共查询到18条相似文献,搜索用时 245 毫秒
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制备了结构为ITO/NPB/CBP:TBPe:rubrene/BAlq:Ir(piq)2(acac)/BAlq/Alq3/Mg:Ag的白色磷光有机电致发光器件.利用两种不同的主体材料,即用双载流子传输型主体材料CBP掺杂荧光染料TBPe及rubrene作为蓝光和橙黄光发光层;用电子传输型主体材料BAlq掺杂磷光染料Ir(piq)2(acac)作为红色发光层.以上双发光层夹于空穴传输层NPB与具有电子传输性的阻挡层BALq之间.讨论了如何控制 相似文献
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利用氧化钼(MoOx)作为p型掺杂剂,以掺杂层4,4'-bis(carbazol-9-yl)biphenyl(CBP):MoOx作为空穴注入层,制备了一种结构为ITO/MoOx/CBP:MoOx/CBP/CBP:tris(2-phenylpyridine)iridium(III)(Ir(ppy)3)/4,7-diphenyl-1,10-phenanthroline(Bphen)/LiF/Al的有机电致发光器件.器件中CBP同时作为空穴注入层、空穴传输层以及发光层母体材料,这种结构具有结构简单同时能有效降低空穴注入势垒等优点.研究发现,随着空穴注入层厚度的增加,器件的电流密度增加,表明p型掺杂层的引入能够有效增强空穴的注入;通过优化器件空穴注入层与空穴传输层厚度,器件性能有所提高,最大电流效率为29.8 cd/A,可以认为合理的优化空穴注入层和空穴传输层的厚度,使载流子在发光层中的分布更加平衡是提高器件发光效率的主要原因.值得指出的是,从电流效率最大值到亮度为 20 000 cd/m2时,优化后器件的效率衰减仅为17.7%,而常规器件的效率衰减则为62.1%,优化后器件效率衰减现象得到了明显的改善.分析认为优化后的器件中未掺杂的CBP有助于展宽激子形成区宽度,进而减弱了三线态-三线态湮灭、三线态-极化子淬灭现象,激子形成区的展宽是改善效率衰减的主要原因. 相似文献
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使用含Alq3、Bphen、BCP、HATNA和Cs2CO3作为阴极缓冲层,制备了基于SubPc和C60的反型平面异质结有机太阳能电池. 比较了有机阴极缓冲层的最低未占有分子轨道和电子迁移率对有机太阳能电池性能的影响. 结果显示,Alq3、Bphen和HATNA能够大幅度提升器件的性能. 使用退火过后的HATNA作为阴极缓冲层获得了最高的效率,比没有阴极缓冲层的器件提升了7倍. 另外,使用空间电荷限制电流理论进行仿真的结果表明,通过加入HATNA作阴极缓冲层,反型有机太阳能电池结构中处于有机/电极界面处的肖特基势垒降低了27%. 相似文献
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以磷光染料Ir(piq)2(acac)作为发光掺杂剂,掺入空穴传输性主体材料NPB中得到红色发光层,荧光材料TBP掺入到主体CBP中作为蓝色发光层,制备了结构为ITO/NPB/NPB:Ir(piq)2(acac)/CBP/CBP:TBPe/BCP/ALq/Mg:Ag的双发光层白色有机电致发光器件.其中ALq3、未掺杂的NPB和CBP及BCP层分别作为电子传输层、空穴传输层和激子阻挡层.实验中通过调节发光层厚度及Ir(piq)2
关键词:
磷光
激子阻挡层
有机电致发光 相似文献
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研究了新型的芴-咔唑共聚物(PFC)与聚乙烯咔唑(PVK)掺杂体系的光致发光和电致发光特性.制备了结构分别为indium-tin-oxide(ITO)/PVK:PFC/bathocuproine(BCP)/tris-(8-hydroxylquinoline)-aluminum (Alq3) /Mg:Ag,ITO/PFC/BCP/Alq3/Mg∶Ag和ITO/PVK/BCP/Alq3/Mg∶Ag的三种有机电致发光器件.对器件的光电特性进行了测试.结果表明,掺杂体系中的PVK有效地抑制了固态膜中PFC激基缔合物的形成.掺杂器件在不同的外加电场作用下发生发光层位置的移动,通过调节外加电场,可以获得从绿光到蓝光的可见光发射.当外加电压大于7V时,掺杂器件的蓝色发光亮度达到1650cd/m2,推测其中可能存在从PVK到PFC的能量传递过程. 相似文献
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空穴注入层对蓝色有机电致发光器件性能的影响 总被引:1,自引:0,他引:1
以DPVBi为发光层,NPB为空穴传输层,在阳极ITO和NPB之间分别插入不同的空穴注入层CuPc和PEDOT:PSS,制备了两种结构的蓝色有机电致发光器件(OLEDs):ITO/CuPc/NPB/DPVBi/BCP/Alq3/Al和ITO/PEDOT:PSS/NPB/DPVBi/BCP/Alq3/Al,研究了不同空穴注入材料对蓝色OLEDs发光性能的影响,并与没有空穴注入层的器件进行了比较.其中CuPc分别采用旋涂和真空蒸镀两种丁艺,比较了不同成膜工艺对器件发光特性的影响.结果表明:加入空穴注入层的器件比没有空穴注入层器件性能要好,其中插入水溶性CuPc的器件,其发光亮度和效率虽然比蒸镀CuPc器件要低,但比插入PEDOT:PSS 器件发光性能要好.又由于水溶性CuPc采用旋涂工艺成膜,与传统CuPc相比,制备工艺简单,所以为一种不错的空穴注入材料. 相似文献
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Tandem organic light-emitting diode with molybdenum tri-oxide thin film interconnector layer 下载免费PDF全文
A 10-nm thickness molybdenum tri-oxide (MoO3) thin film was used as the interconnector layer in tandem organic light-emitting devices (OLEDs). The tandem OLEDs with two identical emissive units consisting of N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)-benzidine (NPB)/tris(8-hydroxyquinoline) aluminum (Alq3) exhibited current efficiency-current density characteristics superior to the conventional single-unit devices. At 20 mA/cm2, the current efficiency of the tandem OLEDs using the interconnector layers of MoO3 thin film was about 4.0 cd/A, which is about twice of that of the corresponding conventional single-unit device (1.8 cd/A). The tandem OLED showed a higher power efficiency than the conventional single-unit device for luminance over 1200 cd/m2. The experimental results demonstrated that a MoO3 thin film with a proper thickness can be used as an effective interconnector layer in tandem OLEDs. Such an interconnector layer can be easily fabricated by simple thermal evaporation, greatly simplifying the device processing and fabrication processes required by previously reported interconnector layers. A possible explanation was proposed for the carrier generation of the MoO3 interconnector layer. 相似文献
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Linsen Li Min Guan Guohua Cao Yiyang Li Yiping Zeng 《Solid State Communications》2010,150(35-36):1683-1685
The tandem organic light-emitting diodes (OLEDs) with an effective charge-generation connection structure of Mg-doped tris(8-hydroxyquinoline) aluminum (Alq3)/Molybdenum oxide (MoO3)-doped 3, 4, 9, 10-perylenetetracarboxylic dianhydride (PTCDA) were presented. At a current density of 50 mA/cm2, the current efficiency of the tandem OLED with two standard NPB/Alq3 emitting units is 4.2 cd/A, which is 1.7 times greater than that of the single EL device. The tandem OLED with the similar connection structure of Mg-doped PTCDA/ MoO3-doped PTCDA was also fabricated and the influences of the different connection units on the current efficiency of the tandem OLED were discussed as well. 相似文献
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Linsen Li Min Guan Guohua Cao Yiyang Li Yiping Zeng 《Applied Physics A: Materials Science & Processing》2010,99(1):251-254
We report highly efficient and stable organic light-emitting diodes (OLEDs) with MoO3-doped perylene-3, 4, 9, 10-tetracarboxylic dianhydride (PTCDA) as hole injection layer (HIL). A green OLED with structure
of ITO/20 wt% MoO3: PTCDA/NPB/Alq3/LiF/Al shows a long lifetime of 1012 h at the initial luminance of 2000 cd/m2, which is 1.3 times more stable than that of the device with MoO3 as HIL. The current efficiency of 4.7 cd/A and power efficiency of 3.7 lm/W at about 100 cd/m2 have been obtained. The charge transfer complex between PTCDA and MoO3 plays a decisive role in improving the performance of OLEDs. 相似文献
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制备了结构为ITO/NPB/CBP:TBPe:rubrene/BAlq:Ir(piq)2(acac)/BAlq/Alq3/Mg:Ag的白色磷光有机电致发光器件.利用两种不同的主体材料,即用双载流子传输型主体材料CBP掺杂荧光染料TBPe及rubrene作为蓝光和橙黄光发光层;用电子传输型主体材料BAlq掺杂磷光染料Ir(piq)2(acac)作为红色发光层.以上双发光层夹于空穴传输层NPB与具有电子传输性的阻挡层BALq之间.讨论了如何控制
关键词:
有机电致发光
磷光染料
掺杂
白光 相似文献
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Mingxia Wang Dashan Qin Yuhuan Chen Lei Chen Guifang Li Wenbo Wang 《Applied Physics A: Materials Science & Processing》2013,113(3):811-815
The hole-injecting structure of 15 nm MoO3-doped 4,4-N,N-bis [N-1-naphthyl-N-phenyl-amino]biphenyl (NPB:MoO3)/5 nm MoO3-doped 4,4′-N,N′-dicarbazole-biphenyl (CBP:MoO3) has been used in organic light emitting diodes (OLEDs). It was found that a device using the 15 nm NPB:MoO3/5 nm CBP:MoO3/NPB combination was superior to one adopting the 20 nm NPB:MoO3/NPB combination due to two major causes: the NPB:MoO3/CBP:MoO3 interface is a quasi-ohmic contact, and the hole transport barrier from CBP:MoO3 to NPB is smaller than that from NPB:MoO3 to NPB; moreover, it outperformed the device employing the 20 nm CBP:MoO3/NPB combination, mostly because of the higher conductivity of NPB:MoO3 compared to CBP:MoO3. We demonstrate that using a structure resulting from uniting two p-doped hole transporters is a beneficial, simple method of achieving an improved trade-off between high conductivity and small hole transport barrier, thereby leading to a significantly reduced ohmic loss in the hole current conduction in the OLEDs, relative to the single p-doped layers. 相似文献
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制备了一种结构为ITO/NPB/NPB:Ir(piq)2(acac)/CBP:TBPe/BAlq:rubrene/BAlq/Alq3/Mg:Ag的白色磷光有机电致发光器件.其中空穴传输型主体NPB掺杂磷光染料Ir(piq)2(acac)作为红色发光层,双载流子传输型主体4,4′-N,N′-dicarbazole-biphenyl (CBP)掺杂TBPe作为蓝色发光层,电子传输型主体材料BAlq掺杂rubrene作为绿色发光层.以上发光层夹于
关键词:
电致发光
磷光染料
异质结
白光 相似文献
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Improved performances of the organic light-emitting devices by doping in the mixed layer 总被引:4,自引:0,他引:4
Gao W.B. Sun J.X. Yang K.X. Liu H.Y. Zhao J.H. Liu S.Y. 《Optical and Quantum Electronics》2003,35(13):1149-1155
The brightness, efficiency and lifetime of organic light-emitting diodes (OLEDs) were remarkably improved by doping in a mixed layer. In this device, the emitting layer consists of a mixture of -naphthylphenybiphenyl amine (NPB), tris (8-hydroxyquinolinolate) aluminum (Alq3) (referred to as the mixed layer) and an emissive dopant 5,6,11,12-petraphenylnaphthacene (rubrene), where the concentration of NPB declined while the concentration of Alq3 was increased gradually in the deposition process. The device exhibited a maximum emission of 49,300 cd/m2 at a destroy voltage of 35 V and a maximum efficiency of 7.96 cd/A at 10 V, respectively. The efficiency improves twofold in comparison with the conventional doped devices. Meanwhile, the device exhibited superior operational stability with a half-life time of 1000 h at a starting luminance of 1000 cd/m2 by a constant current driver. 相似文献
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制备了三种结构的白色有机电致发光器件,通过比较得出:在发光层中间插入2,9-二甲基-4,7-二苯基-1,10-菲咯啉(BCP)能有效控制载流子在不同发光层的分布,进而对器件色度进行调节;而掺杂磷光染料Ir(ppy)3作敏化剂能有效提高器件的效率. 结构为:氧化铟锡/聚乙烯基咔唑∶N,N′-二(1-萘基)-N,N′-二苯基-1,1′-联苯-4-4′-二胺(30nm)/二-(2-甲基-8-羟基喹啉)-4-联苯酚铝:3.0 wt%2,5,8,11-tetra-tertbutylperylene(TBPe)(30nm)/BCP(5.0nm)/4,4N,N二咔唑基二苯:5.0 wt%Ir(ppy)3:2.0 wt%红荧烯(15nm)/BCP(10nm)/Mg:Ag的器件色度和效率俱佳. 其在17V工作电压下具有的亮度为4670cd/m2,对应色坐标为(0.31,0.37). 器件具有的最大外量子效率为1.4%,当驱动电压从5.0V升高到17V,器件色坐标严格位于白光色域区内.
关键词:
磷光染料
阻挡层
白光
双发光层 相似文献