Stability of electrostatic ion cyclotron waves in a multi-ion plasma

We have studied the stability of the electrostatic ion cyclotron wave in a plasma consisting of isotropic hydrogen ions (H⁺) and temperature-anisotropic positively (O⁺) and negatively (O⁻) charged oxygen ions, with the electrons drifting parallel to the magnetic field. Analytical expressions have been derived for the frequency and growth/damping rate of ion cyclotron waves around the first harmonic of both hydrogen and oxygen ion gyrofrequencies. We find that the frequencies and growth/damping rates are dependent on the densities and temperatures of all species of ions. A detailed numerical study, for parameters relevant to comet Halley, shows that the growth rate is dependent on the magnitude of the frequency. The ion cyclotron waves are driven by the electron drift parallel to the magnetic field; the temperature anisotropy of the oxygen ions only slightly enhance the growth rates for small values of temperature anisotropies. A simple explanation, in terms of wave exponentiation times, is offered for the absence of electrostatic ion cyclotron waves in the multi-ion plasma of comet Halley.     

Luminescence in collisions of low-energy ions with graphite and Al<Subscript>2</Subscript>O<Subscript>3</Subscript>

Excitation of H⁺, H₂ ⁺, H₃ ⁺, He⁺, and Ar⁺ ions by impact on graphite and Al₂O₃ was investigated by means of emission spectroscopy in the 50–1000 eV energy range of the projectiles. Emission of Balmer series from excited neutral hydrogen is observed for both targets. In addition, for the Al₂O₃ target a continuum emission is observed. The continuum probably originates from excited M_nO_m molecules produced in the collision cascade, when surface atoms bound by ionic bonds are released after the bond breaking caused by neutralization. The spectra obtained under Ar⁺ -bombardment show Ar II lines emitted by backscattered ions.     

Intensity and detuning dependence of fine structure changing collisions in a 85 Rb magneto-optical trap

In an experimental study, the multi-ionisation of metallic clusters (Na_n) has been analysed in collisions with light ions in low charge states (H⁺, He⁺, He²⁺, O³⁺) at collision velocities below 1 a.u. Cluster ions are produced in charge states up to 5+. The average charge of the nano-particles is found to increase linearly with the variation of projectile velocity and the square of the effective projectile charge, well in agreement with the electronic stopping power of the bulk material. A fraction of 50% to 30% of the total projectile energy loss (decreasing with velocity) is transferred into vibrational modes in good agreement with recent theoretical predictions. Received 8 November 2000 and Received in final form 26 January 2001     

Polar-center phase nuclei in He+-irradiated CuO single crystals

Irradiation of various single-crystal CuO faces [ac,bc,(110)] with 4.6-MeV He⁺ ions has been found to result in reduction of CuO to Cu₂O and Cu on the irradiated and unirradiated sides, lifting of forbiddenness from optical transitions in the [CuO₄]⁷⁻ electron center in the 0.7–0.95-eV energy range, a change in dichroism near the bands corresponding to transitions in the hole centers, [CuO₄]⁵⁻, and electron centers, [CuO₄]⁷⁻, as well as in a resonant increase of absorption at 0.95–1.30 eV with an unusual polarization dependence. The results of He⁺ irradiation of CuO single crystals are discussed in terms of a model of the nucleation of the phase of polar (electron and hole) centers in copper-oxygen systems. Fiz. Tverd. Tela (St. Petersburg) 40, 419–424 (March 1998)     

Synthesis and ionic conduction of apatite-type materials

Apatite is a mineral with general formula M₁₀(XO₄)₆Z₂, where M are metallic elements such as Li⁺, Na⁺, K⁺, Ca²⁺, Sr²⁺, Ba²⁺, Ln³⁺ etc.; X=P, V, S, Si, Ge, Re, Cr etc; Z=F⁻, Cl⁻, I⁻, OH⁻, O²⁻, S²⁻ etc. Some materials with apatite structure (S.G. P6₃/m) exhibit quite high cationic (Li⁺, H⁺ etc.) and/or anionic (F⁻, Cl⁻ etc.) conduction. Recently, it was reported that some rare earth silicates, e.g., La₁₀(SiO₄)₆O₃, exhibit quite high oxide-ion conductivity. In this paper, we discuss chemical composition, structure, synthetic procedure and ionic conduction of apatite-type materials. Recent improvements are briefly reviewed. High ionic conductivity has been observed for both cation deficient, oxygen stoichiometric La_9.33(SiO₄)₆O₂ and cation stoichiometric, oxygen excess La₁₀(SiO₄)₆O₃ compositions. Grain boundary conductivity is usually low, which tends to dominate the impedance response. The resistance, particularly the grain boundary resistance is also found to depend on pO₂. Paper presented at the 7th Euroconference on Ionics, Calcatoggio, Corsica, France, Oct. 1–7, 2000.     

T-violation and neutron optics experiments

It is shown that a two-step model of the reaction pd→³HeX (X=η, η′ eω, φ), involving the subprocesses pp) →dπ⁺ and π⁺ n→Xp, can account for the form of the energy dependence of experimental cross sections above the thresholds under the assumption that the singlet part of the pp→dπ⁺ amplitude dominates. The spin-spin asymmetry for the reaction dp→³HeX has been found to be ∼;−1 in the forward-backward approximation. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 1, 3–7 (10 January 1996) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Spectroscopy study of air plasma induced by IR CO2 laser pulses

A spectroscopic study of ambient air plasma, initially at room temperature and pressures ranging from 32 to 101 kPa, produced by high-power transverse excitation atmospheric (TEA) CO₂ laser (λ=9.621 and 10.591 μm; τ _FWHM≈64 ns; power densities ranging from 0.29 to 6.31 GW cm⁻²) has been carried out in an attempt to clarify the processes involved in laser-induced breakdown (LIB) air plasma. The strong emission observed in the plasma region is mainly due to electronic relaxation of excited N, O and ionic fragments N⁺. The medium-weak emission is due to excited species O⁺, N²⁺, O²⁺, C, C⁺, C²⁺, H, Ar and molecular band systems of N ₂⁺(_{2}^{+}( B ²\varSigma _u⁺^{2}\varSigma _{\mathrm{u}}^{+} –X ²\varSigma _g⁺)^{2}\varSigma _{\mathrm{g}}^{+}) , N₂(C³ Π _u–B³ Π _g), N ₂⁺(_{2}^{+}( D² Π _g–A² Π _u) and OH(A² Σ ⁺–X² Π). Excitation temperatures of 23400±700 K and 26600±1400 K were estimated by means of N⁺ and O⁺ ionic lines, respectively. Electron number densities of the order of (0.5–2.4)×10¹⁷ cm⁻³ and (0.6–7.5)×10¹⁷ cm⁻³ were deduced from the Stark broadening of several ionic N⁺ and O⁺ lines, respectively. Estimates of vibrational and rotational temperatures of N ₂⁺_{2}^{+} electronically excited species are reported. The characteristics of the spectral emission intensities from different species have been investigated as functions of the air pressure and laser irradiance. Optical breakdown threshold intensities in air at 10.591 μm have been measured.     

Study of YBa2Cu3O7−x films at various stages of their growth by medium-energy ion scattering

The initial stages in the formation and growth of yttrium-barium cuprate films have been studied in the course of magnetron sputtering of a ceramic target by combining medium-energy-ion scattering (MEIS) and scanning-electron microscopy. The growth mechanisms of YBa₂Cu₃O_7−x films on MgO and substrates having the perovskite structure, SrTiO₃ and LaAlO₃, at deposition temperatures of 700–780 °C and (Ar+O₂) pressure of ∼70 Pa were found to be essentially different. Simulation of MEIS spectra (H⁺ or He⁺ ions with initial energies of 150–250 keV) and comparison of these results with experimental data revealed that in the first case a film forms from pyramid-shaped islands and, in the second, it grows by a two-dimensional layer-by-layer process starting practically with the first monolayer. For the island mechanism, MEIS permitted determination of the substrate surface coverage and showed the growth of the YBa₂Cu₃O_7−x phase to be paralleled by formation of epitaxial nuclei of a Cu₂O phase. After the first, initial stage in the film formation, the second stage, regular growth within reduced thicknesses of 7–15 nm, sets in. This stage is characterized by a practically complete coverage of the substrate and a stable composition. The third stage, regular growth, of an apparently helical nature, was observed to set in at thicknesses above 100 nm. In this stage, the quality of film structure in the bulk and on the surface was found to be somewhat inferior to that of YBa₂Cu₃O_7−x single crystals and did not depend on substrate type. Fiz. Tverd. Tela (St. Petersburg) 41, 588–595 (April 1999)     

Interaction of chloride ions with water clusters absorbing ozone: A computer experiment

The molecular dynamics method is used to investigate the interaction of two, four, and six chloride ions with (H₂O)₅₀, clusters absorbing six ozone molecules. Chloride ions moving toward the cluster penetrate into it. The presence of ozone increases the residence time of Cl⁻ ions in the cluster. The duration of the perturbation increases with the number of Cl⁻ ions surrounding the 6O₃ + (H₂O)₅₀ system. The interaction with Cl⁻ ions enhances the positional disorder of the molecules in the system and enhances the intensity of absorption and emission of infrared radiation. These changes, however, are not monotonic function of the number of ions perturbing the system. As a result of the interaction with Cl⁻ ions, the integrated intensity of the Raman scattering on the (O₃)₆(H₂O)₅₀ cluster in the frequency range 0 ≤ ω ≤ 1100 cm⁻¹ is significantly lower and the number of peaks in the spectrum is smaller.     

Sputtering yields for light ions as a function of angle of incidence

The sputtering yield of Ni, Mo, and Au have been measured at oblique angles of incidence for H⁺-, D⁺-, and⁴He⁺-ion irradiation in the energy region from 1 to 8 keV. The yields were determined from the weight loss of the targets. For Ni and Mo the dependence of the sputtering yield on the angle of incidence was found to be much stronger for H⁺- and D⁺-ion than for⁴He⁺-ion irradiation. In all cases the maximum in the yield was found at angles of incidence ϑ≧80°, where ϑ is the angle measured from the surface normal. Furthermore the ratio of the maximum yield to the yeild at normal incidence increases with increasing surface binding energy of the target material as well as with increasing ion energy in the energy region inveestigated. The results are discussed qualitatively in view of a model for the sputtering mechanism for light ions.     

Electron-stimulated desorption of negative O? ions from the oxidized O/Ru surface

This paper reports on a study of the electron-stimulated desorption of negative oxygen ions from the O/Ru surface, which represents an additional factor responsible for the destruction of the protective oxide layer of the mirrors used in ultraviolet lithography. The cross section of degradation of the O/Ru layer due to the electron-stimulated desorption of the O⁺ and O⁻ ions and the O atoms has been found to be 1.6 × 10⁻¹⁹ cm². A comparison of the dependences of the electron-stimulated desorption yield of O⁺ and O⁻ ions on the incident electron energy E with the ionization cross section of the adsorbate core level σ _O2s (E) has revealed that the ionization of the O 2s level is the main channel of the electron-stimulated desorption of O⁻ ions.     

Screening effects in secondary electron production by equal velocity H+, H+2, He+, He++ions

Electron spectra produced by equal velocity (0.75 MeV/amu) H⁺, H⁺₂, He⁺ and He ⁺⁺ ions are shown. Screening effects are observed for He⁺ ions but not for H⁺₂. He⁺⁺ cross sections scale like Z² = 4 when compared to H⁺ cross sections.     

Quiet-time solar-wind ionic composition

Summary The ISEE-B EGD solar-wind plasma experiment often observes heavy ions in the solar wind. Selecting two periods of quiet solar wind with no particles observed backstreaming from the Earth’s bow-shock, we show that different ion species follow similar trends in terms of changes in the bulk speed and changes in the particle number density. In particular, quiet-solar-wind ionic abundances in these two cases are (relative to H⁺)⁴He²⁺=(1”5)·10⁻²,³He²⁺=1.5·10⁻⁴, 0⁺⁶=(3”15)·10⁻⁴, O⁺⁷=3·10⁻⁴, Si=1·10⁻⁴, Fe=0.5·10⁻⁴. We show that, if⁴He²⁺ abundance increases, the same occurs for the Si, O⁺⁷ and O⁺⁶ abundances. Finally the O⁺⁶ density fluctuations seem to be anticorrelated with⁴He²⁺ density fluctuations.

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Riassunto L’esperimento sul plasma del vento solare dell’EGD ISEE-B spesso osserva ioni pesanti nel vento solare. Scegliendo due periodi di vento solare quieto in cui non si osservano particelle che rifluiscono dall’onda d’urto della Terra, si mostra che differenti specie di ioni hanno andamenti simili delle variazioni della velocità complessiva e dei cambiamenti nella densità numerica delle particelle. In particolare le abbondanze ioniche nei periodi di vento solare quieto sono in questi due casi (relativamente all’H⁺)⁴He²⁺=(1”5)·10⁻²,³He²⁺=1.5·10⁻⁴, O⁺⁶=(3”15)·10⁻⁴, O⁺⁷=3·10⁻⁴, Si=1·10⁻⁴, Fe=0.5·10⁻⁴. Si mostra che, se l’abbondanza dell’⁴He²⁺ cresce, lo stesso avviene dalle abbondanze di Si, O⁺⁷ e O⁺⁶. Infine, le fluttuazioni della densità dell’O⁺⁶ sembrano essere anticorrelate a quelle dell’⁴He²⁺.

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Резюме При проведении плазменного эксперимента ISEE-B EGD часто обнаруживают тяжелые ионы в солнечном ветре. Отбирая два периода спокойного солнечного ветра, мы показываем, что различные ионные компоненты подчиняются аналогичным тенденциям в изменениях объемной скорости и в изменениях плотности числа частиц. При особенно спокойном солнечном ветре ионные концентрации в указанных двух случаях составляют (по отношению к H⁺)⁴He²⁺=(1”5)·10⁻²,³He²⁺=1.5·10⁻⁴, O⁺⁶=(3”15)·10⁻⁴, O⁺⁷=3·10⁻⁴, Si=1·10⁻⁴, Fe=0.5·10⁻⁴. Мы показываем, что если распространенность⁴He²⁺ увеличивается, то имеет место увеличение распространенностей Si, O⁺⁷ и O⁺⁶. Флуктуации плотности O⁺⁶, по-видимому, антикоррелируют с флуктуациями плотности⁴He²⁺.

     

Fluorophotometric Determination of Hydrogen Peroxide with Fluorescin in the Presence of Cobalt (II) and Reaction Against Other Reactive Oxygen Species

A fluorophotometric method for the determination of hydrogen peroxide (H₂O₂) using fluorescin was developed. This method was based on the oxidative reaction of fluorescin, a colorless, non-fluorescent lactoid fluorescein, by H₂O₂ to give highly fluorescein fluorescence emission. In the determination of H₂O₂, the calibration curve exhibited linearity over the H₂O₂ concentration range of 1.5–310 ng mL⁻¹ at an emission wavelength of 525 nm with an excitation of 500 nm and with relative standard deviations (n = 6) of 2.51%, 2.48%, and 1.31% for 3.1 ng mL⁻¹, 30.8 ng mL⁻¹, and for 308 ng mL⁻¹ of H₂O₂, respectively. The detection limit for H₂O₂ was 1.9 ng mL⁻¹ six blank determinations was performed (ρ = 6). This proposed method was applied to detection of other reactive oxygen species and nitrogen species (ROS/RNS) such as singlet oxygen (¹O₂), hydroxyl radical (^•OH), peroxynitrite (ONOO⁻) etc., and it was possible to detect them with a high sensitivity. In addition, this proposed method was applied to the recovery tests of H₂O₂ in calf serum, human saliva, rain water, and wheat noodles; the results were satisfactory.     

Ion-molecular interactions in solutions of methanesulfonic acid in diethylamine according to IR spectroscopy data

The methanesulfonic acid (MSA)-diethylamine (DEA) binary liquid system is studied over the entire range of compositions at 30°C by using multiple frustrated total internal reflection IR spectroscopy. Solutions with acid: base equimolar ratio contain only 1 : 1 ion pairs. Upon adding the acid, a MSA molecule abstracts an anion from the 1 : 1 complex to produce a protonated DEA and an (H₃C(O₂)SO…H…OS(O₂)CH₃)⁻ anion with a strong H bond: (C₂H₅)₂(H)NH⁺ · OS(O₂)CH₃⁻ + HOS(O₂)CH₃ ↔ (C₂H₅)₂(H)NH⁺ + (H₃C(O₂)SO…H…OS(O₂)CH₃)⁻. This equilibrium is shifted to the left. The 1 : 1 complex is present in solutions even at an significant excess of the acid. To protonate the complex, it is required at least two MSA molecules. Under conditions of an excess of the base, DEA molecules do not solvate the 1 : 1 complex. The solution separates into two phases, composed of (C₂H₅)₂(H)NH⁺ · OS(O₂)CH₃⁻ complexes and pure DEA.     

Radiative capture of deuterons in154Sm and238U

Angular — and velocity — distributions of electrons emitted near zero degree from projectile ions (H⁺, H ₂ ⁺ , H ₃ ⁺ , He⁺, He⁺⁺ at 1.7 MeV/u) traversing solid carbon foils (2 to 20) μg/cm²) have been measured. The data give clear evidence of production mechanisms which go beyond those reported elsewhere.     

Theory for Relative Strengths of Trapping of He+ Ions in Solid, Liquid and Gaseous Hydrogen

The study of trapping of He⁺ ion in solid hydrogen is important both as a problem in solid state physics and also as an applied physics problem in the field of muon catalyzed fusion (μCF). In μCF, He⁺ ion acts as a trap for μ⁻, interrupting the chain reaction aspect of the catalytic role of μ⁻ in producing fusion of deuteron and triton and of triton and triton in solid hydrogen composed of ²H–³H and ³H–³H molecules, respectively. Using the Hartree–Fock procedure, combined with procedures for including many-body effects, as well as relaxation effects associated with the He⁺–H₂ distances and the adjustment of the H–H separation, we have investigated the trapping of He⁺ in gaseous and solid state environments. For the former, the environment of He⁺ is simulated by a single hydrogen molecule and for the solid by clusters appropriately chosen to represent the hexagonal close-packed structure. Our results for the gaseous state indicate that the trapping is rather strong with a binding energy of 8.5 eV, with almost equal binding energy in the linear and triangular configurations with respect to the H–H direction. For the solid, both the likely sites for He⁺ trapping, namely the tetrahedral and octahedral interstitial sites, are also found to provide deep traps (8.6 eV) of almost equal strength, independent of the orientations of the neighboring molecules, showing that the trapping is not influenced by the orientational disorder in the surrounding hydrogen molecules. Further, the influence of next nearest neighbor hydrogen molecules is found to enhance the trapping energy for He⁺ substantially, by 0.6 eV, with the incorporation of the third nearest neighbors having a much smaller added effect, demonstrating the convergence of our results with respect to the size of the cluster chosen to simulate the solid. The substantial influence on the He⁺ trapping energy found for the neighbors beyond the nearest ones provides an explanation of the greater accumulation of helium in the solid state of hydrogen in μCF experiments as compared to the liquid. Suggestions are made regarding the possible reasons for the almost negligible accumulation of helium in the liquid state. This revised version was published online in August 2006 with corrections to the Cover Date.     

The infrared spectra of tutton salts 1. A comparative study of (NH4)2 M″(SO4)2·6H2O (M″=Ni,Co or Mg)

The infrared spectra of (NH₄)₂M″(SO₄)₂.6H₂O has been analysed in the region 4000–250 cm⁻¹. The dynamics of each crystal has been discussed in terms of 234 phonon modes, including 3 acoustical ones, using the unit cell approximation. The ambiguity in the assignments of the bands in the region 900–500 cm⁻¹ has been removed by assigning the bands in this region to the libratory modes of H₂O molecules. It has been concluded that the NH ₄ ⁺ and SO ₄ ²⁻ ions have a symmetry lower thanT _dand also the complex [M″(H₂O)₆]²⁺ has a symmetry lower than O _h . The hydrogen bonding is the strongest in the Ni-salt and the weakest in the Mg-salt.     

High-resolution mass spectra of the residual gas in a metallic vacuum system

The mass spectra of the residual gas in a metallic vacuum chamber of capacity 3 l are studied with an MI-9303 high-resolution magnetic resonance mass spectrometer in the mass range 1–140 u. The experiments are carried out under four evacuation conditions in the pressure range P = 10⁻⁸–10⁻¹⁰ Torr, and almost all the mass peaks forming multiplets are resolved. It is shown that the multiplets with mass numbers M≤80 have, as a rule, a multicomponent structure and hydrogen is the basic component responsible for the total pressure in the chamber irrespective of evacuation conditions. Next in order of intensity in the mass spectra are, CH ₄ ⁺ , H²O⁺, CO⁺, and CO ₂ ⁺ peaks. Other lines in the residual gas spectra are largely due to various C-, H-, N-, and O-based compounds. In addition, the background mass spectrum involves Cl-and F-based compounds and noble gas isotopes. The multiplets with M > 80 often degenerate into a single hydrocarbon line.