共查询到18条相似文献,搜索用时 78 毫秒
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报道了H+5的实验结果.分析讨论了H+5的 形成和分解途径.根据理论分析,以稳定的H+3为核心与一个或多个氢分子结合可能形成稳定的H+ sup>n氢团簇离子.另一方面,在高频离子源中, 有发生H+3与H2反应的条件.实 验中,从高频离子源引出的离子束被静电加速器加速,然后用9
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+5团簇离子')" href="#">H+5团簇离子
3中性团簇')" href="#">H3中性团簇
4中性团簇')" href="#">H4中性团簇 相似文献
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报道了关于H+4团簇的实验研究结果,从H+4的分解能谱发现可能存在H3团簇.分析讨论了H+4的形成方式和可能的分解途径. 相似文献
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用激光溅射 -分子束技术研究了Cu等离子体与乙腈团簇的气相反应 .观察到Cu+ (CH3 CN) n、CH2 CN+ (CH3 CN) n、H+ (CH3 CN) n 和CH3 CHCN+ (CH3 CN) n 四个种类的团簇离子 .考察了等离子体作用于脉冲分子束的不同位置 ,对团簇产物的种类和尺寸大小的影响 .实验结果表明 ,Cu+ (CH3 CN) n 是由Cu+ 与乙腈团簇直接缔合而成 ,CH2 CN+ (CH3 CN) n、H+ (CH3 CN) n 主要是激光等离子体中的电子与乙腈团簇碰撞电离产生的 ,而CH3 CHCN+ (CH3 CN) n 是由乙腈团簇离子内的离子 分子反应生成的 . 相似文献
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利用多光子电离技术结合飞行时间质谱仪对甲醇/水混合团簇进行了研究.在脉冲激光波长为355 nm条件下观测到团簇离子.主要的电离产物为质子化的(CH3OH)n(H2O)H+(n=l-13)混合团簇离子与(CH3OH)nH+团簇离子,经分析(CH3OH)1o(H2O) H+和(CH3OH)3H+为幻数结构.甲醇水混合团簇电离后团簇离子发生内部质子化转移反应是形成质子化团簇离子的主要原因.不同尺寸团簇离子信号强度随电离激光光强变化的光强指数曲线显示,团簇均发生四光子电离过程. 相似文献
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用激光溅射 分子束技术研究了气相中Ni的等离子体与甲醇分子团簇的反应 .观察到Ni+ (CH3 OH) n、NiO+ (CH3 OH) n、H+ (CH3 OH) n、H3 O+ (CH3 OH) n 四个种类的团簇正离子和CH3 O-(CH3 OH) n(n≤ 2 5 )一种团簇负离子 .详细考察了激光烧蚀等离子体作用于脉冲分子束的不同位置时 ,对团簇产物种类和团簇尺寸大小的影响 .发现NiO+ (CH3 OH) n 是由Ni+ (CH3 OH) n 团簇内的脱甲烷反应生成的 ,而H+ (CH3 OH) n、H3 O+ (CH3 OH) n主要是激光等离子体中的电子与甲醇团簇碰撞电离产生的 相似文献
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采用卢瑟福背散射方法,测得了每质子能量为650 keV的H+2,H+3团簇离子在Si晶体<100>和<110>沟道条件下的质子背散射能谱.结果发现,由于H+2,H+3团簇在晶体中的库仑爆炸和团簇效应,H+2的背散射质子产额大于H+的背散射产额,而H+3的背散射质子产额又大于H+2的背散射质子产额.通过计算,分别得到了H+2,H+3在<100>和<110>沟道方向的背散射质子产额相对于随机方向背散射产额之比随深度的分布. 相似文献
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利用瑞利散射方法研究了超声喷流Ar-CH4混合团簇和超声喷流Ar-H2混合团簇的特性.通过测量不同混合比例和不同背压下所形成混合团簇的散射信号发现,当用Ar气和CH4的混合气体进行超声喷流时很容易形成Ar-CH4混合团簇,当Ar气含量为50%时混合团簇尺度最大且大于相同气压下纯Ar团簇尺度和纯CH4团簇尺度.实验发现,与纯H2团簇只能在低温条件下获得不同,常温下即可形成Ar-H2混合团簇,实现了常温下含氢团簇的获取,从而有效降低了制备成本.在H2含量大于40%时混合团簇开始形成并在60%时达到最大尺度.含氢(氘)混合团簇在氢(氘)团簇的基础上引入了更重的异核Ar元素,在激光氘团簇聚变实验中它将进一步加速氘离子从而获得更高的能量,并具有更高的中子产额和聚变效率. 相似文献
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M. Kimura L. Pichl Y. Li H.-P. Liebermann R. J. Buenker I. F. Schneider 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,38(1):85-91
The positive water and hydronium ions are of interest in a
variety of chemical and biological applications. Here we study the
steric effect in charge transfer collisions, i.e. the spatial
dependence of single electron capture, in collisions mediated by
these ions. In particular, the steric effect is demonstrated in the
O+(2D)/H2 and H+/H2O charge transfer collisions in
the energy range of 100 eV/amu to 10 keV/amu. 相似文献
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Using a photon-particle delayed coincidence method the energy distributions of H +H(2p) and H++H(2p) fragment pairs have been measured arising from collisional dissociation of 10 keV H 2 + ions incident on various target gases. H fragments in their 2p state are identified by the Lymanα radiation emitted. The distribution of H+H(2p) fragment pairs arising from dissociative charge exchange reveals a sharp increase below 0.2 eV in the center-of-mass frame of the H 2 + ion. This is ascribed to predissociation of vibrational levels of higher H2 Rydberg states close above then=2 dissociation limit by those H2 Rydberg states which separate into H+H(2p) fragments. Only direct transitions into the continuum of theGK 1 ∑ g + state may compete. Some structure at 0.3–0.5 eV is attributed to the three statesI 1 П g,i 3 П g, andh 3 bE g + having potential barriers of this height. The distributions for H++H(2p) have maxima at 3.4, 3.8, and 4.2 eV for a H2, Ar, and He target, respectively, indicating that the 2pπ u state as well as the 3dσ g state ofH 2 + is excited. The H+H(2p) process has a greater probability than the H++H(2p) process for Ar and H2 targets, though all electronic H2 states under consideration are bound. 相似文献
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Collision-induced absorption in the translation-rotation band of H2 and H2-He mixtures has been measured from 20 to 900 cm-1 at 77.4, 195 and 292 K. To establish the accuracy of the results, various sources of error are investigated. The zeroth and first spectral moments are evaluated from experiment and theory for H2 at the various temperatures. To obtain theoretical moments consistent with the experimental values, the quantum pair-distribution function must be used. The major portion of the experimental moments can be accounted for by quadrupole-induced dipoles in H2 pairs. The remaining portion is attributable to an anistropic overlap interaction, although its magnitude depends on the value of the molecular parameters required to calculate the quadrupole contribution. 相似文献
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应用改进的排列通道量子力学方法(ACQM)对H+2离子与H原子的相互作用进行了研究.研究结果表明,H+2离子与H原子相互作用能够形成稳定的正三角形构型的H+3离子,从而为实验上制备H+3离子找到了一种新的方法. 相似文献
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Moate CP O'Brien MC Dunn JL Bates CA Liu YM Polinger VZ 《Physical review letters》1996,77(21):4362-4365