ZnS:Cu,Eu,Br粉末ACEL的老化

退火的处理方法对ZnS:Cu,Eu,Br粉末ACEL材料的老化性能有明显的改善,但处理时颗粒表面必须包有过剩的铜,否则将破坏发光性能。若用氰化钾洗去表面过剩的铜后,再进行包铜退火处理,发光亮度部分恢复,老化性能改善。我们认为处理后老化性能改善的原因,不是改善了发光中心的条件,可能是改善了Cu2S相的条件,因而抑制了离子的迁移。     

交流粉末电致发光体的老化研究

本文通过离子探针实验首次证实了电致发光老化过程中铜离子由晶格最深部向颗粒表面迁移的事实.这结论与正电子湮灭寿命谱,顺磁共振实验所得结论是相互支持的.实验结果还表明,经过退火和淬火的材料,铜在颗粒中分布发生了变化,析出的铜聚集在颗粒表面上.形成了高场所必需的硫化锌-硫化铜结,增加了势叠高度和场分布的不均匀性,减缓老化过程中铜离子由晶格内部向表面的迁移,因而改善了电致发光老化. 改进后的材料,在5kHz,200V激发下,发光屏初始亮度为450cd/m~2,老化4000小时后,亮度为125.5cd/m~2.若改用喷屏法制屏,增大介质的介电常数,发光屏初始亮度最大值可达766cd/m~2.     

交流粉末电致发光体的老化研究

本文通过离子探针实验首次证实了电致发光老化过程中铜离子由晶格最深部向颗粒表面迁移的事实.这结论与正电子湮灭寿命谱,顺磁共振实验所得结论是相互支持的.实验结果还表明,经过退火和淬火的材料,铜在颗粒中分布发生了变化,析出的铜聚集在颗粒表面上.形成了高场所必需的硫化锌-硫化铜结,增加了势叠高度和场分布的不均匀性,减缓老化过程中铜离子由晶格内部向表面的迁移,因而改善了电致发光老化. 改进后的材料,在5kHz,200V激发下,发光屏初始亮度为450cd/m2,老化4000小时后,亮度为125.5cd/m2.若改用喷屏法制屏,增大介质的介电常数,发光屏初始亮度最大值可达766cd/m22.     

(Zn,Cd)S：Cu,Cl发光材料的热释发光

在ZnS中分别掺杂质量分数为5%、7%、10%、15%、20%的CdS,得到一系列(Zn,Cd)S:Cu,Cl粉末电致发光材料样品。测量样品材料的热释发光曲线,发现五个样品在温度-180～-20℃范围内均有两个明显的热释发光峰。CdS含量的变化对材料中陷阱的种类和陷阱深度没有明显的影响,两个峰值温度在-150℃和-50℃附近。Cd离子的掺入改变了材料较深陷阱中载流子的浓度,随着CdS量的增加,使得在-50℃的热释发光峰的相对强度增大。通过测量样品的发光光谱和发光亮度,发现随着CdS含量的增加,样品材料的发射光谱向长波方向移动,发光亮度呈下降的趋势。     

(Zn,Cd)S∶Cu,Cl发光材料的热释发光

在ZnS中分别掺杂质量分数为5%、7%、10%、15%、20%的CdS,得到一系列(Zn,Cd)S∶Cu,Cl粉末电致发光材料样品。测量样品材料的热释发光曲线,发现五个样品在温度-180～-20℃范围内均有两个明显的热释发光峰。CdS含量的变化对材料中陷阱的种类和陷阱深度没有明显的影响,两个峰值温度在-150℃和-50℃附近。Cd离子的掺入改变了材料较深陷阱中载流子的浓度,随着CdS量的增加,使得在-50℃的热释发光峰的相对强度增大。通过测量样品的发光光谱和发光亮度,发现随着CdS含量的增加,样品材料的发射光谱向长波方向移动,发光亮度呈下降的趋势。     

ESR在ACEL ZnS:Mn,Cu和ZnS:Cu材料研究中的应用

ZnS:Mn,Cu粉末发光材料的ESR谱随Mn2+浓度和制备条件的不同有着明显的变化。根据耦合Mn2+的ESR谱理论分析,计算ESR谱参数及其饱和现象表明,当Mn2+浓度>0.2%,Mn2+开始形成离子团,Mn2+团的形成和Mn2+离子与晶格间耦合随Mn2+浓度的增大而增强是发光浓度猝灭的主要原因,Mn2+浓度约为0.7%具有最高发光亮度。本文还讨论了退火条件对ZnS:Mn,Cu ESR谱的影响以及老化的ZnS:Cu中Cu2+的ESR谱。     

Eu3+掺杂硼酸盐晶体及玻璃材料的光谱性质

控制不同的烧结条件，制备了Eu^3 掺杂La2O3—3B2O3体系的晶体及玻璃材料。在这两种组分相同但物相不同的基质中，Eu^3 离子表现出不同的光谱性质。通过对比两种材料的发射光谱、声子边带、电荷迁移带及荧光寿命，讨论了Eu^3 离子周围局域结构的改变对其发光性质的影响。     

ZnS:Mn,Cu粉末p-V-n结直流电致发光

对ZnS:Mn,Cu粉末DCEL屏的形成过程及光电特性作了研究.观测到经形成的EL屏具有整流特性及相位开关效应,发光局限于阳极附近,EL屏具有光生伏特效应.随着形成电压的提高与形成时间的延续,EL屏的电容量由大变小,局部发光区(结区)也从阳极附近向体内迁移.上述实验结果表明:经形成EL屏的阳极附近存在势垒-CuxS-ZnS:Mn,Cu异质结.文中采用p-v-n结模型分析发光屏的导电机构及激发机制,指出发光区的迁移是EL屏退化的重要因素之一.采用正弦电压(频率20Hz—20kHz)激励,观测EL屏的形成过程.初步认为,EL屏的形成与老化过程主要由热引起.因此,制备具有高度热稳定性的包铜ZnS粉末屏是十分重要的.     

基质中非4f组态的电子态对Pr~(3+)离子发光的影响（英文）

三价镨离子(Pr~(3+))是一种备受关注的稀土发光离子。学者们在过去几十年里对其发光性质进行了大量的理论和实验研究。在不同的基质材料中,由于非4f组态的电子态与Pr~(3+)离子发光能级相互作用,Pr~(3+)离子可以展现从紫外到红外波段的不同特征的光发射。影响Pr~(3+)离子发光的这些电子态可能源于4f5d激发组态、电荷迁移态或类激子态。本文中,我们以几种具有代表性的发光材料为例,简短地总结和评述了Pr~(3+)离子发光的不同谱形;也尝试解释了几个新颖的实验现象,例如:杂质束缚激子态和电荷迁移态对发光的猝灭影响。我们希望这些相关概念和谱学结果的整理有助于读者更好地理解一些实验上的发光现象,并为设计发光材料提供新的思路。     

基质中非4 f组态的电子态对Pr3+离子发光的影响

三价镨离子(Pr3+)是一种备受关注的稀土发光离子。学者们在过去几十年里对其发光性质进行了大量的理论和实验研究。在不同的基质材料中,由于非4f 组态的电子态与 Pr3+离子发光能级相互作用,Pr3+离子可以展现从紫外到红外波段的不同特征的光发射。影响 Pr3+离子发光的这些电子态可能源于4f5d 激发组态、电荷迁移态或类激子态。本文中,我们以几种具有代表性的发光材料为例,简短地总结和评述了 Pr3+离子发光的不同谱形；也尝试解释了几个新颖的实验现象,例如：杂质束缚激子态和电荷迁移态对发光的猝灭影响。我们希望这些相关概念和谱学结果的整理有助于读者更好地理解一些实验上的发光现象,并为设计发光材料提供新的思路。     

退火和淬火对电致发光材料老化的影响

退火和淬火对交流粉末电致发光老化的改善是最有效的方法,原因尚未清楚。本文通过发射光谱、热释光和离子探针实验首次提出:在退火和淬火速冷过程中铜的分布发生了变化,由于铜的析出,聚集在晶体表面缺陷上,形成了高场所必需的硫化锌—硫化铜结,增加了晶体中场分布的不均匀性和势垒高度,稳定了硫化铜相,改善了场的分布和初电子注入条件,因而,改善了电致发光老化。     

Lu2SiO5∶Ce荧光粉的热释光特性研究

采用溶胶-凝胶(Sol-Gel)技术,分别在空气中和石墨提供的弱还原气氛下制备出Lu2SiO5∶Ce0.006荧光粉。通过分析样品的结构,光致激发、发射谱和热释光谱等特性,发现弱还原气氛下制备的样品不仅光致发光强度比空气中的强,而且热释光曲线中598K处的高温热释光峰也得到了抑制。进一步考察空气中制备的Lu2SiO5∶Ce0.006,Kx(x=0.01～0.08)荧光粉,结果表明就光致发光和热释光特性而言,K+共掺杂具有与还原气氛类似的作用。综合以上两方面分析结果,可认为598K处热释光峰是由与Ce4+相关的缺陷引起的,并对K+共掺杂LSO∶Ce发光增强的原因给出了合理解释。     

Thermally stimulated luminescence and infrared studies of CaS : Bi,Tm phosphors

Calcium sulphide phosphors doped with bismuth and thulium are prepared from Indian minerals. The glow curves are recorded in the temperature range of 96–320 °K. The activation energies are determined by analyzing the glow peaks after thermal cleaning, using different methods. The results show that, in these phosphors, the electron traps responsible for thermoluminescence are present prior to irradiation. The infrared absorption spectra are recorded in the range of 4000-250 cm^-1. It is concluded that the traps are due to host lattice defects which may arise from S^-2 ion vacancies, created during phosphor preparation.     

Photoluminescence and Thermoluminescence Investigation of Europium- and Dysprosium-Doped Dibarium Magnesium Silicate Phosphor

Europium- and dysprosium-doped barium magnesium silicate powder with different concentrations of dysprosium was synthesized using solid state reactions. The prepared phosphors were characterized using photoluminescence. Prominent green color emissions were obtained under ultraviolet excitation. The thermoluminescence glow curves of the samples were measured after various delay times. With increased delay time, the intensity of the thermoluminescence peak decays, and the position of the thermoluminescence peak shifts to higher temperatures, indicating the considerable retrapping associated with general order kinetics. Refined lattice parameters of monoclinic phosphor were calculated.     

TL, OSL and ESR studies on beryllium oxide

Electron spin resonance (ESR) studies were carried out to identify the defect centres responsible for the thermoluminescence (TL) and optically stimulated luminescence (OSL) processes in BeO phosphor. Two defect centres were identified in irradiated BeO phosphor by ESR measurements, which were carried out at room temperature and these were assigned to an O⁻ ion and Al²⁺ centre. The O⁻ ion (hole centre) correlates with the main 190 °C TL peak. The Al²⁺ centre (electron centre), which acts as a recombination centre, also correlates to the 190 °C TL peak. A third centre, observed during thermal annealing studies, is assigned to an O⁻ ion and is related to the high temperature TL at 317 °C. This centre also appears to be responsible for the observed OSL process in BeO phosphor.     

Luminescence in LiNaSO4:Eu phosphor

Abstract

LiNaSO₄: Eu is a recently discovered thermoluminescence dosimetry (TLD) phosphor which is more sensitive than the widely used CaSO₄:Dy. In this paper results are reported on TL glow curves, TL emission spectra and PL photoluminescence. These measurements help to understand the role of impurity and the mechanism of thermoluminescence in this phosphor.     

Luminescence studies of rare earth doped yttrium gadolinium mixed oxide phosphor

This paper reports the photoluminescence and thermoluminescence properties of gamma ray induced rare earth doped yttrium gadolinium mixed oxide phosphor. The europium (Eu³⁺) was used as rare earth dopant. The phosphor was prepared by chemical co-precipitation method according to the formula (Y_2−x−yGd_x) O₃: Eu_y³⁺ (x=0.5; y=0.05). The photoluminescence emission spectrum of the prepared phosphor shows intense peaks in the red region at 615 nm for ⁵D₀→⁷F₂ transitions and the photoluminescence excitation spectra show a broad band located around 220–270 nm for the emission wavelength fixed at 615 nm. The thermoluminescence studies were carried out after irradiating the phosphor by gamma rays in the dose range from 100 Gy to 1 KGy. In the thermoluminescence glow curves, one single peak was observed at about 300 °C of which the intensity increases linearly in the studied dose range of gamma rays. The glow peak was deconvoluted by GlowFit program and the kinetic parameters associated with the deconvoluted peaks were calculated. The kinetic parameters were also calculated by various glow curve shape and heating rate methods.     

Synthesis and luminescence properties of red long-lasting phosphor Y2O2S:Eu3+, Zn2+, Ti4+ nanotubes via hydrothermal method

Red long-lasting phosphor Y₂O₂S:Eu³⁺, Zn²⁺, Ti⁴⁺ nanotubes were prepared by hydrothermal method. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence and thermoluminescence spectra (TL) were used to characterize the long-lasting phosphor. XRD investigation revealed that the product synthesised under 750 °C for 6 h was a pure phase of Y₂O₂S. SEM observation showed that the sulfuretted phosphor inherited the tube-like shape from the precursor. Under 325 nm UV excitation, the result indicated the strongest red-emission lines at 627 nm, corresponded to the transition from ⁵D₀ to ⁷F₂ level of Eu³⁺ ion. Both the afterglow decay curves and TL curves revealed that the phosphor had efficient luminescent and excellent long-lasting properties.