共查询到20条相似文献,搜索用时 703 毫秒
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Peng Tao Yanqin Miao Hua Wang Bingshe Xu Qiang Zhao 《Chemical record (New York, N.Y.)》2019,19(8):1531-1561
Organic electroluminescence is considered as the most competitive alternative for the future solid‐state displays and lighting techniques owing to many advantages such as self‐luminescence, high efficiency, high contrast, high color rendering index, ultra‐thin thickness, transparency, flat and flexibility, etc. The development of high‐performance organic electroluminescence has become the continuing focus of research. In this personal account, a brief overview of representative achievements in our study on the design of highly efficient novel organic light‐emitting materials (including fluorescent materials, phosphorescent iridium(III) complexes and conjugated polymers bearing phosphorescent iridium(III) complex) and high‐performance device structures together with working principles are given. At last, we will give some perspectives on this fascinating field, and also try to provide some potential directions of research on the basis of the current stage of organic electroluminescence. 相似文献
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《Angewandte Chemie (International ed. in English)》2017,56(18):4915-4916
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Rodinel Ardeleanu Ionel Mangalagiu Gabriela Sacarescu Mihaela Simionescu Liviu Sacarescu 《Macromolecular rapid communications》2004,25(13):1231-1235
Summary: This work presents the first synthesis of a new polymer obtained by catalytic addition of the Si H groups of a poly[methyl(H)silane‐co‐methylphenylsilane] backbone to an N‐(allyl)cycloimmonium salt. This hybrid polymer was characterized by spectroscopic analysis, thermogravimetric analysis and gel‐permeation chromatography (GPC). The pendant N‐(allyl)cycloimmonium segments lead to the formation of molecular dipoles, as evidenced by electrical polarization experiments.
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Organic emitting compounds that are based on π‐conjugated skeletons have emerged as promising next‐generation materials for application in optoelectronic devices. In this Minireview, recent advances in the development of organic emitters that irradiate room‐temperature phosphorescence and/or thermally activated delayed fluorescence with extraordinary luminescence properties, such as aggregation‐induced emission, mechanochromic luminescence, and circularly polarized luminescence, are discussed. 相似文献
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Phosphorus‐based materials have received widespread attention in recent years, in particular as possible candidates for practical application in organic electronics. The geometry and electronic nature of phosphorus make it a favorable heteroatom for property tuning in order to obtain better performing organic electronics. This Focus Review discusses recent structural modifications and syntheses of phosphorus‐based materials, illustrates property tuning at the same time, and highlights specific examples for device applications. 相似文献
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Dr. Taehyung Kim Dr. Lingyan Zhu Prof. Dr. Rabih O. Al‐Kaysi Prof. Dr. Christopher J. Bardeen 《Chemphyschem》2014,15(3):400-414
Organic molecules can transform photons into Angstrom‐scale motions by undergoing photochemical reactions. Ordered media, for example, liquid crystals or molecular crystals, can align these molecular‐scale motions to produce motion on much larger (micron to millimeter) length scales. In this Review, we describe the basic principles that underlie organic photomechanical materials, starting with a brief survey of molecular photochromic systems that have been used as elements of photomechanical materials. We then describe various options for incorporating these active elements into a solid‐state material, including dispersal in a polymer matrix, covalent attachment to a polymer chain, or self‐assembly into molecular crystals. Particular emphasis is placed on ordered media, such as liquid‐crystal elastomers and molecular crystals, that have been shown to produce motion on large (micron to millimeter) length scales. We also discuss other mechanisms for generating photomechanical motion that do not involve photochemical reactions, such as photothermal expansion and photoinduced charge transfer. Finally, we identify areas for future research, ranging from the study of basic phenomena in solid‐state photochemistry, to molecular and host matrix design, and the optimization of photoexcitation conditions. The ultimate realization of photon‐fueled micromachines will likely involve advances spanning the disciplines of chemistry, physics and engineering. 相似文献
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硼元素因其独特的价层电子结构——价电子数少于价轨道数,而拥有一个空的p轨道,其三配位化合物既可以和邻近的π体系产生有效共轭,又可以容易地与路易斯碱发生络合,形成四配位化合物。将硼元素引入传统的光电功能分子当中,往往能给整个体系带来独特的光电性质,这已成为新型有机光电功能分子设计的重要思路。本文围绕硼元素的三配位化合物和四配位化合物,从分子设计理念、化合物光电性质、相关器件的结构与效率等方面对含硼有机光电功能分子及其器件的研究进展进行综述,并对其未来发展做出展望。 相似文献
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Xinhong Xiong Hong Wang Lulu Xue Jiaxi Cui 《Angewandte Chemie (International ed. in English)》2023,62(47):e202306565
The growth of living systems is ubiquitous. Living organisms can continually update their sizes, shapes, and properties to meet various environmental challenges. Such a capability is also demonstrated by emerging self-growing materials that can incorporate externally provided compounds to grow as living organisms. In this Minireview, we summarize these materials in terms of six aspects. First, we discuss their essential characteristics, then describe the strategies for enabling crosslinked organic materials to self-grow from nutrient solutions containing polymerizable compounds. The developed examples are grouped into five categories based on their molecular mechanisms. We then explain the mechanism of mass transport within polymer networks during growth, which is critical for controlling the shape and morphology of the grown products. Afterwards, simulation models built to explain the interesting phenomena observed in self-growing materials are discussed. The development of self-growing materials is accompanied by various applications, including tuning bulk properties, creating textured surfaces, growth-induced self-healing, 4D printing, self-growing implants, actuation, self-growing structural coloration, and others. These examples are then summed up. Finally, we discuss the opportunities brought by self-growing materials and their facing challenges. 相似文献
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Much progress has been made in the field of research on organic near‐infrared materials for potential applications in photonics, communications, energy, and biophotonics. This account mainly describes our research work on organic near‐infrared materials; in particular, donor‐acceptor small molecules, organometallics, and donor‐acceptor polymers with the bandgaps less than 1.2 eV. The molecular designs, structure‐property relationships, unique near‐infrared absorption, emission and color/wavelength‐changing properties, and some emerging applications are discussed. 相似文献
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有机电致发光材料是有机电子学和光电信息功能材料领域的研究热点之一,在有机π共轭体系中引入杂原子是一种有效调节材料光电性能的手段。磷原子既可以通过其d轨道与π共轭体系间的σ-π相互作用来改变材料的电子结构,又具有很好的可修饰性,如被氧化、硫化或与金属配位等,从而能有效地调控材料的光电性能。因此,磷原子的引入为有机光电功能材料的分子结构设计和光电性能改善等方面的研究提供了广阔的空间,近年来得到了研究者较多的关注。本文根据引入磷原子的不同方式,综述了磷杂环戊二烯、二噻吩并磷杂环戊二烯、磷芴以及磷杂聚苯撑乙烯等材料的结构特点和在有机电致发光材料方面的研究现状,展望了含磷有机电致发光材料的应用前景和发展趋势。 相似文献
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It is important to balance holes and electrons in the emitting layer of organic light‐emitting diodes to maximize recombination efficiency and the accompanying external quantum efficiency. Therefore, the host materials of the emitting layer should transport both holes and electrons for the charge balance. From this perspective, bipolar hosts have been popular as the host materials of thermally activated delayed fluorescent devices and phosphorescent organic light‐emitting diodes. In this review, we have summarized recent developments of bipolar hosts and suggested perspectives of host materials for organic light‐emitting diodes. 相似文献