Superconductivity in polymeric sulfur nitride (SN)x at high pressure

Investigations of the pressure dependence of the superconducting transition temperature T_c up to 17 kbar, and of the normal conductivity up to 50 kbar are reported. It is observed that below 8 kbar, the value of T_c increases linearly with the pressure. In addition, there is a significant drop of T_c at about 9 kbar which may be due to a phase transition.     

Pressure-induced structural phase transition in ReO3

We have investigated the pressure-induced structural phase transition in ReO₃ by neutron diffraction on a single crystal. We collected neutron diffraction intensities from the ambient and high pressure phases at P=7 kbar and refined the crystal structures. We have determined the stability of the high pressure phase as a function temperature down to T=2 K and have constructed the (P-T) phase diagram. The critical pressure is P_c=5.2 kbar at T=300 K and decreases almost linearly with decreasing temperature to become P_c=2.5 kbar at T=50 K. The phase transition is driven by the softening of the M₃ phonon mode. The high pressure phase is formed by the rigid rotation of almost undistorted ReO₆ octahedra and the Re-O-Re angle deviates from 180°. We do not see any evidence for the existence of the tetragonal (P4/mbm) intermediate pressure phase reported earlier.     

Pressure-induced phase transformation in In2Bi

We have made measurements of the pressure dependence of the superconducting transition temperature, T_c, for In₂Bi and related alloys. For In₂Bi- phase alloys, a large discontinuity in T_c is seen at 15–20 kbar, which we associate with a phase transformation first seen by Bridgman [1]. Our measurements suggest that this transformation is produced by the decomposition of In₂Bi into In₅Bi₃ and an In-rich phase. In the low pressure phase, T_c shows a minimum at 9–15 kbar whereas it depends linearly on pressure in the high pressure phase with ?T_c/?P equal to -4.9 × 10^-5 K bar^-1.     

Pressure effect on the anomalous electrical conductivity of magnetite

The temperature dependence of the electrical conductivity of magnetite was measured under hydrostatic pressure up to 18.4 kbar. It is found that the temperature of the conductivity maximum in the high temperature phase is more rapidly reduced by pressure (dT_m/dP = -4.1 K/kbar) than the Verwey temperature (dT_v/dP = -0.27 K/kbar). The discontinuous change of the conductivity at T_v appears to increase with applied pressure as a result of a lowering of T_m.     

Die Supraleitung von Zinn und Blei unter sehr hohem Druck

The dependence of the critical temperatureT _c upon pressureP is measured in the pressure range up to 160 kbar. The experimental technique developed for very high pressure-low temperature experiments (preceding article) is improved by introducing a double-sample electrical resistance cell. An internal pressure calibration is therefore possible at some well-established room temperature pressure reference points commonly used. Both metals, tetragonal white tin and fcc-lead, show a monotonic decrease ofT _c vs.P with upward curvature. The results recommend the use of Pb as a secondary standard for very high pressure experiments at Helium temperatures. In addition, high pressure polymorphic modifications of Sn and Pb are found to show superconductivity withT _c =(5.30±0.10) ?K for Sn III atP=113 kbar andT _c =(3.55±0.10) ?K for Pb II atP=160 kbar.     

Superconducting Properties of Indium Nanostructured in Pores of Thin Films of SiO<Subscript>2</Subscript> Microspheres

Samples of a superconducting indium nanocomposite based on a thin-film porous dielectric matrix prepared by the Langmuir–Blodgett method are obtained for the first time, and their low-temperature electrophysical and magnetic properties are studied. Films with thickness b ≤ 5 μm were made from silicon dioxide spheres with diameter D = 200 and 250 nm; indium was introduced into the pores of the films from the melt at a pressure of P ≤ 5 kbar. Thus, a three-dimensional weakly ordered structure of indium nanogranules was created in the pores, forming a continuous current-conducting grid. Measurements of the temperature and magnetic field dependences of the resistance and magnetic moment of the samples showed an increase in the critical parameters of the superconductivity state of nanostructured indium (critical temperature T_c ≤ 3.62 K and critical magnetic field H_c at T = 0 K H_c(0) ≤ 1700 Oe) with respect to the massive material (T_c = 3.41 K, H_c(0) = 280 Oe). In the dependence of the resistance on temperature and the magnetic field, a step transition to the superconductivity state associated with the nanocomposite structure was observed. A pronounced hysteresis M(H) is observed in the dependence of the magnetic moment M of the nanocomposite on the magnetic field at T < T_c, caused by the multiply connected structure of the current-conducting indium grid. The results obtained are interpreted taking into account the dimensional dependence of the superconducting characteristics of the nanocomposite.     

Effect of pressure on the Curie temperature of CoCr2O4

The pressure effect on the Curie temperature T_c of CoCr₂O₄ was measured under pressures up to 11.5 kbar. The pressure derivative of T_c is found to be +0.25 K/kbar. On the basis of this result, the relationship between the magnetic transition temperature and volume is discussed.     

Pressure dependence of the superconducting transition temperature of the stage-2 potassium mercurographitide intercalation compound

Measurements of the pressure (P) dependence of the superconducting transition temperature T_c of stage-two KHgC₈ are reported. T_c is found to decrease with applied pressure from a room pressure value of 1.85K at a rate dT_c/dP=-6.5 × 10^-5K/bar, similar to typical superconducting elements such as Sn. No superconductivity was detected for stage-one KHgC₄ or K_0.5Hg_0.5 amalgam to a limiting temperature T = 1.3K and a limiting pressure P = 22 kbar. These results are discussed in reference to the possible occurence of structural and charge density wave transitions in these materials and recent theoretical models of superconducting graphire intercalation compounds.     

Low temperature magnetoresistance in La1.32Sr1.68Mn2O7 layered manganite under hydrostatic pressure

The La_1.32Sr_1.68Mn₂O₇ layered manganite system has been studied by the low temperature electrical resistance and magnetoresistance under hydrostatic pressure up to 25 kbar. We have observe both, a Curie temperature (T_C) and a metal-insulator transition (T_MI) at 118 K in the ambient pressure. The applied pressure shifts the T_MI to higher temperature values and induces a second metal-insulator transition (T²_MI) at 90 K, in the temperature dependence of resistivity measurements. Also, the pressure suppresses the peak resistance abruptly at T_C. When an external field of 5 T is applied, we have observed a large negative magnetoresistance of 300% at the transition temperature and a 128% at 4.5 K. However, the increased pressure decreases the magnetoresistance ratio gradually. When the pressure reaches its maximum available value of 25 kbar, the magnetoresistance ratio decreases at a rate of 1.3%/kbar. From our experimental results, the decrease of magnetoresistance ratio with pressure is explained by the pressure induced canted spin state which is not favor for the spin polarized intergrain tunneling in layered manganites.     

Pressure dependence of the superconducting transition temperature of a (Mo0.6Ru0.4)86B14 metallic glass

We have studied the pressure dependence of the superconducting transition temperature of amorphous (Mo_0.6Ru_0.4)₈₆B₁₄ for hydrostatic pressures up to P ～ 9 kbar. The transition temperature T_c decreases with pressure at a rate dT_c/dP=-(9±1) mK kbar^-1. We estimate the Grüneisen parameter and the volume dependence of the electron-phonon coupling constant.     

Structure and superconductivity of La1.8Sr0.2CuO4 and multi-phase Y1.2Ba0.8CuO4 under high pressure

Superconducting La_1.8Sr_0.2CuO₄ has been investigated under pressure. Its resistiveT _c -midpoint was found to be 37 K at ambient pressure. It inductively determinedT _c is 33 K monotonically shifting up to 38.4 K at 19.2 kbar. The initial linear increase is 0.295 K/kbar. X-ray investigations in a diamond anvil revealed no phase transformation of the K₂NiF₄ structure up to about 50 kbar at 300 K, 60 K and 15 K. The bulk modulus of La_1.8Sr_0.2CuO₄ was 1070 kbar at 300 K and 1500 kbar at 15 K. Thec/a ratio decreases and shows pronounced differences between room temperature and low temperature data under pressure. Multi-phase Y–Ba–Cu-Oxide with resistiveT _c -onset of 90 K was investigated under pressure, too. The inductive transition starts at 70 K and is completed at 20 K. The superconducting volume fraction was estimated to be about 2% at 10 K.     

Pressure dependence of the weak itinerant ferromagnetism of Y(Co1-xAlx)2

Abstract

Y(Co_1-xAl_x)₂ is a weak itinerant ferromagnet for 0.12 < x < 0.20 with a maximum Curie point of about 25 K near x = 0.15. The pressure dependence of the Curie point for samples with 0.14 < x < 0.18 was measured in the temperature and pressure range 5–25 K and 0–8 kbar using a liquid filled lock cell. It was found that T_c was linear in pressure and extrapolated to OK at P_c = 9 ± 1 kbar for all samples. The volume expansion from YCo₂ to x = 0.15 is equivalent to a chemical pressure of -40 kbar so ferromagnetism cannot occur at the lattice constant of YCo₂.     

Exponential Increase in the Resistivity upon Cooling and Superconductivity in Indium-Doped Pb<Subscript>0.45</Subscript>Sn<Subscript>0.55</Subscript>Te

We have analyzed the temperature and magnetic-field dependences of resistivity ρ(T, H) of semiconducting compound Pb_0.45Sn_0.55Te doped with 5 at % In under a hydrostatic compression at P < 12 kbar. It is found that the temperature dependence ρ(T) at all pressures at T < 100 K is exponential with the activation energy decreasing upon an increase in pressure; this is accompanied with a superconducting transition on the ρ(T) and ρ(H) dependences at P > 4.8 kbar at T > 1 K (T _c = 1.72 K at a level of 0.5ρ _N at P = 6.8 kbar). We consider the model describing the low-temperature “dielectrization” of the semiconducting solid solution and the formation of the superconducting state upon an increase in the hydrostatic compression P > 4 kbar.     

Effect of hydrostatic pressure on the magnetic and lattice properties of the ferromagnet La(Fe0.86Si0.14)13

The temperature dependence of the lattice constant of the ferromagnet La(Fe_0.86Si_0.14)₁₃ has been measured at different pressures and temperatures. The numerical value of the bulk modulus at room temperature has been determined. The measurements of the temperature dependence of the lattice constant of the ferromagnet La(Fe_0.86Si_0.14)₁₃ at zero pressure and at 11.5 kbar have demonstrated that, at zero pressure, the lattice constant sharply decreases in the range from 160 to 210 K, whereas at a pressure of 11.5 kbar, the lattice constant decreases in the range from 110 to 180 K. This indicates that the Curie temperature T _C changes from 210 to ～170 K under pressure. The experimental results have been analyzed using the equations of states for the magnetic and elastic subsystems of the ferromagnet.     

Magnetic properties and hydrostatic pressure effect on the curie temperature of (Co,Mn)2B amorphous alloys

The temperature dependence of magnetization and magnetic susceptibility and hydrostatic pressure effect on the Surie temperature (dT_c/dP) are measured for (Co_1-xMn_x)₂B (0?x?0.4) amorphous alloys and the results are compared with those of crystalline compounds with the same composition. The Curie temperature decreases linearly with an increasing Mn content but magnetization shows a maximum around x=0.15. The reciprocal magnetic susceptibility of all the prepared alloys obeys the Curie-Weiss law above T_c. The magnitude of the negative value of dT_c/dP decreases linearly with increasing x from about 1.1 K/kbar (x=0) to zero (x=0.4), the composition dependence of which is opposite to that of the crystalline compound. The composition dependence of the average magnetic moment per transition metal atom and the Curie temperature and dT_c/dP are analysed on the basis of the local environment and the pair order interaction mode, respectively.     

The pressure dependence of the néel temperature in FeF2

A Mössbauer measurement of the pressure dependence of the Néel temperature in FeF₂ is reported. Up to the maximum pressure of 50 kbar T_N increases at the rate of 0.27 ± 0.03°K/kbar. When this pressure dependence is converted to volume dependence, the result, d In T_N/d In V = 3.2 ± 0.3, is found to obey the $\text{“10}\text{3}$ rule” established by Bloch for a wide variety of antiferromagnetic insulators.     

Superconductivity in α- and ω-Zirconium under high pressure

The pressure dependence of the superconducting transition temperatureT _c (p) of α-Zr has been investigated in both solid and liquid pressure transmitting media. Up to about 45 kbardT _c /dp was measured to be + 3.5 × 10^?6 K/bar. Cold working at 4.2 K produced a strong irreversible effect onT _c . The superconductivity of the high pressure phase, ω-Zr, has been studied in its region of stability, i.e. above 60 kbar. For ω-Zr,dT _c /dp=+7.7 × 10^?6K/bar, andT _c (0)=0.72 K (by extrapolation).     

Ferroelastic phase transition and anomalous elastic and thermal properties of betaine borate (CH3)3NCH2COO·H3BO3

The temperature and pressure derivatives of the elastic constants of orthorhombic betaine borate, (CH₃)₃NCH₂COO·H₃BO₃, have been determined by measuring temperature and stress induced shifts of resonance frequencies of thick plates at ca. 15 MHz in the range between 140 and 300 K and 0 and 3 kbar. The elastic ‘shear’ resistance c₄₄ exhibits a value as low as 0.0492×10¹⁰Nm^-2at 293 K. With decreasing temperature c₄₄ approaches zero at ca. 142.5 K, indicating an acoustic soft mode behaviour connected with a ferroelastic phase transition. The softening of c₄₄ is described in a good approximation by c₄₄(T)_p=0 =alogT/T₀ with a=0.0663×10¹⁰Nm^-2 and T₀ = 139.5 K. Further, c₄₄ decreases with increasing pressure according to the linear relation c₄₄(p)_{T=293 K} = 0.0492?0.184×10^-4p (p in bar, c₄₄ in 10¹⁰ Nm^-2). All other elastic constants show a quite normal temperature and pressure dependence. At 293 K the transition is induced by a pressure of 2.65 kbar. The transition temperature T_c depends linearly on pressure according to T_c = 142.5+0.0568 p (pinbar, T_cinK). Passing through the transition no discontinuous change of the lattice constants is observed. The three principal coefficients of thermal expansion and the pressure derivatives of the dielectric constants exhibit discontinuities at the transition. The transition is of strongly second order.     

Measurement of the pressure dependence of Tc for superconducting spinel compounds

The superconducting transition temperatures (T_c) of CuRh₂Se₄, CuRh₂S₄ and LiTi₂O₄ were all found to increase linearly under hydrostatic pressure up to 22 kbar, at a rate of 1–5 × 10^-5 Kbar^-1. These results are discussed in terms of the dependence of T_c on Debye temperature previously found for this set of compounds from heat capacity measurements at zero pressure.