Multipole resonance in the interaction of a spherical Ag nanoparticle with an emitting dipole

The effect of multipole resonance in the interaction between a spherical metallic nanoparticle （MNP） and an emitting dipole is studied with the Mie theory. The results show that the absorption peak of the MNP with respect to the field of the emitting dipole is blue-shifted with the decrease of the spacing between MNP and emitting dipole due to the enhanced multipole resonance. At a short distance, the enhanced multipole terms of scattering are not obvious compared with the dipole term. For the decay rate of the emitting dipole, multipole resonance brings about the enhancement of it largely at short spacing. For the radiative decay rate, the behavior is quite different. The dipole term is dominant at a short spacing, and the multipole term is dominant at a larger spacing.     

CsPbBr_3钙钛矿/Pt杂化纳米结构中等离激元-激子耦合引起的发光猝灭和辐射速率减小

研究了半导体纳米粒子(SNPs)-金属纳米颗粒(MNPs)耦合导致的SNPs的发光强度猝灭和荧光寿命增强潜在的物理机制,并用传统F?ster共振能量传递(FRET)理论描述和分析实验结果。光致发光光谱(PL)和时间分辨光谱观测表明,SNPs的PL强度发生了明显的猝灭,荧光寿命从17.7 ns到30.8 ns延长了近2倍。这种杂化纳米结构表现出不同于杂化前各独立组分的新的协同相互作用光学性质。胶体化学使杂化SNP_SMNP纳米结构中SNP_S和MNP构成一个新的单元称为等离激子激元(Plexciton)或激子等离子激元(Excimon),这已在一系列杂化结构中被确认。基于泵浦-探测技术的飞秒瞬态吸收(TA)的实验结果证实了这种从激子-等离激元到等离激子的转换。实验结果分析表明,传统F?ster共振能量传递理论不能很好地描述实验结果,在金属存在的情况下,还需要对该理论进一步调整和改进。     

Quantum speed limit of the double quantum dot in pure dephasing environment under measurement

The quantum speed limit (QSL) of the double quantum dot (DQD) system has been theoretically investigated by adopting the detection of the quantum point contact (QPC) in the pure dephasing environment. The Mandelstam-Tamm (MT) type of the QSL bound which is based on the trace distance has been extended to the DQD system for calculating the shortest evolving time. The increase of decoherence rate can weaken the capacity for potential speedup (CPS) and delay the evolving process due to the frequently measurement localizing the electron in the DQD system. The system needs longer time to evolve to the target state as the enhancement of dephasing rate, because the strong interaction between pure dephasing environment and the DQD system could vary the oscillation of the electron. Increasing the dephasing rate can sharp the QSL bound, but the decoherence rate would weaken the former effect and vice versa. Moreover, the CPS would be raised by increasing the energy displacement, while the enhancement of the coupling strength between two quantum dots can diminish it. It is interesting that there has an inflection point, when the coupling strength is less than the value of the point, the increasing effect of the CPS from the energy displacement is dominant, otherwise the decreasing tendency of the CPS is determined by the coupling strength and suppress the action of the energy displacement if the coupling strength is greater than the point. Our results provide theoretical reference for studying the QSL time in a semiconductor device affected by numerous factors.     

Optical determination of vacuum Rabi splitting in a semiconductor quantum dot induced by a metal nanoparticle

We propose a theoretical scheme to determine the vacuum Rabi splitting in a single semiconductor quantum dot (SQD) induced by a metal nanoparticle (MNP). Based on cavity quantum electrodynamics, the exciton-plasmon interaction between the SQD and the MNP is considered while a strong pump laser and a weak probe laser are simultaneously presented. By decreasing the distance between them, we can increase the coupling strength. At resonance, thanks to the strong coupling, a vacuum Rabi splitting can be observed clearly in the probe absorption spectrum. The coupling strength can be obtained by measuring the vacuum Rabi splitting. This strong coupling is significant for the investigation of surface-plasmon-based quantum information processing.     

Third-order nonlinear optical response in quantum dot–metal nanoparticle hybrid structures

Third-order nonlinear optical response of a semiconductor quantum dot, modulated by the metal nanoparticle (MNP), has been studied by using the effective mass and the rotating wave approximation. Considering multiple effects in the local and nonlocal optical response of the MNP, the dependence of the dispersion and the absorption on the size of the hybrid system are investigated in detail. By controlling the geometrical parameters of the hybrid structure and the direction of the electric field polarization, a significant enhancement of the nonlinear response is shown. The enhancement factor is nearly two orders of the magnitude, which is consistent with the experiment. Compared to the results obtained with the local effect, the center frequency shows blueshift obviously in the case of the nonlocal effect. In particular, the presence of the MNP leads to a strong absorption band appearance, which promises applications in the field of light transmission and the optical switching.     

Spin-dependent Kondo effect induced by Rashba spin-orbit interaction in parallel coupled double quantum dots

Electronic transport through parallel coupled double quantum dots (DQD) with Rashba spin-orbit (RSO) interaction is investigated in Kondo regime by means of the slave-boson mean field approximation at zero temperature. By the co-action of the phase factor deduced by RSO interaction and the magnetic flux penetrating the parallel DQD, an interesting spin-dependent Kondo effect emerges. The molecular state representation theory is used to obtain a detailed understanding of the spin-dependent Kondo effect. It is shown that Quantum interference between the bonding Kondo state and antibonding state, which is modulated by the RSO interaction, plays a crucial role to the density of states and the linear conductance. The magnitude of each spin component conductance can be modulated by the RSO interaction strength. The conductance of each spin component exhibits 4π-periodic function with respect to φR. Moreover, the swap operation in the parallel DQD system can be implemented by tuning the RSO interaction.     

Transition between quantum states in a parallel-coupled double quantum dot

Strong electron and spin correlations in a double quantum dot (DQD) can give rise to different quantum states. We observe a continuous transition from a Kondo state exhibiting a single-peak Kondo resonance to another exhibiting a double peak by increasing the interdot coupling (t) in a parallel-coupled DQD. The transition into the double-peak state provides evidence for spin entanglement between the excess electrons on each dot. Toward the transition, the peak splitting merges and becomes substantially smaller than t because of strong Coulomb effects. Our device tunability bodes well for future quantum computation applications.     

Quantum Information Transfer from a Double Quantum Dot System to a Cavity Field＊

In this paper, we propose a scheme to realize quantum information transfer from a double quantum dot （DQD） system to a quantized cavity field. The DQD and the cavity field are treated as a two-state charge qubit and a continuous-variable system, respectively. It is shown that quantum information encoded in the two-state DQD system can be transferred to quantum states of the cavity field with a continuous-variable basis through appropriate projective measurements with respect to the DQD.     

Parameter-dependent third-order optical nonlinearity in a CdSe/ZnS quantum dot quantum well in the vicinity of a gold nanoparticle

The nonlinear optical properties of the CdSe/ZnS quantum dot quantum well (QDQW) in the vicinity of a spherical metal nano-particle (MNP) have been described. The third-order nonlinear optical susceptibility induced by the transition between E₁ (inside the well) and E₂ (outside the well) has been calculated for the third-harmonic generation (THG) under the effective mass approximation and modified by the local field theory. The parameters-dependent third-order nonlinear optical susceptibility for the THG has been specifically explored and the influence of the distance between the QDQW and the MNP on the third-order susceptibility for the THG in the system has been shown and analyzed.     

Synthesis,characterization and a.c. magnetic analysis of magnetite nanoparticles

In the last years, the study of Fe-based magnetic nanoparticles (MNP) has attracted increasing interest either for the physical properties shown by nanosized materials (electric and magnetic properties are strongly affected by dimension and surface effects) either for the different technological applications of these materials (catalysis, drug delivery, magnetic resonance imaging, contaminants removal from groundwater, new exchange coupled magnets, soft nanomagnets for high frequency applications, etc.). In this article, the results obtained in the synthesis and characterization of the Fe₃O₄ MNP is reported. The magnetite nanoparticles were synthesized by a modified Massart method. Structural characterization was performed using X-ray diffraction analysis and a complete morphological and dimensional study was carried out by means of Transmission Electron Microscopy, and a.c. magnetic susceptibility measured as a function of the frequency of the applied magnetic field. Diameters of the superparamagnetic Fe₃O₄ nanoparticles are ranging from 2 to 10 nm, as evidenced by all the techniques employed. The size distribution of the hydrated aggregates in solution has been obtained by quantitative analysis of the frequency dependence of the a.c. susceptibility. The mathematical approach adopted will be described and all the obtained results will be compared and discussed.     

Majorana fermions induced fast-and slow-light in a hybrid semiconducting nanowire/superconductor device

We investigate theoretically Rabi-like splitting and Fano resonance in absorption spectra of quantum dots(QDs)based on a hybrid QD-semiconducting nanowire/superconductor(SNW/SC)device mediated by Majorana fermions(MFs).Under the condition of pump on-resonance and off-resonance,the absorption spectrum experiences the conversion from Fano resonance to Rabi-like splitting in different parametric regimes.In addition,the Fano resonances are accompanied by the rapid normal phase dispersion,which will indicate the coherent optical propagation.The results indicate that the group velocity index is tunable with controlling the interaction between the QD and MFs,which can reach the conversion between the fast-and slow-light.Fano resonance will be another method to detect MFs and our research may indicate prospective applications in quantum information processing based on the hybrid QD-SNW/SC devices.     

Thermoelectric properties of correlated double quantum dot system in Coulomb blockade regime

We theoretically study thermoelectric properties of a coupled double quantum dot (DQD) system coupled to normal leads using two impurity Anderson model with intra- as well as interdot Coulomb interactions. A generic formulation, which was earlier developed to study electronic properties (zero bias maximum of differential conductance and interesting partial swapping in Fano phenomena) of DQD system within Coulomb blockade regime for a non-magnetic case, is extended to investigate thermoelectric properties i.e. electrical conductance, thermoelectric power and thermal conductance of the same system, as a function of temperature by varying interdot Coulomb interaction and interdot tunneling. Interdot Coulomb interaction is found to trigger some novel features like crossover in thermoelectric power with temperature in all the configurations (series, parallel and T-shape) and a small peak in thermal conductance toward low temperatures, T≈Γ/10, in series and T-shape configurations, which is found to be missing in case of symmetric parallel configuration. The origin of these novel features is attributed to the interplay of renormalization of energy levels caused by the interdot Coulomb interaction which is interpreted in terms of local density of states and the asymmetry effects related to dot-lead couplings/interference effects.     

The influence of resonance IR laser radiation on magnetoabsorption in quantum wires

The coefficient of interband absorption of a weak electromagnetic wave by quantum wires in a transverse magnetic field and an intense laser radiation field is calculated. It is shown that, if the laser radiation frequency is equal either to the size quantization frequency (dimensional infrared resonance) or to a hybrid frequency (magnetoinfrared resonance), laser illumination can determine the shape of absorption oscillations. In particular, it is shown that the second magnetoabsorption peak is split into two peaks, the half-widths of which and the distance between which depend on the intensity of resonance laser radiation. The influence of the polarization of IR radiation on the interband absorption in quantum wires is discussed. The dynamics of the frequency dependence of the optical absorption coefficient with increasing intensity of resonance laser radiation is studied.     

Kondo Resonance versus Fano Interference in Double Quantum Dots Coupled to a Two-Lead One-Ring System

We analyse the transport properties of a coupled double quantum dot （DQD） device with one of the dots （QD1） coupled to metallic leads and the other （QD2） embedded in an Aharonov-Bhom （A-B） ring by means of the slaveboson mean-field theory. It is found that in this system, the Kondo resonance and the Fano interference exist simultaneously, the enhancing Kondo effect and the increasing hopping of the QD2-Ring destroy the localized electron state in the QD2 for the QD1-leads, and accordingly, the Fano interference between the DQD-leads and the QD1-leads are suppressed. Under some conditions, the Fano interference can be quenched fully and the single Kondo resonance of the QD1-leads comes into being. Moreover, when the magnetic flux of the A-B ring is zero, the influence of the parity of the A-B ring on the transport properties is very weak, but this influence becomes more obvious with non-zero magnetic flux. Thus this model may be a candidate for future device applications.     

In vitro study of magnetic nanoparticles as the implant for implant assisted magnetic drug targeting

Magnetic nanoparticle (MNP) seeds were studied in vitro for use as an implant in implant assisted-magnetic drug targeting (IA-MDT). The magnetite seeds were captured in a porous polymer, mimicking capillary tissue, with an external magnetic field (70 mT) and then used subsequently to capture magnetic drug carrier particles (MDCPs) (0.87 μm diameter) with the same magnetic field. The effects of the MNP seed diameter (10, 50 and 100 nm), MNP seed concentration (0.25-2.0 mg/mL), and fluid velocity (0.03-0.15 cm/s) on the capture efficiency (CE) of both the MNP seeds and the MDCPs were studied. The CE of the 10 nm MNP seeds was never more than 30%, while those of the 50 and 100 nm MNP seeds was always greater than 80% and in many cases exceeded 90%. Only the MNP seed concentration affected its CE. The 10 nm MNP seeds did not increase the MDCP CE over that obtained in the absence of the MNP seeds, while the 50 and 100 nm MNP seeds increased significantly, typically by more than a factor of two. The 50 and 100 nm MNP seeds also exhibited similar abilities to capture the MDCPs, with the MDCP CE always increasing with decreasing fluid velocity and generally increasing with increasing MNP seed concentration. The MNP seed size, magnetic properties, and capacity to self-agglomerate and form clusters were key properties that make them a viable implant in IA-MDT.     

Inter and intrasubband transitions via LO phonons in quantum wires

We investigate the effects of the finite confining potential V₀ on the absorption and emission scattering rates of electrons interacting with LO phonons for a cylindrical GaAs quantum wire. The emission rates are qualitatively similar to those of the 2D case. The absorption rates on the other hand exhibit two different regimes: 1) for a wire radius smaller than a certain value (80 Å in the case where V₀ = 190 meV) the behavior is similar to the 2D and 3D analogues, but 2) for larger radius the absorption rates initially increase with increasing energy, reach a maximum value and then decrease monotonicaly. A complete study is made as a function of wire radius, and electron energy.     

同心椭圆柱-纳米管结构的双重Fano共振研究

提出了一种同心椭圆柱-纳米管复合结构,该结构由金纳米管中内嵌椭圆形金柱构成,利用时域有限差分法分析了尺寸参数、周围环境及纳米管内核材料对该结构光学性质的影响.结果表明,调节椭圆柱芯的旋转角度可产生双重偶极-偶极Fano共振,其主要是由椭圆柱芯的纵向或横向偶极共振模式与纳米管的偶极成键和反成键模式杂化形成的超辐射成键模式和亚辐射成键模式之间的相互作用产生的,且共振特性可通过调节复合结构的尺寸参数控制,随椭圆柱长轴或短轴的增大而红移,随纳米管外径的增大或整体尺寸的减小而蓝移,当纳米管内径增大时高频Fano共振随着红移,而低频Fano共振先蓝移再红移,同时其对外界环境的变化不敏感,但对纳米管内核材料变化有着较好的响应.利用等离激元杂化理论对该现象进行了解释.这些结果可为构造其他类型的多波段Fano共振二维或三维纳米结构提供一种新的方式.     

On surface plasmon damping in metallic nanoparticles

Two possible mechanisms of damping of surface plasmon (SP) oscillations in metallic nanoparticles (MNPs), not connected with the electron–phonon interaction, are investigated theoretically: (a) radiation damping of SPs and (b) resonant coupling of SP oscillations with electronic transitions in the matrix. For the mechanism (a) it is shown that the radiation damping rate is proportional to the number of electrons in a MNP and therefore this channel of energy outflow from the MNP becomes essential for relatively large particles. The strong frequency and size dependence of the radiation damping rate obtained allows us to separate the contributions of radiative processes and the electron–phonon interaction to the energy leakage. The investigation of the mechanism (b) shows that the rate of energy leakage of SP oscillations from a MNP does not depend on particle size and is fully determined by the optical characteristics of the matrix. It is demonstrated that for very small MNPs of -–3 5nm size, where the strong three-dimensional size quantization effect suppresses the electron–phonon interaction, the resonance coupling in certain cases provides an effective energy outflow. PACS 78.67.Bf     

基于量子点接触的开放双量子点系统电子转移特性

基于量子点接触探测器(QPC)理论上研究了双量子点(DQD)系统在耗散环境和纯退相环境影响下的电子转移特性.结果表明,耗散环境中探测器导致的退相干会增大平均电流和Fano factor随时间演化的值,并观察到量子芝诺效应的存在.在对称的DQD情况下,弛豫减小了平均电流随时间演化的震荡振幅.在非对称的DQD情况下,弛豫降低了Fano factor随时间演化的峰值.纯退相环境中测量会阻碍共隧穿过程中不同电流通道之间的转换,导致Fano factor的极高值.在对称的DQD情况下,增大纯退相速率会提高Fano factor.在非对称的DQD情况下,动力学随时间的演化对纯退相环境不敏感.另外,还发现探测器内n个电子的转移几率只受QPC与DQD耦合的影响.我们的结论可以为实验工作者研究电子输运特性提供理论参考.     

柯里拉京与DNA相互作用的光谱研究

在p H 7.4的生理条件下,以溴化乙锭(EB)作为荧光探针,利用荧光光谱、紫外-可见吸收光谱、共振散射光谱法结合盐效应和DNA熔点(T_m)实验研究了柯里拉京(Cor)与小牛胸腺DNA分子之间的相互作用机制。实验结果表明,Cor静态猝灭DNA-EB体系的荧光。Cor与DNA作用后,其特征吸收峰强度发生减色效应;与DNA作用导致Cor在480.5 nm处的共振散射峰增强,并在330.2 nm处出现新共振散射峰。盐效应对Cor与DNA分子相互作用的影响较小。与Cor作用引起DNA的T_m值升高5.5℃。由此推断,Cor与DNA相互作用的主要方式为嵌插,两者间形成了超分子体系。通过计算获得Cor与DNA间结合常数(K_A)为5.82×10~3L/mol(298 K)、2.47×10~4L/mol(310 K),它们之间的作用为熵驱动的自发、吸热过程,疏水作用力是主要的非共价作用方式。