Nonlinear fluctuation-dissipation relations and stochastic models in nonequilibrium thermodynamics: II. Kinetic potential and variational principles for nonlinear irreversible processes

On the basis of a complete system of fluctuation-dissipation relations, considered in the first part of this series, a variational principle for nonlinear irreversible processes is derived. According to this principle the virtual entropy production functional (analogous to the action in mechanics) has an absolute minimum meaning on the real trajectory of a system. The universal structure of the “kinetic potential” and the “lagrangian” of a system, each contain complete information about fluctuations of macrovariables. The connection of the lagrangian with the markovian kinetic operator of macrovariables is stated. Fundamental properties of dissipative potentials, reflecting microscopic reversibility, are considered. The derived variational principle can be applied to closed systems (the steady state of which is equilibrium) as well as to open ones (when external dynamic forces cause entropy flux through the system and put it into a steady non-equilibrium state). Canonical transformations of macrovariables are considered.     

Variational Principle in the Theory of Partial Distribution Functions

We have constructed thermodynamically consistent theory of correlations in a classical equilibrium system. The theory is based on a variational principle for thermodynamic potential, as functional of correlation functions. Both the thermodynamic potential and correlation functions are determined simultaneously from a uniform variation problem for this functional. We have offered also methods of consecutive approximations system construction for the solution of the obtained variational problem.     

Dynamics of nonholonomic systems from variational principles embedded variation identity

Nondeterminacy of dynamics, i.e., the nonholonomic or the vakonomic, fundamental variational principles, e.g., the Lagrange-d'Alembert or Hamiltonian, and variational operators, etc., of nonholonomic mechanical systems can be attributed to the non-uniqueness of ways how to realize nonholonomic constraints. Making use of a variation identity of nonholonomic constraints embedded into the Hamilton's principle with the method of Lagrange undetermined multipliers, three kinds of dynamics for the nonholonomic systems including the vakonomic and nonholonomic ones and a new one are obtained if the variation is respectively reduced to three conditional variations: vakonomic variation, Hölder's variation and Suslov's variation, defined by the identity. Therefore, different dynamics of nonholonomic systems can be derived from an integral variational principle, utilizing one way of embedding constraints into the principle, with different variations. It is verified that the similar embedding of the identity into the Lagrange-d'Alembert principle gives rise to the nonholonomic dynamics but fails to give the vakonomic one unless the constraints are integrable.     

一类扰动洛伦兹系统的解法

研究了一个大气物理中洛伦兹系统的求解问题.首先利用广义变分原理构造一组变分迭代,其次决定系统的初始近似,最后通过变分迭代方法得到了对应模型的各次近似解.广义变分迭代方法是一个解析方法,得到的解还能够继续进行解析运算. 关键词： 洛伦兹方程 变分原理 近似解     

阴极透镜象差的变分理论

本文运用变分原理研究了电磁复合聚焦阴极透镜的象差理论,导出了在任意象平面中象差系数的普遍公式。它们可以用Glaser导出的象差系数的线性组合来表示。这就表明了宽束与细束电子光学系统的象差都可以用统一的变分方法处理,并建立了两者之间的联系,本文采用矢量形式描写阴极透镜的近轴轨迹,并采用矩阵形式描写象差。本文所得的象差系数较之文献上已有结果形式更为简洁且适用于计算机计算。本文考虑了阴极面上磁场和横向电场不为零的情况,因而所得结果较为普遍。 关键词：     

Stability of general relativistic gaseous masses and variational principles

The Einstein field equations for a self-gravitating fluid that obeys an equation of state of the formp=p(w),p the pressure andw the energy density may be derived from a variational principle. The perturbations of the metric tensor and the fluid dynamic variables satisfy equations which may be derived from a related variational principle, namely the principle associated with the second variation problem. It is shown that the variational principle given by Chandrasekhar from which a sufficient criterion may be obtained for deciding when a self gravitating spherical gaseous mass is unstable against spherically symmetric perturbations is that given by the second variation problem. It is further shown that this criterion is equivalent to requiring that the integral entering into the second variation be negative. The latter form of the criterion may be used in general situations.This work was supported in part by the United States Atomic Energy Commission under contract number AT (11-1)-34, Project Agreement Number 125.     

Deduction of the Quasi-linear Transport Equations of Hydro-thermodynamics from the Gyarmati Principle

From the universal form of Gyarmati's variational principle of thermodynamics the differential equations governing the internal energy and impulse transport of one component hydro-thermodynamic systems are derived. In our particular case Gyarmati's “supplementary theorem” is confirmed, by which the validity of the universal form of Gyarmati's variational principle is guaranted also in non-linear cases. Finally some problems of the Gyarmati principle and of non-linear thermodynamics are discussed.     

Frictional effects with neutrals and Rayleigh-Taylor instability of a compressible Hall plasma

The effect of neutral gas friction is considered on the Rayleigh-Taylor instability of a compressible plasma in the presence of Hall currents. The prevailing magnetic field is assumed to be uniform and horizontal. It is shown that the solution is characterized by a variational principle. Based on the variational principle the dispersion relation is derived for a composite plasma, confined between two horizontal planes at a finite distance, in which the density is stratified in the direction of gravity according to the exponential law. It is found that the effect of collisions with neutrals, Hall currents and compressibility of the medium have destabilizing influence as the wave number range which is stable in their absence, is rendered unstable by their presence.     

Variational properties of irreversible processes

The thermodynamic integral principle, equivalent to the Onsager theory of irreversible thermodynamics, is analyzed in detail for a purely dissipative system. Different reformulations of the principle are also given together with the derivation of the corresponding Euler—Lagrange equations. One of them, the dual field formulation, is of special interest: It is an exact variational principle in terms of the intensive parameters and their dual fields introduced in place of the thermodynamic current densities. Finally, the possibility of deducing variational statements in terms of volume and surface dissipation functionals is discussed.     

Variational principle for the thermodynamics of irreversible processes

A general variational principle equivalent to the balance equations is considered. Conditions of variation are based on stochastic ideas. A connection between the varied expression and the entropy is derived for both the relativistic case and the nonrelativistic approximation.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 47–51, May, 1980.     

Extremal properties of distribution function and statistical operator in equilibrium and nonequilibrium thermodynamics

It is shown that the distribution function and the statistical operator, in the case that the considered system is close to the equilibrium state, can be received by the method relying upon minimizing the information gain, which is connected with the transition of the system from a nonequilibrium state to the equilibrium state. For the systems far from equilibrium the nonequilibrium distribution function or the nonequilibrium statistical operator can be derived using a variational principle based on Jaynes' maximum entropy formalism including memory effects.     

A new variational calculation for N-dimensional polarons in the strong-coupling limit

A novel variational approach is presented for the calculation of the ground-state energy of the polaron in arbitrary N dimensions in the strong-coupling limit. By using the phonon coherent state to represent the wavefunction of phonons, a self-consistent integro-differential equation for the electron wavefunction is derived. The calculated results of the ground-state energy for N = 1, 2 and 3 agree well with the best results in the literature. It is also found that, for arbitrary N, the present results are less than the Feynman path integral ones by small percentages. It is proposed that this approach should be universal for systems involving polarons in the strong-coupling regime.     

Inclusions and inhomogeneities in electroelastic media with hexagonal symmetry

For a long time, the absence of explicit Green's functions (fundamental solutions) for electroelastic media has hindered progress in the modelling of the properties of piezoelectric materials. Michelitsch's recently derived explicit electroelastic Green's function for the infinite medium with hexagonal symmetry (transversely isotropic medium) [4] is used here to obtain compact closed-form expressions for the electroelastic analogue of the Eshelby tensor for spheroidal inclusions. This represents a key quantity for the material properties of piezoelectric solids and analysis of the related electroelastic fields in inclusions. For the limiting case of continuous fibers our results coincide with Levin's expressions [8]. The derived method is useful for an extension to non-spheroidal inclusions or inhomogeneities having an axis of rotational symmetry parallel to the hexagonal c-axis. Received 14 September 1999     

Dissipation and large thermodynamic fluctuations

The results of recent work of Kipnis, Olla, and Varadhan on the dynamic large deviations from a hydrodynamic limit for some interacting particle models are formally extended to a general hydrodynamic situation, including non-equilibrium steady states, as a fluctuation-dissipation hypothesis. The basic conjecture is that the exponent of decay in the probability of a large thermodynamic fluctuation is given by the dissipation of the force required to produce the fluctuation. It is shown that this hypothesis leads to a nonlinear version of Onsager-Machlup fluctuation theory that had previously been proposed by Graham. A direct consequence of the theory is a dynamic variational principle for the most probable thermodynamic history subject to imposed constraints (Onsager's principle of least dissipation). Following Graham, the theory leads also to a generalized potential, analogous to an equilibrium free energy, for the nonequilibrium steady state and an associated static variational principle. Finally, a formulation of nonlinear fluctuating hydrodynamics is proposed in which the noise enters multiplicatively so as to reproduce the conjectured large-deviations theory on a formal analogy with the results of Freidlin and Wentzell for finite-dimensional systems.     

An Evolution Based on Various Energy Strategies

The simplest model of the evolution of agents with different energy strategies is considered. The model is based on the most general thermodynamic ideas and includes the procedures for selection, inheritance, and variability. The problem of finding a universal strategy (principle) as a selection of possible competing strategies is solved. It is shown that when there is non-equilibrium between the medium and agents, a direction in the evolution of agents arises, but at the same time, depending on the conditions of the evolution, different strategies can be successful. However, for this case, the simulation results reveal that in the presence of significant competition of agents, the strategy that has the maximum total energy dissipation of agents arising as a result of evolution turns out to be successful. Thus, it is not the specific strategy that is universal, but the maximization of dissipation. This result discovers an interesting connection between the basic principles of Darwin–Wallace evolution and the maximum entropy production principle.     

基于变分方法的混沌系统参数估计

提出一种基于变分原理的估计混沌系统未知参数的方法,对以x= F(x,θ) 为控制方程的所有混沌系统具有普适性.首先将混沌系统方程引入到目标泛函中;接着利用变分原理导出了混沌系统的伴随方程和待辨识参数泛函梯度的通用公式;然后设计了估计混沌系统未知参数的算法;最后对典型的Lorenz混沌系统和超混沌Chen系统的未知参数进行了估计.数值仿真结果表明该方法是一种非常有效的估计混沌系统未知参数的方法. 关键词： 混沌系统 参数估计 变分方法 伴随方程     

A Note on Cactus Trees: Variational vs. Recursive Approach

In this article we deal with the variational approach to cactus trees (Husimi trees) and the more common recursive approach, that are in principle equivalent for finite systems. We discuss in detail the conditions under which the two methods are equivalent also in the analysis of infinite (self-similar) cactus trees, usually investigated to the purpose of approximating ordinary lattice systems. Such issue is hardly ever considered in the literature. We show (on significant test models) that the phase diagram and the thermodynamic quantities computed by the variational method, when they deviates from the exact bulk properties of the cactus system, generally provide a better approximation to the behavior of a corresponding ordinary system. Generalizing a property proved by Kikuchi, we also show that the numerical algorithm usually employed to perform the free energy minimization in the variational approach is always convergent.     

Symplectic-energy-first integrators of discrete mechanico-electrical dynamical systems

A discrete total variation calculus with variable time steps is presented for mechanico-electrical systems where there exist non-potential and dissipative forces. By using this discrete variation calculus, the symplectic-energy-first integrators for mechanico-electrical systems are derived. To do this, the time step adaptation is employed. The discrete variational principle and the Euler--Lagrange equation are derived for the systems. By using this discrete algorithm it is shown that mechanico-electrical systems are not symplectic and their energies are not conserved unless they are Lagrange mechanico-electrical systems. A practical example is presented to illustrate these results.     

Analytic phase structures and thermodynamic curvature for the charged AdS black hole in alternative phase space

In this paper, we visit the thermodynamic criticality and thermodynamic curvature of the charged AdS black hole in a new phase space. It is shown that when the square of the total charge of the charged black hole is considered as a thermodynamic quantity, the charged AdS black hole also admits a van der Waals-type critical behavior without the help of thermodynamic pressure and thermodynamic volume. Based on this, we study the fine phase structures of the charged AdS black hole with fixed AdS background in the new framework. On the one hand, we give the phase diagram structures of the charged AdS black hole accurately and analytically, which fills up the gap in dealing with the phase transition of the charged AdS black holes by taking the square of the charge as a thermodynamic quantity. On the other hand, we analyse the thermodynamic curvature of the black hole in two coordinate spaces. The thermodynamic curvatures obtained in two different coordinate spaces are equivalent to each other and are also positive. Based on an empirical conclusion under the framework of thermodynamic geometry, we speculate that when the square of charge is treated as an independent thermodynamic quantity, the charged AdS black hole is likely to present a repulsive between its molecules. More importantly, based on the thermodynamic curvature, we obtain a universal exponent at the critical point of phase transition.