Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.     

P-polarized nonlinear surface polaritons near the surface of a saturable self-defocusing medium: Threshold case

We have obtained the solution of the stationary problem for P-polarized nonlinear surface polaritons (NLSP) near the interface of two media, one of which is optically linear and the other having an optical nonlinearity with saturation and a dielectric function of the form: =_xx=_zz=₀+a|E|²/(1+b|E|²), where E is the amplitude of the electric field. On this basis the NLSP energy and propagation properties, the polarization structure and the localization depth of the NLSP field as well as the physically allowed region in the parameter space have been investigated for the case in which the parameter ₀ is positive, b is non-negative, and a and ₁ are negative (₁ is the dielectric function of the linear medium); ₀>|₁|.     

Retardation of electromagnetic waves by helices of large diameters

This paper is devoted to the study of the wave retardation by helices of large diameters, when the lengthL of one turn of the helix is larger than the vacuum wavelength, i.e.L/>1. The dispersion equation of the tape helix wound up on a dielectric cylinder was derived and the dependence of the phase velocity of slowed-down waves on the diameter of helix was calculated. The theory was verified experimentally at a frequencyf=2·385 GHz. Helices were wound up on polyfoam (=1·04) and plexiglass (=2·55) cylinders of various diameters. For the helix wound up on plexiglass cylinders it was found that the wave retardation depends on the form of conductor from which the helix is made. The retardation of waves is determined by an effective dielectric constant _ef which is equal either ( _i + _e)/2 for the tape helix or ( _{i e}) for the helix made from a wire of the circular cross-section; here _i is the dielectric constant of inner dielectric rod and _e is that of outer space.     

Asymptotic theory of multidimensional chaos

A delay-differential equationu(t)+u(t)=f(u(t–1)), 0t < , and its generalization are investigated in the limit 0, when the attractor's dimension increases infinitely. It is shown that a number of statistical characteristics are asymptotically independent of. As for the attractor, it can be regarded as a direct product ofO(1/) equivalent subattractors, their statistical characteristics being asymptotically independent of . The results enable one to predict some characteristics of the attractor with fractal dimensionD 1 for the case 1, when they are inaccessible numerically. The approach developed seems to be applicable for a wide class of spatiotemporal systems.     

One-dimensional harmonic lattice caricature of hydrodynamics

We derive the hydrodynamic (Euler) approximation for the harmonic time evolution of infinite classical oscillator system on one-dimensional lattice ¹ It is known that equilibrium (i.e., time-invariant attractive) states for this model are translationally invariant Gaussian ones, with the mean 0, which satisfy some linear relations involving the interaction quadratic form. The natural parameter characterizing equilibrium states is the spectral density matrix function (SDMF)F(), [– , ). Time evolution of a space profile of local equilibrium parameters is described by a space-time SDMFF(t;x, ) t, xR ¹. The hydrodynamic equation forF(t; x, ) which we derive in this paper means that the normal mode profiles indexed by are moving according to linear laws and are mutually independent. The procedure of deriving the hydrodynamic equation is the following: We fix an initial SDMF profileF(x, ) and a familyP ,>0 of mean 0 states which satisfy the two conditions imposed on the covariance of spins at various lattice points: (a) the covariance at points close to the value ^–1 x in the stateP is approximately described by the SDMFF(x, ); (b) The covariance (on large distances) decreases with distance quickly enough and uniformly in. Given nonzerotR ¹, we consider the states P _–1 ,>0, describing the system at the time moments ^–1 t during its harmonic time evolution. We check that the covariance at lattice points close to ^–1 x in the state P _–1 is approximately described by a SDMFF(t;x, ) and establish the connection betweenF(t; x, ) andF(x,).     

Dielectric properties of titanium and gadolinium doped MgO single crystals

The dielectric properties of titanium doped magnesium oxide (Ti/MgO) and gadolinium doped magnesium oxide (Gd/MgO) single crystals have been measured at room temperature over the frequency range 500 Hz to 50 kHz. For both the crystals, the dielectric constant is found to be independent of frequency and the ac conductivity Re{_ae} agrees well with the relation Re{_ae} ⁿ , being the angular frequency with n=0.84±0.05 for Ti/MgO andn=0.81±0.03 for Gd/MgO. The data fits well with the relation ^n–1(n<1), being the dielectric loss factor. An explanation may be found on the basis of the hopping phenomenon.     

Kinetic limits of the HPP cellular automaton

We study the Boltzmann-Grad limit in various versions of the two-dimensional HPP cellular automaton. In the completely deterministic case we prove convergence to an evolution that is not of kinetic type, a well-known phenomenon after Uchyiama's paper on the Broadwell gas, whereas the limiting equation becomes of kinetic type in the model with random collisions. The main part of the paper concerns the case where the collisions are deterministic and the randomness comes from inserting, between any two successive HPP updatings, ^- stirring updatings, <1 being any fixed positive number and a parameter which tends to 0. The initial measure is a product measure with average occupation numbers of the order of (low-density limit) and varying on distances of the order of ^–1. The limit as 0 of the system evolved for times of the order of ^-1- corresponds to the Boltzmann-Grad limit. We prove propagation of chaos and that the renormalized average occupation numbers (i.e., divided by) converge to the solution of the Broadwell equation. Convergence is proven at all times for which the solution of the Broadwell equation is bounded.     

Spectral behavior of quasi periodic potentials

Spectral properties of Schrödinger operators of the typeH =–+V, where is the Laplacian,V a quasiperiodic potential and a coupling constant, are developed.V is taken to be finite sum of exponentials with generic frequencies. For small a strong stability is shown. On the other hand, examples (in the finite diffeence case) are given, for which a transition in the type of spectrum occurs, as is increased.Research supported in part by grant NSF MCS 7900813     

The Statistics of the Trajectory of a Certain Billiard in a Flat Two-Torus

We consider a billiard in the punctured torus obtained by removing a small disk of radius >0 from the flat torus ², with trajectory starting from the center of the puncture. In this case the phase space is given by the range of the velocity only. Let (), and respectively R(), denote the first exit time (length of the trajectory), and respectively the number of collisions with the side cushions when ² is being identified with [0,1)². We prove that the probability measures on [0, ) associated with the random variables and R are weakly convergent as 0⁺ and explicitly compute the densities of the limits. Research partially supported by ANSTI grant C6189/2000.     

Static and dynamic properties of XY systems with extended defects in cubic anisotropic crystallines

Static and dynamic critical behavior ofXY systems in cubic anisotropic crystallines, with extended defects (or quenched nonmagnetic impurities) strongly correlated along _d -dimensional space and randomly distributed ind – _d dimensions, were studied. These extended defects make the systems coordinate anisotropic, resulting in unique critical behavior due to competition between the cubic anisotropy and the coordinate anisotropy. The systems were analyzed by an ^1/2 (4 – d) type of expansion with double expansion parameters based on a renormalization-group (RG) approach. Critical exponents were calculated near the second-order phase transition point and the behavior of the first-order transition was evaluated near the tricritical point.     

Lattice and continuum wavelets and the block renormalization group

We obtain a resolution of the identity operator, for functions on a latticeZ ^d, which is derived from the block renormalization group. We use eigenfunctions of the terms of the decomposition to form a basis forl ₂(Z^d) and show how the basis is generated from lattice wavelets. The lattice spacing is taken to zero and continuum wavelets are obtained.     

Photopyroelectric spectroscopy (P2ES) of electronic defect centers in crystalline n-CdS

The electrical and dielectric properties of mercuric iodide were studied at room temperature under various intensities and colours of light in the frequency range 1 Hz–10 kHz. In the high-frequency region (>40 Hz), the real part of the dielectric constant () is almost constant with frequency (f), colour and intensity of light. At lower frequencies, varies nearly as 1/f and monotonically increases with intensity (I) of the yellow (or green) light, whereas it is almost constant with red light intensity. This behaviour is discussed in the view of the different polarization contributions. The imaginary part of the dielectric constant () was found to vary as 1/f over the frequency range studied. This behaviour was observed whether the crystal was in dark or illuminated implying that the roomtemperature ac dark- or photo-conductivity () is independent of frequency. The observed variation of with intensity of yellow (or green) light was found to follow anI ^1/2 dependence and a weaker dependence for the red light. the red light. The conductivity behaviour is discussed in the view of the current theories.     

Localization effects and dispersion of the dielectric response function in one-dimensional metals

We report the results of calculations and analysis concerning the dependence of the dielectric response function(, q) on frequency and wave numberq in one-dimensional conductors. The localization of electron states leads to unusually complicated dependences of(, q) on andq in low-frequency and long-wavelength regions, while the spatial and time dispersions become closely interwoven with each other. The effect of geometric resonance is discussed. It appears as quasiharmonical oscillations of complex susceptibility as function of andq, owing to the hopping nature of electron conductivity in a nonuniform electromagnetic field.     

Self-focusing of laser beams in inhomogeneous dielectrics

This paper presents a theoretical investigation of the propagation and focusing of an electromagnetic wave in an inhomogeneous dielectric whose dielectric constant is given by= ₀(z)+(r, z), whereZ-axis is the direction of propagation of the beam. The quantity (r, z) may either be due to non-linear effects or due to inhomogeneity in the actual fabrication of the guide.Numerical calculations show that for a cylindrically symmetrical Gaussian beam, even a small axial inhomogeneity has appreciable effect on self-focusing; if the real part ofd ₀ (z)/dz is larger than zero the focusing effect increases withz, and vice-versa.Work supported by Institute of Telecomm. Science, Boulder, Coloado and NSF, USA.     

Calculations of TM-polarized nonlinear waves guided by thin dielectric films

We found the dispersion relations for TM-polarized nonlinear waves guided by a dielectric film of thicknessd bounded on one side by a nonlinear uniaxial medium characterized by a dielectric tensor _xx = _y = _c , _zz = _c + _c |E _z |², _c >0 (self-focusing medium),E _z being the electric-field component perpendicular to the surfaces. Numerical calculations are given for the power dependence of the propagation wave vector. For sufficiently larged/ (: wavelength) we have found regions with multiple solutions corresponding to the same power flow. This suggests possible applications to optical devices.     

An upgraded analysis of ɛ′/ɛ at the next-to-leading order

An upgraded analysis of ,x _d and /, using the latest determinations of the relevant experimental and theoretical parameters, is presented. Using the recent determination of the top quark mass,m _t =(174±17) GeV, our best estimate is /=(3.1±2.5)×10^–, which lies in the range given by E731. We describe our detemination of / and make a comparison with other similar studies. A detailed discussion of the matching of the full theory to the effective Hamiltonian, written in terms of lattice operators, is also given.     

Effect of structural changes on dielectric properties of gallium arsenide

Temperature and frequency dependence of dielectric permittivity and tangent of the dielectric loss angle are studied in epitaxial gallium arsenide structures. It is shown that nonmonotonic change in with temperature is caused by change in the volume of conductive gallium microinclusions and a difference between the structural perfection of the layer and substrate. The space charge relaxation time on inhomogeneities is evaluated (10^–5–10^–6 sec) and its contribution to GaAs dielectric properties is evaluated. An oscillation in dielectric permittivity upon heating is observed and explained.Deceased.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 18–21, February, 1989.     

Dispersion of the permittivity of high-resistance semiconductors

We consider the mechanism of macroscopic polarization of semiconducting plates owing to the interaction of free carriers with an impurity level, in which role the level of the residual impurity of compensated semiconductors may appear. This mechanism, in combination with the diffusion-drift mechanism of polarization, results in additional dispersion of the real () and imaginary () parts of the dielectric permittivity, this being particularly significant for semiconductors of thickness smaller than the screening length L_s of free carriers. The character of the behavior of and depends on the relation between the Maxwell relation time _M and the times of carrier capture: _c and ejection _e by an impurity center. For _cetm and (/L_s) _e/_c1 the dispersion of and is the same as for thick plates (/L_s1). For _{c m e} and (/L_s)_e/_c1 the () curve has a characteristic kink in the region 1/_e, indicating additional absorption associated with the ejection of carriers into the surface region.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 11–13, October, 1981.     

Correlations and spectra of an intermittent chaos near its onset point

A one-parameter family of piecewise-linear discontinuous maps, which bifurcates from a periodic state of periodm, (m=2, 3,...) to an intermittent chaos, is studied as a new model for the onset of turbulence via intermittency. The onset of chaos of this model is due to the excitation of an infinite number of unstable periodic orbits and hence differs from Pomeau-Manneville's mechanism, which is a collapse of a pair of stable and unstable periodic orbits. The invariant density, the time-correlation function, and the power spectrum are analytically calculated for an infinite sequence of values of the bifurcation parameter which accumulate to the onset point _c from the chaos side - _c > 0. The power spectrum near=0 is found to consist of a large number of Lorentzian lines with two dominant peaks. The highest peak lies around frequency=2/m with the power-law envelope l/¦-(2/m)¦⁴. The second-highest peak lies around o = 0 with the envelope l/¦¦². The width of each line decreases as, and the separation between lines decreases as/lg3^–1. It is also shown that the Liapunov exponent takes the form-/m and the mean lifetime of the periodic state in the intermittent chaos is given bym ^–1(ln ^–1+1).     

Scattering states and bound states in λ℘(φ)2

By analyzing the Bethe-Salpeter equation for even ()₂ models we show that for weak coupling the mass spectrum is discrete and of finite multiplicity below 2m. Moreover on even states of energy less than 4(m–) we show that theS matrix is unitary. Herem is the physical mass and =()0 as 0. Our results rely essentially only on a simple assumption about the analyticity of the Bethe-Salpeter kernel which has been verified for weak coupling. For the interaction ⁴, (/m _o ² 1) we show that there are no even bound states of energy less than 4(m–).Work supported in part by NSF, Grant MPS 74-13252