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基于近红外光谱技术的内燃机油鉴别研究 总被引:4,自引:0,他引:4
针对常规近红外光谱技术测试内燃机油时光谱信号响应低,对大分子基团分辨率不高,以及光谱信息与其结构组成之间存在非线性关系等难点,提出了一种基于电压为外扰方式的内燃机油二维近红外光谱测试技术,介绍了近红外光谱具有分形的特征.运用小波变换将近红外光谱分解至不同分辨尺度,然后计算各尺度分量的分形维数(盒维数),用近红外光谱的小波基分形参量替代近红外光谱的采样值.计算结果表明,在不同小波基和不同分解尺度下,内燃机油近红外光谱具有不同的盒维数,得到了近红外光谱在分形意义下的特征信息.以美孚、埃索和壳牌3种内燃机油品种鉴别分类问题为实例,比较研究了近红外光谱采样值与小波基分形参量,K近邻法的交互验证计算结果表明,小波基分形参量的分类效果优于近红外光谱采样值.采用近红外光谱技术测试内燃机油的结构组成信息是可行的. 相似文献
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采用褶合光谱法考察紫外线致脱氧核糖核酸(DNA)突变,并以褶合光谱差谱值δ的形式量化地表达DNA细微突变的程度,其灵敏度远高于二附导数光谱法。DNA中添加二甲亚砜后表现的褶合光谱差谱变化与高效毛细管电泳指纹图谱的结果一致。褶合光谱法分析过程简单快速,可以用于抗紫外线损伤、抗突变药物的初步筛选。 相似文献
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小波变换结合多维偏最小二乘方法用于近红外光谱定量分析 总被引:1,自引:0,他引:1
将小波变换和多维偏最小二乘法相结合用于近红外光谱定量校正模型的建立。首先将原始光谱进行小波变换分解,得到系列小波细节系数,通过选取一组受外界因素少、信息强的小波系数组成三维光谱阵,然后再采用多维偏最小二乘法建立校正模型。实验结果表明,该方法所建近红外校正模捌的预测能力更强,并更具稳健性。 相似文献
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应用傅里叶变换近红外漫反射光谱技术,通过对光谱预处理方法的选择和模型优化,建立了准确度较好的聚乙烯醇醇解度近红外定量分析模型,并验证了其可行性。通过验证试验表明,其预测值接近于化学法测定值,适合聚乙烯醇醇解度快速测定。 相似文献
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褶合曲线分析法用于同步荧光光谱法同时测定苯酚和对苯二酚 总被引:9,自引:2,他引:9
采用计算机辅助褶合曲线分析法结合同步荧光光谱法对双组分体系(苯酚/对苯二酚、苯酚/邻苯二酚)同时测定。苯酚和对苯二酚的荧光光谱重叠比较严重,同步荧光光谱虽使选择性有所改善,但仍有重叠,苯酚和对苯二酚的同步荧光峰相差仅20nm。褶合曲线分析法可很好地用来测定苯酚和对苯二酚,方法简便、准确、易于自动化,同时证明,褶合曲线分析法在荧光分析方面具有很好的应用前景。进一步试验苯酚和邻苯二酚双组分的同时测定,苯酚和邻苯二酚的同步荧光峰相差仅10nm,结果表明,该法虽然能在苯酚存在的情况下测定邻苯二酚,但不能同时测定苯酚。 相似文献
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Liu H Gao H Qu L Huang Y Xiang B 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,71(4):1228-1233
Four aromatic medicines (acetaminophen; niacinamide; p-aminophenol; nicotinic acid) containing nitrogen were investigated by FT-NIR (Fourier transform near-infrared) spectroscopy and generalized two-dimensional (2D) correlation spectroscopy. The FT-NIR spectra were measured over a temperature range of 30-130 degrees C. By combining near-infrared spectroscopy, generalized 2D correlation spectroscopy and references, the molecular structures (especially the hydrogen bond related with nitrogen) were analyzed and the NIR band assignments were performed. The results will be helpful to the understanding of aromatic medicines containing nitrogen and the utility of these substances. 相似文献
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扑热息痛片剂药品的近红外光谱法非破坏定量分析 总被引:5,自引:0,他引:5
现代近红外光谱分析技术将近红外光谱 (NIR)法同计算机科学和化学计量学结合 ,实现了对样品进行无损非破坏性定量分析 .该法具有速度快、操作简单及所需样品少等特点 ,能够实现样品分析的时间同步、地点同步及无损非破坏分析 .为实现生产过程中即时、在线的质量控制提供了新的手段[1 ] .本文应用人工神经网络 [2 ]与近红外漫反射光谱相结合对扑热息痛片剂药品进行了非破坏快速定量分析 .用扑热息痛片剂药品的近红外漫反射光谱数据、一阶导数光谱数据及二阶导数光谱数据分别建立了 ANN模型 ,预测未知样品 ,讨论了影响网络的因素 ,使用了新… 相似文献
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Herbal products produced from multiple plants have special characteristics in the clinical practice of traditional Chinese medicine. These traits provide the opportunity for fraudulent merchants to mix other herbal products similar in appearance into authentic herbal medicine. Shihu is a tonic herbal medicine from the Dendrobium plants with complex botanical origins. In this context, 11 Dendrobium plants including 109 individuals from China were collected for authentication work. Nine species have been described as herbal medicines in the literature while D. hookerianum and D. xichouense are not reported to have medicinal benefits. A key feature of this study was that multiple recognition approaches, based on near-infrared and ultraviolet–visible spectra as well as their combination, were compared to investigate their classification performance. Intuitively, score plots using principal component analysis and hierarchical cluster diagrams were used to evaluate the genetic relationships among these species. Compared with support vector machine discrimination analysis and k-nearest neighbor models, the partial least square discrimination analysis model combined with low-level data fusion provided excellent performance for authentication and was the most robust model with 100% accuracy rates for the training and prediction sets. The results indicated that near-infrared and ultraviolet–visible spectra and their fusion dataset combined with supervised recognition analysis are effective and therefore recommended for the authentication of genuine and sham of herbal Shihu species. 相似文献
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Yanhong WuYi Zheng Qingqing LiJibran Iqbal Lingyi ZhangWeibing Zhang Yiping Du 《Vibrational Spectroscopy》2011,55(2):201-206
Ginseng is a precious traditional Chinese herbal medicine. Different parts of ginseng are deemed to have different medicinal values and properties. Rapid and non-destructive methods, such as diffuse reflectance near-infrared spectroscopy (DR-NIR), Fourier transform infrared spectroscopy with attenuated total reflectance (ATR-FTIR), were used to evaluate the differences of epidermis, phloem and xylem in ginseng, respectively. Samples were grounded into 200-mesh fine powder or cut into slices with about 2 mm thickness for DR-NIR and ATR-FTIR spectra measurement, respectively. To explore the classifications between different parts of ginseng, the spectra of DR-NIR and ATR-FTIR were pretreated to calculate first derivative and then was analyzed with principal component analysis (PCA). The PCA results of DR-NIR spectra indicate that epidermis and xylem part of ginseng have distinct difference, and even different positions of epidermis or xylem part show regular and gradual differences. ATR-FTIR spectra directly show that three parts of ginseng are different at 2920, 2852, 1736 and 925.7 cm−1 peaks, especially for epidermis of ginseng. The PCA results of ATR-FTIR spectra yield clear classifications of the three parts of ginseng. 相似文献
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Maghemite nanoparticles were synthesized by the coprecipitation method. Silica was coated to the maghemite nanoparticles and
amino silane was modified to the surface of the silica magnetic nanoparticles. We use the biofunctional magnetic nanoparticles
as a general agent to immobilize and separate the proteins in a broad range from different traditional Chinese medicines.
The transmission electron microscopy results showed that the average diameter of the well-dispersed silica-coated nanoparticles
was about 60 nm. The Fourier transform infrared spectrum indicated that the amino group had been successfully coupled to the
surface of the maghemite particles. And the protein immobilization effect was characterized by the microplate reader. The
characterization results proved that the synthesized functional magnetic nanoparticles could effectively immobilize and separate
the proteins from traditional Chinese medicines. 相似文献
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有机质谱学在蛇床子素、厚朴酚、和厚朴酚与鱼腥草素结构确定中的应用 总被引:2,自引:0,他引:2
有机质谱学在中药药效物质的结构确定中起到了至关重要的作用. 对中药药效物质质谱的确切解释需要对这些药效物质质谱的关键裂解规律有足够的了解. 应用有机质谱学规律对中药药效物质的结构确定进行了讨论. 这些中药的药效物质包括: 应用超临界二氧化碳从蛇床子中提取的蛇床子素和从厚朴中提取的厚朴酚与和厚朴酚; 应用水蒸汽蒸馏从鱼腥草中提取的鱼腥草素等. 具有较高丰度的质谱关键碎片峰 m/z 229 的出现是蛇床子素质谱的典型特征; 质谱关键碎片峰 m/z 169 的出现是鱼腥草素质谱的典型特征. 而质谱关键碎片峰 m/z 247 是否出现则是区分厚朴酚与和厚朴酚的质谱典型特征. 在此基础上, 尝试构建中药药效物质的有机质谱学平台. 相似文献
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微量元素研究对中药研究和应用的指导作用 总被引:4,自引:2,他引:4
通过对微量元素与中药材的栽培,中药的炮制加工,中成药的工艺研究及中药的合理应用之间相关性的综述,阐明了微量元素研究对中药研究和应用的指导意义,同时也给研究人员对微量元素的研究提出了新课题。 相似文献
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Multi‐component determination and chemometric analysis of Paris polyphylla by ultra high performance liquid chromatography with photodiode array detection 下载免费PDF全文
Multi‐source analysis of traditional Chinese medicine is key to ensuring its safety and efficacy. Compared with traditional experimental differentiation, chemometric analysis is a simpler strategy to identify traditional Chinese medicines. Multi‐component analysis plays an increasingly vital role in the quality control of traditional Chinese medicines. A novel strategy, based on chemometric analysis and quantitative analysis of multiple components, was proposed to easily and effectively control the quality of traditional Chinese medicines such as Chonglou. Ultra high performance liquid chromatography was more convenient and efficient. Five species of Chonglou were distinguished by chemometric analysis and nine saponins, including Chonglou saponins I, II, V, VI, VII, D, and H, as well as dioscin and gracillin, were determined in 18 min. The method is feasible and credible, and enables to improve quality control of traditional Chinese medicines and natural products. 相似文献
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吕明松 《广东微量元素科学》1998,5(1):57-59
有机锗广泛存在于某些中药中,某些补益中药所含有机锗对抗癌有积极意义,为人们辨病选药提供了相应依据,用补益中益治疗肝癌收到良好效果。重点讨论了补益中药所含有机锗的抗癌作用机理。 相似文献