MnFeP0.45As0.55材料中的相变研究

利用不同的测量方法，研究了MnFeP_１-xAs_x（0.32关键词： MnFePAs 磁致伸缩 巡游电子变磁性 一级磁相变     

MnFeP_(0.45)As_(0.55)材料中的相变研究

利用不同的测量方法,研究了MnFeP1-xAsx(0·32相似文献   

MnFePo.45Aso.55材料中的相变研究

利用不同的测量方法,研究了MnFeP1-xAsx(0.32＜x＜0.66)材料巡游电子变磁性转变附近一级相变与其他物理性质变化的关系.可以发现,材料的一级相变是一个温度滞后为10K,但持续发生在至少66K的一个很大的温度区间的结构相变.磁性相变与一级相变的温度点并不对应.晶格突变与居里温度和一级相变温度点并不一一对应,属于磁致伸缩的机制,来源于磁弹性耦合.实验指出,顺磁-铁磁转变是在一级相变的过程中,由于晶格的连续变化,导致了a-b面内最近邻Fe-Fe原子间的距离增大,而非观察到的晶格突变所引起.     

哈斯勒合金Ni-Mn-Sn的马氏体相变与反磁热性质

通过结构以及磁性测量,研究了哈斯勒合金Ni₅₀Mn_25+xSn_25-x (x=11,12)的马氏体相变和磁热性质.结果表明,与样品在奥氏体相的磁性不同,由于在马氏体相中反铁磁交换作用的增强,导致铁磁和反铁磁在马氏体状态下共存.此外,通过Maxwell方程,研究了两样品在不同磁场变化下马氏体相变温度附近的反磁热性质,并阐明了该系列合金产生大的正磁熵变(ΔS_M)不仅与其在降温过程中发生马氏体相变所导致的磁跃变(ΔM)有关,而且与发生马氏体相变所经历的温度区间有密切的联系. 关键词： 哈斯勒合金 Ni-Mn-Sn 马氏体相变 正磁熵变     

NaZn13型结构LaFe13-xAlxCy化合物的磁熵变与磁相变的研究

研究了NaZn13型结构LaFe13-xAlxC0.1(x=1.6,1.8)间隙化合物的磁制冷能力和磁相变.利用麦克斯韦关系式计算得到,高Al含量LaFe13-xAlx碳化物的最大磁熵变值|ΔS|m低于低Al含量碳化物的最大磁熵变值.随Al含量的增加,化合物的磁熵变峰展宽,但由于磁熵变大幅降低,衡量磁制冷能力的q值随之降低.基于朗道相变原理,考虑到自旋涨落的影响,磁自由能可以展开到磁化强度的6次方项,材料的相变类型由磁化强度的4次方项系数a3(T)的符号来进行判断.随着Al含量的增加,研究的碳化物相变由弱的一级相变转为二级相变.     

Ni47Mn32Ga21多晶合金的磁熵变和磁感生应变

对定向凝固方法制备的Ni₄₇Mn₃₂Ga₂₁多晶合金,通过扫描电镜、金相、电子能谱等手段研究其组份和组织形貌,通过对合金磁化强度与温度关系、等温磁化曲线及磁感生应变曲线等的测量分析,研究了合金结构相变和磁相变过程中的磁熵变及不同压力下的磁感生应变. 研究结果表明:合金组份与设计组份基本一致,室温下合金大部分为马氏体相. 升温过程中合金的磁熵变在居里温度(365 K)附近有最大值,并有较大的磁熵变峰值半高宽,747 kA/m的磁场下该磁熵变最大值为-1.45 J/kg ·K,磁熵变峰值的半高宽为21 K. 合金在室温(298 K)下有较好的双向可恢复磁感生应变,480 kA/m磁场下,无压力时合金的磁感生应变值达到-670×10^-6,并趋饱和;而在与磁场方向平行的27.3 MPa外压力作用下合金的磁感生应变值增大到-1300×10^-6,且未饱和. 关键词： Ni-Mn-Ga 铁磁形状记忆合金 磁熵变 磁感生应变     

磁熵变测量实验装置

简述了磁熵概念及磁熵变测量原理,介绍了应用于教学的磁熵变测量实验装置.利用该装置测量了金属钆在0～50℃温度范围,最大磁场为2T的等温磁化曲线,计算了不同温度下的磁熵变.     

Eu 掺杂双钙钛矿氧化物 Dy2CoMnO6 的磁性研究

本文通过传统的固相反应方法制备了双钙钛矿氧化物系列样品 Dy2 -xEuxCoMnO6 (x =0,0.1 ,0.3) . 利用对该系列样品的 XRD 谱线、 磁化强度随温度的变化曲线(M-T ) 、 等温磁化曲线(M-H ) 的测量, 研究了随着Eu 掺杂对类 Griffiths 相、 磁熵变等的影响. 研究表明, 双层钙钛矿氧化物 Dy2 -xEuxCoMnO6 (x =0,0.1 ,0.3) 系列样品均显示出良好的单相性; 样品在T >TG 和T 相似文献   

(La0.55Gd0.15)Sr0.3MnO3中的磁热效应

本对A位掺杂的超大磁阻材料（La0.55Gd0.15)Sr0.3MnO3的磁热效应进行了研究，通过不同温度下的等温磁化（M-H）曲线的测量和计算，发现伴随铁磁-顺磁相变出现大的磁热效应，额外的磁性交换作用将导致额外的磁熵变化。     

间隙原子H,B,C对LaFe_(11.5)Al_(1.5)化合物磁性和磁热效应的影响

研究了金属化合物LaFe_(11.5)Al_(1.5)H_x(x=0,0.12,0.6,1.3),LaFe_(11.5)Al_(1.5)B_y(y=0.1,0.2,0.3)和LaFe_(11.5)Al_(1.5)C_z(z=0.1,0.2,0.3,0.4,0.5)的磁性、结构和磁热效应.金属化合物样品均形成了良好的NaZn_(13)型单相结构.基于固相-气相反应或者固相-固相反应引入间隙H,B,C原子后,磁性基态从反铁磁态变为铁磁态,饱和磁化强度(M_s)和居里温度(T_c)均呈升高趋势.值得注意的是:随着B和C含量的增加,化合物的相变性质由弱一级相变过渡至二级相变;而随着H含量的增加,相变性质却从二级相变过渡至弱一级相变.同时,化合物LaFe_(11.5)Al_(1.5)H_x,LaFe_(11.5)Al_(1.5)B_y和LaFe_(11.5)Al_(1.5)C_z均呈现出相当大的磁熵变.在0—5 T的外磁场作用下,LaFe_(11.5)Al_(1.5)H_(1.3),LaFe_(11.5)Al_(1.5)B_(0.1)和LaFe_(11.5)Al_(1.5)C_(0.2)的最大磁熵变分别达到12.3,9.6和10.8 J/kg·K.此外,在0—5 T的外磁场作用下,LaFe_(11.5)Al_(1.5)H_(0.6)的制冷能力达到259.2 J/kg,LaFe_(11.5)Al_(1.5)B_(0.1)的制冷能力达到116.4 J/kg,而LaFe_(11.5)Al_(1.5)C_(0.1)的制冷能力达到230.4 J/kg.     

On the origin of giant magnetocaloric effect and thermal hysteresis in multifunctional α-FeRh thin films

We report temperature and field dependent lattice structure, magnetic properties and magnetocaloric effect in epitaxial Fe₅₀Rh₅₀ thin films with (001) texture. Temperature-dependent XRD measurements reveal an irreversible first-order phase transition with 0.66% lattice change upon heating/cooling. First-principle calculation shows a state change of Rh from non-magnetic (0 μ_B) for antiferromagnetic phase to magnetic (0.93 μ_B) state for ferromagnetic phase. A jump of magnetization at temperature of 305 K and field more than 5 T indicates a field-assisted magnetic state change of Ru that contributes to the jump. Giant positive magnetic entropy change was confirmed by isothermal magnetization measurements and an in-situ temperature rise of 15 K. The magnetic state change of Rh between antiferromagnetic and ferromagnetic states is the main origin of giant magnetic entropy change and large thermal hysteresis observed.     

Phenomenological modeling of magnetic and magnetocaloric properties in rare earth doped La0.8Ca0.2MnO3

La_0.8Ca_0.2MnO₃ manganese oxides have been prepared by the conventional solid-state reaction. The samples crystallize in the orthorhombic structure with Pnma space group. A first-order magnetic phase transition from ferromagnetic to paramagnetic state is observed at the Curie temperature that is found to be around 241?K. The magnetic and magnetocaloric properties have been simulated using a phenomenological model. The maximum of magnetic entropy change is of order 8.2?J/kg?K for an applied magnetic field of 5?T, and the adiabatic temperature change is found to be of 4?K under a same magnetic field; this high value gives the sample the possibility of technologic application in the magnetic refrigeration area. The simulated results of magnetization and magnetic entropy change are compared with the experimental measurements. Finely, we found a good agreement between experimental and theoretical results.     

The order of magnetic phase transition in La(Fe1−xCox)11.4Si1.6 compounds

Magnetic transitions in La(Fe_1−xCo_x)_11.4Si_1.6 compounds with x=0–0.08, have been studied by DC magnetic measurements and Mössbauer spectroscopy. The temperature dependence of the Landau coefficients has been derived by fitting the magnetization, M(μ₀H), using the Landau expansion of the magnetic free energy. For x0.02 there is a strongly first-order magnetic phase transition between ferromagnetic and paramagnetic (F–P) states in zero external field and a metamagnetic transition from paramagnetic to ferromagnetic (P–F) above T_c. Increasing the cobalt content drives the F–P transition towards second order and eliminates the metamagnetic transition.     

Investigation of magnetocaloric effect in La0.45Pr0.25Ca0.3MnO3 by magnetic,differential scanning calorimetry and thermal analysis

We investigated magnetocaloric effect in La_0.45Pr_0.25Ca_0.3MnO₃ by direct methods (changes in temperature and latent heat) and indirect method (magnetization isotherms). This compound undergoes a first-order paramagnetic to ferromagnetic transition with T_C=200 K upon cooling. The paramagnetic phase becomes unstable and it transforms into a ferromagnetic phase under the application of magnetic field, which results in a field-induced metamagnetic transition (FIMMT). The FIMMT is accompanied by release of latent heat and temperature of the sample as evidenced from differential scanning calorimetry and thermal analysis experiments. A large magnetic entropy change of ΔS_m=−7.2 J kg⁻¹ K⁻¹ at T=212.5 K and refrigeration capacity of 228 J kg⁻¹ are found for a field change of ΔH=5 T. It is suggested that destruction of magnetic polarons and growth of ferromagnetic phase accompanied by a lattice volume change with increasing magnetic field is responsible for the large magnetocaloric effect in this compound.     

Tb掺杂双层锰氧化物La_(4/3)Sr_(5/3)Mn_2O_7的磁熵变和电输运性质

研究了Tb掺杂对双层锰氧化物La_(4/3)Sr_(5/3)Mn_2O_7磁熵变和电输运性质的影响.样品采用传统固相反应法制备,两样品的名义组分可以表示为(La_(1-x)Tb_x)_(4/3)Sr_(5/3)Mn_2O_7(x=0,0.025),磁场为7 T时的最大磁熵变?S_M分别为-4.60 J/(kg·K)和-4.18 J/(kg·K).比较后发现,Tb元素的掺杂使得最大磁熵变值减小,但同时增大了相对制冷温区.电性测量结果表明,x=0.025的样品在高温区的导电机制可以用小极化子模型解释,与母体三维变程跳跃模型不同;当温度降低至三维长程铁磁有序温度(T_c~(3D))附近时,掺杂样品发生金属绝缘相变;掺杂后样品在T_c~(3D)附近,磁电阻取得极大值(约为56%),表明是本征磁电阻效应.     

La2/3Ca1/3MnO3的巨磁熵效应

本文对超大磁阻材料Ｌａ２／３Ｃａ１／３ＭｎＯ３的巨磁熵效应进行了研究,通过测量不同磁场下的磁化－温度曲线,发现伴随铁磁－顺磁相变有一个大的磁熵变化,这个结果表明钙钛矿锰氧化物可以作为磁致冷技术中的工作物质。     

Magnetic field and temperature-induced first-order transition in Gd5(Si1.5Ge2.5): a study of the electrical resistance behavior

Magnetic field (0–4 T) and temperature dependencies (4.2–320 K) of the electrical resistance of Gd₅(Si_1.5Ge_2.5), which undergoes a reversible first-order ferromagnetic↔paramagnetic phase transition, have been measured. The electrical resistance of Gd₅(Si_1.5Ge_2.5) indicates that the magnetic phase transition can be induced by both temperature and magnetic field. The temperature dependence of the electrical resistance, R(T), for heating at low temperatures in the zero magnetic field has the usual metallic character, but at a critical temperature of T_cr=216 K the resistance shows a 20% negative discontinuity due to the transition from the low-temperature high-resistance state to the high-temperature low-resistance state. The R(T) dependence for cooling shows a similar but positive 25% discontinuity at 198 K. The isothermal magnetic field dependence of the electrical resistance from 212T224 K indicates the presence of temperature-dependent critical magnetic fields which can reversibly transform the paramagnetic phase into the ferromagnetic phase and vice versa. The critical magnetic fields diagram determined from the isothermal magnetic field dependencies of the electrical resistance of Gd₅(Si_1.5Ge_2.5) shows that the FM↔PM transition in zero magnetic field on cooling and heating occurs at 206 and 213 K, respectively. The full isothermal magnetic filed hysteresis for the FM↔PM transition is 2 T, and the isofield temperature gap between critical magnetic fields is 7 K.     

Effect of magnetic field on the TC and magnetic properties for the aligned MnBi compound

In the compound MnBi, a first-order transition from the paramagnetic to the ferromagnetic state can be triggered by an applied magnetic field and the Curie temperature increases nearly linearly with an increase in magnetic field by ∼2 K/T. Under a field of 10 T, T_C increases by 20 and 22 K during heating and cooling, respectively. Under certain conditions a reversible magnetic field or temperature induced transition between the paramagnetic and ferromagnetic states can occur. A magnetic and crystallographic H-T phase diagram for MnBi is given. Magnetic properties of MnBi compound aligned in a Bi matrix have been investigated. In the low temperature phase MnBi, a spin-reorientation takes place during which the magnetic moments rotate from being parallel to the c-axis towards the basal plane at ∼90 K. A measuring Dc magnetic field applied parallel to the c-axis of MnBi suppresses partly the spin-reorientation transition. Interestingly, the fabricated magnetic field increases the temperature of spin-reorientation transition T_s and the change in magnetization for MnBi. For the sample solidified under 0.5 T, the change in magnetization is ∼70% and T_s is ∼91 K.     

On the determination of the magnetic entropy change in materials with first-order transitions

An accurate method to determine the magnetic entropy change in materials with hysteretic first-order transitions is presented, which is needed to estimate their potential for applications. We have investigated the effect of the maximal entropy change derived from magnetization measurements performed in different measurement processes. The results show that the isothermal entropy change can be derived from the Maxwell relations even for samples with large thermal hysteresis. In the temperature region with hysteresis, overestimating the entropy change can be avoided by measuring the isothermal magnetization of the sample after it is cooled from the paramagnetic state to the measurement temperature. In this way the so-called peak effect is not observed as shown here for a few compounds.     

Exchange bias in bulk layered hydroxylammonium fluorocobaltate (NH?OH)?CoF?

The magnetic properties of layered hydroxylammonium fluorocobaltate (NH(3)OH)(2)CoF(4) were investigated by measuring its dc magnetic susceptibility in zero-field-cooled (ZFC) and field-cooled (FC) regimes, its frequency dependent ac susceptibility, its isothermal magnetization curves after ZFC and FC regimes, and its heat capacity. Effects of pressure and magnetic field on magnetic phase transitions were studied by susceptibility and heat capacity measurements, respectively. The system undergoes a magnetic phase transition from a paramagnetic state to a canted antiferromagnetic state exhibiting a weak ferromagnetic behavior at T(C) = 46.5 K and an antiferromagnetic transition at T(N) = 2.9 K. The most spectacular manifestation of the complex magnetic behavior in this system is a shift of the isothermal magnetization hysteresis loop in a temperature range below 20 K after the FC regime-an exchange bias phenomenon. We investigated the exchange bias as a function of the magnetic field during cooling and as a function of temperature. The observed exchange bias was attributed to the large exchange anisotropy which exists due to the quasi-2D structure of the layered (NH(3)OH)(2)CoF(4) material.