COMPLEX SALTS [Pd(NH3)4][Pd(NH3)3NO2] [CrOx3]·H2O AND [Pd(NH3)4][Pd(NH3)3NO2] [CoOx3]·H2O AND SOLID SOLUTIONS [Pd(NH3)4] [Pd(NH3)3NO2][CoOx3]x[RhOx3]1–x·H2O : PROMISING PRECURSORS FOR POROUS NANOALLOYS

Journal of Structural Chemistry - New complex salts [Pd(NH3)4][Pd(NH3)3NO2][CrOx3]·H2O I, [Pd(NH3)4][Pd(NH3)3NO2][CoOx3]·H2O II, and a series of solid solutions...     

Crystal structures of [Pd(NH3)3(NO2)][Rh(NH3)2(NO2)4] and [PdEn2][Rh(NH3)(NO2)5]·0.75H2O

The structure of double complex salts [Pd(NH₃)₃(NO₂)][Rh(NH₃)₂(NO₂)₄] and [PdEn₂][Rh(NH₃)(NO₂)₅]·0.75H₂O is determined by single crystal X-ray diffraction. In the structures, the main structural moieties are identified.     

KBrO3-CH3CH(NH2)CO2H-MnSO4-[Fe(phen)3]SO4-H2SO4体系的化学振荡反应

本文首次报道须在两种金属离子同时作用下的振荡反应——KBrO_3-CH_3CH(NH_2)CO_2H-MnSO_4-[Fe(phen)_3]SO_2-H_2SO_4体系的振荡反应,对反应产物作了分析,研究了两种金属离子在振荡反应中的不同作用,Mn~(2+)起催化氧化丙氨酸以产生丙酮酸的作用,而[Fe(phen)_3]~(2+)则是丙酮酸-BZ型反应的催化剂.研究了温度变化对振荡反应的影响,从而得出振荡反应各阶段的表观活化能.考察了Cl~-、自由基抑制剂及反应物浓度对振荡反应的影响.实验证明,振荡反应同时受Br~-及Br_2的控制,振荡机理与Br_2-水解控制模型相同.     

KBrO3-CH3CH(NH2)CO2H-MnSO4-[Fe(phen)3]SO4-H2SO4体系的化学振荡反应

本文首次报道须在两种金属离子同时作用下的振荡反应─KBrO3-CH3CH(NH2)CO2H-MnSO4-[F3(phen)3]SO4-H2SO4体系的振荡反应, 对反应产物作了分析, 研究了两种金属离子在振荡反应中的不同作用, Mn^2^+起催化氧化丙氨酸以产生丙酮酸的作用, 而[Fe(phen)3]^2^+则是丙酮酸-BZ型反应的催化剂。研究了温度变化对振荡反应的影响, 从而得出振荡反应各阶段的有观活化能。考察了Cl^-、自由基抑制剂及反应物浓度对振荡反应的影响。实验证明, 振荡反应同时受Br^-及Br2的控制, 振荡机理与Br2^-水解控制模型相同。     

Structural study of complex [Rh(NH3)5(NO2)](NO3)2·H2O, [Rh(NH3)5(NO2)][Pd(NO2)4], and K2[Rh(NH3)(NO2)5]·H2O salts

Compounds [Rh(NH₃)₅(NO₂)](NO₃)₂·H₂O (I) with a = 7.6230(3) Å, b = 7.6230(3) Å, c = 10.3584(4) Å, space group I-42m, Z = 2, d _calc = 2.026 g/cm³, V = 601.93(4) ų, Rh-NH_{3 eq} = 2.074 Å, Rh-NH_{3 ax} (NO₂) = 2.048 Å; [Rh(NH₃)₅(NO₂)][Pd(NO₂)₄] (II) with a = 8.095(3) Å, b = 22.422(8) Å, c = 7.887(3) Å, β = 98.559(17)°, space group Cc, Z = 4, d _calc = 2.461 g/cm³, V = 1415.6(9) ų, Rh-NH_{3 eq} = 2.069 Å, Rh-NH_{3 ax} = 2.090 Å, Rh-NO₂ = 2.002 Å; K₂[Rh(NH₃)(NO₂)₅]·H₂O (III) with a = 7.5177(5) Å, b = 20.9856(15) Å, c = 7.7017(5) Å, space group Cmc2₁, Z = 4, d _calc = 2.439 g/cm³, V = 1215.05(14) ų, Rh-NH_{3 ax} (NO₂) = 2.094 Å, Rh-NO_{2 eq} = 2.030 Å are synthesized and studied using single crystal X-ray diffraction.     

Synthesis,Crystal and Molecular Structures of [Co(MH)2(Thio)2][BF4] · H2O and [Co(DH)2(NH3)2][BF4]

Crystal structures of [Co(MH)₂(Thio)₂][BF₄] · H₂O (I) and [Co(DH)₂(NH₃)₂][BF₄] (II), where MH^– is H₃C–C(NOH)–C(NO^–)–H and DH^– is H₃C–C(NOH)–C(NO^–)–CH₃, were determined by X-ray diffraction. The crystals are monoclinic, space group C2/c, unit cell parameters (for I and II, respectively): a = 22.018(2) Å, b = 7.943(1) Å, c = 11.681(1) Å, = 92.68(1)° and a = 21.436(2) Å, b = 6.400(2) Å, c = 12.389(2) Å, = 113.13(1)°. In both cases, the Co(III) coordination polyhedron is a centrosymmetrical trans-octahedron, N₄S₂ for I and N₆ for II. In the crystals of I and II, the complex cations and the outer-sphere [BF₄]^– anions (and the crystal water molecules in I) form elaborate hydrogen bonding system.     

Three-body dissociation dynamics of (SO2)3 studied through dissociative photodetachment of (SO2)3−

The dissociative photodetachment dynamics of (SO₂)₃⁻ were studied by photoelectron–photofragment coincidence spectroscopy at 258 nm. Correlation between the photoelectron and photofragment translational energies was observed as previously seen in the dimer system, implying the presence of a dimer core. The three-body dissociation dynamics of (SO₂)₃ after photodetachment are consistent with a dimer core solvated by a spectator SO₂ molecule with a broad distribution in initial geometry.     

Crystal structure of Lebedinskii’s trisulfitotriammine Na3[Rh(SO3)3(NH3)3]·6H2O

A single crystal X-ray diffraction study of Na₃[Rh(SO₃)₃(NH₃)₃]·6H₂O was carried out (X8 APEX BRUKER automated diffractometer, MoK _α radiation, graphite monochromator); crystal data are a = 10.1844(1) Å, c = 64.0815(13) Å, V = 5756.17(14) ų, space group R $\bar 3$ c, Z = 12. The general motif of the structure was analyzed in terms of the mutual spatial arrangement of the [(NH₃)₃Rh(SO₃)₃-Na-(SO₃)₃Rh(NH₃)₃]^5? fragments, where the Na⁺ cation is surrounded by six oxygen atoms belonging to six SO₃ groups. This cation resides on the inversion center, all Na-O distances are identical, 2.347 Å. The selected fragments follow the nodes of a rhombohedral sublattice (a _c = 12.19 Å, α_c = 49.38°) formed by the intersection of three symmetry-related families of planes (1 0 2).     

(NH4)2SO4在TiO2表面上的行为研究

硫助金属氧化物(sulfate promoted metal oxides)是一类新型固体酸催化剂,可用于多种酸催化反应.用(NH_4)_2SO_4、SO_3、SO_2或H_2S 作为助剂,以Fe_2O_3、TiO_2和ZrO_2为底物均可制得硫助金属氧化物(SPMO).     

Binary Complexes [M(NH3)5Cl][PdCl4] · H2O (M = Rh, Co): Crystal Structure of [Rh(NH3)5Cl][PdCl4] · H2O

Monohydrates of chloropentammine rhodium(III) and chloropentammine cobalt(III) tetracloropalladates(II) were synthesized. Single crystals of [Rh(NH₃)₅Cl][PdCl₄] · H₂O were obtained and studied by Xray diffraction. The crystallographic data are as follows: a = 7.8730(16) Å, b = 10.905(2) Å, c = 16.038(3) Å, = 102.70(3)°, V = 1343.3(5) ų, space group P2₁/c, Z = 4, d_calc = 2.422 g/cm³. The structure consists of alternating layers of [Rh(NH₃)₅Cl]²⁺ complex cations and [PdCl₄]^2- complex anions. Each anion layer contains two crystallographically independent Pd atoms, and the square coordination environment of one of these atoms is converted to a bipyramide. The structure of the compound [Co(NH₃)₅Cl][PdCl₄] · H₂O is determined and its unitcell parameters are refined: a = 7.813(3) , b = 10.896(4) , c = 15.966(5) , = 102.85(4)°, V = 1325.2(8) ³, and d_calc = 2.148 g/cm³. The synthesis temperature is shown to have an effect on the content of hydrated and anhydrous complexes in the mixture formed during precipitation of these binary salts from aqueous solutions.     

Hydrothermal synthesis,crystal structure and thermal stability of a new 2D layered metal(II) phosphonate: [NH3CH2CH2NH3][Fe2(O3PCH(OH)CO2)2(H2O)2]·2H2O

In the presence of ethylenediamine template agents, a metal(II) phosphonate, [NH₃CH₂CH₂NH₃][Fe₂(O₃PCH(OH)CO₂)₂(H₂O)₂]?·?2H₂O (1) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction as well as infrared spectroscopy, elemental analysis and thermogravimetric analysis. The compound crystallines in the monoclinic space group P2₁/n: Crystal data for 1: a?=?8.4523(8)?Å, b?=?9.8196(9)?Å, c?=?10.9217(10)?Å, β?=?105.9500(10)°, V?=?871.58(14)?Å, Z?=?2, D _c?=?2.103?g?cm^?3, R ₁?=?0.0290, wR ₂?=?0.0811. The Fe (II) cation is octahedrally coordinated by six oxygen atoms from the three ligands and one coordinated water molecule to form a 2D layered structure with a one-dimensional channel system in the a-axis direction.     

二维配位聚合物(NH3+CH2CH2NH3+)(NH2CH2CH2NH3+)2[(VO)4(PO4)4(H2O)2]·2H2O的水热合成及晶体结构

无机-有机杂化钒氧酸盐由于其结构的多样性以及在催化、医药、光、电、磁等材料领域中的应用前景而受到人们的广泛关注。近年来这一研究领域的重大进步是将有机氮配体或者过渡金属配合物直接连接到矾氧骨架上以获得各种新奇结构。合成出许多属于L/V/O、MXLY/V/O、L/P/V/O和MXLY     

Solubility and stability of (NH4)2SO4 · H2O2 in aqueous solutions and change in some crystallographic parameters of (NH4)2SO4 precipitates

Stability of (NH₄)₂SO₄ · H₂O₂ aqueous solutions and some structural changes in ammonium sulfate in the course of its solvation and subsequent desolvation were studied.     

Complex [Ag(PPh3)4][2-B10H9NH3 · 2DMF]: Synthesis and Structure

Russian Journal of Coordination Chemistry - The formation of complex salt [Ag(PPh3)4][2-B10H9NH3 ? 2DMF] (I) by the reaction of the salts of the [2-B10H9NH3]– anion with [Ag(PPh3)4]NO3...     

Phase Equilibria in the System NH4Al(SO4)2–H2SO4–H2O

Equilibrium solubility curves of the ammonium aluminium sulphate in aqueous solutions of sulphuric acid have been calculated using checked literature data and our own measurements. The concentration of sulphuric acid ranged from 0 to 23 mass%, temperature range between 20 and 60°C has been extrapolated up to 75°C by means of a thermodynamically based correlation method. The solubility correlation as well as the hydration analysis implied a possible destructuralization of solutions at higher acid concentrations. This revised version was published online in August 2006 with corrections to the Cover Date.     

Organically Templated Vanadium Oxide Phases: Synthesis and Structures of [H3NCH2CH2NH3][V2O6] and [HN(CH2CH2)3NH][VV2VIV4O14]·H2O

The synthesis and crystal structures of [H₃NCH₂CH₂NH₃][V₂O₆] (1) and [HN(CH₂CH₂)₃NH][V^V ₂V^IV ₄O₁₄]·H₂O (2) are described. The structure of the oxidized compound 1 consists of parallel stacks of vanadium oxide chains of corner sharing {VO₄} tetrahedra. The chains are stabilized by extensive hydrogen bonding involving oxide ligands of the chains and ethylenediammonium ions which fill the space between the stacks of chains. The structure of compound 2 consists of vanadium oxide layers separated by doubly protonated 1,4-diazabicyclo[2.2.2]octane and lattice water. The vanadium oxide layers, containing mixed-valence vanadium (V^V and V^IV) centers, are composed of zigzag ribbons of edge-sharing {VO₅} square pyramids interconnected by {VO₄} tetrahedra. Crystal data. C₂H₁₀N₂O₆V₂ , 1: monoclinic, space group P2₁/c (No. 14), a=5.5359(5), b=12.9430(12), c=5.6856(5) Å, =90, =97.460(2), =90°, V=403.93(6) ų, Z=2. A total of 2506 reflections ( _max=27.89°) was collected, of which 954 were used to resolve the structure. The structure was solved by direct methods and least-squares refinement converged at R=0.0592. C₆H₁₆N₂O₁₅V₆, 2: monoclinic, space group C2 (No. 5), a=19.303(4), b=6.667(2), c=7.579(2) Å, =90, =111.31(2), =90°, V=908.4(4) ų, Z=2. A total of 1779 reflections was collected, of which 1591 unique reflections were used for structural elucidation. The structure was solved by direct methods and least-squares refinement converged at R=0.0314.     

Rational Design of the Metal-Free KBe2BO3F2⋅(KBBF) Family Member C(NH2)3SO3F with Ultraviolet Optical Nonlinearity

The first fluorosulfonic ultraviolet (UV) nonlinear optical (NLO) material, C(NH₂)₃SO₃F, is rationally designed by taking KBe₂BO₃F₂ (KBBF) as the parent compound. C(NH₂)₃SO₃F features similar topological layers as KBBF by replacing inorganic (BO₃)³⁻ with organic C(NH₂)₃⁺ trigonal units and BeO₃F with SO₃F⁻ tetrahedra. Therefore, C(NH₂)₃SO₃F is a metal-free UV NLO crystal. Benefiting from the coplanar configuration of the C(NH₂)₃⁺ cationic groups, it possesses a large SHG response of 5×KDP and moderate birefringence of 0.133@1064 nm. Besides, it has a short UV cutoff edge of 200 nm. The calculated results reveal the shortest SHG phase-matching wavelengths can reach 200 nm. These findings highlight the exploration of metal-free compounds as nontoxic and low-cost UV NLO materials as a new research area.     

A theoretical investigation on the structures of (NH3)·(H2SO4)·(H2O)0-14 clusters

Ternary clusters (NH₃)·(H₂SO₄)·(H₂O)_n have been widely studied. However, the structures and binding energies of relatively larger cluster (n > 6) remain unclear, which hinders the study of other interesting properties. Ternary clusters of (NH₃)·(H₂SO₄)·(H₂O)_n, n = 0-14, were investigated using MD simulations and quantum chemical calculations. For n = 1, a proton was transferred from H₂SO₄ to NH₃. For n = 10, both protons of H₂SO₄ were transferred to NH₃ and H₂O, respectively. The NH₄⁺ and HSO₄⁻ formed a contact ion-pair [NH₄⁺-HSO₄⁻] for n = 1-6 and a solvent separated ion-pair [NH₄⁺-H₂O-HSO₄⁻] for n = 7-9. Therefore, we observed two obvious transitions from neutral to single protonation (from H₂SO₄ to NH₃) to double protonation (from H₂SO₄ to NH₃ and H₂O) with increasing n. In general, the structures with single protonation and solvated ion-pair were higher in entropy than those with double protonation and contact ion-pair of single protonation and were thus preferred at higher temperature. As a result, the inversion between single and double protonated clusters was postponed until n = 12 according to the average binding Gibbs free energy at the normal condition. These results can serve as a good start point for studies of the other properties of these clusters and as a model for the solvation of the [H₂SO₄-NH₃] complex in bulk water.     

CO(NH2)2-H3BO3-H2O体系相平衡研究

农作物不仅需要吸收C、H、O、N、P、K、Ca、Mg等营养元素,而且还需要吸收B、Mn、Zn等营养元素,以维持它们正常生长的需要.尿素是一种含氮量很高(46.60%)、性能很好的氮肥,而硼化合物又是一种很重要的微量元素肥料.因此,研究尿素与硼化合物间的相互作用,以得到既含氮又含硼的一种化合物,是一种很有意义的工作。目前,国外已开展了尿素与硼酸间相互作用的研究工作.研究结果表明,在一定条     

Unusual potassium-oxalate coordination in the two-dimensional trimetallic [CoCl(NH3)5][KCr(C2O4)3]·0.5H2O complex

A new heterometallic compound, [CoCl(NH₃)₅][KCr(C₂O₄)₃]·0.5H₂O (1), has been synthesized and characterized by elemental analysis, IR and electronic spectra, thermal analysis, variable temperature magnetic susceptibility measurements, and single crystal X-ray diffraction. Compound 1 consists of two-dimensional [{KCr(C₂O₄)₃}_n]^2n? layers, [CoCl(NH₃)₅]²⁺ ions and water molecules. Within the 2-D layer, three different types of oxalate coordination modes are present. Each K cation is coordinated by eight oxygen atoms from oxalate groups and also weakly interacts with the ninth oxygen atom. The extensive network of hydrogen bond is formed between the [KCr(C₂O₄)₃]^2? layer and the [CoCl(NH₃)₅]²⁺ ions. These interactions involve all hydrogen atoms of ammonia ligads and water molecule.