共查询到18条相似文献,搜索用时 156 毫秒
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本文对Nd-Fe-Si三元系富铁区域相的结构和磁性进行了研究。结果表明,Nd-Fe-Si三元系富铁区域(Fe>40at%), 除出现NdFe_2Si_2三元金属间化合物外(Si>20at%),同时只出现Nd_2(Fe,Si)_(17)赝二元金属间化合物,其中Si取代9d位的Fe原子,而不能形成类似于Nd_2Fe_(14)B的三元金属间化合物,Si取代Nd_2Fe_(17)中的9d位Fe原子后,使晶胞体积缩小;使饱和磁化强度减小;同时使Fe次晶格的铁磁相互作用增强,导致居里温度增高;还使得Fe次晶格的易面各向异性减弱,造成室温下各向异性场减小。 相似文献
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SmTiFex(x的数值为8—11)可形成稳定的金属间化合物,经测定,晶体结构属于ThMn12型四方结构,空间群为14/mmm,本文着重分析了Sm(TiFe)12和Gd(TiFe)12的结构和磁性。Sm(TiFe)12具有很强的单轴磁晶各向异性,易磁化方向为c轴,居里温度610K。通过对Gd(TiFe)12磁性的研究,进一步分析了在Sm(TiFe)12中Sm和Fe次晶格的各向异性,实验结果表明,Sm和Fe次晶格都具有单轴磁晶各向异性,易磁化方向皆沿c轴。这是继Nd2Fe14B型永磁体以后发现的又一种具有单轴磁晶各向异性的三元稀土-铁金属间化合物。
关键词: 相似文献
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通过X射线衍射和磁性测量等手段研究了(Nd1-xGdx)3Fe27.31Ti1.69(0≤x≤0.6)化合物的结构和磁性.X射线衍射测量结果表明Gd替代后并未改变Nd3(Fe,Ti)29化合物的晶体结构,但引起了晶胞体积收缩.随着Gd含量的增加,化合物的居里温度TC和室温磁晶各向异性场Ba单调增加,而自旋重取向
关键词:
1-xGdx)3Fe27.31Ti1.69化合物')" href="#">(Nd1-xGdx)3Fe27.31Ti1.69化合物
磁晶各向异性
自旋重取向
磁相图 相似文献
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合成了Er3Fe29-x-yCoxMy化合物(M=Cr, V, Ti, Mn, Ga, Nb )并用x射线衍射和磁测量等手段研究了它们的结构和磁性. 发现Fe基Er3(Fe,M)29化合物结晶成哑铃对Fe-Fe无序替代的Th2Ni17型结构(P63/mmc空间群)而不能形成Nd3(Fe,Ti)29型结构,因此其化学式也可以用Er2-n(Fe,M)17+2n (n=0.2)表示. 当Er3Fe29化合物中部分Fe原子被M原子所取代时,其居里温度均有一定程度的提高. 所有Er3(Fe,M)29化合物在室温均为易面型各向异性. 当Er3(Fe,M)29 (M=Cr, V)中的部分Fe原子被Co原子取代且Co原子数与Fe原子数达到一定比值时,得到一个单斜结构的新相. 磁测量表明Er3Fe19.5Co6V3.5在室温可能为单轴各向异性,在162K出现自旋重取向,其各向异性由易轴型变为易面型. 在5K下于难磁化方向磁化时观察到一个一级磁化过程(FOMP).
关键词:
稀土金属间化合物
晶体结构
磁晶各向异性 相似文献
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通过x射线衍射及磁测量手段研究了Y2(Fe1-y-x,Coy,C rx)17化合物的结 构及居里温度.研究结果表明Y2(Fe1-y-x,Coy,Crx)17化合物具有六 角相的Th2Ni17型结构.随着x的增加,Y2(Fe
关键词:
2(Fe1-y-x')" href="#">Y2(Fe1-y-x
y')" href="#">Coy
x)1 7化合物')" href="#">Crx)1 7化合物
x射线衍射
居里温度 相似文献
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The crystal structure of a ternary compound, whose chemical composition is Nd5Fe18B18, has been determined. Nd atoms on the one hand, Fe and B atoms on the other hand, form 2 different substructures, both of tetragonal symmetry. In a previous investigation1 only incommensurate or very long period ordering along the directions between the 2 substructures was proposed, with non-definite composition. The whole structure is now described in the Pccn orthorhombic space group (a=b=7.117Å ; c = 35.07Å). This compound appears then as a new Nowotny-like phase. Fe atoms are essentially non magnetic. Ferromagnetic order between Nd atoms occurs only below 14 K. 2nd order Crystalline Electric Fiel (CEF) terms are deduced from the anisotropy of the paramagnetic susceptibility. Higher order CEF terms must also be considered. 相似文献
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利用x射线衍射和磁测量研究了不同稳定元素Co以及Ti,V和Cr替代对Nd3Fe29-x-yCoxMy(M=Ti,V,Cr)化合物结构和磁性的影响.研究发现:每一个稳定元素都有一替代量极限,在此极限以内所有化合物均为Nd3(Fe,Ti)29型结构,A2/m空间群.不同稳定元素的溶解极限不同.Co的替代量与稳定元素有关,当以Cr作为稳定元素时,Cr的替代量随着Co含量的提高而提高
关键词:
3(Fe')" href="#">Nd3(Fe
Co
29')" href="#">M)29
结构
磁性 相似文献
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Crystallographic and magnetic properties of a new structural series of ternary borides with composition R1+εFe4B4 (R = Ce, Pr, Nd, Sm, Gd, Tb, 0.11(Pr) ≤ε≤ 0.15(Tb) are reported. The compounds are built of incommensurate substructures of rare earth atoms (linear strings ?? c?), iron atoms (chains of edge sharing tetrahedra ?? c?),and boron atom pairs. A single crystal X-ray diffraction study of one representative (Sm1.13Fe4B4) based on a commensurate structure model (composition : Sm17(Fe4B4)15, a = 7.07 Å, c ≡ 17cSm ≡ 15cFe= 58.69 Å, space group P42/n) revealed a periodic twist modulation of the Fe tetrahedra chains around c?. Magnetic susceptibility measurements on single crystals of another representative (Nd1.11Fe4B4) revealed ferromagnetic ordering at Tc = 13 K. Above this temperature the magnetic properties are dominated by ferromagnetic inclusions (Fe2B, Nd2Fe14B). 相似文献
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A. Gholizadeh N. TajaborM. Behdani M. KriegischF. Kubel M. SchönhartF. Pourarian R. Grössinger 《Physica B: Condensed Matter》2011,406(18):3465-3469
In this work, the structural and magnetic properties of Tb3 (Fe28−xCox) V1.0 (x=0, 3, 6) compounds have been investigated. The structural characterization of compounds by X-ray powder diffraction is an evidence for a monoclinic Nd3(Fe, Ti)29-type structure (A2/m space group). The refined lattice parameters a and b (but not c) and the unit cell volume V, obtained from the XRD data by the Rietveld method, are found to decrease with increasing Co concentration. The unit cell parameters behavior has been attributed to the smaller Co atoms and a preferential substitution of Fe by Co. The anisotropy field (Ha) as well as critical field (Hcr) was measured using the singular point detection (SPD) technique from 5 to 300 K in a pulsed magnetic field of up to 30 T. At T=5 K, a FOMP of type 2 was observed for all samples and persists at all temperatures up to 300 K. For sample x=0, Hcr=10.6 and 2.0 T at 5 and 300 K, respectively, is equal to that reported earlier. The occurrence of canting angles between the magnetic sublattices during the magnetization process instead of high-order anisotropy contributions (at room temperature are usually negligible) has been considered to explain the survival of the FOMP at room temperature. The anisotropy and critical fields behave differently for samples with x=0, 3 compared with x=6. The observed behavior has been related to the fact that the Co substitution for Fe takes place with a preferential entrance in the inequivalent crystallographic sites of the 3:29 structure. The contribution of the Tb-sublattice in the Tb3(Fe, V)29 compound with uniaxial anisotropy has been scaled from the anisotropy field measured on a Y3(Fe, V)29 single crystal with easy plane anisotropy. 相似文献
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The crystallographic and magnetic structures of Nd2Fe17Nx(x = 2.5, 3.0, 5.5) at room temperature were refined by Rietveld analysis of neutron powder diffraction data. We found that Nd2Fe17Nx has a Th2Zn17 type structure (S.G. R3m) and the nitrogen atoms occupy both 9e and 18g sites simultaneously and at different rates. 相似文献
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Diffusion in ordered Fe-Si alloys 总被引:1,自引:0,他引:1
The measurement of the diffusional Mössbauer line broadening in single crystalline samples at high temperatures provides microscopic information about atomic jumps. We can separate jumps of iron atoms between the various sublattices of Fe-Si intermetallic alloys (D03 structure) and measure their frequencies. The diffusion of iron in Fe-Si samples with Fe concentrations between 75 and 82 at% shows a drastic composition dependence: the jump frequency and the proportion between jumps on Fe sublattices and into antistructure (Si) sublattice positions change greatly. Close to Fe3Si stoichiometry iron diffusion is extremely fast and jumps are performed exclusively between the three Fe sublattices. The change in the diffusion process when changing the alloy composition from stoichiometric Fe3Si to the iron-rich side is discussed. 相似文献