液晶的转动粘质系数的测试原理与方法

液晶的转动粘质度是液晶用于显示和通讯的重要物理参量.本文设计开发了基于微机的液晶参数测试光学系统，在该系统上研究了液晶的转动粘质系数的测试原理与方法：通过测试液晶盒在偏置电压下相位驰预时间，推导出转动粘质系数的值.测试Merck公司的 E7液晶的转动粘质系数随温度变化的曲线，进行了理论拟合，测试结果与理论符合得很好.通过分析另一系统对液晶介质常数随温度变化的曲线的测试结果，验证了该测试原理与方法的正确性.该测试方法具有简单、自动化的特点.     

Hydrodynamics of nematic liquid crystals due to direct volume expansion

Hydrodynamics of planar nematic liquid crystal molecules under the influence of horizontal pressure gradient was studied, theoretically. The pressure gradient is due to nematic liquid crystal volume expansion which is a consequence of the incompressibility of the liquid. The resulting director reorientation which is due to coupling between the director orientation and fluidity of the liquid is calculated numerically for the hard and weak anchoring conditions at the cell walls.     

Entropy-driven enhanced self-diffusion in confined reentrant supernematics

We present a molecular dynamics study of reentrant nematic phases using the Gay-Berne-Kihara model of a liquid crystal in nanoconfinement. At densities above those characteristic of smectic A phases, reentrant nematic phases form that are characterized by a large value of the nematic order parameter S?1. Along the nematic director these "supernematic" phases exhibit a remarkably high self-diffusivity, which exceeds that for ordinary, lower-density nematic phases by an order of magnitude. Enhancement of self-diffusivity is attributed to a decrease of rotational configurational entropy in confinement. Recent developments in the pulsed field gradient NMR technique are shown to provide favorable conditions for an experimental confirmation of our simulations.     

Dielectric and electrooptical properties of hockey-stick-shaped liquid crystal with a negative dielectric anisotropy

We investigated dielectric properties of a hockey-stick-shaped liquid crystal (HLC). Two dielectric relaxation modes were observed at 0.91 kHz and 4.51 MHz. The low frequency relaxation modes in isotropic, smectic, and nematic phases are related to the motion of ions, collective tilt fluctuation, and rotation around the long molecular axis, respectively. Meanwhile, the high frequency relaxation modes in nematic and smectic phases was due to the rotation around the short axis of the molecules and hindered by the resistance of the ITO layers. We also examined the electrooptical response of the 5.0 wt% HLC-doped commercial nematic liquid crystal (LC) mixtures. The birefringence of the LC mixture was slightly increased, while the falling time and the rotational viscosity was decreased in the nematic phase.     

Thermal orientation effect in a nematic liquid crystal

The system of equations describing the thermal orientation effect in nonchiral liquid crystals, which was observed earlier, is proposed and substantiated. The effect of the director reorientation under the action of the temperature gradient is in many ways analogous to the Freedericksz transition in electric or magnetic fields. The angle of deviation of the director from the initial position is determined by the square of the temperature gradient. The effect is observed for a nematic liquid crystal, initially uniformly oriented, and is not accompanied by macroscopic fluxes of the medium under stationary conditions.     

Effective frequency-dependent anchoring coefficient and rotational viscosity of nematic liquid crystals

The effective rotational viscosity and polar anchoring coefficient of a nematic liquid crystal were determined using electro-optical response by changing the frequency of the electric field in the kilohertz range. Both quantities monotonically decreased with an increase in the frequency and converged to a certain value at several tens of kilohertz. The effective rotational viscosity changes more than the order of magnitude in experimental range. On the other hand, the effective value of anchoring coefficient changes several times. We tried to explain the trends with the effect of an electric field induced by the motion of ionic impurity in liquid crystal.     

向列相液晶动态全息存储特性的研究

研究了C60掺杂向列相液晶中全息光栅的形成, 实验中我们利用了一种特殊的全息再现方法：即低电压记录, 高电压再现, 观察到清晰的全息再现像. 实验结果表明样品具有良好的全息存储能力. 分析了电压对实验结果的影响, 实验表明：为了避免动态散射的出现应使用较低的记录电压, 而再现时应采取高电压以重新激发隐藏的光栅, 提高再现的质量.     

扭曲向列相液晶电光效应的微观机理研究

为了探究液晶电光效应的微观机理,以扭曲向列相液晶为研究对象,对液晶分子的变化情况进行了理论分析。运用连续体弹性理论分析了扭曲向列相液晶分子的指向矢取向变化,并对液晶电光效应曲线不同区间范围液晶微观结构的变化进行了系统分析。结果表明:液晶分子在零电场条件下的扭曲是均匀的;当外加电场大于某一值时,液晶分子开始转向,液晶产生电光效应。研究结果对液晶显示器件设计和深入理解液晶电光效应机理具有一定的指导意义。     

液晶指向矢分布的模拟和比较研究

用差分迭代法计算了扭曲、超扭曲以及混合排列丝状液晶在电场中指向矢的空间分布,与牛顿法和张弛法的计算作了比较;并应用于液晶电光特性的模拟计算 关键词： 液晶 指向矢 差分迭代     

Nematic liquid crystals formed by living amoeboid cells

Interacting cells have the ability to form liquid crystal phases: (i) A cluster of a polar nematic liquid crystal is formed by cells which emit molecules for attracting other cells and (ii) an apolar nematic liquid crystal is formed by elongated cells which have an anisotropic steric repulsion. The angle distribution function is predicted by using the characteristics of an automatic controller where the extracellular guiding field is approximated by two-dimensional mean-field. The nematic liquid crystal state is quite well described by the model. Received 7 September 1998 and Received in final form 4 March 1999     

Amplification of the emission of a liquid-crystal microlaser by means of a uniform liquid-crystal layer

The amplification of the emission of a microlaser based on a cholesteric liquid crystal by means of a uniformly oriented layer of a laser-dye-doped nematic liquid crystal is demonstrated. The nematic liquid crystal is characterized by the anisotropy of optical properties, including the amplification coefficient, which opens the possibility of creating amplifiers controlled by a low electric field.     

Creation of tunable absolute bandgaps in a two-dimensional anisotropic photonic crystal modulated by a nematic liquid crystal

Photonic crystals (PCs) have many potential applications because of their ability to control light-wave propagation. We have investigated the tunable absolute bandgap in a two-dimensional anisotropic photonic crystal structures modulated by a nematic liquid crystal. The PC structure composed of an anisotropic-dielectric cylinder in the liquid crystal medium is studied by solving Maxwell's equations using the plane wave expansion method. The photonic band structures are found to exhibit absolute bandgaps for the square and triangular lattices. Numerical simulations show that the absolute bandgaps can be continuously tuned in the square and triangular lattices consisting of anisotropic-dielectric cylinders by infiltrating nematic liquid crystals. Such a mechanism of bandgap adjustment should open up a new application for designing components in photonic integrated circuits.     

Self-asymmetrization of phase grating profile in a nematic S layer: Partially continuous model

The self-asymmetrization of dynamic phase grating profile in a model medium with properties of nematic liquid crystal, caused by the internal electric field induced in this medium, has been numerically simulated.     

Preparation and characterization of vinyltriethoxysilane based inorganic–organic gel glasses dispersed 4′-n-pentyl-4-cyanobiphenyl nematic liquid crystal

Vinyltriethoxysilane based inorganic–organic glasses dispersed with 4′-n-pentyl-4-cyanobiphenyl nematic liquid crystal are designed to fabricate a new type of gel glass dispersed with liquid crystal. Scanning electron microscopy shows that the nematic liquid crystal phase, occupying the interconnected cavities, is continuously embedded in the inorganic–organic matrixes. The effect of the nematic liquid crystal weight concentration on the morphology is investigated. The differential scanning calorimetry shows that the nematic-isotropic transition temperature depends on the nematic liquid crystal weight concentration. The Raman spectra show that there are no obvious Raman frequency shifts, compared with pure nematic liquid crystal. The in situ diffuse reflectance FTIR spectra show that the integral intensity of bands of hydroxyls has not varied.     

Order parameter dependence of the viscosity coefficients of a biaxial nematic liquid crystal

We derive expressions for the order parameter dependence of the viscosity coefficients of a biaxial nematic liquid crystal by comparing its dissipation function expressed in terms of directors with that expressed in terms of order tensors. The results enable us to identify the dominant flow viscosity coefficients and to compare their temperature variation according to their dependence on the dominant scalar order parameters. By considering different orientations of an external field, we identify three characteristic switching times corresponding to three rotational viscosities, and we estimate the ratio of the switching times of the primary and the secondary directors.     

Hysteresis and noise from electronic nematicity in high-temperature superconductors

An electron nematic is a translationally invariant state which spontaneously breaks the discrete rotational symmetry of a host crystal. In a clean square lattice, the electron nematic has two preferred orientations, while dopant disorder favors one or the other orientations locally. In this way, the electron nematic in a host crystal maps to the random field Ising model. Since the electron nematic has anisotropic conductivity, we associate each Ising configuration with a resistor network and use what is known about the random field Ising model to predict new ways to test for local electronic nematic order (nematicity) using noise and hysteresis. In particular, we have uncovered a remarkably robust linear relation between the orientational order and the resistance anisotropy which holds over a wide range of circumstances.     

One- and two-dimensional deformations in nematic liquid crystals: Influence of the flexoelectric polarization

Summary The elastic deformations in nematic liquid crystals are analysed in one and two dimensions. The influence of the flexoelectric polarization on the elastic properties of the medium is studied. It is shown that for one-dimensional deformations, the presence of the flexoelectric polarization introduces a renormalization of the elastic constants. On the contrary in the bidimensional case, the effect of the flexoelectricity is not a simple renormalization of the elastic constants. The profiles of the electric potential and of the tilt angle are evaluated for the cases in which the substrate is an insulating or conducting material. The validity of the calculations is discussed by considering the value of Debye's screening length of the nematic liquid crystal.     

Lowering of the Magnetic Fréedericksz transition threshold in nematic liquid crystals doped with ferromagnetic nanoparticles

We show that magnetic colloids could increase the coupling of a liquid crystal to a week magnetic field. Magnetic Fréedericksz transition in a planarly oriented nematic liquid crystal doped with spherical ferromagnetic nanoparticles is considered theoretically. It is shown that even spherical nanoparticles could decrease a threshold of this transition because they strongly increase the magnetic field in the medium. This phenomenon indicates the possibility to use the considered system in magneto-optical displays.     

Localized electromagnetic modes and the transmission spectrum of a one-dimensional photonic crystal with lattice defects

The properties of localized electromagnetic modes in a one-dimensional photonic crystal with a structural defect layer were studied. The role of the defect was played by an anisotropic nematic liquid crystal layer. The frequency and the damping factor of defect modes were shown to substantially depend on the defect layer thickness and the orientation of the optical axis of the nematic. The transmission spectra of photonic crystals with one and two lattice defects were studied. Taking into account the special feature of nematic liquid crystals distinguishing them from usual crystals, namely, large permittivity anisotropy, it was shown that the transmission spectrum of the photonic crystal could be controlled by varying the orientation of the optical axis of the nematic, for instance, under the action of an external electric field.