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1.
通过离子注入结合二次离子质谱分析方法 ,研究了高压下Co在Zr4 6 .75Ti8.2 5Cu7.5Ni1 0 Be2 7.5大块金属玻璃过冷液相区中的扩散行为 .在 6 0 3K时 ,Co在Zr4 6 .75Ti8.2 5Cu7.5Ni1 0 Be2 7.5大块金属玻璃中的扩散系数随压力的增大而增大 ,其扩散激活体积ΔV =- 1.2 36Ω ,Ω是合金的平均原子体积 .结果表明 ,在热平衡状态下Co在Zr4 6 .75Ti8.2 5Cu7.5Ni1 0Be2 7.5大块金属玻璃中的扩散是通过间隙机理进行的  相似文献   

2.
利用X射线衍射和差示扫描量热分析研究了高温高压下Zr46.75Ti8.25Cu7.5Ni10Be27.5大块非晶合金的玻璃转变和晶化行为,结果发现压力降低了该大块非晶合金中的自由体积、热焓和晶化激活能.  相似文献   

3.
测量了块体金属玻璃Zr46.75Ti8.25Cu7.5Ni10Be27.5在退火前后其电阻值随温度的变化,测量的温度范围为1.5-300K.样品在退火前后都发现有超导现象.零磁场下其超导转变温度Tc分别为1.84和3.76K.在5-300K温度范围内,原始样品具有负的电阻温度系数.如果取Zr,Ti,Cu,Ni及Be分别贡献出1.5,1.5,0.5,0.5及两个传导电子,则可以用扩展的Faber-Ziman理论去解释原始样品的负电阻温度系数.还对块体金属玻璃Zr46.75Ti8.25Cu7.5Ni10Be27.5在温度范围5-300K之间的R(T)曲线用一个多项式进行了拟合.  相似文献   

4.
测量了块体金属玻璃Zr46.75Ti8.25Cu7.5Ni10Be27.5在退火前后其电阻值随温度的变化,测量的温度范围为1.5—300K.样品在退火前后都发现有超导现象.零磁场下其超导转变温度Tc分别为1.84和3.76K.在5—300K温度范围内,原始样品具有负的电阻温度系数.如果取Zr, Ti, Cu, Ni及Be分别贡献出1.5, 1.5, 0.5, 0.5及两个传导 关键词: 块体金属玻璃 超导 电阻温度系数  相似文献   

5.
大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5的流变行为研究   总被引:2,自引:0,他引:2       下载免费PDF全文
王敬丰  柳林  蒲健  肖建中 《物理学报》2004,53(6):1916-1922
采用静态拉伸方法在连续升温条件下动态地测量了大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5(Vit1)的黏度随温度的变化关系.在应变速率与温度的关系曲线中,观测到了与玻璃转变和晶化过程相联系的多个应变速率峰.在玻璃转变温度Tg以上,大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5的过冷液体呈现Newton流体特征,其黏度与温度的关系符合Vogel Fulcher-Tammann (VFT)关系式,拟合得到脆度D*=36,VFT温度T0=319K,脆度参数m=30,这说明Zr41T 关键词: 大块金属玻璃 应变速率 剪切黏度 自由体积  相似文献   

6.
采用静态拉伸方法在连续升温条件下动态地测量了大块金属玻璃Zr41 Ti14Cu12.5Ni10Be225(Vitl)的黏度随温度的变化关系.在应变速率与温度的关系曲线中,观测到了与玻璃转变和晶化过程相联系的多个应变速率峰.在玻璃转变温度Tg以上,大块金属玻璃Zr41Ti14Cu125Ni10Be225的过冷液体呈现Newton流体特征,其黏度与温度的关系符合Vogel-Fulcher-Tammann(VFT)关系式,拟合得到脆度D*=36,VFT温度T0=319K,脆度参数m=30,这说明Zr41 Ti14Cu12.5Ni10Be225的过冷液体是一种类似于硅酸盐类的"强"液体.在玻璃转变温度Tg以下,粘度与温度的关系偏离VFT关系,从结构弛豫的观点出发,借助金属玻璃的自由体积模型对其进行了分析和讨论.  相似文献   

7.
利用X射线衍射和差示扫描量热分析研究了高温高压下Zr46.75Ti8.25Cu7.5Ni10Be27.5大块非晶合金的玻璃转变和晶化行为,结果发现压力降低了该大块非晶合金中的自由体积、热焓和晶化激活能. 关键词: 大块非晶合金 高压 差示扫描量热分析 玻璃转变  相似文献   

8.
金属玻璃的断裂机理与其断裂韧度的关系   总被引:1,自引:0,他引:1       下载免费PDF全文
吴飞飞  余鹏  卞西磊  谭军  王建国  王刚 《物理学报》2014,63(5):58101-058101
本文选取了三种不同断裂韧度值的金属玻璃Zr41.25Ti13.75Ni10Cu12.5Be22.5,Ce68Al10Cu20Co2和Fe41Co7Cr15Mo14Y2C15B6,通过压缩实验测量了它们的应力-应变关系;样品断裂以后观察了其断口形貌,发现这三种金属玻璃具有不同的断裂模式.经过对这三种金属玻璃做缺口三点弯曲实验,利用数字散斑技术研究了缺口前端应变集中方向弹性应变场的演化过程.根据金属玻璃的屈服准则,阐述了不同断裂韧度值的金属玻璃的断裂机理.  相似文献   

9.
聚变堆第一镜材料块体金属玻璃表面特性   总被引:2,自引:0,他引:2       下载免费PDF全文
研究了块体金属玻璃(块体非晶合金)Zr65Al7.5Ni10Cu17.5, Co61.2B26.2Si7.8Ta4.8和金属多晶钼3种第一镜材料经低温等离子体H和Ar辐照后的表面特性变化。结果表明,两种块体金属玻璃的抗H等离子体溅射能力与其成分有关。随着等离子体辐照时间的增加,金属多晶钼和块体金属玻璃Zr65Al7.5Ni10Cu17.5的表面粗糙度增大,镜面反射率降低;而块体金属玻璃Co61.2B26.2Si7.8Ta4.8的表面粗糙度减小,镜面反射率升高。X射线衍射仪(XRD)分析表明,块体金属玻璃在离子体溅射过程中,表面微结构具有自修复性。  相似文献   

10.
利用能量为3 MeV的Ar12+离子辐照金属玻璃Al7.5Cu17.8Ni10.7Zr64和金属W,研究了金属玻璃的Ar离子辐照损伤,辐照剂量分别为1×1014,1×1015和1×1016 ions/cm2。XRD分析发现在不同剂量辐照下Al7.5Cu17.8Ni10.7Zr64均保持非晶为主要结构。不同剂量辐照后的金属玻璃样品表面没有明显的辐照损伤,而金属W在剂量为1×016 ions/cm2时表面出现大面积不规则的裂纹和孔洞。AFM分析显示Al7.5Cu17.8Ni10.7Zr64的表面均方根粗糙度随辐照剂量的增大而增大;辐照后金属玻璃的表面硬度略有降低,而金属W的硬度有所升高。在低于金属玻璃的玻璃化转变温度时,金属玻璃Al7.5Cu17.8Ni10.7Zr64的耐Ar12+溅射能力好于金属W。  相似文献   

11.
Results of radionuclide activity concentration measurements in deposition and ground-level air conducted at the station of the Institute of Physics situated 3.5 km from the Ignalina Nuclear Power Plant (Ignalina NPP) in 2005 are analyzed. Atmospheric depositional fluxes of 7Be, 60Co and 137Cs are estimated. Radionuclide particle deposition rates are calculated. The Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model of the global dispersion and deposition is used to explain variations in the 137Cs activity concentration in the ground-level air in the Ignalina NPP region in 2005. An increase in the 137Cs activity concentration of up to 17.4 μBq m−3 on 30 October-5 November is studied. Modelling results show that the Chernobyl NPP Unit 4 Sarcophagus and the radiocaesium resuspension from the Chernobyl NPP accident polluted regions are sources of 137Cs to the environment of the Ignalina NPP. Results on solubility in water of aerosols — carriers of 137Cs — are discussed.  相似文献   

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14.
High spin states have been investigated by the reaction90Zr(19F, 3), using an Anticompton spectrometer device, for the nucleus106In, for which no in-beamγ-spectroscopic information was available up to now. A level scheme has been constructed up to anI =(13,14) state.  相似文献   

15.
In this paper, we investigate the data of industries in China and find that the frequency distributions of fixed assets and fixed-assets’ investment of industries obey power laws. We show that these power-law modes can be explained by the rules of the Simon Model, rather than the existing investment theories such as the classical investment theory or acceleration principle. Moreover, the mechanism of the investment distribution may be similar to the forest-fire model of self-organizing criticality. By introducing the complex system methods, this research changes the traditional opinion of the investment and gains some meaningful understanding in the dynamics of industries and the economic cycle.  相似文献   

16.
The solutions of a renormalized BCS equation are studied in three space dimensions in s, p and d waves for finite-range separable potentials in the weak to medium coupling region. In the weak-coupling limit, the present BCS model yields a small coherence length and a large critical temperature, , appropriate for some high- materials. The BCS gap, , and specific heat as a function of zero-temperature condensation energy are found to exhibit potential-independent universal scalings. The entropy, specific heat, spin susceptibility and penetration depth as a function of temperature exhibit universal scaling below in p and d waves. Received: 18 July 1997 / Revised: 8 September 1997 / Accepted: 29 September 1997  相似文献   

17.
The thermal instability of a layer of Rivlin-Ericksen elastico-viscous fluid in porous medium acted on by a uniform magnetic field is considered. For stationary convection, Rivlin-Ericksen elastico-viscous fluid behaves like a Newtonian fluid. The magnetic field is found to have stabilizing effect whereas medium permeability has destabilizing effect. The magnetic field introduces oscillatory modes in the system, A sufficient condition for the non-existence of overstability is also obtained.  相似文献   

18.
It is shown that bulk semiconductors exhibit strongly asymmetric Fano-type resonance profiles in magnetoabsorption processes involving the formation of hot electron-hole pairs (EHPs) and accompanied by the scattering of the EHPs by defects. This result is valid for transitions to electronic states with large Landau quantum numbers, when the Coulomb interaction plays a small role. The physical reason for such a sharp change in the magnetoabsorption coefficient as compared with the expected result for the ordinary density of states in a quantizing magnetic field is that the electronic excitations are quasi-one-dimensional. The form of the resonance absorption is in good qualitative agreement with the experimental data. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 8, 619–622 (25 April 1996)  相似文献   

19.
We present the action and transformation laws of supergravity in 11 dimensions which is expected to be closely related to the O(8) theory in 4 dimensions after dimensional reduction.  相似文献   

20.
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