Experimental and Numerical Modeling of the Thermal Conductivity of High-Viscosity Hydrocarbon Systems

A mathematical model is developed to numerically predict the heating of heavy hydrocarbon systems. A comparative analysis of numerical and experimental data is performed. It is found that the thermal conductivity of a hydrocarbon system under study heated from an initial temperature of 24°C to 100°C increases by a factor of 40 and, with allowance for free convection, an additional substantial (up to 16 times) increase in heat transfer due to enhanced effective thermal conductivity is observed. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 6, pp. 96–102, November–December, 2005.     

Temperature dependence of the interfacial tension of PS/PMMA, PS/PE, and PMMA/PE blends

The effect of temperature on the interfacial tension for PS/PMMA, PS/PE, and PMMA/PE was measured using the imbedded fiber retraction method. Interfacial tensions for PS/PMMA, PS/PE, and PMMA/PE were measured over temperature ranges of 160–250 °C, 140–220 °C, and 140–220 °C, respectively. The interfacial tension was found to follow a dependence of 3.6–0.013 T dyn/cm, 7.6–0.051 T dyn/cm and 11.8–0.017 T dyn/cm for PS/PMMA, PS/PE, and PMMA/PE, respectively. Comparison of the data with the mean field theory of Helfand and Sapse were made; however, a simple linear fit to the data described the temperature dependence in the experimental window as well as the predictions of the mean field theory. Received: 6 July 1999 Accepted: 23 March 2000     

A study of loop heat pipe with biporous wicks

The purpose of this study is to investigate the effects of various bimodal pore size distributions of biporous wicks for a loop heat pipe (LHP). The study was conducted following a statistical method using a two-level factorial plan involving three variables (particle size of pore former:74–88 and 125–149 μm Na₂CO₃, pore former content:20% by volume and 25% by volume, sintering temperature:700 and 750°C). Finally, the heat transport capability of the LHP between monoporous wicks and biporous wicks has been investigated. Experimental results show that, at the sink temperature of 10°C and the allowable evaporator temperature of 80°C, the heat transfer capacity of the better biporous wick achieved 200 W and the total thermal resistance was 0.31°C/W. The performance is enhanced about 60%, compared to a monoporous wick for 125 W and 0.53°C/W. Therefore, LHPs with biporous wicks are very attractive for high heat flux applications in the future.     

Effect of the Nonmonotonic Temperature Dependence of Water Density on the Propagation of a Vertical Plane Jet

This paper gives results of two experiments in which warmer water in the form of a vertical plane jet was let into colder water. In one experiment, the temperature of inflowing and initially quiescent water exceeded 4°C and warm water propagated only along the free surface. In the other experiment, the temperature of inflowing water was above 4°C and that of quiescent water was below 4°C. In this case, two jets — surface and bottom — first formed, and then the inflowing liquid was entirely concentrated in the bottom jet. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 2, pp. 23–29, March–April, 2006.     

Turbulent flow past a transverse cavity with inclined side walls. 2. Heat transfer

Convective heat transfer in a transverse cavity with a small aspect ratio, angle of wall inclination ϕ = 30–90°, and heated bottom, frontal, and rear walls of the cavity is studied experimentally. Temperature distributions are measured in longitudinal and transverse sections on three walls; temperature fields are measured over the entire heated surface. Local and mean heat-transfer coefficients are calculated. The highest intensification of heat transfer is found to occur on the rear wall for low values of ϕ Reconstruction of the one-cell structure to the two-cell structure of the primary vortex in the cavity leads to a drastic decrease in heat transfer over the cavity span from the end faces toward the center in the case with ϕ = 60 and 70°. A certain increase in the mean heat-transfer coefficient averaged over the entire heated surface is noted for ϕ = 60°. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 4, pp. 23–29, July–August, 2007.     

Application of 2-D LIF temperature measurements in water using a Nd : YAG laser

 The application of Laser Induced Fluorescence (LIF) for temperature measurements in water using a Nd : YAG laser is investigated. A natural convection problem is used to test the applicability of LIF in the temperature range of 20–60°C. The measured temperature field is compared with numerical results and the influences of shadowgraph effects on the measured temperature field are investigated. An accuracy of 1.7°C is attained if shadowgraph effects can be neglected. This only holds if correction for photobleaching and variation of laser power output is applied. Received: 8 July 1998/Accepted: 3 February 1999     

Rheological properties of gluten plasticized with glycerol: dependence on temperature, glycerol content and mixing conditions

The rheological behaviour of a gluten plasticized with glycerol has been studied in oscillatory shear. The mixing operation in a Haake batch mixer leads to a maximum torque for a level of specific energy (500–600 kJ/kg) and temperature (50–60 °C) quite independent of mixing conditions (rotor speed, mixing time, filling ratio). The gluten/glycerol dough behaves as a classical gluten/water dough, with a storage modulus higher than the loss modulus over the frequency range under study. A temperature increase induces a decrease of moduli, but the material is not thermorheologically simple. Glycerol has a plasticizing effect, which can be classically described by an exponential dependence. Mixing conditions influence the viscoelastic properties of the material, mainly through the specific mechanical energy input (to 2000 kJ/kg) and temperature increase (to 80 °C). Above 50 °C, specific mechanical energy highly increases the complex modulus. The aggregation of proteins, as evidenced by size-exclusion chromatography measurements, occurs later as the dough temperature reaches 70 °C. The nature of network interactions and the respective influence of hydrophobic and disulphide contribution is discussed. A general expression is proposed for describing the viscous behaviour of a gluten/glycerol mix, which could seem simplistic for such a complex rheological behaviour, but would remain sufficient for modelling the flow behaviour in a twin screw extruder. Received: 24 November 1997 Accepted: 28 April 1999     

2D temperature measurements in the wake of a heated cylinder using LIF

A technique is described to measure the instantaneous 2D temperature distribution in the wake of a heated cylinder using `laser-induced fluorescence'. Rhodamine B, a fluorescent dye, is used as a temperature indicator. The relation between fluorescence intensity and temperature is determined by means of calibration experiments in the temperature range of 20–35 °C with an accuracy of ±0.1 °C. The temperature distribution behind the heated cylinder is well visible and can be measured with a high spatial resolution. Corrections for variation in laser energy and intensity distribution in the laser sheet have to be made to further improve the accuracy of the measuring method. Received: 3 January 2001/Accepted: 18 May 2001     

Crystallization of an ethylene-based butene plastomer: the effect of uniaxial extension

In this paper, the effect of uniaxial extension on the crystallization of an ethylene-based butane plastomer is examined by using rheometry coupled with differential scanning calorimetry (DSC). Uniaxial extension experiments were performed at temperatures below and above the peak melting point of the polyethylene in order to characterize its flow-induced crystallization behavior at extensional rates relevant to processing. The degree of crystallinity of the stretched samples was quantified by DSC, i.e., by analyzing the thermal behavior of samples after stretching. Analysis of the tensile strain-hardening behavior very near the peak melt temperature revealed that crystallization depends on temperature, strain, and strain rate. In addition, it was revealed that a very small window of temperatures spanning just 1–2°C can have a dramatic effect on polymer crystallization. Finally, flow-induced crystallization experiments at temperatures close to the peak melting point have shown the recrystallization of multiple crystalline structures within a polymer matrix, witnessed by double peaks within a narrow window of 89–93°C in the DSC thermographs, with the most demonstrable double peak behavior occurring at a temperature of 91°C, a temperature that is just 1°C cooler than the peak melt temperature of the polymer.     

Experimental investigation on the sensible effectiveness of LiCl wheel

Experimental investigation on the sensible effectiveness of LiCl wheel is reported. The measurements were made for balanced flow (C* = 1) for a wide range of rotational speed 0–10 rpm, regeneration temperature of 50–70°C and airflow rate 150–550 kg/h. The results revealed that the operation rotational speed for LiCl wheel is about 5 rpm which is significantly lower that for Silica gel wheel. It is also found that the sensible effectiveness is independent of the regeneration temperature. The experimental results are also fitted to the existing correlation of Simonson et al. (ASHRAE Trans 106(1):301–310, 2000). For the range of the applicability of the correlation, most of the experimental data fit the correlation within an error band of ±5%.     

Some specific features of high-temperature deformation of materials

Experimental results for high-temperature deformation of an iron-based structural material in the temperature ranges including the points of the Fe_α→Fe_β→Fe_ψ transition are given. It is shown that the strain-strength properties of the material change nonmonotonically on the interval 700°C<T<1000°C and that the internal phase-structural changes exert an effect on the thermal effects. Approximating dependences that permit one to describe deformation processes in the indicated temperature ranges upon uniaxial loading are proposed. Lavrent'ev Institute of Hydrodynamics, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 40, No. 6, pp. 152–156, November–December, 1999.     

Mixed Convection in Water Near the Density Extremum Along a Vertical Plate with Sinusoidal Surface Temperature Variation Embedded in a Porous Medium

A steady laminar boundary layer flowing along a vertical plate immersed in a Darcy–Brinkman porous medium saturated with water at 4°C is studied. The plate temperature varies sinusoidally along the plate between 0 and 8°C where the density of water varies parabolically and is almost symmetrical at about 4°C. Except for the existence of the buoyancy force, it is assumed that either the plate moves upwards or the ambient water moves upwards (moving stream). The results are obtained with the direct numerical solution of the boundary layer equations taking into account the temperature dependence of water thermophysical properties (ρ, μ and c _p). Results are presented for the wall temperature gradient and the wall shear stress along the plate for free convection and mixed convection. Temperature and velocity profiles are also presented.     

Critical Stresses in Spalling and Dynamic Rupture of Metals

Results of dynamic rupture tests of a series of metals obtained using a composite Hopkinson bar and shock-wave loading of plane specimens are described. It is shown that the actual rupture strength at a strain rate of 5 · 10³ sec⁻¹ is very close to the spall strength at higher strain rates. Results of testing the same metals using a composite Hopkinson bar within a temperature range of 20–350°C are given. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 6, pp. 103–107, November–December, 2005.     

Thin-layer drying characteristics of sweet potato slices and mathematical modelling

The effect of blanching and drying temperature (50, 60 and 70°C) on drying kinetics and rehydration ratio of sweet potatoes was investigated. It was observed that both the drying temperature and blanching affected the drying time and rehydration ratio. The logarithmic model showed the best fit to experimental drying data. The values of effective moisture diffusivity and activation energy ranged from 9.32 × 10⁻¹¹ to 1.75 × 10⁻¹⁰ m²/s, and 22.7–23.2 kJ/mol, respectively.     

The influence of temperature on rheological properties of blood mixtures with different volume expanders—implications in numerical arterial hemodynamics simulations

During the complicated cardiac surgery on a non-beating heart with cardiopulmonary bypass, protection of the heart is accomplished by injecting cold cardioplegic solutions. In most forms of circulatory shock, it is necessary to immediately restore the circulating volume. Intravenous solutions of volume expanders, such as hydroxyethyl starch and dextrans, are used to increase the volume of fluid in the circulating blood. In this work, blood samples of six donors were obtained and used to prepare mixtures with different volume expanders in concentrations ranging from 10 to 50 vol./vol.%. The flow curves of all mixtures in the temperature range from 4°C to 37°C were constructed and fitted to the Herschel–Bulkley model, in order to extract the shear thinning and yield stress parameters. To assess the influence of the observed changes in the rheological properties of blood on the hemodynamics in arterial vasculature, a realistic three-dimensional rigid-wall computational model was constructed from MRI images of the right carotid bifurcation obtained in vivo from a healthy male volunteer. The time-varying flow field was numerically computed using the Newtonian model as well as the Herschel–Bulkley model with the Papanastasiou regularization. The numerical simulations indicate only moderate changes in the time-averaged flow field that become accentuated when the instantaneous flow field is considered. We also found that although the influence of temperature, hematocrit, and volume expanders on hemodynamics is significant, this can primarily be attributed to the changes in the nominal viscosity of the flow medium.     

Fatigue of the Near-Alpha Ti-Alloy Ti6242

Ti6242 is the workhorse of high-temperature Ti-alloys in the high pressure compressor of aero engines. In this study the influence on isothermal fatigue of different load controls, i.e. stress, total strain and plastic strain control at different temperatures and environments was investigated. The alloy had a bi-modal microstructure (some 30 vol.% primary alpha), which yields a good balance between fatigue and creep properties. In addition thermomechanical fatigue (TMF) tests were also performed. Modelling lifetime on the basis of a Basquin–Coffin–Manson relationship revealed only marginal scattering in the temperature range between 350°C and 650°C. Increasing the temperature led to a decrease in lifetime. This can be attributed to increased oxidation and creep. The latter one is clearly seen in isothermal tests under stress control. Tests in vacuum resulted in longer lifetimes. In-phase TMF tests exhibited a longer lifetime than out-of-phase tests, with a factor of about 4. Lifetime and stress response of in-phase tests are similar to the corresponding lifetime of an isothermal test at the maximum temperature. This similarity can be considered as a starting point for modelling TMF behaviour on the basis of isothermal fatigue.     

The modified imbedded disc retraction method for measurement of interfacial tension in polymer melts

The imbedded disc retraction method is used to estimate interfacial tension in LLDPE/PS system with PS as the imbedded disc. Shape evolution of a disc of one material (PS) imbedded into the matrix of another material is observed (LLDPE). Three to five repetitions at three different temperature levels are observed. The Newtonian model of Rundqvist et al. (1996) for the imbedded disc retraction is modified to include elastic effects. The modified model is derived assuming uniaxial extension, starting with the lower convected Maxwell model. Both the original model and modified imbedded disc retraction model are used in data analysis. The mean values of interfacial tension at 190 °C, 200 °C, and 210 °C are 6.8 ± 0.7 mN/m, 3.9 ± 0.3 mN/m, and 3.7 ± 0.2 mN/m, respectively. A method of estimating whether elastic effects will significantly affect the estimated interfacial tension value during retraction for the given polymer pair is provided. Received: 6 August 1999 Accepted: 2 January 2001     

Molecular dynamics of the glass relaxation process of the soft phase in block copolymers: effect of molecular architecture

To determine the impact of molecular architecture on the molecular dynamics of the glass relaxation processes of soft blocks in different types of block copolymers, model block copolymers with a variation in both molecular architecture and chemical composition were studied. Four block copolymer models, namely, two styrene–butadiene–styrene (S-B-S) block copolymers and two styrene–styrene butadiene–styrene (S-SB-S) were chosen. In each pair of block copolymers, one is linear triblock and the other is star asymmetric. For the sake of comparison, two polybutadiene (PB) homopolymer samples, having similar chain lengths of the PB blocks present in the S-B-S block copolymers, have been investigated. Dynamic mechanical measurements have been carried out for the real and imaginary parts of the complex shear modulus (G′, G”) in the temperature and frequency ranges from −110 to 30 °C and from 10⁻² to 15.9 Hz, respectively. Complete master curves have been constructed for all samples investigated. Moreover, broadband dielectric spectroscopy has been carried out to cover wide temperature and frequency windows, −120 to 0 °C and 10⁻¹ to 10⁷ Hz, respectively. The results showed that the molecular dynamics of the glass relaxation process of the PB or statistical PSB soft phases in the block copolymers is dramatically changed when compared to the PB homopolymer. In addition, the molecular architecture is found to be an important factor in determining the molecular mobility of the soft blocks. The results are discussed in terms of the applied confinement of the counter PS hard phase, block lengths, domain thicknesses and the type of end-to-end junctions between the different polymeric blocks. Paper presented 3rd Annual European Rheology Conference (AERC 2006) April 27–29, 2006, Crete, Greece.