external-field photons with an appropriate polynomial deformation of the algebra SU(2). We show that localized quantum structures corresponding to stable elementary excitations of the atoms and the field in the condensate can be formed in principle. We also analyze the purely quantum effects of collapse and revival for the level populations of the Bose condensate and the change in atomic statistics as well as determine the conditions for the formation of superstructure of these unsteady states for the Bose system. 相似文献
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操控原子玻色-爱因斯坦凝聚体在双势阱中的动力学通常是通过改变势阱深度来实现,本文提出了一种基于调节原子有效质量的控制方案,可以在不改变双阱势的前提下操控凝聚体的双阱动力学.利用双模近似,本文解析地导出了超冷原子在双阱势中的隧穿强度和相互作用强度对有效质量的依赖关系,并基于平均场近似数值模拟了在有效质量调节下的凝聚体动力学演化,展示了隧穿振荡和自束缚等典型的双阱动力学行为.此外,本文的研究还发现,借助负有效质量效应,这一方案甚至可以等效地实现对负散射长度原子凝聚体双阱动力学行为的操控. 相似文献
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《Comptes Rendus de l''Academie des Sciences Series IV Physics》2001,2(4):687-693
We analyze the atomic state obtained by photo-dissociation of a molecular condensate. We show that the dissociation process produces an atomic condensate in a squeezed state in analogy with the down-conversion process leading to squeezed light in quantum optics. 相似文献
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Damski B Santos L Tiemann E Lewenstein M Kotochigova S Julienne P Zoller P 《Physical review letters》2003,90(11):110401
We show that, by loading a Bose-Einstein condensate of two different atomic species into an optical lattice, it is possible to achieve a Mott-insulator phase with exactly one atom of each species per lattice site. A subsequent photoassociation leads to the formation of one heteronuclear molecule with a large electric dipole moment, at each lattice site. The melting of such a dipolar Mott insulator creates a dipolar superfluid, and eventually a dipolar molecular condensate. 相似文献
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Stuhler J Griesmaier A Koch T Fattori M Pfau T Giovanazzi S Pedri P Santos L 《Physical review letters》2005,95(15):150406
We have investigated the expansion of a Bose-Einstein condensate of strongly magnetic chromium atoms. The long-range and anisotropic magnetic dipole-dipole interaction leads to an anisotropic deformation of the expanding chromium condensate which depends on the orientation of the atomic dipole moments. Our measurements are consistent with the theory of dipolar quantum gases and show that a chromium condensate is an excellent model system to study dipolar interactions in such gases. 相似文献
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We show that in an atomic Bose gas near a Feshbach resonance a quantum phase transition occurs between a phase with only a molecular Bose-Einstein condensate and a phase with both an atomic and a molecular Bose-Einstein condensate. We show that the transition is characterized by an Ising order parameter. We also determine the phase diagram of the gas as a function of magnetic field and temperature: the quantum critical point extends into a line of finite temperature Ising transitions. 相似文献
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We study dynamics of nonclassical correlations by exactly solving a model consisting of two atomic qubits with spontaneous emission. We find that the nonclassical correlations defined by different measures give different qualitative characterizations of those correlations. The relative behaviors of those correlation measures are presented explicitly for various quantum states in the two-qubit atomic system. In particular, we find that the robustness of quantum correlations can be greatly enhanced by performing appropriate local unitary operations on the initial state of the system. 相似文献