Temperature dependence of the quenching of N<Subscript>2</Subscript> (C <Superscript>3</Superscript>Π<Subscript>u</Subscript>) by N<Subscript>2</Subscript> (X) and O<Subscript>2</Subscript> (X)

The temperature dependences of the quenching rate constants of the states N₂ (${\rm C} \ {^{3}{ \rm \Pi }_{u}}${\rm C} \ {^{3}{ \rm \Pi }_{u}} v^′=0,1) by N₂ (X) and of the state N₂ (${\rm C} \ {^{3}{ \rm \Pi }_{u}} \ v^{\prime}=0${\rm C} \ {^{3}{ \rm \Pi }_{u}} \ v^{\prime}=0) by O₂ (X) are studied. Time-resolved light emission from the gas was analyzed in the temperature range from 300 K to 210 K keeping the gas at constant density. In case of quenching by N₂ (X), the quenching rate constant for the vibrational level v^′= 0 increases by (13 ±3)% with gas cooling whereas the quenching rate constant for v^′= 1 decreases by (5.0 ±2.5)% in this temperature range. For quenching by O₂ (X), the quenching rate constant decreases by (3 ±2)% with gas cooling. The temperature variation of the N₂ (C ³Π_u v^′=0) emission intensity for pure nitrogen and dry air are calculated using the obtained quenching rate constants and is compared with the experimental data available in the literature.     

Weakly Non-Ergodic Statistical Physics

For weakly non ergodic systems, the probability density function of a time average observable is where is the value of the observable when the system is in state j=1,…L. p _j ^eq is the probability that a member of an ensemble of systems occupies state j in equilibrium. For a particle undergoing a fractional diffusion process in a binding force field, with thermal detailed balance conditions, p _j ^eq is Boltzmann’s canonical probability. Within the unbiased sub-diffusive continuous time random walk model, the exponent 0<α<1 is the anomalous diffusion exponent 〈x ²〉∼t ^α found for free boundary conditions. When α→1 ergodic statistical mechanics is recovered . We briefly discuss possible physical applications in single particle experiments.     

On the Spectrum of an Hamiltonian in Fock Space. Discrete Spectrum Asymptotics

A model operator H associated with the energy operator of a system describing three particles in interaction, without conservation of the number of particles, is considered. The location of the essential spectrum of H is described. The existence of infinitely many eigenvalues (resp. the finiteness of eigenvalues) below the bottom τ_ess(H) of the essential spectrum of H is proved for the case where the associated Friedrichs model has a threshold energy resonance (resp. a threshold eigenvalue). For the number N(z) of eigenvalues of H lying below z < τ_ess(H) the following asymptotics is found

Non-Equilibrium Dynamics of Dyson’s Model with an Infinite Number of Particles

Dyson’s model is a one-dimensional system of Brownian motions with long-range repulsive forces acting between any pair of particles with strength proportional to the inverse of distances with proportionality constant β/2. We give sufficient conditions for initial configurations so that Dyson’s model with β = 2 and an infinite number of particles is well defined in the sense that any multitime correlation function is given by a determinant with a continuous kernel. The class of infinite-dimensional configurations satisfying our conditions is large enough to study non-equilibrium dynamics. For example, we obtain the relaxation process starting from a configuration, in which every point of \mathbbZ{\mathbb{Z}} is occupied by one particle, to the stationary state, which is the determinantal point process with the sine kernel.     

On the Mixing Time of the 2D Stochastic Ising Model with “Plus” Boundary Conditions at Low Temperature

We consider the Glauber dynamics for the 2D Ising model in a box of side L, at inverse temperature β and random boundary conditions τ whose distribution P either stochastically dominates the extremal plus phase (hence the quotation marks in the title) or is stochastically dominated by the extremal minus phase. A particular case is when P is concentrated on the homogeneous configuration identically equal to +  (equal to ?). For β large enough we show that for any ${\varepsilon >0 }We consider the Glauber dynamics for the 2D Ising model in a box of side L, at inverse temperature β and random boundary conditions τ whose distribution P either stochastically dominates the extremal plus phase (hence the quotation marks in the title) or is stochastically dominated by the extremal minus phase. A particular case is when P is concentrated on the homogeneous configuration identically equal to +  (equal to −). For β large enough we show that for any ${\varepsilon >0 }${\varepsilon >0 } there exists c=c(b,e){c=c(\beta,\varepsilon)} such that the corresponding mixing time T _mix satisfies lim_L?￥ P(T_mix 3 exp(cL^e)) = 0{{\rm lim}_{L\to\infty}\,{\bf P}\left(T_{\rm mix}\ge {\rm exp}({cL^\varepsilon})\right) =0}. In the non-random case τ ≡ +  (or τ ≡ −), this implies that T_mix ￡ exp(cL^e){T_{\rm mix}\le {\rm exp}({cL^\varepsilon})}. The same bound holds when the boundary conditions are all +  on three sides and all − on the remaining one. The result, although still very far from the expected Lifshitz behavior T _mix = O(L ²), considerably improves upon the previous known estimates of the form T_mix ￡ exp(c L^{\frac 12 + e}){T_{\rm mix}\le {\rm exp}({c L^{\frac 12 + \varepsilon}})}. The techniques are based on induction over length scales, combined with a judicious use of the so-called “censoring inequality” of Y. Peres and P. Winkler, which in a sense allows us to guide the dynamics to its equilibrium measure.     

Condensation of the Roots of Real Random Polynomials on the Real Axis

We introduce a family of real random polynomials of degree n whose coefficients a _k are symmetric independent Gaussian variables with variance , indexed by a real α≥0. We compute exactly the mean number of real roots 〈N _n 〉 for large n. As α is varied, one finds three different phases. First, for 0≤α<1, one finds that . For 1<α<2, there is an intermediate phase where 〈N _n 〉 grows algebraically with a continuously varying exponent, . And finally for α>2, one finds a third phase where 〈N _n 〉∼n. This family of real random polynomials thus exhibits a condensation of their roots on the real line in the sense that, for large n, a finite fraction of their roots 〈N _n 〉/n are real. This condensation occurs via a localization of the real roots around the values , 1≪k≤n.     

A Volume Inequality for Quantum Fisher Information and the Uncertainty Principle

Let A ₁,…,A _N be complex self-adjoint matrices and let ρ be a density matrix. The Robertson uncertainty principle

A Construction of Blow up Solutions for Co-rotational Wave Maps

The existence of co-rotational finite time blow up solutions to the wave map problem from ${\mathbb{R}^{2+1} \to N}The existence of co-rotational finite time blow up solutions to the wave map problem from \mathbbR²⁺¹ ? N{\mathbb{R}^{2+1} \to N} , where N is a surface of revolution with metric d ρ ² + g(ρ)² dθ², g an entire function, is proven. These are of the form u(t,r)=Q(l(t)t)+R(t,r){u(t,r)=Q(\lambda(t)t)+\mathcal{R}(t,r)} , where Q is a time independent solution of the co-rotational wave map equation −u _tt  + u _rr  + r ⁻¹ u _r  = r ⁻² g(u)g′(u), λ(t) = t ^−1-ν, ν > 1/2 is arbitrary, and R{\mathcal{R}} is a term whose local energy goes to zero as t → 0.     

Magnetocaloric properties of as-quenched Ni50.4Mn34.9In14.7 ferromagnetic shape memory alloy ribbons

The temperature dependences of magnetic entropy change and refrigerant capacity have been calculated for a maximum field change of Δ H=30 kOe in as-quenched ribbons of the ferromagnetic shape memory alloy Ni_50.4Mn_34.9In_14.7 around the structural reverse martensitic transformation and magnetic transition of austenite. The ribbons crystallize into a single-phase austenite with the L2₁-type crystal structure and Curie point of 284 K. At 262 K austenite starts its transformation into a 10-layered structurally modulated monoclinic martensite. The first- and second-order character of the structural and magnetic transitions was confirmed by the Arrott plot method. Despite the superior absolute value of the maximum magnetic entropy change obtained in the temperature interval where the reverse martensitic transformation occurs (|\varDelta S_M^max|=7.2 J kg^-1 K^-1)(|\varDelta S_{\mathrm{M}}^{\max}|=7.2\mbox{ J}\,\mbox{kg}^{-1}\,\mbox{K}^{-1}) with respect to that obtained around the ferromagnetic transition of austenite (|\varDelta S_M^max|=2.6 J kg^-1 K^-1)(|\varDelta S_{\mathrm{M}}^{\max}|=2.6\mbox{ J}\,\mbox{kg}^{-1}\,\mbox{K}^{-1}), the large average hysteretic losses due to the effect of the magnetic field on the phase transformation as well as the narrow thermal dependence of the magnetic entropy change make the temperature interval around the ferromagnetic transition of austenite of a higher effective refrigerant capacity (RC^magn_eff=95J kg^-1\mathrm{RC}^{\mathrm{magn}}_{\mathrm{eff}}=95\mbox{J}\,\mbox{kg}^{-1} versus RC^struct_eff=60J kg^-1)\mathrm{RC}^{\mathrm{struct}}_{\mathrm{eff}}=60\mbox{J}\,\mbox{kg}^{-1}).     

Dirac Operators on Quantum Projective Spaces

We construct a family of self-adjoint operators D _N , ${N\in{\mathbb Z}}We construct a family of self-adjoint operators D _N , N ? \mathbb Z{N\in{\mathbb Z}} , which have compact resolvent and bounded commutators with the coordinate algebra of the quantum projective space \mathbb CP^l_q{{\mathbb C}{\rm P}^{\ell}_q} , for any ℓ ≥ 2 and 0 < q < 1. They provide 0⁺-dimensional equivariant even spectral triples. If ℓ is odd and N=\frac12(l+1){N=\frac{1}{2}(\ell+1)} , the spectral triple is real with KO-dimension 2ℓ mod 8.     

Constraining the low-energy pion electromagnetic form factor with space-like and phase of time-like data

The Taylor coefficients c and d of the EM form factor of the pion are constrained using analyticity, knowledge of the phase of the form factor in the time-like region, 4m _π ²≤t≤t _in and its value at one space-like point, using as input the (g−2) of the muon. This is achieved using the technique of Lagrange multipliers, which gives a transparent expression for the corresponding bounds. We present a detailed study of the sensitivity of the bounds to the choice of time-like phase and errors present in the space-like data, taken from recent experiments. We find that our results constrain c stringently. We compare our results with those in the literature and find agreement with the chiral perturbation-theory results for c. We obtain when c is set to the chiral perturbation-theory values.     

Temperature stable low loss PTFE/rutile composites using secondary polymer

Rutile filled PTFE composites have been fabricated through Sigma Mixing, Extrusion, Calendering and Hot pressing (SMECH) process. Dielectric constant (e_r￠\varepsilon_{r}') and loss tangent (tan δ) of filled composites at microwave frequency region were measured by waveguide cavity perturbation technique using a Vector Network Analyzer. The temperature coefficient of dielectric constant (t_er￠\tau_{\varepsilon_{r}'}) was measured in the 0–100°C temperature range. In order to tailor the temperature coefficient of dielectric constant of the composite, thermoplastic Poly (ether ether ketone) (PEEK) has been used as a secondary polymer. Flexible laminate having a dielectric constant, e_r￠ ~ 10.4\varepsilon_{r}'\sim10.4, loss tangent tan δ∼0.0045 and t_er￠ ~ -40 ppm/K\tau_{\varepsilon_{r}'}\sim-40\mbox{ ppm}/\mbox{K} was realized in Polytetrafluroethylene (PTFE)/rutile composites with the addition of 8 wt% PEEK. The reduction in t_er￠\tau_{\varepsilon_{r}'} is mainly attributed to the positive t_er￠\tau_{\varepsilon_{r}'} of PEEK and increased interface region in the composites as a result of the PEEK addition.     

A Modified Generalized Chaplygin Gas as the Unified Dark Matter–Dark Energy Revisited

A modified generalized Chaplygin gas (MGCG) is considered as the unified dark matter–dark energy revisited. The character of MGCG is endued with the dual role, which behaves as matter at early times and as a quiessence dark energy at late times. The equation of state for MGCG is p?=???αρ/(1?+?α)????(z)ρ ^???α /(1?+?α) , where $\vartheta(z)=-[\,\rho_{\,\rm 0c}(1+z)^{3}]\,^{(1+\alpha)}(1-\Omega_{\,\rm 0B})^{\alpha}\{\alpha\Omega_{\,\rm 0DM}+ \Omega_{\,\rm 0DE}[\,\omega_{\,\rm DE}+\alpha(1+\omega_{\rm DE})](1+z)^{3\omega_{\rm DE}(1+\alpha)}\}$ . Some cosmological quantities, such as the densities of different components of the universe Ω _i (i, respectively, denotes baryons, dark matter, and dark energy) and the deceleration parameter q, are obtained. The present deceleration parameter q ₀, the transition redshift z _T, and the redshift z _eq, which describes the epoch when the densities in dark matter and dark energy are equal, are also calculated. To distinguish MGCG from others, we then apply the Statefinder diagnostic. Later on, the parameters (α and ω _DE) of MGCG are constrained by combination of the sound speed $c^{2}_{\rm s}$ , the age of the universe t ₀, the growth factor m, and the bias parameter b. It yields $\alpha=-3.07^{+5.66}_{-4.98}\times10^{-2}$ and $\omega_{\rm DE}=-1.05^{+0.06}_{-0.11}$ . Through the analysis of the growth of density perturbations for MGCG, it is found that the energy will transfer from dark matter to dark energy which reach equal at z _eq～0.48 and the density fluctuations start deviating from the linear behavior at z～0.25 caused by the dominance of dark energy.     

Holographic dark energy in Brans–Dicke theory

In this paper, the holographic dark-energy model is considered in Brans–Dicke theory, where the holographic dark-energy density ρ _Λ =3c ² M _pl² L ⁻² is replaced by ρ _h=3c ² Φ(t)L ⁻². Here is the time-variable Newton constant. With this replacement, it is found that no accelerated expansion for the universe will be achieved when the Hubble horizon is taken to play the role of an IR cut-off. When the event horizon is adopted as the IR cut-off, accelerated expansion for the universe is obtained. In this case, the equation of state of holographic dark energy, w _h, takes the modified form . In the limit α→0, the ‘standard’ holographic dark energy is recovered. In the holographic dark-energy dominated epoch, power-law and de Sitter time-space solutions are obtained.     

Random Walk Weakly Attracted to a Wall

We consider a random walk X _n in ℤ₊, starting at X ₀=x≥0, with transition probabilities

On the Rate of Explosion for Infinite Energy Solutions of the Spatially Homogeneous Boltzmann Equation

Let μ ₀ be a probability measure on ℝ³ representing an initial velocity distribution for the spatially homogeneous Boltzmann equation for pseudo Maxwellian molecules. As long as the initial energy is finite, the solution μ _t will tend to a Maxwellian limit. We show here that if , then instead, all of the mass “explodes to infinity” at a rate governed by the tail behavior of μ ₀. Specifically, for L0, define

An ab initio molecular dynamics study of ionic conductivity in hexagonal lithium lanthanum titanate oxide La0.5Li0.5TiO3

To date, the fastest lithium ion-conducting solid electrolytes known are the perovskite-type ABO₃ oxide, with A = Li, La and B = Ti, lithium lanthanum titanate (LLTO) Li_3x La_{( 2 \mathord}

Chirality-asymmetry force between ɑ-quartz and copper block

The chirality-asymmetry macroscopic force mediated by light pseudoscalar particles between α -quartz and some achiral matter is studied. If this force between achiral source mass and α -quartz with some chirality is attractive, it will become repulsive when the chirality of the α -quartz crystal is changed. According to the tested limits of the coupling constant g_s g_p /\hbar c< 1.5× 10^-24 at the Compton wavelength λ = 10^-3 m, the force (F) between a 0.08× 0.08× 0.002 m³ block of α -quartz and a 0.08× 0.08× 0.01 m³ copper block with a separation being 0.5× 10^-3 \mbox{m} in between, is estimated from the published data at less than 4.64× 10^-24 N, i.e. F < 4.64× 10^-24 N.     

Universality in the Two Matrix Model with a Monomial Quartic and a General Even Polynomial Potential

In this paper we studied the asymptotic eigenvalue statistics of the 2 matrix model with the probability measure