Influence of the weakly interacting light U boson on the properties of massive protoneutron stars

Considering the octet baryons in relativistic mean field theory and selecting entropy per baryon S=l,we calculate and discuss the influence of U bosons on the equation of state,mass-radius,moment of inertia and gravitational redshift of massive protoneutron stars(PNSs).The effective coupling constant gu of U bosons and nucleons is selected from 0 to 70 GeV~(-2).The results indicate that U bosons will stiffen the equation of state(EOS).The influence of U bosons on the pressure is more obvious at low density than high density,while the influence of U bosons on the energy density is more obvious at high density than low density.The U bosons play a significant role in increasing the maximum mass and radius of PNS.When the value of gu changes from 0 to 70 GeV~(-2),the maximum mass of a massive PNS increases from 2.11M_⊙ to 2.58M_⊙,and the radius of a PNS corresponding to PSR J0348+0432 increases from 13.71 km to 24.35 km.The U bosons will increase the moment of inertia and decrease the gravitational redshift of a PNS.For the PNS of the massive PSR J0348+0432,the radius and moment of inertia vary directly with gu,and the gravitational redshift varies approximately inversely with gu.     

Constraints on the properties of the massive neutron star PSR J0348+0432 from the f0(975) and φ(1020) mesons

The effect of the f ₀(975) and φ(1020) mesons on the properties of the massive neutron star PSR J0348+0432 is examined in the framework of the relativistic mean-field theory by choosing the suitable hyperon coupling constants. It is found that, compared with that without the f ₀(975) and φ(1020) mesons, the radius of the neutron star PSR J0348+0432 increases from R = 12.072 km to R = 12.08 km (i.e. by 0.07%), the central energy density ? _c decreases from 5.6695 fm^?4 to 5.6492 fm^?4 (i.e. by 0.36%), the central pressure decreases from 1.585 fm^?4 to 1.58 fm^?4 (i.e. by 0.32%), the moment of inertia increases from 1.4592 × 10⁴⁵ g · cm² to 1.4615 × 10⁴⁵ g · cm² (i.e. by 0.16%) and the surface gravitational redshift decreases from z = 0.4026 to z = 0.4022 (i.e. by 0.1%). Our results show that the effect of the f ₀(975) and φ(1020) mesons on the properties of the massive neutron star PSR J0348+0432 is very small (i.e. no more than 0.5%) and therefore they do not play a major role.     

The hyperon coupling constants and the surface gravitational redshift of massive neutron stars

With relativistic mean field theory we examine effect of hyperon coupling constants of hyperon Ξ on the surface gravitational redshift of the massive neutron star (NS) PSR J1614-2230 and NS PSR J0348+0432 as the potential well depth of hyperon Ξ is fixed. We find that the mass and radius of a NS increase with the increase of the coupling constant of hyperon Ξ. With the increase of the coupling constant of the hyperon Ξ, the surface gravitational redshift will decrease for a same NS mass but will increase for a same NS radius. The surface gravitational redshift of the more massive NS PSR J0348+0432 decreases by more than that of the less massive NS PSR J1614-2230. We also find that the value range of the surface gravitational redshift of NS will become narrower with the increase of the coupling constant of hyperon Ξ. The greater the NS mass, the greater the influence of the coupling constant of hyperon Ξ on the value range of the surface gravitational redshift of the NS.     

Influence of Entropy on Composition and Structure of Massive Protoneutron Stars

Adjusting the suitable coupling constants in relativistic mean field (RMF) theory and focusing on thermal effect of an entropy per baryon (S) from 0 to 3, we investigate the composition and structure of massive protoneutron stars corresponding PSR J1614-2230 and PSR J0348+0432. It is found that massive protoneutron stars (PNSs) have more hyperons than cold neutron stars. The entropy per baryon will stiffen the equation of state, and the influence on the pressure is more obvious at low density than high density, while the influence on the energy density is more obvious at high density than low density. It is found that higher entropy will give higher maximum mass, higher central temperature and lower central density. The entropy per baryon changes from 0 to 3, the radius of a PNS corresponding PSR J0348+0432 will increase from 12.86 km to 19.31 km and PSR J1612-2230 will increase from 13.03 km to 19.93 km. The entropy per baryon will raise the central temperature of massive PNSs in higher entropy per baryon, but the central temperature of massive PNSs maybe keep unchanged in lower entropy per baryon. The entropy per baryon will increase the moment of inertia of a massive protoneutron star, while decrease gravitational redshift of a massive neutron star.     

The Stability of Some Viable Stars and Electromagnetic Field

We examine the impact of electromagnetic field on the stability of compact stars corresponding' to embedded class one metric using the concept of cracking.For this purpose,we develop the generalized hydrostatic equilibrium equation for charged perfect fluid distribution of compact stars and perturb it by means of local density perturbation scheme to check the stability of inner matter configuration.We investigate the cracking of Her X-1,PSR 1937+21,PSR J 1614-2230,PSR J 0348+0432 and RX J 1856-37.We conclude that PSR J 0348+0432 and RX J 1856-37 exhibit cracking when charge is introduced on these astrophysical objects.     

Comparative Study on Three Different Systems of Chemiluminescence Flow‐Injection Determination of Leucogen

Abstract

The effects of three systems on the chemiluminescence (CL) intensity have been studied in this paper, such as leucogen–potassium permanganate–rhodamine B, leucogen–cerium (IV)–rhodamine B, and leucogen–luminol–hydrogen peroxide (called system 1, system 2, and system 3, respectively). The mechanism of these reactions is also discussed. Surfactant (CTMAB) has a remarkably sensitive effect on these systems mentioned above. Therefore, three new flow injection chemiluminescence methods for the determination of leucogen have been established. For system 1, the linear range is 8.0×10^?8 to 4.0×10^?5 g mL^?1, with limits of detection 2×10^?8 g mL^?1; the relative standard deviation is 2.5% (n=11, Cs=4.0×10^?6 g mL^?1). For system 2, the linear range is 1.0×10^?8 to 5.0×10^?6 g mL^?1, with limits of detection 3×10^?9 g mL^?1; the relative standard deviation is 5.1% (n=11, Cs=1.0×10^?6 g mL^?1). For system 3, the linear range is 4.0×10^?8 to 2.0×10^?6 g mL^?1, with limits of detection 1×10^?8 g mL^?1; the relative standard deviation is 1.3% (n=11, Cs=1.0×10^?7 g mL^?1). Compared with the three methods above, system 3 is confirmed as the best method. This method has been applied to the determination of leucogen with satisfactory results.     

Flow‐Injection Chemiluminescence Study of Luminol–Hydrogen Peroxide–Carbendazim System

Abstract

A new flow‐injection chemiluminescence (CL) method is described for the determination of carbendazim. The method is based on the CL reaction of luminol and hydrogen peroxide (H₂O₂). Carbendazim can greatly enhance the chemiluminescence intensity in sodium hydroxide–sodium dihydrogen phosphate (NaOH–NaH₂PO₄) medium (pH=12.6). Under the optimum conditions, the linear range for the determination of carbendazim is 2.00×10^?8 to 2.00×10^?6 g mL^?1 with a detection limit (S/N=3) of 7.24×10^?9 g mL^?1. The relative standard deviation is 1.8% for 1.0×10^?7 g mL^?1 carbendazim (n=8). The proposed method has been applied to the determination of carbendazim in tap‐water samples. Furthermore, the possible enhanced CL mechanism is discussed by examining the CL spectra and fluorescence spectra.     

Two New Hyperon Coupling Models in the Light of the Massive Neutron Star PSR J0348+0432*

In the context of the relativistic mean field theory, we propose two new hyperon coupling models, namely the limitation model and the potential well depth model, in the light of the observed data for the massive neutron PSR J0348+0432. The radius of PSR J0348+0432 given by the limitation model is found to be $12.52 \text{ km}\sim12.97\text{ km}$, while the radius given by the potential well depth model is found to be $12.19\text{ km}\sim12.89 \text{ km}$. We also calculate the gravitational redshift of PSR J0348+0432 within these two models, for which the limitation model gives $0.346\sim0.391$ and the potential well depth model gives $0.350\sim0.409$. Further exploration of these two models shows that, these two models are almost degenerate for neutron stars lighter than $1.85 M_{\odot}$, and start to give different results for massive neutron stars heavier than $1.85 M_{\odot}$. Therefore, the studies of massive neutron stars could be crucial for discriminating these two models and help deepen our understanding of hyper-nuclear interactions.     

Estimation of microbial methane generation and oxidation rates in the municipal solid waste landfill of Kaluga city,Russia

Using a theoretical model and mass isotopic balance, biogas (methane and CO₂) released from buried products at their microbial degradation was analysed in the landfill of municipal and non-toxic industrial solid organic waste near Kaluga city, Russia. The landfill contains about 1.34×10⁶ tons of waste buried using a ‘sandwich technique’ (successive application of sand–clay and waste layers). The δ¹³C values of biogenic methane with respect to CO₂ were?56.8 (±2.5) ‰, whereas the δ¹³C of CO₂ peaked at+9.12‰ (+1.4±2.3‰ on average), reflecting a virtual fractionation of carbon isotopes in the course of bacterial CO₂ reduction at the landfill body. After passing through the aerated soil layers, methane was partially oxidised and characterised by δ¹³C in the range of?50.6 to?38.2‰, evidencing enrichment in ¹³C, while the released carbon dioxide had δ¹³C of?23.3 to?4.04‰, respectively. On the mass isotopic balance for the δ¹³C values, the methane production in the landfill anaerobic zone and the methane emitted through the aerated landfill surface to the atmosphere, the portion of methane oxidised by methanotrophic bacteria was calculated to be from 10 to 40% (averaged about 25%). According to the theoretical estimation and field measurements, the annual rate of methane production in the landfill reached about 2.9(±1.4)×10⁹ g C CH₄ yr^?1 or 5.3(±2.6)×10⁶ m³ CH₄ yr^?1. The average rates of methane production in the landfill and methane emission from landfill to the atmosphere are estimated as about 53 (±26) g C CH₄ m^?2 d^?1 (or 4 (±2) mol CH₄ m^?2 d^?1) and 33 (±12) g C CH₄ m^?2 d^?1 (or 2.7 (±1) mol CH₄ m^?2 d^?1), respectively. The calculated part of methane consumed by methanotrophic bacteria in the aerated part of the landfill was 13(±7) g C CH₄ m^?2 d^?1 (or 1.1(±0.6) mol CH₄ m^?2 d^?1) on average.     

Synthesis of 2-Mercaptonicotinic Acid-Capped CdSe Quantum Dots and its Application to Spectrofluorometric Determination of Cr(VI) in Water Samples

The CdSe quantum dots (QDs) capped with 2-mercaptonicotinic acid (H₂MN) were prepared through a controllable process at 80 °C. The prepared QDs were characterized by XRD, TEM, IR, UV–Vis and fluorescence (FL) techniques. It was found that the QDs were nearly mono-disperse with the diameters in the range of 8–10 nm. These QDs are capable to exhibit strong FL even in concentrated acidic media. They exhibit an enhanced fluorescence in the presence of Cr(VI), which was used for the determination of Cr(VI) in water samples. The linear range was found to be 1?×?10^?7–6.0?×?10^?6 M with the RSD and DL of 0.92 % and 5?×?10^?8 M, respectively. Except that Ca²⁺ and Fe³⁺ which can be eliminated through a simple precipitation process, the other co-existent ions present in natural water were not interfered. The recoveries obtained for the added amounts of Cr(VI) were in the range of 96.9–103.2 %, which denote on application of the method, satisfactorily.     

Correlation of plume dynamics and oxygen pressure with VO2 stoichiometry during pulsed laser deposition

Vanadium dioxide thin films have been deposited on Corning glass substrates by a KrF laser ablation of V₂O₅ target at the laser fluence of 2 J?cm^?2. The substrate temperature and the target-substrate distance were set to 500 ^°C and 4 cm, respectively. X-ray diffraction analysis showed that pure VO₂ is only obtained at an oxygen pressure range of 4×10^?3–2×10^?2 mbar. A higher optical switching contrast was obtained for the VO₂ films deposited at 4×10^?3–10^?2 mbar. The films properties were correlated to the plume-oxygen gas interaction monitored by fast imaging of the plume.     

Meson Effect in the Proto Neutron Star PSR J0348+0432

The effect of mesons f ₀(975) (named as f), ?(1020) (named as ?) and δ on the moment of inertia of the PNS PSR J0348+0432 is examined in the framework of the relativistic mean field theory considering the baryon octet. It is found that the energy density ε and pressure p will increase considering the mesons δ whereas will decrease as the mesons f and ? being considered. When the mesons f,? and δ are considered, the energy density and pressure will all decrease. It is also found that the contribution of mesons f, ? and δ to the central energy density is only the central energy density’s 0.06 ～0.6% whereas the contribution of mesons f, ? and δ to the central pressure is the central pressure’s 4 ～7%. For the radius, it will decrease when the contributions of mesons f, ? and δ are considered. The moment of inertia I will increase considering the mesons δ whereas will decrease as the mesons f and ? being considered. When the mesons f, ? and δ are all considered, the moment of inertia will decrease. It is found that the contribution of mesons f and ? to moment of inertia is 4 ～9 times larger than that of mesons δ. Our results show that the mesons f, ? and δ contribute to the moment of inertia’s 2 ～5%.     

A New Candidate Laser Dye Based 1,4-Bis[β-(2-Naphthothiazolyle)Vinyl]Benzene. Spectroscopic Behavior,Laser Parameters and Excitation Energy Transfer

A new candidate laser dye based 1,4-bis[β-(2-naphthothisolyl) vinyl] benzene (BNTVB) were prepared, and characterized in various organic solvents. The center polarity is less sensitive than electronic absorption. A red shift was noticed in the fluorescence spectra (ca. 40 nm) with increment in the solvent’s polarity, this means that BNTVB’s polarity appreciates upon excitation. The dipole moment of ground state (μ_g) and the excited singlet state dipole moment (μ_e) are determined from Kawski – Chamma and Bakshiev–Viallet equations using the disparity of Stokes shift with solvent polarity function of ε (dielectric constant) and n (refractive index) of the solvent. The result was found to be 0.019D and 5.13D for ground and exited state, in succession. DFT/TD-DFT manners were used to understand the electronic structures and geometric of BNTVB in other solvents. The experimental and theoretical results showed a good agreement. The photochemical quantum yield (Ф_c) of BNTVB was calculated in variable organic reagents such as Dioxane, CHCl₃, EtOH and MeOH at room temperature. The values of φ_c were calculated as 2.3?×?10^?4, 3.3?×?10^?3, 9.7?×?10^?5 and 6.2?×?10^?5 in Dioxane, CHCl₃, EtOH and MeOH, respectively. The dye solutions (2?×?10^?4 M) in DMF, MeOH and EtOH give laser emission in the blue-green region. The green zone is excited by nitrogen pulse 337.1 nm. The tuning range, gain coefficient (α) and cross – section emission (σ_e) of laser were also estimated. Excitation energy transfer from BNTVB to rhodamine-6G (R6G) and N,N-bis(2,6-dimethyphenyl)-3,4:9,10-perylenebis-(dicarboximide) (BDP) was also studied in EtOH to increase the laser emission output from R6G and BDP when excited by nitrogen laser. The dye-transfer power laser system (ETDL) obeys the Foster Power Transmission (FERT) mechanism with a critical transmission distance, R_o of 40 and 32 ? and k_ET equals 2.6?×?10¹³ and 1.06?×?10¹³ M^?1 s^?1 for BNTVB / R6G and BNTVB / BDP pair, respectively.     

Swift heavy ion provoked structural, optical and electrical properties in SnO2 thin films

SnO₂ thin films grown on glass substrates at 300 ^°C by reactive thermal evaporation and annealed at 600 ^°C were irradiated by 120 MeV Ag⁹⁺ ions. Though irradiation is known to induce lattice disorder and suppression of crystallinity, we observe grain growth at a certain fluence of irradiation. X-ray diffraction (XRD) revealed the crystalline nature of the films. The particle size estimated by Scherrer’s formula for the irradiated films was in the range 10–25 nm. The crystallite size increases with increase in fluence up to 1×10¹² ions?cm^?2, whereas after that the size starts decreasing. Atomic force microscope (AFM) results showed the surface modification of nanostructures for films irradiated with fluences of 1×10¹¹ ions?cm^?2 to 1×10¹³ ions?cm^?2. The UV–visible spectrum showed the band gap of the irradiated films in the range of 3.56 eV–3.95 eV. The resistivity decreases with fluence up to 5×10¹² ions?cm^?2 and starts increasing after that. Rutherford Backscattering (RBS) reveals the composition of the films and sputtering of ions due to irradiation at higher fluence.     

A selective sensor for nanolevel detection of lead (II) in hazardous wastes using ionic-liquid/Schiff base/MWCNTs/nanosilica as a highly sensitive composite

An effective potentiometric sensor had been fabricated for the rapid determination of Pb²⁺ based on carbon paste electrode consisting of room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF₆), multiwalled carbon nanotubes (MWCNTs), nanosilica, synthesized Schiff base, as an ionophore, and graphite powder. The constructed nanocomposite electrode showed better sensitivity, selectivity, response time, response stability, and lifetime in comparison with typical Pb²⁺ carbon paste electrode for the successfully determination of Pb²⁺ ions in water and in waste water samples. The best response for nanocomposite electrode was obtained with electrode composition of 18% ionophore, 20% BMIM-PF₆, 49% graphite powder, 10% MWCNT, and 3% nanosilica. The new electrode exhibited a Nernstian response (29.76?±?0.10 mV decade^?1) toward Pb²⁺ ions in the range of 5?×?10^?9?C1.0?×?10^?1 mol L^?1 with a detection limit of 2.51?×?10^?9 mol L^?1. The potentiometric response of prepared sensor is independent of the pH of test solution in the pH range of 4.5?C8.0. It has quick response with response time of about 6 s. The proposed electrode show fairly good selectivity over some alkali, alkaline earth, transition, and heavy metal ions.     

Optical properties of Yb3+ ions in fluorophosphate glasses for 1.0 μm solid-state infrared lasers

Yb³⁺-doped fluorophosphate glasses were prepared by melt-quenching technique and characterized their spectroscopic properties to assess the laser performance parameters. The magnitude of absorption (emission) cross-sections at 975 nm for all the studied Yb³⁺-doped glasses is found to be in the range of 0.29–1.50 × 10^?20 (0.59–1.99 × 10^?20 cm²) which is much higher than those of commercial Kigre QX/Yb: 1.06 × 10^?20 (0.5 × 10^?20 cm²) laser glass. The luminescence lifetimes of ²F_5/2 level decrease (1.15–0.45 ms) with increase in Yb₂O₃ concentration (0.1–4.0 mol%). Effect of OH^? content on luminescence properties of Yb³⁺ ions has also been investigated. The effect of radiative trapping has been discussed by using McCumber (McC) and Fuchtbauer–Ladenburge (F–L) methods. The product of experimental lifetimes and emission cross-sections for 0.1 mol% Yb₂O₃-doped glass is found to be 2.28 × 10^?20 cm² ms which indicates that the higher energy storage and extraction capability could be possible. The detailed spectroscopic results suggest that the studied glasses can be considered for high-power and ultrashort pulse laser applications.     

Studies of some physical properties of PrFe0.7Ni0.3O3 thin films after 200 MeV Ag15+ irradiation

PrFe_0.7Ni_0.3O₃ thin films (thickness ~ 200 nm) were prepared by pulsed laser ablation technique on LaAlO₃ substrate. These films were irradiated with 200?MeV Ag¹⁵⁺ ions at various fluencies, ranging from 1 × 10¹¹ to 1 × 10¹² ions/cm². These irradiated thin films were characterized by using X-ray diffraction, dc conductivity, dc magnetization and atomic force microscopy. These films exhibit orthorhombic structure and retain it even after irradiations. The crystallite size (110–137?nm), micro strain (1.48 × 10^?2–1.75 × 10^?2 line^?2?m^?4) and dislocation density (79.7 × 10¹⁴–53.2 × 10¹⁴ line/m²) vary with ion fluencies. An enhancement in resistivity at certain fluence and then a decrease in its value (0.22175–0.21813?Ω?cm) are seen. A drastic change in observed magnetism after ion irradiation is seen. With ion irradiation, an increase in surface roughness, due to the formation of hillocks and other factors, is observed. Destruction of magnetic domains after irradiation can also be visualized with magnetic force microscopy and is in close agreement with magnetization data. The impact on various physical properties in these thin films after irradiation indicates a distortion in the lattice structure and consequently on single-particle band width caused by stress-induced defects.     

Li+ transportation kinetics of FeF3 · 0.33H2O/C nanocomposite synthesized by one-step solid state method

A new cathode material for lithium ion battery FeF₃?·?0.33H₂O/C was synthesized successfully by a simple one-step chemico-mechanical method. It showed a noticeable initial discharge capacity of 233.9 mAh g^?1 and corresponding charge capacity of 186.4 mAh g^?1. A reversible capacity of ca.157.4 mAh g^?1 at 20 mA g^?1 can be obtained after 50 charge/discharge cycles. To elucidate the lithium ion transportation in the cathode material, the methods of electrochemical impedance spectroscopy (EIS) and galvanostatic intermittent titration technique (GITT) were applied to obtain the lithium diffusion coefficients of the material. Within the voltage level of 2.05–3.18 V, the method of EIS showed that \( {D}_{{\mathrm{Li}}^{+}} \) varied in the range of 1.2?×?10^?13?~?3.6?×?10^?14 cm² s^?1 with a maximum of 1.2?×?10^?13 cm² s^?1 at 2.5 V. The method of GITT gave a result of 8.1?×?10^?14?~?1.2?×?10^?15 cm² s^?1. The way and the range of the variation for lithium ion diffusion coefficients measured by the GITT method show close similarity with those obtained by the EIS method. Besides, they both reached their maximum at a voltage level of 2.5 V.     

The intercalation/deintercalation kinetic studies on the structure-integrated cathode material 0.5Li2MnO3 0.5LiNi0.5Mn0.5O2

A cathode material, 0.5Li₂MnO₃ 0.5LiNi_0.5Mn_0.5O₂, was prepared by citric acid-assisted sol–gel method and its electrochemical performance was investigated. It delivered a charge capacity of 270 mAh g^?1 and a discharge capacity of 189 mAh g^?1 in the first cycle. With the increase of current density from 14 to 28 mA g^?1, the discharge capacity dropped severely to 130 mA g^?1. Obviously, the rate capability of the material was inferior to most of the oxide cathode materials. The diffusion coefficient of this material was calculated to be 6.04?×?10^?12 cm² s^?1 from the results of cyclic voltammetry measurements. Moreover, diffusion coefficients between 3.13?×?10^?12 and 1.22?×?10^?10 cm² s^?1 in the voltage range of 3.8–4.7 V were obtained by capacity intermittent titration technique. This, together with the localized Li₂MnO₃ domains in the crystal structure, may validate the poor rate capability.     

Determination of Protein by Fluorescence Enhancement of Curcumin in Lanthanum-Curcumin-Sodium Dodecyl Benzene Sulfonate-Protein System

We found that the fluorescence intensity of the lanthanum (La³⁺)-curcumin (CU) complex can be highly enhanced by proteins in the presence of sodium dodecyl benzene sulphonate (SDBS). Based on this finding, a new fluorimetric method for the determination of protein was developed. Under optimized conditions, the enhanced intensities of fluorescence are quantitatively in proportion to the concentrations of proteins in the range 0.0080?C20.0 ??g·mL^?1 for bovine serum albumin (BSA) and 0.00080?C20.0 ??g·mL^?1 for human serum albumin (HSA) with excitation of 425 nm, and 0.00020?C20.0 ??g·mL^?1 for bovine serum albumin (BSA) and 0.00080?C20.0 ??g·mL^?1for human serum albumin (HSA) with excitation of 280 nm, while corresponding qualitative detection limits (S/N????3) are as low as 5.368, 0.573, 0.049, 0.562 µg·mL^?1, respectively. Study on reaction mechanism reveals that proteins can bind with La³⁺, CU and SDBS through self-assembling function with electrostatic attraction, hydrogen bonding, hydrophobic interaction and van der Waals forces, etc. The proteins form a supermolecular association with multilayer structure, in which La³⁺-CU is clamped between BSA and SDBS. The unique high fluorescence enhancement of CU is resulted through synergic effects of favorable hydrophobic microenvironment provided by BSA and SDBS, and efficient intermolecular energy transfer among BSA, SDBS and CU. In energy transfer process, La³⁺ plays a crucial role because it not only shortens the distance between SDBS and CU, but also acts as a ??bridge?? for transferring the energy from BSA to CU.