Dust Self‐Organized Structures II. Solutions of Master Equations for Small Diffusion

Master equations for spherical dust structures are solved numerically using the asymptotic solutions at the center of the structures for the case of absence of external ionization and small diffusions. The structures are determined by a single parameter, the external plasma flux at the surface of the structure. The equilibrium states that are possible in a limited range of this parameter are investigated numerically. It is demonstrated that in the range of existence of equilibria the structures are changing their shapes and type of distributions inside the structures. For large external fluxes the ion and dust distributions can have peaks inside the structures while for low external fluxes the dust distribution has a single maximum at the structure center. The lower is the external flux supporting the structure the larger is its size. An increase of the external flux decreases the accumulation of dust and ions at the center. The total number of dust confined by the structure is larger for larger size structures. Estimates of dust crystallization inside structures are given. The role of diffusion is calculated by perturbations and is shown to be small in all structure regions except the structure edges. In the perturbation theory we use the exact expressions of the diffusion coefficients calculated previously numerically. The regions with dust density peaks inside the structures have been calculated with two order of magnitude larger precision that allows to resolve the structure parameter dependencies inside the peaks. It is shown that although in peaks the gradients of all parameters are increased the diffusion flux is still small and that the continuity and hydrodynamic approach are applicable within an accuracy about several %‐s (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Dust Self‐Organized Structures I. Role of Ion Drag and Ion Diffusion on Screened Grains

Self‐organized dust structures are investigated using a Gurevich‐Parker model for non‐linear dust screening. The non‐linear dust drag coefficients and non‐linear diffusion coefficients are calculated numerically as functions of nonlinear parameter for screening, dust density and ion flux drift velocity. Nonlinear ion dust drag inside the structures creates an electric field with potential well for ions at the structure center. The equilibrium dust structures confine both the dust grains and the plasma particles, have a finite size and have inside an enhanced dust and ion densities. The necessary conditions for existence of equilibrium dust structures are found. The equilibrium dust structures are determined by two global parameters related to the external plasma flux and to the power of ionization. The equilibrium exist only in a restricted phase space of these two parameters and depends on the the drag coefficient at the structure center. The equilibrium requirements are found using non‐linear drag coefficient calculated numerically. It is shown that this phase space area can be broad but it is systematically decreasing with an increase of the ionization rate. It is found that equilibrium exists for dust structures with large dust and ion density concentration at the center and that for these structures the ion diffusion is strongly suppressed by ion scattering on non‐linearly screened grains. The results of the theory can be used to interpret the recently observed compact dust structures in micro‐gravity experiments and can provide some recommendations for future micro‐gravity experiments in spherical chambers (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Dispersion of Dust Acoustic Modes and Perturbations of Plasma Flux Balance

Previous considerations of dust acoustic waves is demonstrated to be inconsistent ‐ the required equilibrium state for perturbations was not defined since balance of plasma fluxes was neglecting. The self‐consistent treatment shows that plasma flux perturbations are accompanying any collective waves propagating in dusty plasmas and can play an important role in wave dispersion, wave damping and can create instabilities. This is illustrated by the derivation of dispersion relation for dust acoustic modes taking into account the plasma flux balances and plasma flux perturbations by waves. The result of this approach shows that the dust acoustic waves with linear dependence of wave frequency on the wave number exist only in restricted range of the wave numbers. Only for wave numbers larger than some critical wave number for low frequency modes the frequency can be have approximately a linear dependence on wave number and can be called as dust acoustic wave but the phase velocity of these waves is different from that which can be obtained neglecting the flux balance and depends on grain charge variations which are determined by the balance of fluxes. The presence of plasma fluxes previously neglected is the main typical feature of dusty plasmas. The dispersion relation in the range of small wave numbers is found to be mainly determined by the change of the plasma fluxes and is quite different from that of dust acoustic type, namely it is found to have the same form as the well known dispersion relation for the gravitational instability. This result proves in general way the existence of the collective grain attractions of negatively charged grains for for large distances between them and for any source of ionization. The attraction of grains found from dispersion relation of the dust acoustic branch coincides with that found previously for pair grain interactions using some models for the ionization source. For the existing experiments the effective Jeans length for such attraction is estimated to be about 8 – 10 times larger than the ion Debye length and the effective gravitational constant for the grain attraction is estimated to be several orders of magnitude larger than the usual gravitational constant. The grain attraction at large inter‐grain distances described by the gravitationlike grain instability is considered as the simplest explanation for observed dust cloud clustering, formation of dust structures including the plasma crystals. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Dust in Plasma II. Effects of Secondary Electrons: Ionization and Surface Emission

In this second paper, the effect of secondary electrons on the charge and potential of a dust particle immersed in plasma has been studied. The processes of electron‐induced ionization and those of photo‐electron and secondary electron emission from the particle surface as a function of primary electron temperature have been taken into account. Starting from temperatures as low as 6 eV in an Ar plasma, ionization produces an extra ion flux to the dust surface comparable to that of the ion charge exchange effect. For what concerns the surface emission, results show that a transition from negative to positive dust charge/potential takes place, and that the transition regime is characterized by a non‐monotonic behavior of the electric potential around the particle. In the case of photoelectric emission, the dust charge and potential are monotonic decreasing functions of the electron temperature, while in the case of emission induced by primary electrons a minimum charge/potential is reached before they grow towards positive values. In no case multiple dust charge states have been observed due to the presence of the potential well attached to the particle surface. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Effect of levitated dust kinetics in the dynamic evolution of inhomogeneous plasma sheath

The main goal here is to study theoretically the formation of plasma sheath in an inhomogeneous dusty plasma. The effect of weak ionization of the dust grains as similar to the Townsend discharge has been incorporated to see how it influences the evolution of sheath. Sheath equation has been derived to describe the properties of sheath structures analytically and numerically. It has shown that the ionization along with the inhomogeneity affects significantly the growth of sheath which has been highlighted elaborately for some typical plasma parameters. After getting well defined sheath region, dynamical behaviour of levitated dust grains into the sheath has been studied. The totality of the findings has been centred around the estimation of dust surface potential, dust sizes along with the generation of net force on dust grains. Both inhomogeneous and ionization effects allow the dust grains in acquiring different potential to sustain equilibrium in different places. As a result of this, nebulons and the dust cloudlike structures are electrically charged.     

Stability of small planar dust cluster in the presence of an external magnetic field

Oscillations and stability of planar symmetric dust clusters shaped as a regular polygon and a regular polygon with a particle at the center in the presence of an external uniform magnetic field are analyzed. The structure stability against small perturbations is considered. To this end, the equation of motion was linearized with respect to small coordinate variations. As a result, a dispersion relation (quartic algebraic equation) was derived and numerically studied for particular types of interactions between particles. A comparison of stability regions for a quadrangle and a triangle with a particle at the center, as well as a pentagon and a quadrangle with a particle at the center shows that there are ranges of parameters, where configurations without particle at the center are stable and configurations with a particle at the center are unstable, and vice versa.     

Effect of ion mean free path length on plasma polarization behind a dust particle in an external electric field

In this paper, a self‐consistent numerical model that describes the behavior of plasma around an isolated, highly charged dust particle is presented. Using the developed model, self‐consistent distributions of the space charge density and plasma potential in the presence of an external electric field are obtained. These distributions are thoroughly analysed though Legendre decomposition. For different dust plasma parameters, such as the radius of the dust particle, the amplitude of the external field, and the mean free path of ions, the dipole moment of the ion cloud surrounding the dust particle is calculated. It turns out that the dependencies of the dipole moment on the value of the external electric field obtained for different parameters are reduced to a single curve by simple scaling.     

The influence of dust particle geometry on its charge and plasma potential

In this paper, a self‐consistent numerical model describing the behaviour of plasma around isolated highly charged dust particles with different shapes of rotation figures is presented. Dust particles in the form of a sphere, oblate ellipsoids (disk‐like particles), and elongated ellipsoids (rod‐like particles) are considered in the presence of an external electric field. Using the developed model, self‐consistent distributions of a space charge and plasma potential are obtained around non‐spherical dust particles. These distributions are carefully analysed by decomposing them in a series of Legendre polynomials. Decompositions of these distributions are compared with particles of different geometry. In addition, for different geometries of dust particles, the dependencies of the charge of a dust particle on geometry in the absence of an external field are investigated.     

On the Modelling of a Nonequilibrium Spherical Microwave Discharge at Atmospheric Pressure

The work presents results of calculation of a spherical microwave discharge characteristics in an argon at atmospheric pressure against the external parameters (the mode, frequency and power of the applied electromagnetic field and the size of the discharge chamber). Model assumes a thermal and ionization non‐equilibrium of discharge plasma and takes into account first three modes of incident electromagnetic waves. Calculation results are compared with the results for the ionization equilibrium model. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Theory of dust voids in plasmas

Dusty plasmas in a gas discharge often feature a stable void, i.e., a dust-free region inside the dust cloud. This occurs under conditions relevant to both plasma processing discharges and plasma crystal experiments. The void results from a balance of the electrostatic and ion drag forces on a dust particle. The ion drag force is driven by a flow of ions outward from an ionization source and toward the surrounding dust cloud, which has a negative space charge. In equilibrium the force balance for dust particles requires that the boundary with the dust cloud be sharp, provided that the particles are cold and monodispersive. Numerical solutions of the one-dimensional nonlinear fluid equations are carried out including dust charging and dust-neutral collisions, but not ion-neutral collisions. The regions of parameter space that allow stable void equilibria are identified. There is a minimum ionization rate that can sustain a void. Spatial profiles of plasma parameters in the void are reported. In the absence of ion-neutral collisions, the ion flow enters the dust cloud's edge at Mach number M=1. Phase diagrams for expanding or contracting voids reveal a stationary point corresponding to a single stable equilibrium void size, provided the ionization rate is constant. Large voids contract and small voids expand until they attain this stationary void size. On the other hand, if the ionization rate is not constant, the void size can oscillate. Results are compared to recent laboratory and microgravity experiments.     

Dust‐ion‐acoustic solitary waves in a magnetized dusty pair‐ion plasma with Cairns‐Gurevich electrons and opposite polarity dust particles

The nonlinear dust‐ion‐acoustic (DIA) solitary structures have been studied in a dusty plasma, including the Cairns‐Gurevich distribution for electrons, both negative and positive ions, and immobile opposite polarity dust grains. The external magnetic field directed along the z‐axis is considered. By using the standard reductive perturbation technique and the hydrodynamics model for the ion fluid, the modified Zakharov–Kuznetsov equation was derived for small but finite amplitude waves and was provided the solitary wave solution for the parameters relevant. Using the appropriate independent variable, we could find the modified Korteweg–de Vries equation. By plotting some figures, we have discussed and emphasized how the different plasma values, such as the trapping parameter, the positive (or negative) dust number density, the non‐thermal electron parameter, and the ion cyclotron frequency, can influence the solitary wave structures. In addition, using the bifurcation theory of planar dynamical systems, we have extracted the centre and saddle points and illustrated the phase portrait of such a system for some particular plasma parameters. Finally, we have graphically investigated the behaviour of the solitary energy wave by changing the plasma values as well as by calculating the instability criterion; we have also discussed the growth rate of the solitary waves. The results could be useful for studying the physical mechanism of nonlinear propagation of DIA solitary waves in laboratory and space plasmas where non‐thermal electrons, pair‐ions, and dust particles can exist.     

Ion Heating in Dusty Plasma of Noble Gas Mixtures

Ion heating in dusty plasma of noble gas mixtures is studied by the observation of dust particles in stratified glow discharge. The particles and their formations can be used as a “contact‐free” probe of the ion flows. It is shown that under condition of experiments transition of dust particles into crystalline state in pure gases occur at much lower pressures in comparison to the case of gas mixtures. This observation is also supported by the evaluation of “effective” kinetic temperature of dust particles as defined from the velocity distribution function at the same set of discharge parameters. Absolute value of temperature of dust component in the mixture of helium and argon indicates important role of argon ionization process (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Theoretical model for the effect of dust grains on self‐filamentation of a gaussian electromagnetic beam in a fully ionized plasma

A theoretical model for the effect of dust grains on the self‐filamentation of a Gaussian electromagnetic beam propagating in a fully ionized plasma has been developed by employing the energy balance of the plasma constituents, perturbed electron and ion concentrations, and temperature. In this model, neutral atom ionization, re‐integration and accumulation of electrons and ions, photoelectric emission of electrons from the surface of dust grains, as well as elastic and charging collisions have also been considered. The effective dielectric constant in the presence of dust grains has been constructed. The effect of temporal growth of dust grains on various plasma parameters for different values of the dust density has been explored. The variation of the beam width with the normalized channel of propagation has been observed for distinct dust densities and dust charge states. It is observed that the non‐linearity induced by the effective dielectric constant in the presence of dust grains increases the self‐filamentation of the beam, thus enhancing the effective critical power with the dust density. Some of the outcomes of our approach are in line with experimental observations. These outcomes may be useful for explaining space and laboratory plasma experiments as well as for future studies in complex plasmas.     

Effects of non‐extensive electrons on the sheath of dusty plasmas with variable dust charge

In this study, a detailed investigation of the problem of sheath is presented using the fluid model in a magnetized three‐component dusty plasma system comprising positive ions, dust grains with variable charge and q‐non‐extensive electrons (i.e., the electrons evolve far away from their Maxwellian thermodynamic equilibrium [q = 1]). The effects of q‐non‐extensivity parameter on the plasma sheath parameters are studied numerically. A significant change is observed in the quantities characterizing the sheath with the presence of the super‐extensive electrons (q < 1) and sub‐extensive electrons (q > 1). In addition, based on the orbital motion limited theory, by taking various forces acting on the dust particle into consideration, the dynamics of the dust located within the sheath, that is, the dust grain charging inside the sheath, is examined under different values of q. It is found that the q‐non‐extensivity has affected significantly the dynamics and the charging process of the dust grains in the sheath.     

Development of diamond-based X-ray detection for high-flux beamline diagnostics

High‐quality single‐crystal and polycrystalline chemical‐vapor‐deposition diamond detectors with platinum contacts have been tested at the white‐beam X28C beamline at the National Synchrotron Light Source under high‐flux conditions. The voltage dependence of these devices has been measured under both DC and pulsed‐bias conditions, establishing the presence or absence of photoconductive gain in each device. Linear response consistent with the theoretically determined ionization energy has been achieved over eleven orders of magnitude when combined with previous low‐flux studies. Temporal measurements with single‐crystal diamond detectors have resolved the nanosecond‐scale pulse structures of both the NSLS and the APS. Prototype single‐crystal quadrant detectors have provided the ability to simultaneously resolve the X‐ray beam position and obtain a quantitative measurement of the flux.     

Quasi-stationary stage of a nonequilibrium optical discharge in the field of a Bessel wave beam

The self-consistent stationary distributions of the field and plasma produced by Bessel wave beams in a gas with the ionization and Kerr nonlinearities are studied analytically. Using a stationary model based on the condition of a constant field amplitude in the ionized region, the structures are considered to be formed by Bessel beams of two types: with an azimuthal electric field equal to zero at the symmetry axis and a quasitrans-verse field having a maximum at the axis. A specific feature of the plasma channel formed in the first case is the presence of a nonionized region in its central part (tubular discharge), whose radius is independent of the incident power. In the second case, the channel is continuous. The relation is found between the incident radiation power and the external radius of the discharge. It is shown that the Kerr nonlinearity, which is especially important at small divergence angles of the beam, enhances the maximum plasma density and reduces the discharge radius. The parameters of plasma structures produced upon focusing a Gaussian beam by a conical lens are estimated using the model proposed.     

Dust ion‐acoustic solitons with trapped q‐non‐extensive electrons,dissipative processes,and streaming ions

The characteristics of dust ion‐acoustic waves (DIAWs) that are excited because of streaming ions and hot q‐non‐extensive electrons obeying a vortex‐like distribution are investigated. By exploiting a pseudo‐potential technique, we have derived an energy integral equation. The presence of non‐extensive q‐distributed hot trapped electrons and a streaming ion beam has been shown to influence soliton structure quite significantly. The evolution of the soliton‐like perturbations in complex plasmas, taking into account the dissipation processes, are also investigated, obtained by numerically solving the modified Schamel, equation whose widths are dependant on electron trapping efficiency β. Our illustrations indicate that compressive DIAWs develop in this plasma. As the plasmas in reality have a relative flow, such an analysis can be used to understand the DIA solitary structures observed in the mesospheric noctilucent clouds.     

Equilibrium establishment kinetics for a heavy component in short thermionic discharges

The effect of the heavy component balance in a short Knudsen-type thermionic discharge initiated in cesium vapor is studied. Detailed measurements of the plasma parameters at the instant of discharge initiation and at switching from one quasi-stationary regime to another make it possible to elucidate the temporal hierarchy of processes responsible for the heavy component balance: ionization of atoms in the discharge gap up to an ultimate degree of plasma ionization, establishment of heavy particle-electrode equilibrium, and establishment of heavy particle-buffer volume equilibrium in the discharge gap (the last process is the slowest).     

High‐Capacity Anode Materials for Lithium‐Ion Batteries: Choice of Elements and Structures for Active Particles

Growing market demand for portable energy storage has triggered significant research on high‐capacity lithium‐ion (Li‐ion) battery anodes. Various elements have been utilized in innovative structures to enable these anodes, which can potentially increase the energy density and decrease the cost of Li‐ion batteries. In this review, electrode and material parameters are considered in anode fabrication. The periodic table is then used to explore how the choice of anode material affects rate performance, cycle stability, Li‐ion insertion/extraction potentials, voltage hysteresis, volumetric and specific capacities, and other critical parameters. Silicon (Si), germanium (Ge), and tin (Sn) anodes receive more attention in literature and in this review, but other elements, such as antimony (Sb), lead (Pb), magnesium (Mg), aluminum (Al), gallium (Ga), phosphorus (P), arsenic (As), bismuth (Bi), and zinc (Zn) are also discussed. Among conversion anodes focus is placed on oxides, nitrides, phosphides, and hydrides. Nanostructured carbon (C) receives separate consideration. Issues in high‐ capacity research, such as volume change, insufficient coulombic efficiency, and solid electrolyte interphase (SEI) layer stability are elucidated. Finally, advanced carbon composites utilizing carbon nanotubes (CNT), graphene, and size preserving external shells are discussed, including high mass loading (thick) electrodes and electrodes capable of providing load‐bearing properties.     

Radial Distributions of Dusty Plasma Parameters in a DC Glow Discharge

A non‐stationary non‐local kinetic model for radial distributions of dusty plasma parameters based on the solution of Boltzmann equation for electron energy distribution function is presented. Electrons and ions production in ionizing collisions and their recombination on dust particle surface were taken into account. The drift‐diffusion approximation for ions was used. To obtain the self‐consistent radial distribution of electric potential the Poisson equation was used. It is shown that at high dust particle density the recombination of electrons and ions can exceed their production in ionization collisions in the region of dusty cloud. In this case the non‐monotonous radial distribution of the electric field is formed, the radial electric field becomes reversed and the radial electron and ion fluxes change their direction toward the center of the tube (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)