Properties of optical limitation of radiation in π-conjugated organic systems doped with fullerenes (The COANP-C70 system)

The effect of optical limitation of laser radiation in 2-cyclooctylamino-5-nitropyridine (COANP-C₇₀) doped with fullerene is experimentally studied. The energy density of the incident beam is measured to be ～4–4.5 J cm^?2 and the attenuation coefficients and the absorption spectrum of a new structure are determined. The photoinduced variation of the refractive index of the COANP-fullerene system and its influence on the optical limitation is studied in the visible range upon irradiation by nanosecond laser pulses. The mechanisms of optical limitation of radiation in these structures are specified. The nonlinear optical coefficients n ₂ and χ⁽³⁾ of the fullerene-doped π-conjugated COANP system are measured for the first time by the methods of dynamic holography.     

Optical pump - nuclear resonance probe experiments on spin crossover complexes

A novel sample environment enabling optical pump – nuclear resonance probe experiments has been installed at the beamline P01, Petra III, DESY Hamburg. This set-up has been used to investigate optically induced spin state changes of spin crossover (SCO) complexes by nuclear resonant scattering immediately after excitation by an optical laser pulse. Here, we report the technical details as well as first results of the experiments performed at 290 K and 80 K on the SCO complexes [Fe (NH₂trz)₃]Cl₂ and [Fe(PM-BiA)₂(NCS)₂], respectively. The ⁵⁷Fe-enriched SCO complexes were excited by a 531 nm laser with a pulse length <?100 ps. Evaluation of the nuclear forward scattering data clearly indicate the presence of high spin (HS) states when the complexes are excited by laser pulses and a pure low spin (LS) state in the absence of any laser pulse. Furthermore, the dependence of the optically excited HS-fraction has been determined as a function of the average optical power.     

Simultaneous intracavity optical parametric oscillation and stimulated Raman scattering pumped by a doubly passively Q-switched Nd:GGG laser

By using a doubly passively Q-switched Nd:Gd₃Ga₅O₁₂(Nd:GGG) laser with Cr⁴⁺:YAG and GaAs as saturable absorbers as pump laser, simultaneous intracavity optical parametric oscillation and stimulated Raman scattering based on a single X-cut KTiOPO₄ (KTP) crystal have been realized. Under an incident diode pump power of 10.5 W, the output powers at the signal wave near 1,569 nm and the first Stokes emission near 1,094 nm were 218 and 72 mW, corresponding to the optical-to-optical conversion efficiencies of 2.08 and 0.69 %, respectively. The measured shortest pulse duration at the signal wave near 1,569 nm was 580 ps, generating a pulse peak power of 43.7 kW, while the minimum pulse duration at the first Stokes emission near 1,094 nm was 1.61 ns. By adjusting the tilt angle of the KTP crystal, up to the third Stokes scattering was also obtained.     

Three-Photon Absorption in Photorefractive BSO and BGO Crystals

The possibility of optical limitation of picosecond laser radiation in photorefractive Bi₁₂SiO₂₀ (BSO) and Bi₁₂GeO₂₀ (BGO) crystals at a wavelength of 1064 nm has been demonstrated. It is shown that the mechanism determining the process of optical limitation is three-photon absorption. The coefficients of three-photon absorption have been determined by the Z-scanning method.     

High-peak power multi-wavelength picosecond pulses generated from a BaWO4 Raman-seeded optical parametric amplifier

We report the generation of high-peak power multi-wavelength picosecond laser pulses using optical parametric amplification (OPA) in BBO seeded with pulses generated in a 5-mm length BaWO₄ crystal by stimulated Raman scattering of 18-ps laser pulses at 532 nm. The maximum output energy of the amplified first-Stokes component at 559.7 nm was about 1.76 mJ. The corresponding maximum peak power, pulse duration and spectral line width were measured to be 117.3 MW, 15 ps and 18.0 cm⁻¹, respectively. The multi-wavelength picosecond laser pulses were in the visible and near infrared ranges. Using this Raman-seeded OPA technique, the beam quality of the stimulated Raman scattering pulses can be improved.     

Thomson Scattering Applied to a Noisy Radiative Plasma

Thomson scattering with a 1.5 ms long pulse mode 20 J ruby laser has been applied to a radiative argon plasma with electron densities n_e from 2.5 10¹⁹ m^?3 to 1.5 10²⁰ m^?3 and an electron temperature T_e of about 3 eV. Photon counting techniques have been used. The accuracy of n_e and T_e to be reached is about 5% after 10 shots. The signal to noise ratio S/N has been optimized by the use of optical filters and a special purpose grating. The effects of these elements on S/N have been calculated. The entrance angle, transmission and quantum efficiency have also been optimized. A comparison between 5 possible laser systems, including a normal mode and a Q-switched mode ruby laser, has been carried out.     

6Li与核弹性散射的微观光学势

从基本的Dirac-Brueckner-Hartree-Fock微观理论出发,得到同时包含实部和虚部的核子-核散射的微观光学势,并利用折叠模型直接获得了核-核散射参数无关的整体微观光学势.考虑到核-核散射去弹过程高级项的贡献和⁶Li的碎裂效应,在微观光学势的实部和虚部中引入了修正因子N_R,N_I.系统研究了入射粒子⁶Li与靶核¹²C,²⁸Si,关键词： 弹性散射 Dirac-Brueckner-Hartree-Fock方法 折叠模型 微观光学势     

高能电子与超强激光束作用产生的阿秒脉冲列

利用非线性汤姆孙散射的理论，从理论和数值模拟上研究了单电子在横向穿越高斯激光束束 腰时所辐射的x射线阿秒脉冲列的性质. 主要分析了电子以初始能量γ₀=1M eV—100M eV横向穿越激光振幅参数为a₀=1—10的高斯光束束腰获得的阿秒辐射脉冲的 时间 和空间性质. 计算表明，辐射呈现脉冲列的形式. 脉冲列的包络宽度取决于激光强度、束腰 的宽度以及入射电子能量. 电子的初始能量比激光强度对电子辐射脉冲的影响更大. 辐射脉 宽、脉冲间隔和脉冲包络宽度都正比于1/γ²₀，辐射功率正比于 γ⁶₀，辐射能 量正比于γ⁴₀. 当改变激光振幅a₀时，辐射功率正比 于a²₀、辐射包络中单 个脉冲脉宽正比于1/a₀、脉冲之间的间隔正比于a₀. 当保持激光强 度不变，而改变光束 束腰半径w₀时，辐射的脉冲数量、包络和辐射能量正比于w₀. 当 激光功率保 持不变时而改变激光强度和束腰半径时，脉冲包络宽度和最大辐射能量都基本不变. 当激光 振幅参数a₀=1，电子初始能量为10MeV时，激光束腰为两个激光波长时，电子 辐 射脉冲包络宽度只有14×10^-3τ₀（τ₀为入 射激光周期），达到几个阿秒的量级. 关键词： 阿秒脉冲 非线性汤姆孙散射 高斯激光光束     

Stimulated thermal scattering induced by two-photon absorption and experimental observation of stimulated Brillouin scattering in the UV region

An analysis of the results of previous studies of stimulated scattering of UV pulses in liquids has shown that they disagree with the theory of stimulated scattering. To resolve the inconsistency, stimulated scattering of XeCl excimer laser radiation (λ = 308 nm) with pulse duration τ ≈ 8 ns in liquid hexane is investigated experimentally. A theoretical analysis of the results obtained revealed a new nonlinear optical phenomenon: stimulated thermal scattering induced by the heating due to two-photon absorption, called two-photon stimulated thermal scattering (two-photon STS-2). The stimulated backscatter spectrum contains a previously unknown line corresponding to two-photon STS-2 and a newly discovered SBS line in the UV region. The line is observed in experiment on liquid hexane and is characterized by the frequency shift Ω_B = 0.33 cm^?1 relative to the pump wavelength λ = 308 nm, in complete agreement with the theory of stimulated Brillouin scattering (SBS). The spectral line called the SBS line in previous studies has a frequency shift much smaller than that predicted by the SBS theory and must be interpreted as an unshifted two-photon STS-2 line. When two-photon STS-2 is used to obtain a phase-conjugate wave, the phase-conjugation fidelity is lower than that achieved by using SBS because of thermal self-action and slow decay of the thermal grating.     

A picosecond near-infrared laser source based on a self-seeded optical parametric generator

We report on the design and development of a new type of near-IR laser source. The source comprises of an optical parametric generator (OPG) and a second harmonic generator (SHG) pumped by an 80-MHz, 1064-nm, 7-ps Nd:YVO₄ laser. The OPG is self-seeded with a fraction of its own signal output, which significantly enhances its conversion efficiency. The SHG doubles the frequency of OPG signal to produce a coherent output. The final output beam has a tunable wavelength near 800 nm, an average power of over 1 W, and a pulse duration around 5 ps. The M²-factor of the output beam can reach 1.1 after spatial filtering. With the new laser source, we have successfully demonstrated coherent anti-Stokes Raman scattering microscopy on 1 μm polystyrene beads, which shows that it has the potential to be a substitute for a picosecond optical parametric oscillator in certain microscopy or spectroscopy applications.     

Fabrication and transmission experiments of distributed feedback laser modules for 2.5 Gb s-1 optical transmission systems

A distributed feedback (DFB) laser module has been developed for 2.5 Gbs^-1 optical transmission systems. The DFB laser has a multiple-quantum-well (MQW) active layer and a planar buried heterostructure (PBH) for a low threshold current and stable singlemode operation with low chirping. A PBH DFB laser module with a single-mode fibre pigtail and an optical isolator was designed and fabricated by employing a single lens and a laser welding method. The fabricated MQW PBH DFB laser module is shown to be a suitable light source for 2.5 Gb s^-1 optical transmission systems with a minimum received power of-33 dBm after 47 km conventional optical fibre transmission.     

Structural changes induced on strontium barium niobate glass by femtosecond laser irradiation

Localized modification of the optical properties of erbium doped strontium barium niobate (SBN) glass has been performed using femtosecond laser irradiation. The samples, with composition SrO–BaO–Nb₂O₅–B₂O₅ and doped with 5%mol of Er³⁺, were fabricated using a melt-quenching method. The samples were irradiated with different number of pulses per spot (1–50 pulses) at two different laser fluences (2.6 and 5.6 J/cm²) by using an fs laser amplifier operating at 800 nm and generating pulses with a duration of 120 fs. Micro-luminescent microscopy, using an Ar⁺ laser as excitation source, has been used to analyze the modifications of the luminescent properties of the sample upon fs laser exposure. The emissions of the Er³⁺: ⁴I_11/2→⁴I_15/2 and ⁴I_13/2→⁴I_15/2 transitions allow appreciating the structural modifications caused by femtosecond laser exposure. The lifetimes of the levels involved in these transitions were measured inside and outside the laser irradiated region. These measurements have been compared with those obtained in bulk glass ceramic sample, which is obtained from the glass precursor by a thermal treatment in order to estimate the optimal conditions to produce nanocrystals in a localized region by ultrafast laser irradiation.     

Multi-beam method to increase the stability of bridge deflection measurement

The main limitation to the accuracy of the detection of a bridge deflection using laser-based optical solutions is atmospheric turbulence because of the laser beam propagation in ground proximity. The multi-beam method is presented to increase the stability of bridge deflection measurement. It is based on the use of a four-beam optical system and a subpixel resolution algorithm for the measurement of the deflection of a laser beam that propagates through the system. To obtain accurate results, different algorithms for measuring the position of the deflected beam in different optical systems are tested and compared. Based on this comparison, the four-beam method based on the macropixels iteration centroid and four-beam optical system is selected, and an accuracy of 0.16 pixels is obtained by the determination of the beam position in our setup. The proposed method is adopted to detect the bridge deflection and an accuracy of 0.01 mm is gained when the scintillation index C_n² is 3×10⁻⁴ m^−2/3.     

Light-induced variation in the refractive index in a polyimide-fullerene system

Light-induced variation in the refractive index of the polyimide-C₇₀ system is studied. This process makes a contribution to the nonlinear transmission of this system in the study of the optical limitation of laser radiation and determines the prospects of using this system as a nonlinear holographic medium for reversible data storage. The nonlinear optical coefficients n ₂ and χ⁽³⁾ of fullerene-sensitized polyimides are determined for the first time by the methods of dynamic holography.     

Patterning and morphology of nonlinear optical Gd<Subscript>x</Subscript>Bi<Subscript>1-x</Subscript>BO<Subscript>3</Subscript> crystals in CuO-doped glass by YAG laser irradiation

Dots and lines consisting of nonlinear optical Gd_xBi_1-xBO₃ crystals were patterned on the surface of CuO-doped Gd₂O₃-Bi₂O₃-B₂O₃ glass by heat-assisted (200 °C) Nd:YAG laser irradiations with a wavelength of λ=1064 nm, where the laser energy absorbed by Cu²⁺ is converted to the local heating of the surrounding Cu²⁺. The surface morphology and orientation of crystals in the patterned lines were clarified from confocal scanning laser microscope observations and polarized micro-Raman scattering spectra. Crystal lines with periodic bumps (i.e., ladder-shape like lines) were patterned by laser irradiations with a power of 0.79 W and a scanning speed of 60 μm/s, and the orientation of Gd_xBi_1-xBO₃ crystals in the lines was proposed. The present study demonstrates that the combination of Cu²⁺ and continuous wave Nd:YAG laser with λ=1064 nm is effective in inducting crystallization of oxide glasses. The mechanism of laser-induced crystallization in glass has also been discussed. PACS 61.43.Fs; 42.70.Mp; 68.35.Bs; 78.30.-j; 79.20.Ds     

Cascaded and cross-cascaded χ(3) nonlinear optical effects in a new SRS-active YAlO3 crystal

Stimulated Raman scattering (SRS) is discovered under picosecond laser excitation in a YAlO₃ orthorhombic crystal, and its cascaded and cross-cascaded χ⁽³⁾ nonlinear optical interactions are studied. Investigations revealed three SRS-active phonon modes of the crystal and identified all its recorded Stokes and anti-Stokes generation lines.     

PVP掺杂-ZrO2溶胶-凝胶工艺制备多层激光高反射膜的研究

以丙醇锆(ZrPr)为锆源，二乙醇胺(DEA)为络合剂，原位引入聚乙烯吡咯烷酮(PVP)，在乙醇体系中成功地合成了PVP掺杂-ZrO₂溶胶.采用旋涂法在K9玻璃基片上制备了PVP-ZrO₂单层杂化薄膜.用不同掺杂量的PVP-ZrO₂高折射率膜层与相同的SiO₂低折射率膜层交替沉积四分之一波堆高反射膜.借助小角X射线散射研究胶体微结构，用红外光谱、原子力显微镜、紫外/可见/近红外透射光谱、椭圆偏振仪以及1064nm的强激光辐照实验对薄膜的结构、光学和抗激光损伤性能进行表征.研究发现，体系组成的适当配置可以在溶胶稳定的前提下实现ZrPr的充分水解，赋予薄膜良好的结构、光学和抗激光损伤性能.杂化体系中，DEA与ZPr之间强的配合作用大大降低了ZrO₂颗粒表面羟基的活性，使得PVP大分子只是以微弱的氢键与颗粒的表面羟基作用而均匀分散于ZrO₂颗粒的周围，对颗粒的形成和生长无显著影响.因而在实验研究范围内，随PVP含量的增大，PVP-ZrO₂杂化膜层的折射率和激光损伤阈值均无显著变化.但是，薄膜中均匀分布的PVP柔性链可以有效促进膜层应力松弛，显著削弱不同膜层之间的应力不匹配程度、大大方便多层光学薄膜的制备.当高折射率膜层中PVP的质量分数达到15%—20%时，膜层之间良好的应力匹配使得多层高反射膜的沉积周期数可达到10以上.沉积10个周期的多层反射膜，在中心波长1064nm处透射率约为1.6%—2.1%，接近全反射特征，其激光损伤阈值为16.4—18.2J/cm²(脉冲宽度为1ns). 关键词： 溶胶-凝胶 2')" href="#">PVP-ZrO₂ 高反射膜 激光损伤     

End-pumped Tm,Ho:NaY(WO<Subscript>4</Subscript>)<Subscript>2</Subscript> crystal laser at 2.07 μm

We presented an infrared laser output at 2.07 μm with Tm,Ho:NaY(WO₄)₂ crystal end-pumped by 795 nm laser diode at room temperature. The crystal was grown by the Czochralski method with the concentrations of 5 at % Tm³⁺ and 1 at % Ho³⁺. The highest output power was up to 2.7 W corresponding to the crystal temperature being controlled at 283 K. The overall optical conversion efficiency was 5.4% and the slop efficiency was 26%. The output characteristics and the laser threshold affected by the pulse duration and temperature have been studied. We found the stability of the output power was correlative with the crystal temperature heavily. In addition, the wider pulse duration of pump could promote the output power efficiently.     

X-ray spectroscopic diagnostics of ultrashort laser-cluster interaction at the stage of the nonadiabatic scattering of clusters

X-ray spectroscopic diagnostics of laser-cluster interaction at the stage of nonadiabatic scattering of clusters and formation of a spatially uniform plasma channel has been performed. The experimental investigations have been carried out on a Ti:Sa laser setup with a pulse duration of about 65 fs and an energy up to 600 mJ. It has been shown that, within 10 ps from the beginning of a laser femtosecond pulse, the laser-cluster interaction forms a uniform plasma channel with a length of 0.4 to 1 mm with the parameters N _e ～ 10¹⁹?10²⁰ cm^?3 and T _e ～ 100 eV.