肉类的微波与红外线保鲜实验

从电磁生物效应出发,分析了微波与红外线对细胞的作用,介绍了微波与红外线的保鲜技术. 通过微波与红外线照射猪肉片的实验,研究了2种电磁波对肉类保鲜的作用. 结果表明在一定的时间内二者均有一定的延缓肉类腐败提高新鲜度的作用.     

高功率微波与电子系统电路单元相互作用的理论分析

利用等离子体理论研究了电路中微波等离子体运动对电容元件的影响,给出了可能引起电路扰乱状态的参量条件.当微波等离子体较稀薄?且微波的频率或等离子体电子的渡越时间高到一定程度时,扰乱阈值与微波频率的平方成正比;如果微波的频率或等离子体电子的渡越时间低到一定程度时,其电场的特性接近直流特性,扰乱阈值与微波频率没有明显的依赖关系.从总体上看,微波频率越低,越容易扰乱集成电路的工作状态.如果等离子体频率与高功率微波频率相接近,则会产生共振效应,此时等离子体电子的振荡的幅值会大幅度提高,更容易扰乱电路的工作状态.     

高功率微波与电子系统电路单元相互作用的理论分析

利用等离子体理论研究了电路中微波等离子体运动对电容元件的影响, 给出了 可能引起电路扰乱状态的参量条件. 当微波等离子体较稀薄时, 且微波的频率或等离子体电子的渡越时间高到一定程度时, 扰乱阈值与微波频率的平方成正比; 如果微波的频率或等离子体电子的渡越时间低到一定程度时, 其电场的特性接近直流特性, 扰乱阈值与微波频率没有明显的依赖关系. 从总体上看, 微波频率越低, 越容易扰乱集成电路的工作状态. 如果等离子体频率与高功率微波频率相接近, 则会产生共振效应, 此时等离子体电子的振荡的幅值会大幅度提高, 更容易扰乱电路的工作状态.     

X波段重频过模返波振荡器实验研究

根据两腔振荡器和返波管的特点研制了过模结构返波振荡器, 该器件主要由调制腔和换能腔(慢波结构)两部分组成. 调制腔既是电子束的预调制腔, 也是微波谐振反射腔, 它同换能腔形成一个过模微波谐振腔,经调制腔调制后的电子束在换能腔中实现束波能量转换. 根据加速器的电子束参数(束压为1 MV,束流为20 kA)设计了一个X波段的高功率微波器件,2.5维粒子模拟程序模拟得到微波频率为8.25 GHz,输出功率为5.70 GW. 用超导磁体作为引导磁场,单次运行输出微波功率为5.20 GW,微波频率为(8.25±0. 关键词： 两腔振荡器 返波振荡器 多波切连科夫发生器     

垂直入射条件下厚金属环结构的负磁导率与左手材料行为

用矩形波导法实验研究了微波垂直入射于具有一定厚度的金属铜圆环结构的微波电磁响应行为.结果表明，当金属铜环的厚度增加到一定值时，在中心频率为145GHz处出现透射禁带，并且相位在透射禁带处发生跃变.采用双各向异性媒质理论计算了铜圆环结构的磁导率随频率变化关系，在透射禁带处磁导率为负.对厚金属圆环与金属线一一对应组合的样品，微波沿环面垂直入射时测量到左手透射通带和相位超前，通带带宽达到15GHz，强度为-21dB.     

垂直入射条件下厚金属环结构的负磁导率与左手材料行为

用矩形波导法实验研究了微波垂直入射于具有一定厚度的金属铜圆环结构的微波电磁响应行为.结果表明,当金属铜环的厚度增加到一定值时,在中心频率为145GHz处出现透射禁带,并且相位在透射禁带处发生跃变.采用双各向异性媒质理论计算了铜圆环结构的磁导率随频率变化关系,在透射禁带处磁导率为负.对厚金属圆环与金属线一一对应组合的样品,微波沿环面垂直入射时测量到左手透射通带和相位超前,通带带宽达到15GHz,强度为-21dB. 关键词： 负磁导率 垂直入射     

基于金刚石NV色心系综磁强计相干布局振荡研究

本文介绍了我们通过利用两路微波共同作用下来进行NV色心的量子调控,实验结果出现"烧孔"现象并降低线宽,与此同时得到直流磁噪声灵敏度。在连续波实验条件下,两路微波都调谐到NV色心系综基态3A2之间的共振频率,一路泵浦微波(Pump)设定为给定的频率(m_s=0?ms=±1),一路探测微波(Probe)设定为扫频。在本次实验中我们关注的是两个微波场在NV基态之间跃迁相同的情况(ms=0?ms=+1)。在这种方法下,观察到的光谱表现出一个复杂的窄线宽结构,当探测微波功率一定时,泵浦微波功率越低,线宽越窄。当泵浦微波功率不变,改变微波频率时,烧孔一直出现在改变的微波频率处,最后我们对信号进行了调制解调,由于NV色心系综磁检测的灵敏度与解调曲线的最大斜率成反比,发现相干布局现象的调制斜率提高了20%,进一步提高了直流散粒噪声灵敏度。     

基于光学频率梳的超低噪声微波频率产生

低噪声的微波频率在雷达,长基线干涉仪等领域有重要应用.基于光学频率梳产生的微波信号的相位噪声在1 Hz频偏处低于–100 dBc/Hz,在高频( 100 kHz)处低于–170 dBc/Hz,是目前所有的微波频率产生技术中噪声最低的.文章介绍了光学频率梳产生微波频率的基本原理,对基于光梳产生的微波频率信号的各类噪声和抑制噪声的技术进行了分析和总结.随后对低噪声的测量方法进行介绍,并展示了几种典型的微波频率产生实验装置和结果.随着光学频率梳和噪声抑制技术的不断提升,基于光梳的极低噪声微波频率源将有更广泛的应用前景和应用领域.     

光阴极电子枪微波与激光同步系统研究

光阴极微波电子枪中,微波与激光脉冲的同步问题是其能否稳定工作的关键之一.我们自行设计、采用了一种取样锁相电路,用频率不很稳定的激光脉冲的基波与S波段高频微波直接取样鉴相,提高了锁相精度,实现了超快激光脉冲与高频微波的精准同步,这在国内还是第一次.均方根时间抖动为0.57ps,时间抖动的最大值为2.6ps,锁相精度完全满足SDUV项目光阴极微波电子枪的要求.     

准两腔振荡器的理论和实验研究

根据两腔振荡器和返波管的特点提出了准两腔振荡器，其作用机理是两腔振荡器的机理，结构类似返波管.这种结构主要由调制腔组和换能腔组两部分组成，调制腔组实现电子束速度调制，调制后的电子束在通过一个微波场较弱的区间时实现电子束群聚，然后在换能腔组实现电子能量到微波能量的转化，并通过输出结构输出；同时，调制腔组和换能腔组之间存在微波耦合，换能腔组中的一部分微波能量可以耦合到调制腔组，形成一个正反馈回路，在一定条件下实现微波振荡.根据此理论，根据Sinus-700加速器的参数(800 kV，10 kA)设计了一个X波段的高功率微波器件，2.5维Particle in Cell (PIC)程序模拟的效率为28%，微波频率为9.42GHz，微波输出功率为2.25GW，实验上得到的微波输出为微波频率9.40GHz，微波输出功率2.44GW. 关键词： 两腔振荡器 返波管 多波切仑可夫微波器件     

Mechanism of Thermally Biological Effects of the Millimeter Waves and Its Properties

We think that the thermally biological effects of millimeter waves are caused by the thermal motions of water molecules in the living systems, according to experimental fact that the millimeter waves can heat water, and the skin effect on the surface of the biological tissues arising from the millimeter waves. For clarifying this idea we studied the states and features of the liquid water and calculated the rotational energy-spectra of water molecules in the living systems by quantum mechanics. In fact, there is a large number of water which are polarized and have certain dipole moments in the living systems. This shows that the millimeter waves can interact with the water molecules. Through calculation of quantum rotational energy-spectra of the water molecules, we can confirm that the water molecules can absorb the millimeter waves with certain wavelength to generate the rotations of water molecules according to the principle of resonant absorption. One mechanism of the thermally biological effect of the millimeter waves is just a result produced by disorderly thermal-motions of the water molecules which are transformed from their rotation energy caused by the millimeter waves. Owing to the fact that water has a lot of biological functions and plays an important role in the living activity. Thus the heating waters by the millimeter waves can cause a lot of biological effects and phenomena in the living systems. Another mechanism of the thermally biological effect of the millimeter waves is caused by the Joule-Lenz heat arising from the skin effect of the millimeter waves in the skin layers of human beings and animals and membranes of cells which can facilitate the blood circulation in them. We finally study this effect.PACSnumbers: 87.50.Hj; 05.70.Ce; 87.15.He; 65.50.tm.     

Thermally Biological Effects and Its Medical Functions of the Infrared Rays Absorbed by Living Systems

thermally biological effects of infrared lights absorbed have been studied by nonlinear quantum theory and molecular biological theory on the basis of structures of cell and water molecules. There is a large number of water in the living systems, it play an important role in living activity, and has a lot of biological functions. There would be no life without water. We can confirm that the thermally biological effect is a result produced by disorder motions of bio-water-molecules according to the essence of heat, feature of molecular structure of water, theory of molecular physics, principle of resonante absorption and experimental fact that infrared light can heat liquid water. Therefore, mechanism of this effect is that the infrared light absorbed results in the quantum vibrations of water molecules with hydrogen bonds, the vibrational energy again transformes as thermal energy of disorder motions of a great number of water molecules in the living systems. The heating waters can cause a lot of biological effects and phenomena to occur in the living systems. Therefore, the infrared lights absorbed by the living systems have some medical functions.     

A STATISTICAL THEORY FOR THE BIO-PHOTON EMISSION OF THE LIVING SYSTEMS

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Nonequilibrium Zeldovich-von Neumann-Doring theory and reactive flow modeling of detonation

This paper discusses the Nonequilibrium Zeldovich-von Neumann-Doring (NEZND) theory of self-sustaining detonation waves and the Ignition and Growth reactive flow model of shock initiation and detonation wave propagation in solid explosives. The NEZND theory identified the nonequilibrium excitation processes that precede and follow the exothermic decomposition of a large high explosive molecule into several small reaction product molecules. The thermal energy deposited by the leading shock wave must be distributed to the vibrational modes of the explosive molecule before chemical reactions can occur. The induction time for the onset of the initial endothermic reactions can be calculated using high pressure-high temperature transition state theory. Since the chemical energy is released well behind the leading shock front of a detonation wave, a physical mechanism is required for this chemical energy to reinforce the leading shock front and maintain its overall constant velocity. This mechanism is the amplification of pressure wavelets in the reaction zone by the process of de-excitation of the initially highly vibrationally excited reaction product molecules. This process leads to the development of the three-dimensional structure of detonation waves observed for all explosives. For practical predictions of shock initiation and detonation in hydrodynamic codes, phenomenological reactive flow models have been developed. The Ignition and Growth reactive flow model of shock initiation and detonation in solid explosives has been very successful in describing the overall flow measured by embedded gauges and laser interferometry. This reactive flow model uses pressure and compression dependent reaction rates, because time-resolved experimental temperature data is not yet available. Since all chemical reaction rates are ultimately controlled by temperature, the next generation of reactive flow models will use temperature dependent reaction rates. Progress on a statistical hot spot ignition and growth reactive flow model with multistep Arrhenius chemical reaction pathways is discussed. The text was submitted by the authors in English.     

低维限域结构中水与物质的输运

低维限域结构中水与物质的输运研究,对于解决界面化学和流体力学中的遗留问题十分关键.近年来,研究人员采用分子动力学模拟和实验手段研究低维限域结构中水与物质的输运,并将其应用于物质输运、纳米限域化学反应、纳米材料制备等领域.本文从理论和实验的角度总结一维和二维纳米通道的水与物质输运,介绍了本研究组提出的"量子限域超流体"概念,并用于解释纳米通道中超快物质的输运现象;在此基础上概述了一维纳米通道中的分子动力学模拟和水浸润性,以及外部环境(如温度和电压)对限域结构中水浸润性的调控,同时阐述了低维限域结构中的液体输运;对二维纳米通道中的分子动力学模拟、液体浸润性以及液体输运进行了综述;讨论了纳米通道限域结构在物质输运、纳米限域化学反应和纳米材料制备等领域的应用;对低维限域结构中水与物质输运面临的挑战和前景进行了展望.     

Quantum ergodicity and energy flow in molecules

We review a theory for coupled many-nonlinear oscillator systems that describes quantum ergodicity and energy flow in molecules. The theory exploits the isomorphism between quantum energy flow in Fock space, that is, vibrational state space, and single-particle quantum transport in disordered solid-state systems. The quantum ergodicity transition in molecules is thereby analogous to the Anderson transition in disordered solids. The theory reviewed here, local random matrix theory (LRMT), describes the nature of the quantum ergodicity transition, statistical properties of vibrational eigenstates, and quantum energy flow through the vibrational states of molecules. Predictions of LRMT have been observed in computational studies of coupled nonlinear oscillator systems, which are summarized here. We also review applications of LRMT to molecular spectroscopy and chemical reaction rate theory, including adoption of LRMT in theories that predict rates of conformational change of molecules taking place at energies corresponding to those below and above the quantum ergodicity transition. A number of specific examples are reviewed, including the application of LRMT to predict (1) dilution factors of IR spectra of organic molecules, (2) rates of conformational change in chemical and photochemical reactions, (3) conformational dynamics of biological molecules in molecular beams, (4) rates of hydrogen bond breaking and rearrangement in clusters of biological molecules and water, and (5) excited state proton transfer reactions in proteins.     

模板对异构体选择性生长的动力学控制作用与化学气相沉积金刚石的生长机理

阐述了模板的动力学控制作用对大尺度有序结构特别是亚稳相的生长，对自由能相差很小的异构体的选择生长所具有的重要作用.汲取现有金刚石生长理论的合理思想，以模板概念为基础给出了对化学气相沉积(CVD)过程的动力学热力学综合描述：1)碳原子在碳氢化合物中的化学势高于固相碳，气相碳氢化合物的碳原子有可能落到化学势较低的固态碳的各种异构体.2)气相碳通过表面反应实现向固相碳的转化.3)表面的模板作用是控制气相碳原子转换方式的主要动力学因素，不同的表面(石墨各种取向的表面及金刚石不同取向的表面)选择了落入其上的碳原子的结构方式及能量状态.4)因此,衬底的不同区域可发生几种不同的独立的表面反应过程,这些反应对应于不同表面的生长.5）而这些表面反应的方向性及速度受表面临域热力学因素的影响，反应的方向性决定了某种晶面是生长或刻蚀，在特定的温度、压强及各种气体分压下可以实现金刚石的生长和石墨的刻蚀.6)衬底局域晶格结构及键价结构和衬底表面气相的温度、压强及各种气体分压等热力学条件共同决定了成核的临界条件.7）与外界有能量和物质交换的等离子体系统，以及气相中发生的一系列化学反应，仅起到了维持某种固相表面生长所需要的非平衡热力学条件和化学条件的作用.金刚石和石墨表面具有的模板动力学控制作用，在特定热力学条件下主导自身外延层的生长方式；异质衬底的某些局域微观结构可以作为新相生长成核的局域模板；不同材料、不同的处理方法、及不同的化学环境下的衬底具有不同的局域微观结构，从而决定了多晶薄膜的取向优势. 关键词： 模板 异构体 选择性生长 金刚石薄膜     

Preface - Contributions to the 8th International Conference on Applications of Stable Isotope Techniques to Ecological Studies (ISOECOL), Brest,France, 20–24 August 2012

Abstract

The study is focused on the dolomite-limestone drinking water aquifers in the Bo? massif, as well as on the andesite-aquifer containing mineral water in the vicinity of Roga?ka Slatina. The catchment area is limited and both drinking and mineral waters are discharged from the same source. The increasing use of deeper aquifers means that natural springs and shallow wells have become sporadic. Consequently new techniques of investigating recharge and aquifer capacity are required which can augment classical hydrogeological methods.

Current research into the mineral and drinking water aquifers in the area of Roga?ka Slatina is based on measuring the isotopic composition of light elements, (H, C and O) as natural tracers. It can be concluded that all the groundwaters investigated are typically infiltrated meteoric water. The drinking waters are generally young and were infiltrated up to about ten years ago. The isotopic composition of oxygen is similar to recent precipitation (δ¹⁸O = -9.3 ± 1‰) and the drinking waters contain tritium. It was found that exploited mineral waters recharged aquifers during colder periods; they are only partly mixed with younger water as can be seen from the isotopic composition of oxygen and corrected ¹⁴C dating, which puts the mean ages at between around 100 and 8,000 years. With regard to the “nuclear period” (1960-64) with abnormally high tritium activities of precipitation, all the waters examined can be divided into at least three main infiltration groups depending on their measured tritium content: around 35 years old (> 80 T.U.), older (> 10 T.U.) and younger (10 to 60 T.U.). Detailed dating is possible following the above classification. Isotope exchange between rocks and water is negligible and therefore very deep circulation at the temperature conditions above 80°C does not occur. Dissolved inorganic carbon (DIC) in the drinking waters is the result of equilibrium reactions between carbonates and organically produced CO₂ (δ¹³C = - 14.5 ± ‰), while the high concentrations of DIC (δ¹³C = + 3 ±‰) and CO₂ observed in the mineral waters are generated by low-temperature decarbonatization processes and indicate the deep origin of CO₂, from where gas migrates into mineral water aquifers.

Correlation analyses between the parameters studied are performed. Useful conclusions concerning water circulation and the capacities of aquifer reservoirs are described which support the future optimal pumping of mineral and drinking water at the limited catchment area of Roga?ka Slatina and Bo?.     

Biological surface science

Biological surface science (BioSS), as defined here is the broad interdisciplinary area where properties and processes at interfaces between synthetic materials and biological environments are investigated and biofunctional surfaces are fabricated. Six examples are used to introduce and discuss the subject: Medical implants in the human body, biosensors and biochips for diagnostics, tissue engineering, bioelectronics, artificial photosynthesis, and biomimetic materials. They are areas of varying maturity, together constituting a strong driving force for the current rapid development of BioSS. The second driving force is the purely scientific challenges and opportunities to explore the mutual interaction between biological components and surfaces.

Model systems range from the unique water structures at solid surfaces and water shells around proteins and biomembranes, via amino and nucleic acids, proteins, DNA, phospholipid membranes, to cells and living tissue at surfaces. At one end of the spectrum the scientific challenge is to map out the structures, bonding, dynamics and kinetics of biomolecules at surfaces in a similar way as has been done for simple molecules during the past three decades in surface science. At the other end of the complexity spectrum one addresses how biofunctional surfaces participate in and can be designed to constructively participate in the total communication system of cells and tissue.

Biofunctional surfaces call for advanced design and preparation in order to match the sophisticated (bio) recognition ability of biological systems. Specifically this requires combined topographic, chemical and visco-elastic patterns on surfaces to match proteins at the nm scale and cells at the micrometer scale. Essentially all methods of surface science are useful. High-resolution (e.g. scanning probe) microscopies, spatially resolved and high sensitivity, non-invasive optical spectroscopies, self-organizing monolayers, and nano- and microfabrication are important for BioSS. However, there is also a need to adopt or develop new methods for studies of biointerfaces in the native, liquid state.

For the future it is likely that BioSS will have an even broader definition than above and include native interfaces, and that combinations of molecular (cell) biology and BioSS will contribute to the understanding of the “living state”.     

化学反应与饱和模型对化学氧碘激光性能的影响

 将速率方程（RE）模型与化学动力学模型相结合，讨论了增益饱和模型与化学反应系统对COIL性能的影响。流动为预混的一维模型，考虑了10种成分和21个化学反应，分析计算了未分解碘分子，激发态氧产率，水含量以及温度等因素对COIL性能的影响。计算结果表明，碘流量过多，混合和反应过程中消耗大量能量；碘流量过低，导致粒子数反转和增益过低，对于能量的提取不利。