共查询到20条相似文献,搜索用时 687 毫秒
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提出了一种描述高自旋弱偶合体系NMR实验谱的密度算符方法,给出了高自旋体系密度算符在自旋偶合作用下的演化公式。以氘核(2D)为例,计算了重聚INEPT和同核COSY实验谱。 相似文献
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提出一种描述自旋为1/2的强偶AB自旋体系多脉冲NMR实验的密度算符演化的方法,推导了自旋算符的自由演化公式,具体描述了极化转移INEPT实验和二维DQ-INADEQUATE实验。该方法物理意义直观,计算量较小。 相似文献
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用虚拟自旋-1/2算符理论考察了I=1的核四极共振自旋系统在其能级间隔较小时对1-2个脉冲的响应.由于核四极相互作用表象中的射频场与核自旋的相互作用(Hrf)包含时间,因而用Dyson时序算符来计算密度算符在Hrf作用下的演化. 相似文献
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描述高自旋弱耦合系统的广义积算符 总被引:1,自引:1,他引:0
本文提出了Z算符与角动量积算符相结合的广义积算符,用于描述高自旋弱耦合系统NMR实验谱。给出了高自旋系统在自旋耦合作用下的演变公式,Z算符在脉冲作用下的变化公式。以氘(D)为例,计算了重聚INEPT,DEPT和同核COSY实验谱,并对计算方法作了讨论。 相似文献
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本文报道了利用乘积算符方法分析多脉冲及二维FT-NMR实验的模拟程序PROPER-MT.该程序对分析弱耦合ImSn(I=1/2;S=(1)/2;1 ≤ m十n<4)自旋体系实验脉冲序列是普遍适用的;它可给出实验过程中体系任何时刻算符的解析表达式.用PROPER-MT程序对一些典型的多脉冲及二维FT-NMR实验进行了模拟,特别对多量子滤波及多自旋滤波脉冲序列进行了分析计算,得到了预期的结果. 相似文献
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本文根据算符函数的幂级数展开,给出了描述高自旋弱耦合体系的积算符理论,并用来描述In S((1)/2)体系(其中I=1/2,1,…)的DEPT实验.给出I(1)n S((1)/2)体系(例如CDn)DEPT谱线的增益系数的普遍公式,并提出了用作图法得出谱线结构的方法. 相似文献
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在对称化乘积算符(简称SAPO)方法基础上提出了多量子积算符(简称MQCPO)方法。改进的密度算符理论对InS(I=1/2,S=1/2;n为任意正整数)自旋体系多脉冲及二维核磁共振实验的描述普遍适用。MQCPO与SAPO从不同角度反映了自旋体系的对称性,故它们之间存在简单线性关系。文中给出In(I=1/2,n=2,3)自旋体系MQCPO的SAPO表示。MQCPO有利于自由演化过程的描述,而脉冲作用的描述则是SAPO为佳;利用MQCPO与SAPO的线性关系及SAPO笛卡儿分量的坐标轮换性质,“z”表象下脉冲作用的描述变得简单而直观。对异核谱剪辑及自旋拓扑滤波(spin topology filtration)等实验脉冲序列的分析,该方法是方便的。
关键词: 相似文献
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在能量耗散腔中,原子用泡利算符描述,光场用相干态描述,运用密度矩阵理论,得到了两二能级原子密度矩阵元的演化规律,分析了与单模辐射场作用过程中原子态的自旋压缩、量子Fisher信息和最大自旋涨落.结果表明:自旋压缩,大于1/2的最大自旋涨落可以作为量子纠缠的充分必要判据.自旋压缩,大于1/2的最大自旋涨落和量子纠缠,它们互相等价.大于1的Fisher信息与它们之间没有等价关系,但可以作为自旋压缩和量子纠缠的充分判据. 相似文献
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Ekrem Aydiner Yusuf Yüksel Hamza Polat 《Journal of magnetism and magnetic materials》2009,321(19):3193-3197
In this study, dependence on site dilution of critical and compensation temperatures of a two-dimensional mixed spin-1/2 and spin-1 system has been investigated with Monte Carlo simulation. The dependence of the thermal and magnetic behaviors on dilution of mixed spin system has been discussed. We have shown that the critical and compensation temperatures of diluted mixed spin system linearly decrease with increasing number of diluted sites. 相似文献
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The decoherence process of a central spin-1/2 particle coupling to the surrounding anisotropy spin-1/2 chain in a transverse field at finite temperature is studied in this Letter. We study the Loschmidt echo(LE) of the central spin when the surrounding spin chain is in the thermal equilibrium state. Our results show that the critical enhanced decay of LE at zero temperature becomes indistinct with the temperature increasing and will be completely washed out when the temperature is high enough. 相似文献
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S. Gudder 《Foundations of Physics Letters》1992,5(1):1-13
We present a realistic model in which spin measurements are represented by functions. By employing a simple amplitude density, we derive the usual spin distributions for the spin-1/2 case. Higher order spin measurements are represented by sums of spin-1/2 measurements. We treat the spin-1 and spin-3/2 cases explicitly and show that the model applies to spins of any order. 相似文献
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S. Chen L. Wang Y. P. Wang 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,57(3):265-270
We study the ground-state properties of frustrated Heisenberg ferrimagnetic
ladders with antiferromagnetic exchange interactions and two types of
alternating sublattice spins. In the limit of strong rung couplings, we show
that the mixed spin-1/2 and spin-1 ladders can be systematically mapped onto
a spin-1/2 Heisenberg model with additional next-nearest-neighbor exchanges.
The system is either in a ferrimagnetic state or in a critical spin-liquid
state depending on the competition between the spin exchanges along the legs
and the diagonal exchanges. 相似文献
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Mixed spin transverse Ising model with longitudinal random crystal field interactions 总被引:1,自引:0,他引:1
N. Benayad R. Zerhouni A. Klümper 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(3):687-695
The effect of a longitudinal random crystal field interaction on the phase diagrams of the mixed spin transverse Ising model
consisting of spin-1/2 and spin-1 is investigated within the finite cluster approximation based on a single-site cluster theory.
In order to expand a cluster identity of spin-1, we transform the spin-1 to spin-1/2 representation containing Pauli operators.
We derive the state equations applicable to structures with arbitrary coordination number N. The phase diagrams obtained in the case of a honeycomb lattice (N=3) and a simple-cubic lattice (N=6), are qualitatively different and examined in detail. We find that both systems exhibit a variety of interesting features
resulting from the fluctuation of the crystal field interactions.
Received: 13 February 1998 / Accepted: 17 March 1998 相似文献
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We introduce an exactly solvable SU(2)-invariant spin-1/2 model with exotic spin excitations. With time reversal symmetry (TRS), the ground state is a spin liquid with gapless or gapped spin-1 but fermionic excitations. When TRS is broken, the resulting spin liquid exhibits deconfined vortex excitations which carry spin-1/2 and obey non-Abelian statistics. We show that this SU(2) invariant non-Abelian spin liquid exhibits the spin quantum Hall effect with quantized spin Hall conductivity σ(xy)(s)=?/2π, and that the spin response is effectively described by the SO(3) level-1 Chern-Simons theory at low energy. We further propose that a SU(2) level-2 Chern-Simons theory is the effective field theory describing the topological structure of the non-Abelian SU(2) invariant spin liquid. 相似文献
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Yuri A. Serebrennikov 《Physics letters. A》2008,372(18):3307-3312
For spin-3/2 holes the anisotropic part of the instantaneous Luttinger Hamiltonian can be represented as an effective quadrupole coupling. We investigate the hole spin relaxation process induced by nonadiabatic fluctuations of this interaction. The obtained analytical solution of the stochastic Liouville equation describes the polarization decay of spin-3/2 holes in all regimes of momentum scattering: from collision-dominated to ballistic. Our results create the basis for quantitative interpretation of recent experiments and elucidate the striking difference between the hole spin relaxation process in bulk crystals and 2D semiconductor nanostructures. 相似文献
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The ground-state magnetic properties of the spin-2 transverse Ising model with a longitudinal crystal field are studied within the framework of mean-field theory (MFT) and effective-field theory (EFT), respectively. The phase diagrams and magnetization curves are examined in detail. It is found that the system exhibits a tricritical behavior in the ground-state phase diagrams. Some interesting phenomena have been found, especially the first-order phase transition from one ordered phase to the other ordered phase, which is due to the high spin. The spin correlation has important effect on the magnetic properties of the system. We also find that the ground-state phase diagrams of the spin-2 transverse Ising model are very different from those of the spin-3/2 transverse Ising model. 相似文献