高能脉冲C~(6+)离子束激发Ni靶的K壳层X射线

精确测量离子与原子碰撞引起的靶原子内壳层电离截面,对研究原子内壳层过程以及建立合适的理论模型具有重要的意义.现有的实验数据和理论模型大都集中在中低能区,高能区由于受到实验条件的限制,几乎没有相关实验数据的报道,哪种理论更适合描述高能重离子入射的靶原子内壳层电离截面,还需要进行深入的实验研究.采用电子冷却存储环提供能量分别为165,300,350,430 MeV/u的C~(6+)离子束轰击Ni靶,测量Ni的K壳层X射线.分析了实验中探测到的Ni的K_β和K_α射线强度比,发现入射粒子能量的变化对该强度比影响不明显.分别应用两体碰撞近似(BEA)、平面波玻恩近似(PWBA)和ECPSSR理论对Ni的K壳层X射线的产生截面进行理论计算,并将理论结果与实验结果进行比较.     

不同离子激发Au靶的多电离效应

重离子与固体表面相互作用时,会引起靶原子内壳层的电离,相应空穴退激过程中发射的X射线对研究重离子与固体表面的相互作用有着重要意义,可为相关研究提供基础数据.目前,在K和L壳层电离方面做了一些工作,而M壳层的研究较少,本文依托兰州重离子加速器国家实验室320 kV高电荷态离子综合研究平台,测量了不同能量的H~+, Ar~(8+), Ar~(12+), Kr~(13+)和Eu~(20+)离子与Au表面作用产生的特征X射线谱及其能移,计算了X射线的产额比值.结果表明:重离子引起了靶原子内壳层的多电离,多电离效应使Au的MX射线有不同程度的能移;多电离程度取决于入射离子能量、离子的原子序数和其外壳层的空穴数量.     

Nd L-shell x-ray emission induced by light ions

The L-shell x-ray of Nd has been obtained for 300-600 keV He²⁺ ions impacting, and compared with that produced by H⁺ and H₂⁺ ions. The threshold of projectile kinetic energy for L-shell ionization of Nd is crudely verified in the energy region of about 300-400 keV. It is found that the energy of the distinct L-subshell x-rays has a blue shift. The relative intensity ratios of Lβ_{1, 3, 4} and Lβ_{2, 15} to Lα_{1, 2} x-ray are enlarged compared to the atomic data, and they decrease with the increase of the incident energy, and increase with increasing the effective nuclear charge of the incident ions. That is interpreted by the multiple ionization of outer-shells induced by light ions.     

Aq++H碰撞中的电荷转移

利用CTMC方法计算C^q+,N^q+,O^q+与H原子的碰撞过程的截面.入射粒子的能量范围为10~250keV/amu,离子为部分电离和完全电离的离子.给出了十二个耦合的Hamilton运动方程.用六个伪随机数确定粒子的轨道. A^q+离子和作用电子的势为模型势,其他两个势为纯库仑势。在计算中,需要2000个以上的轨道.引入约化变量σ_tr=σ_tr/q,E=E/q^1/2,得到了q标度的俘获截面,这些截面数据都集中在一条曲线附近.计算结果与其他理论计算结果作了比较,它们符合得很好.     

Atomic collision processes relevant for heavy ion beam probes

Atomic collision processes of fast Tl and Cs ions with particles in a high temperature fusion plasma are investigated. At low beam energies (<5 MeV), ion impact collisions and charge exchange processes can be neglected compared to electron ionization processes. At beam energies above 5 MeV and high plasma ion temperatures, collisions with ions start to contribute significantly to signal generation and attenuation. Also, collisions with the neutral background gas in the beamlines can attenuate the ion beam significantly and lower the signal level, if the vacuum pressure is above 10^-4 Torr. For the heavy ion beam probes operating today, only electron impact ionization processes are important and accurate predictions of the secondary signal level and electron density profile measurements are possible because of the good knowledge of electron impact ionization cross sections for Cs ⁺ and Tl⁺ ions     

H+和Ar11+激发Si的K壳层X射线发射研究

测量了50–250 keV H⁺和1.0–3.0 MeV Ar¹¹⁺ 轰击Si表面过程中辐射的X射线. 结果表明, 在Ar¹¹⁺入射的情况下, 引起了Si的L壳层上3, 4个电子的多电离.计算了Si的K壳层X射线产生截面, 并将两体碰撞近似(BEA), 平面波恩近似, ECPSSR理论计算与实验值进行了对比. ECPSSR理论与质子产生的截面数据能够很好地符合; 而考虑多电离后, BEA理论与Ar¹¹⁺的实验结果符合较好. 关键词： X射线 高电荷态重离子 多电离     

(e,2e)反应中电子的角度分布

利用修正的BBK理论模型,在共面,等能分享,固定相对角度几何条件下,计算了能量分别为58.4,68,81.6,108.8和174.4eV的入射电子碰撞He⁺(1s)(e,2e)反应三重微分截面(TDCS),并讨论了交换,关联与干涉效应及入射道库仑场对TDCS的影响。结果表明,这些效应对决定TDCS的角度分布及大小是非常重要的。     

利用速度成像技术研究碘乙烷多光子电离解离动力学

卤代烷烃会破坏臭氧层,而碘乙烷（C₂H₅I）是卤代烷烃中重要代表物质之一.采用离子速度成像技术、飞秒激光技术和飞行时间质谱技术,探究了C₂H₅I的多光子电离解离动力学.通过分析C₂H₅I在强场作用下多光子电离解离得到的解离通道、碎片的动能、角度分布和各向异性参数等信息来研究碘乙烷离子（C₂H₅I⁺）C–I键裂解机理.根据飞行时间质谱实验,C₂H₅I在飞秒激光脉冲作用下发生多光子电离解离得到的碎片有C₂H₅⁺,I⁺,CH₂I⁺,C₂H₂⁺,C₂H₃⁺,C₂H₄⁺等.与C–I键相关的碎片为C₂H₅⁺和I⁺,解离机制分别对应于C₂H₅I⁺→C₂H₅⁺+I和C₂H₅I⁺→C₂H₅+I⁺.同时,采用离子速度成像技术研究C₂H₅I⁺的C–I键裂解产生的C₂H₅⁺和I⁺的速度影像,得出两者的速度分布和动能分布,分析结果表明C–I键裂解产生C₂H₅⁺和I⁺的过程都存在高能通道和低能通道.进一步分析解离碎片离子的角度分布发现C₂H₅⁺解离时各向异性参数接近于0,可能对应于慢速的振动预解离过程.I⁺在解离时各向异性参数较高,可能源于排斥势能面上的快速解离过程.最后采用密度泛函理论计算了C₂H₅I分子电离前后构型变化、离子态的能级强度及谐振强度,对C₂H₅I⁺的解离机制做了更进一步的分析和讨论.     

电子垂直入射电离氦原子碰撞机理的理论研究

用3C模型和修正后的3C模型在低能、两个出射电子等能分享几何条件下,对电子垂直入射碰撞电离氦原子的三重微分散射截面进行了理论计算,并把计算结果与实验测量结果进行了比较,系统研究了(e,2e)反应中各种屏蔽效应对氦原子三重微分散射截面的影响,同时对截面中形成各峰的碰撞机理做了详细的探讨.研究结果表明:在入射能较低时,各种屏蔽效应对氦原子的三重微分散射截面幅度以及角分布均存在一定影响,并且形成各峰的碰撞机理直接影响截面的变化规律.     

中等光强纳秒激光电离苯团簇产生多价碳离子的数值模拟和实验研究

飞秒强激光与团簇相互作用产生多价离子的现象已被广泛报道,然而近期多个研究小组发现当功率密度低至1010W/cm2的纳秒激光照射团簇时,同样也观察到了多价离子的存在.虽然可以用"多光子电离引发-逆韧致吸收加热-电子碰撞电离"电离机理对这种现象进行解释,但是缺乏相应的数值模拟.建立了一个简化的数值模型,根据有质动力势Up计算团簇内电子能量,再由Lotz公式计算出相应的电离截面,最后由动力学反应速率方程计算出团簇内多价碳离子随时间的演变.详细分析了团簇尺寸、电子密度等关键参数对多价离子产生的影响.数值模拟结果表明:团簇电离在小于0.7 ns时间尺度内完成,C2+,C3+和C4+多价离子强度达到平衡后,离子相对强度由大到小依次为C2+,C3+,C4+,这与实验结果相一致;多价离子的价态随着团簇尺寸的增加而升高,半径为5.6 nm的苯团簇比半径为3 nm的苯团簇更容易产生高价态的离子,这也与实验结果相一致.     

Dependence of the charge transfer between atoms and highly charged ions on the ionization potential of the atoms

Cross sections have been measured for charge transfer in single collisions of 100 keV Xe¹⁰⁺ ions with target atoms B = He, Ne, Ar, Kr, Xe, Cd, Na and Cs. With the decrease of the target ionization potential in the sequence from He (24.58 eV) to Cs (3.89 eV) an overall quadratic increase of the electron capture cross sections was found reaching values up to 1.2 × 10⁻¹³ cm² for the alkali metals.     

Three-dimensional spatiokinetic distributions of sputtered andscattered products of Ar+ and Cu+ impacts onto theCu surface: molecular dynamics simulations

Energy and angular distributions of reflections and sputtered atoms are essential inputs for feature profile evolution simulations. Molecular dynamics simulations are used to compute the three-dimensional energy and angular distributions for reflected and sputtered products when both Ar⁺ and Cu⁺ ions bombard a copper surface. We term these “spatiokinetic” distribution functions (SKDF's). We show by example that SKDF's for reflected Ar⁺ ions focus as the incident angle &thetas;_i (normal=0°) is increased from 60-75° and broaden as the incident energy E_i is increased from 55-175 eV. We show that the SKDF's for glancing-angle reflected Cu⁺ ions focus when E_i is increased from 55-175 eV. We show that the SKDF's for copper atoms sputtered by 175 eV Ar⁺ are insensitive to &thetas;_i;. We report total sputter yields for Ar⁺ and Cu⁺ ions at 55 and 175 eV for incident angles between 0° and 85°, and sticking probabilities for Cu⁺ ions for these energies and angles. Comparison to representative experimental results (Doughty et al., 1997) is given     

Pion-transfer (n, d) and (d, He) reactions leading to deeply bound pionic atoms

Theoretical studies are given on the (n, d) and (d, ³He) reactions leading to deeply bound pionic atoms in heavy nuclei of configuration [(nl)_π·j_n⁻¹]J. The cross sections for various pionic and neutron-hole configurations in the case of a ²⁰⁸Pb target are calculated at incident energies 300–1000 MeV/u by using the effective number approach and the eikonal approximation for distortion. The effective number with a pion in the 1s or 2p state and a neutron hole in the orbit peaks around the same incident energy (T_n = 600 MeV) as the elementary cross section n+n→d+π⁻, where the momentum transfer matches the angular-momentum transfer of L = 5–7. The DWIA cross section for (n,d) producing a pion in the 1s or 2p orbit at T_n = 600 MeV is found to be around 42 or 75 μb/sr, respectively. At T_n = 350 MeV, where the momentum transfer is small, quasi-substitutional states of configurations and are preferentially populated with (n, d) cross sections of 95 and 190 μb/sr, respectively. The (d, ³He) cross sections are estimated to be an order of magnitude smaller than the (n, d) cross sections. Thus, the (n, d) and (d, ³He) reactions are found to be suited for the production of deeply bound pionic atoms.     

Energy distributions of ions produced by electron-stimulated desorption

We have measured the initial kinetic energy distributions of ions produced by electron bombardment of various oxides and halides. The instrument used allows ions directly ejected from the sample surface to be distinguished from ions formed by electron impact in the gas phase. Singly and multiply charged positive ions of species present in the matrix as anions and cations were desorbed by high energy ( 11 keV) electron impact. Directly desorbed positive halogen ions show a narrow, low energy peak, consistent with conventional models of electron stimulated desorption (ESD). In addition, some of the cation species exhibited similar narrow energy spectra. Charge states up to +6 were observed for the halides; with the exception of F²⁺ and Cl²⁺, multiple charge states were due to electron impact ionization of desorbed neutrals. Charge states up to +4 were seen for silicon from electron-bombarded SiO₂; energy distributions of Si⁺, Si²⁺ and Si³⁺ showed that these species were desorbed directly from the surface. The energy distributions of O⁺ and O²⁺ ions ejected from SiO₂ are relatively wide, compared to the energy distribution of Si⁺ ions. In contrast, O⁺ ions ejected from TiO₂ have a much narrower energy distribution, like those observed for the halogen ions.     

类氦离子的电子碰撞电离微分截面

本文主要利用扭曲波玻恩交换近似方法(DBE)计算类氦离子在电子碰撞下,相应不同的末态电子能量分配的电离截面(能量微分截面)。发现对这些微分截面在不同靶电荷及入射能量下,都可用带两个参数的高斯函数αexp(β(x—0.5)²)很好地拟合。还给出两个拟合参数随靶电荷和入射能量的变化曲线,以及讨论了在库仑波玻恩交换近似(CBE)和DBE两种不同近似下所得参数值的差别。计算结果也表阴,在低靶电荷和低入射能量时用DBE计算的必要性。 关键词：     

近玻尔速度氙离子激发钒的K壳层X射线

测量了2.4—6.0 MeV Xe~(20+)离子轰击V靶表面过程中辐射的X射线.计算了V的K壳层X射线发射截面,并将实验结果与平面波恩近似、ECPSSR、两体碰撞近似的理论计算进行了对比.讨论了近玻尔速度非对称碰撞过程中,BEA模型估算高电荷态重离子激发内壳层电离的修正因素.结果表明,综合考虑库仑偏转和有效电荷态修正后,BEA理论与实验结果符合较好.     

Xe~(53+)离子与Xe原子碰撞过程中的辐射电子俘获和辐射退激发光谱的理论研究

基于多组态Dirac-Fock方法和密度矩阵理论,系统地研究了在197 Me V/u的碰撞能量下,Xe~(53+)离子与Xe原子的辐射电子俘获过程(REC)以及电子被俘获到激发态后辐射退激发产生的特征谱线.计算了炮弹Xe~(53+)离子俘获电子到不同壳层np_(1/2,3/2)(n=2—5)的总截面与相应的REC光子能量和角分布,以及由激发组态1snp_(1/2,3/2)(n=2—5)J_f=1向基态1s~2Jd=0辐射退激发的跃迁能量、跃迁概率和特征光子的角分布和线性极化度.计算结果表明,辐射光子具有显著的角各向异性特征.此外,1snp_(3/2)J_f=1→1s~2J_d=0退激发特征光子也显示出很强的线性极化和角各向异性特征,而1snp_(1/2)J_f=1→1s~2J_d=0退激发特征光子的线性极化度趋于零并且角分布也趋于各向同性.     

氟利昂F113分子在飞秒激光作用下的多光子电离解离动力学

大气臭氧层因吸收太阳紫外光, 是人类必不可少的保护伞. 氟利昂在太阳光辐射下解离生成破坏臭氧的游离态氯原子, 是破坏大气臭氧层的主要元凶之一. 本文利用飞行时间质谱技术和离子速度成像技术研究了氟利昂F113(三氟三氯乙烷)分子在800 nm 飞秒光作用下的多光子电离解离动力学. 利用飞行时间质谱探测技术, 得到了三氟三氯乙烷在该波长飞秒激光作用下发生多光子电离解离产生的碎片质谱. 通过荷质比对碎片质谱进行了详细的标定和分析. 在质谱上未发现母体离子, 所有观察到的离子都是由于激光脉冲作用下产生的碎片. 三个最主要的碎片离子是CFCl₂⁺, CF₂Cl⁺, C₂F₃Cl₂⁺. 通过飞行时间质谱标定, 发现并归属了多个解离通道. 三个主要的解离机理分别为: 1) C-Cl键断裂直接生产氯自由基的通道C₂F₃Cl₃⁺→C₂F₃Cl₂⁺+Cl; 2) C--C键断裂C₂F₃Cl₃⁺→CFCl₂⁺+CF₂Cl; 3) C--C键断裂C₂F₃Cl₃⁺→CF₂Cl⁺+CFCl₂. 利用离子速度成像技术对这三个主要通道产生的碎片离子进行成像, 得到了C₂F₃Cl₂⁺, CFCl₂⁺和CF₂Cl⁺离子的速度影像. 由C--Cl键断裂产生的碎片离子C₂F₃Cl₂^{+}的速度分布由两个高斯分布曲线拟合, 而由C--C键断裂产生的碎片离子CFCl₂⁺和CF₂Cl⁺可以用一个高斯曲线拟合. 通过影像分析得到了解离碎片的平动能分布和角向分布各向异性参数等详尽的动力学信息. 结合高精度密度泛函理论计算对解离动力学进行了进一步的分析和讨论.深入认识氟利昂的解离动力学可为进一步控制破坏臭氧层提供理论参考和实验依据.     

原子轨道强耦合方法研究He2+-H-碰撞的电荷转移过程

应用双中心原子轨道强耦合方法研究He²⁺-H^-碰撞的单次电荷转移过程.计算中,对入射粒子He²⁺,包含n=1~7的所有束缚态,计算的能量本征值与NIST标准数据在百分之几的精度内符合很好;对靶H^-,包括一个束缚态1s和五个连续态ns(n=2~6),束缚态能量与他人理论结果一致.在4~400 keV的入射粒子能量范围,计算单电子俘获过程的总截面及到各个壳层上的态选择截面.发现在较低的入射粒子能量,电子主要俘获到He⁺离子主量子数n=3~5的壳层,高能区俘获到n=2的壳层为主;对同一主量子数n,在低能区俘获到高角动量态(l=n-1,n-2)的电荷转移截面相对较大,在高能区主要俘获到l=1的p壳层.同时还计算入射粒子能量分别为4 keV和400 keV时,电子俘获到激发态辐射退激发产生的电荷转移发射光谱,并发现cascade效应的影响很大.     

THE STUDIES OF NON-RUTHERFORD BACKSCATTERING CROSS SECTIONS OF 4He FROM 16O

In this article, we report the 170° backscattering cross sections of ⁴He from ¹⁶O in the energy range of 2.0-9.0 MeV. Our measurements show that the alpha-oxygen scattering remains Rutherford scattering up to E_α=2.35 MeV, and there exist two energy regions, namely 5.55-5.85MeV and 8.50-8.80MeV, where the cross sections are enhanced and show a smooth variation. The measured laboratory cross sections are 9.50-9.97 and 35.0-33.0 times greater than the Rutherford values, respectively. In the 8.50-8.80MeV region, the cross sections at scattering angles of 160°, 165°, 170° and 175° were measured and found to be strongly angle-dependent. A most strong resonance occurred at 7.60 MeV, where the cross section is 200 times of its Rutherford value. This resonance has been used to measure the ¹⁶O concentration on a Cu surface, with a sensitivity of 1×10¹⁵ oxygen atoms/cm², Besides, we have studied the backscattering angle dependence of the threshold energy, i.e., the energy at which the elastic cross section begins to deviate from its Rutherford value. The experimental result seems not in agreement with the prediction made from the analytical formula developed by Bozoian et al.