双硫腙-活性炭柱富集分离水中痕量铅的条件研究

本文研究了用活性炭加双硫腙柱富集、分离水中痕量铅的适宜条件。用火焰原子吸收法分析了不同分离条件下铅的回收率。并讨论了几种干扰离子的影响情况。     

火焰原子吸收光谱法测定茶叶中的铅

用火焰原子吸收光谱法测定了茶叶中铅含量，在一定的条件下，茶叶样品的铅可不经MIBK萃取分离而直接用火焰原子吸收光谱法进行测定，测定结果令人满意。     

印迹壳聚糖/凹土分离富集-火焰原子吸收光谱法测定中药中的痕量铅

建立了用离子印迹壳聚糖/凹凸棒石(MICA)分离富集-火焰原子吸收光谱法(FAAS)测定中药中痕量铅的新方法.在动态吸附条件下,系统地研究了溶液pH值、流速、洗脱条件和干扰离子对痕量铅分离富集的影响;在pH 4.5,上样流速为0.60mL/min的条件下,铅能被MICA定量富集;吸附的铅可用1.0mol/L HCl-0...     

准液膜分离富集-火焰原子吸收法测定痕量镁、铅

本文建立了一种新型分离富集水溶液中痕量镁、铅的方法－准液膜法。用磷酸二异辛脂迁移Ｍ＾２＋离子，用硫酸解吸Ｍ＾２＋离子，迁移与解吸同步进行，在最佳液膜体系及操作条件下，镁及铅的回收率可达９０％以上，利用此方法可降低火焰原子吸收光谱法的检测下限。     

气相色谱／石英炉（Ⅲ型）原子吸收光谱联用及烷基铅化学形态分析…

本文较系统地研究了色谱／原子吸收光谱联用的工作条件对测定烷基铅的影响，选择了分析条件，并对烷基铅样品进行了分离测定。分析结果的相对标准差为３．３１－４．１２％，回收率为９４．６－１０４．０％。     

气相色谱／石英炉（Ⅲ型）原子吸收光谱联用及烷基铅化学形态分析的研究

本文较系统地研究了色谱／原子吸收光谱联用的工作条件对测定烷基铅的影响，选择了分析条件，并对烷基铅样品进行了分离与测定。分析结果的相对标准差为３．３１～４．１２％，回收率为９４．６～１０４．０％     

火焰原子吸收光谱法测定食盐中痕量铅

对巯基棉富集 Pb( )的条件作了研究 ,经过巯基棉分离富集后 ,用火焰原子吸收光谱法测定了食盐中的痕量铅 ,实验回收率 97.3%— 97.5 % ,RSD<5 %。方法简便 ,可用于食盐中痕量铅的测定     

APDC共沉淀分离富集—火焰原子吸收分光光度法测定明矾中的痕量铅

本文研究了ＡＰＤＣ－Ｃｕ（Ⅱ）共沉淀分离富集，开槽管原子捕集火焰原子吸收光谱测定铅的条件，发现痕量铅在ｐＨ值为２－８条件下能被ＡＰＤＣ－Ｃｕ（Ⅱ）定量共沉淀，方法的检出限可达１．５×１０＾－２μｇ／ｍＬ。用于明矾中痕量铅的分离富集和测定，共存物质不产生干扰，样品６次平行测定的相对标准偏差〈４％。加标回收率在９８％－１０３％之间。     

原子吸收法测定加氢脱炔催化剂中的钯和铅

着重研究了空气－乙炔火焰原子吸收法测定钯和铅的介质影响条件，以及消除对钯干扰的释放剂和保护剂，拟定了采用酸浸溶不经分离直接测定的方法     

模拟全血基体中铅及其同位素的富集与分离研究

利用富集分离方法,克服高浓度基体对铅浓度及铅同位素测定的影响。应用专利方法对模拟全血基体中的铅进行富集分离,用ICP-MS测定富集分离前后的铅浓度、基体浓度及铅同位素比值。富集分离后的铅回收率均在99%以上,对Na和K等主要离子的去除率约为80%;各个铅同位素的浓度值随着基体浓度的增大而减小(p<0.001),但铅各同位素的比值则与基体浓度无关;当基体浓度>62.5μg.mL-1时,各个铅同位素强度会随着测定次数的增加而迅速衰减。富集分离专利方法对复杂基体中痕量铅的回收率高,对杂质离子的去除率较好;明显消除了高浓度基体对ICP-MS进样系统的堵塞现象,操作简便、成本低、引入污染少,可以提高各个铅同位素浓度测定的准确度和精密度,且对铅同位素比值测定准确度无明显影响。     

氢化物-原子荧光光谱法检测生活饮用水中的痕量铅

建立一种简便准确的氢化物-原子荧光光谱法检测生活饮用水中痕量铅的方法.在酸性介质中,以铁氰化钾为氧化剂,2%的盐酸为载流,样品中的铅与硼氢化钠(NaBH<,4>)或硼氢化钾(KBH<,4>)反应生成铅的挥发性氢化物(PbH<,4>),将氢化物导入原子化器中,检测其荧光强度.铅在0.00-30.0μg/L范围内,荧光强度...     

Ge(Ⅳ)与Ga(Ⅲ)、Pb(Ⅱ)、Ce(Ⅲ)、V(Ⅴ)和W(Ⅵ)的析相绿色萃取分离和富集

用光度法研究了正丙醇-碘化钾-水体系萃取分离锗的行为,探讨了Ge（Ⅳ）与一些金属离子的分离条件。实验表明.当溶液中正丙醇、碘化钾和硫酸铵的浓度分别为30%（V/V）、8.0×10^-3mol/L和0.20g/mL时,Ge（Ⅳ）与Ga（Ⅲ）、Pb（Ⅱ）、Ce（Ⅲ）、V（Ⅴ）和W（Ⅵ）可定量分离。     

Research on bandgap property of a novel small size multi-band phononic crystal

A novel small size multi-band gaps phononic crystal (hPC) composed of the periodic plumbum and aluminum mass has been investigated in this paper, we calculated the dispersion relations and the displacement fields with finite element method (FEM). The influences of the geometrical parameters and materials parameters on the band structure are further investigated. We studied the influence factors of band gap by the model of origin anti-resonance. There are many flat bands in the characteristic frequency curve. The band gap covers a large range in low frequency.     

Temperature Dependence of Quasilocal Energy Levels in PbSe Doped with Thallium and Superstoichiometric Plumbum

Spectral dependences of the absorption coefficient in p-PbSe doped with thallium and superstoichiometric plumbum impurity are investigated within the temperature interval 96–600 K. Additional absorption bands, which are associated with the presence of thallium and chalcogen vacancies are revealed and identified. The energies of optical ionization of thallium and chalcogen vacancy are estimated. These are shown to increase with the temperature, while the energy of thermal ionization of thallium, according to the data on the transport phenomena studies, is decreased with increasing temperature. Probable reasons for different signs at the temperature-dependent rate of variation in the energy of optical and thermal ionization of thallium in plumbum chalcogenides are discussed. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 51–56, July, 2005.     

六味药材中重金属含量的测定

采用原子吸收分光光度法和原子荧光光谱法测定 6味中药材中重金属铅、铜、镉、砷、汞的含量。方法操作简便、快速 ,且准确度和精密度高 ,适用于中药材中这 5种重金属的含量测定 ,结果令人满意     

Complete low-frequency bandgap in a two-dimensional phononic crystal with spindle-shaped inclusions

A two-dimensional phononic crystal(PC) structure possessing a relatively low frequency range of complete bandgap is presented. The structure is composed of periodic spindle-shaped plumbum inclusions in a rubber matrix which forms a square lattice. The dispersion relation, transmission spectrum and displacement field are studied using the finite element method in conjunction with the Bloch theorem. Numerical results show that the present PC structure can achieve a large complete bandgap in a relatively low frequency range compared with two inclusions of different materials, which is useful in low-frequency noise and vibration control and can be designed as a low frequency acoustic filter and waveguides. Moreover,the transmission spectrum and effective mass are evaluated to validate the obtained band structure. It is interesting to see that within the band gap the effective mass becomes negative, resulting in an imaginary wave speed and wave exponential attenuation. Finally, sensitivity analysis of the effect of geometrical parameters of the presented PC structure on the lowest bandgap is performed to investigate the variations of the bandgap width and frequency.     

Design and calibration of a piezoelectric actuator for interferometric applications

The present work reports a possible solution for a low-cost piezoelectric actuator available for interferometric applications. In the paper the design, the assembly and the calibration of the actuator are described in detail.

The solution adopted consists of a machined stainless steel case deformed by three low-voltage multilayer plumbum zirconate titanate (PZT) ceramic blocks. In the proposed arrangement a three degree of freedom device is obtained, by which a translation and two rotations can be performed.

The PZTs are driven by a supply voltage provided by a 16 bit D/A converter directly connected to the parallel port of a personal computer which guarantees a very accurate output. This voltage is applied on each ceramic by means of a variable resistor, by which it is possible to adjust the maximum driving voltage for the single block. This electrical solution allows to match up the strokes of the ceramics in order to obtain a straight expansion of the whole actuator.

After the mechanical and electrical set-up of the actuator, a static calibration was carried out by inserting it along one arm of a Michelson speckle interferometer. The calibration procedure had emphasized the hysteresis loop and the non-linearity of the electromechanical behaviour of the actuator.     

激光干涉法检测回流离子特征参数的实验研究

 分析了回流离子基本物理特性及特征参数的检测与信号处理方法,设计了激光干涉实验方案。简要介绍了该实验方案的优缺点,并针对具体实验调试工作中出现的不利于信号检测的问题,总结出了解决方法：严格按照成像质量要求进行光学元器件的设计、加工、选型、调试,可获得较为理想的静态干涉图像;在激光干涉条纹输出与分幅相机之间增加一定缩束比例的缩束镜,可获得动态干涉图像;采用铅等重金属材料对分幅相机进行屏蔽可提高测量图像的信噪比;在6 μs时间段内,采用变时延和时间间隔的方法,获得了回流离子的状态信息。最后对实验所获得的干涉图像进行了分析处理,获得了假设条件下回流离子的密度分布。     

Theory of magnetoelectric effect in double-layer ferromagnetic-piezoelectric structures

A theory of magnetoelectric effect in double-layer ferromagnetic-piezoelectric plate-shape structures is presented. Using the material and motion of continuum equations, an expression for the magnetic coefficient is derived in terms of the parameters characterizing the magnetic and piezoelectric phases. It is shown that in the region of electromagnetic resonance there is a considerable increase in the magnetoelectric coefficient value. A relationship is obtained between the ferromagnetic and piezoelectric thicknesses for which the magnetoelectric coefficient is maximal. The coefficients calculated for the structures based on permendure — plumbum zirconate-titanate are given, and the results of calculations are compared to the experimental data.__________Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 3–6, December 2004.