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The glass transition is treated as a spontaneous emergence of the shear components of strain and stress elastic fields upon cooling a liquid at a rate exceeding the critical value. The stationary elastic strains and stresses and the effective relaxation time are determined within the adiabatic approximation. It is shown that the glass transition process occurs through the mechanism of a first-order kinetic transition with allowance made for the strain dependence of the shear modulus. The critical cooling rate turns out to be proportional to the thermal diffusivity and unrelaxed shear modulus and inversely proportional to the temperature derivative of the relaxed shear modulus and the square of the heat conductivity length of the sample. 相似文献
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The stability of nanoscale devices is directly related to elasticity and the effect of temperature on the elasticity of thin films and nanocrystals. The elastic instability induced by rising temperature will cause the failure of integrated circuits and other microelectronic devices in service. The temperature effect on the elastic modulus of thin films and nanocrystals is unclear although the temperature dependence of the modulus of bulk materials has been studied for over half a century. In this paper, a theoretical model of the temperature-dependent elastic modulus of thin films and nanocrystals is developed based on the physical definition of the modulus by considering the size effect of the related cohesive energy and the thermal expansion coefficient. Moreover, the temperature effect on the modulus of Cu thin films is simulated by the molecular dynamics method. The results indicate that the elastic modulus decreases with increasing temperature and the rate of the modulus decrease increases with reducing thickness of thin films. The theoretical predictions based on the model are consistent with the results of computational simulations, semi-continuum calculations and the experimental measurements for Cu, Si thin films and Pd nanocrystals. 相似文献
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Besides their structural complexity, the acoustic behavior of polymer-based poro-elastic layers is complicated also due to their frequency dependent elasticity. In this work, we address the frequency and temperature dependence of the elastic behavior in general, and the shear modulus in particular, of poro-visco-elastic materials. The analysis is based on the monitoring of mechanically excited guided acoustic wave propagation by means of a laser Doppler vibrometer scanning technique. The concept and practical implementation of the experimental method are presented, as well as the signal processing procedure and data analysis. Experimental data are presented for a polyurethane foam. The observed visco-elastic behavior, complemented with dielectric spectroscopy data, is interpreted in the framework of two underlying relaxation processes. 相似文献
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Ling Zhang Congde Qiao Yunqiao Ding Jinyong Cheng Tianduo Li 《Journal of Macromolecular Science: Physics》2013,52(4):747-749
Gelatin/1-allyl-3-methylimidazolium chloride solutions with different gelatin concentrations were prepared by using the ionic liquid 1-allyl-3-methylimidazolium chloride [AMIM]Cl as a solvent. Rheological properties of the gelatin ionic liquid solutions were investigated by steady shear and oscillatory shear measurements. In the steady shear measurements, all gelatin solutions showed a shear-thinning behavior at low shear rates, which we suggest reflect the characteristics of solvent [AMIM]Cl. In the oscillatory shear measurements, the effects of concentration and temperature on solution viscoelasticity were determined. The results show that the storage modulus G′ of gelatin solutions was essentially independent of gelatin concentration and temperature at all frequencies, while the solution viscosity greatly depended on polymer concentration and temperature. The loss modulus G″ increased with increase in concentration and decreased with rising temperature. This indicated that physical origins of elastic and dissipative behaviors were completely different. The influence of dissolved gelatin on the elasticity of solutions seemed to be minor. 相似文献
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H. Montes T. Chaussée A. Papon F. Lequeux L. Guy 《The European physical journal. E, Soft matter》2010,31(3):263-268
We have been able to design model filled rubbers with exactly the same chemical structure but different filler arrangements.
From these model systems, we show that the particle arrangement in the elastomeric matrix controls the strain softening at
small strain amplitude known as the Payne effect, as well as the elastic modulus dependence on the temperature. More precisely,
we observed that the Payne effect disappears and the elastic modulus only weakly depends on the temperature when the particles
are well separated. On the contrary, samples with the same interfacial physical chemistry but with aggregated particles show
large amplitudes of the Payne effect and their elastic modulus decreases significantly with the temperature. We discuss these
effects in terms of glassy bridge formation between filler particles. The observed effects provide evidence that glassy bridges
play a key role on the mechanical properties of filled rubbers. 相似文献
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铼具有高体积弹性模量、高熔点、优良的抗蠕变性能,是一种重要科学研究与工程应用材料。铼的弹性剪切系数C44对温度和压力的响应特性对铼及其合金材料的设计与工程应用具有重要意义。激光拉曼散射技术在研究不同温度和压力条件下六方密堆积结构(hcp)金属的弹性剪切系数C44上具有独特的优势。但由于金属的强反射作用和浅的穿透深度,hcp金属的低波数拉曼散射信号往往很难获取,在一定的温度和压力加载下拉曼信号的获取尤为困难。利用侧向激发拉曼散射技术,有效降低了金属强反射对拉曼光谱采集的影响,成功测量到多晶铼在不同压力与温度条件下的E2g拉曼振动模,获得铼在常温常压条件的弹性剪切系数(C44=133 GPa)以及其弹性剪切系数C44对温度和压力的响应特性。研究结果表明,多晶铼的弹性剪切系数C44模量随压强的增加而增大,随温度的增加而减小。这也为用光散射方法研究金属材料剪切模量提供了良好研究方法。 相似文献
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In the open literature, reports of mechanical properties are limited for semiconducting thermoelectric materials, including the temperature dependence of elastic moduli. In this study, for both cast ingots and hot-pressed billets of Ag-, Sb-, Sn- and S-doped PbTe thermoelectric materials, resonant ultrasound spectroscopy (RUS) was utilized to determine the temperature dependence of elastic moduli, including Young's modulus, shear modulus and Poisson's ratio. This study is the first to determine the temperature-dependent elastic moduli for these PbTe-based thermoelectrics, and among the few determinations of elasticity of any thermoelectric material for temperatures above 300 K. The Young's modulus and Poisson's ratio, measured from room temperature to 773 K during heating and cooling, agreed well. Also, the observed Young's modulus, E, versus temperature, T, relationship, E(T) = E 0(1–bT), is consistent with predictions for materials in the range well above the Debye temperature. A nanoindentation study of Young's modulus on the specimen faces showed that both the cast and hot-pressed specimens were approximately elastically isotropic. 相似文献
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Elastic and anelastic behaviour of single crystal and ceramic samples of Pb(Mg(1/3)Nb(2/3))O(3) has been investigated at frequencies of ~0.1-1.2 MHz through the temperature interval 10-800 K by resonant ultrasound spectroscopy (RUS). Comparison with data from the literature shows that softening of the shear modulus between the Burns temperature and the freezing interval is independent of frequency. The softening is attributed to coupling between acoustic modes and the relaxation mode(s) responsible for central peaks in Raman and neutron scattering spectra below the Burns temperature, and can be described with Vogel-Fulcher parameters. Shear elastic compliance and dielectric permittivity show similar patterns of temperature dependence through the freezing interval, demonstrating strong coupling between ferroelectric polarization and strain such that the response to applied stress is more or less the same as the response to an applied electric field, with a frequency dependence consistent with Vogel-Fulcher-like freezing in both cases. Differences in detail show, however, that shearing induces flipping between different twin orientations, in comparison with the influence of an electric field, which induces 180° flipping: the activation energy barrier for the former appears to be higher than for the latter. Below the freezing interval, the anelastic loss also has a similar pattern of evolution to the dielectric loss, signifying again that essentially the same mechanism is involved in the freezing process. Overall softening at low temperatures is attributed to the contributions of strain relaxations due to coupling with the local ferroelectric order parameter and of coupling between acoustic modes and continuing relaxational modes of the polar nanostructure. Dissipation is attributed to movement of boundaries between PNRs or between correlated clusters of PNRs. Overall, strain coupling is fundamental to the development of the characteristic strain, dielectric and elastic properties of relaxors. 相似文献
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Fen Luo Zhi-Cheng Guo Xiu-Lu Zhang Chang-Ying Yuan Cheng-An Liu Ling-Cang Cai 《Molecular physics》2013,111(12):1501-1507
The study aims at the elastic, mechanical, electronic properties and hardness of Nb2AsC using first principles based on the density functional theory method within the generalised gradient approximation. The calculated lattice parameters of Nb2AsC are in good agreement with the experimental data. The five independent elastic constants are firstly calculated as a function of pressure, and our results indicate that it is mechanically stable in the applied pressure. The elastic anisotropy is examined through the computation of the direction dependence of Young's modulus. The pressure dependences of the bulk modulus, shear modulus, average velocity of acoustic waves and Debye temperature of Nb2AsC are systematically investigated. The band structure and density of states are discussed, and the results show that the strong hybridisations C p–Nb d and As p–Nb d would be beneficial to the structure stability of Nb2AsC. Based on the Mulliken population analysis, the hardness of Nb2AsC is predicted. 相似文献
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Run-Yue Li 《哲学杂志》2016,96(10):972-990
First principles calculations were performed to systematically investigate structure properties, phase stability and mechanical properties of MB (M = Cr, Mo, W) monoborides in orthorhombic and tetragonal structures. The results of equilibrium structures are in good agreement with other available theoretical and experimental data. The elastic properties, including bulk modulus B, shear modulus G, Young’s modulus E and Poisson’s ratio ν were calculated by the Voigt-Reuss-Hill approximation. All considered monoborides are mechanically stable. The results of elastic anisotropies show that elastic anisotropy of orthorhombic structure is larger than that of tetragonal structure. Moreover, the minimum thermal conductivities were also estimated using the Cahill’s model, and the results indicate that the minimum thermal conductivities show a dependence on directions. 相似文献
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Using pseudo-potential plane-wave method based on the density functional theory in conjunction with the generalized gradient approximation, structural parameters, electronic structures, elastic stiffness and thermal properties of M2PC, with M=V, Nb, Ta, were studied. The optimized zero pressure geometrical parameters are in good agreement with the available results. Pressure effect, up to 20 GPa, on the lattice parameters was investigated. Electronic properties are studied throughout the calculation of densities of states and band structures. The elastic constants and their pressure dependence were predicted using the static finite strain technique. We performed numerical estimations of the bulk modulus, shear modulus, Young's modulus, Poisson's ratio and average sound velocity for ideal polycrystalline M2PC aggregates in framework of the Voigt-Reuss-Hill approximation. We estimated the Debye temperature and the theoretical minimum thermal conductivity of M2PC. 相似文献
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Possibilities of using torsional oscillations for measuring viscoelastic properties of liquids are discussed. The theory of
torsional oscillations of an elastic tube filled with the media to be investigated possessing viscosity and shear elasticity
is developed. It is shown that to determine a complex shear modulus it is sufficient to determine the resonance frequency
and Q-factor of torsional oscillations. An experimental installation and the results of measurements of viscoelastic modulus
of glycerin and oil of one oilfield within the temperature range from −10° to 60°C are given. The experimental installation
allows measuring a viscoelastic modulus within the range of acoustic logging frequencies (10–20 kHz). The obtained results
are compared with the results of rheometric measurements. 相似文献
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Determination of elastic,piezoelectric,and dielectric constants of an R:BaTiO<sub>3</sub> single crystal by Brillouin scattering 下载免费PDF全文
From the sound velocity measured using the Brillouin scattering technique,the elastic,piezoelectric,and dielectric constants of a high-quality monodomain tetragonal Rh:BaTiO3 single crystal are determined at room temperature.The elastic constants are in fairly good agreement with those of the BaTiO3 single crystal,measured previously by Brillouin scattering and the low-frequency equivalent circuit methods.However,their electromechanical properties are significantly different.Based on the sound propagation equations and these results,the directional dependence of the compressional modulus and the shear modulus of Rh:BaTiO3 in the(010) plane is investigated.Some properties of sound propagation and electromechanical coupling in the crystal are discussed. 相似文献
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Gardel ML Nakamura F Hartwig J Crocker JC Stossel TP Weitz DA 《Physical review letters》2006,96(8):088102
Networks of filamentous actin cross-linked with the actin-binding protein filamin A exhibit remarkable strain stiffening leading to an increase in differential elastic modulus by several orders of magnitude over the linear value. The variation of the frequency dependence of the differential elastic and loss moduli as a function of prestress is consistent with that observed in living cells, suggesting that cell elasticity is always measured in the nonlinear regime, and that prestress is an essential control parameter. 相似文献
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AbstractThe pressure dependence of the structural, elastic, electronic and thermal properties of Kondo insulator SmB6 have been systematically studied by density functional theory combined with the quasi-harmonic Debye model. The calculated structure at zero pressure is in good agreement with the available experimental results at low temperature. The obtained elastic constants, bulk modulus and shear modulus indicate that SmB6 is mechanically stable and behaves in a brittle manner under the applied pressure 0–20 GPa, consistent with available experimental data. In addition, the elastic-relevant properties, Young’s modulus and the Poisson ratio manifest that increasing pressure results in an enhancement in the stiffness of the compound. It is found that unlike temperature, pressure has little effect on the heat capacity of SmB6. What more important is that we observed an insulator to metal phase transition at about 5.5 GPa through the disappearance of the band gap, well consistent with the experimental data. This transition has little effect on the physical properties of SmB6. 相似文献
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We study elasticity of spontaneously orientationally ordered amorphous solids, characterized by a vanishing transverse shear modulus, as realized by nematic elastomers and gels. We show that local heterogeneities and elastic nonlinearities conspire to lead to anomalous nonlocal universal elasticity controlled by a nontrivial infrared fixed point. Namely, such solids are characterized by universal shear and bending moduli that, respectively, vanish and diverge at long scales, are universally incompressible, and exhibit a universal negative Poisson ratio and a non-Hookean elasticity down to arbitrarily low strains. Based on expansion about five dimensions, we argue that the nematic order is stable to thermal fluctuation and local heterogeneities down to d(lc)<3. 相似文献