Preparation and characterization of transparent Nd:YAG ceramics

Transparent Nd:YAG ceramics were produced by solid.state reaction of high.purity (4N) nanometric oxides powders, i.e., Al₂O₃, Y₂O₃ and Nd₂O₃. After sintering, mean grain sizes of 2% Nd:YAG samples were about 20 μm and their transparency were a bit worse than that of 0.9% Nd:YAG single crystal. Two types of active elements: rods and slabs were fabricated and characterized in several diode pumping schemes. In end pumping configuration as a pump source 20.W fiber coupled laser diode operating in low duty cycle regime (1 ms pump duration/20 Hz) was deployed. In the best case, 3.7 W of output power for 18 W of absorbed pump power, M² < 1.4 were demonstrated for uncoated ceramics Nd:YAG rod of ϕ 4×3mm size in preliminary experiments. For the ceramics of two times lower Nd dopant level above 30% slope efficiency was achieved. In case of Nd:YAG ceramic slab side pumped by 600.W laser diode stack above 12 W was demonstrated with slope efficiency of 3.5%.     

Photolumiscent Properties of Nanorods and Nanoplates Y<Subscript>2</Subscript>O<Subscript>3</Subscript>:Eu<Superscript>3+</Superscript>

Nanorods and nanoplates of Y₂O₃:Eu³⁺ powders were synthesized through the thermal decomposition of the Y(OH)₃ precursors using a microwave-hydrothermal method in a very short reaction time. These powders were analyzed by X-ray diffraction, field emission scanning electron microscopy, Fourrier transform Raman, as well as photoluminescence measurements. Based on these results, these materials presented nanoplates and nanorods morphologies. The broad emission band between 300 and 440 nm ascribed to the photoluminescence of Y₂O₃ matrix shifts as the procedure used in the microwave-hydrothermal assisted method changes in the Y₂O₃:Eu³⁺ samples. The presence of Eu³⁺ and the hydrothermal treatment time are responsible for the band shifts in Y₂O₃:Eu³⁺ powders, since in the pure Y₂O₃ matrix this behavior was not observed. Y₂O₃:Eu³⁺ powders also show the characteristic Eu³⁺ emission lines at 580, 591, 610, 651 and 695 nm, when excited at 393 nm. The most intense band at 610 nm is responsible for the Eu³⁺ red emission in these materials, and the Eu³⁺ lifetime for this transition presented a slight increase as the time used in the microwave-hydrothermal assisted method increases.     

Effect of iso- and heterovalent additives on characteristics of highly transparent Nd(Yb):Y<Subscript>2</Subscript>O<Subscript>3</Subscript> ceramics

The possibility of synthesis and characteristics of highly transparent Y₂O₃ ceramics doped with Nd³⁺ and Yb³⁺ were studied. The ceramics crystal structure was disordered for the first time by simultaneously substituting Y³⁺ cations by Lu³⁺ or Sc³⁺ isovalent ions and Zr⁴⁺ heterovalent ions. The developed technique allowed synthesis of highly transparent Nd³⁺:Y₂O₃, Nd³⁺: Y₂O₃ + 6 mol % ZrO₂, Nd³⁺: (Lu_0.25Y_0.75)₂O₃ + 6 mol % ZrO₂, Nd³⁺:(Sc_0.25Y_0.75)₂O₃ + 6 mol % ZrO₂, and Yb³⁺:(Sc_0.25Y_0.75)₂O₃ + 6 mol % ZrO₂ ceramics with transmittance to 82.2%. It was shown that introduction of iso- and heterovalent additives Sc₂O₃, Lu₂O₃, and ZrO₂ into Nd³⁺:Y₂O₃ decreases average crystallite sizes to ∼1 μm and reduces the pore content, thus making it possible to produce pore-free ceramics. These additives broaden the spectral band of the ⁴ F _3/2 → ⁴ I _11/2 transition of the neodymium ion to 40 nm.     

Performance comparisons of passively Q-switched intracavity-frequency-doubled Nd:Gd<Subscript>0.19</Subscript>Y<Subscript>0.81</Subscript>VO<Subscript>4</Subscript> and Nd:Gd<Subscript>0.83</Subscript>Y<Subscript>0.17</Subscript>VO<Subscript>4</Subscript> lasers at 671 nm

Performance comparisons of laser-diode pumped passively Q-switched intracavity-frequency-doubled Nd:Gd_0.19Y_0.81VO₄ and Nd:Gd_0.83Y_0.17VO₄ lasers at 671 nm are demonstrated for the first time to our knowledge. KTP crystal is used as the frequency doubling material and V:YAG crystal as the saturable absorber with initial transmission of 89%. The dependences of average output power, pulse width, pulse repetition rate, single-pulse energy and peak power on incident pump power are measured and contrasted. The experimental results show that, Nd:Gd_0.83Y_0.17VO₄ laser has more excellent properties than Nd:Gd_0.19Y_0.81VO₄ laser at 671 nm.     

Diode-pumped CW Nd:YAG laser at 1356 nm based on the <Superscript>4</Superscript><Emphasis Type="Italic">F</Emphasis><Subscript>3/2</Subscript>-<Superscript>4</Superscript><Emphasis Type="Italic">I</Emphasis><Subscript>13/2</Subscript> transition

We describe the output performances of the 1356 nm ⁴ F _3/2-⁴ I _13/2 transition (generally used for a 1319 nm transition) in Nd:YAG under in-band pumping with diode laser at the 809 nm wavelength. An end-pumped Nd:YAG crystal yielded 1.02 W of continuous-wave (CW) output power for 18.2 W of incident pump power. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a power of 290 mW at 678 nm by using a LiB₃O₅ (LBO) nonlinear crystal. The red beam quality factor M ₂ was less than 1.37. The red power stability was less 3.2% in 4 h.     

Efficiency intracavity frequency-doubled Nd:Y<Subscript>0.36</Subscript>Gd<Subscript>0.64</Subscript>VO<Subscript>4</Subscript>-LBO green laser at 532 nm with direct pumping

We report an efficient laser emission on the 1064 nm ⁴ F _3/2 to ⁴ I _11/2 transition in mixed vanadate crystal Nd:Y_0.36Gd_0.64VO₄ under the pump with diode laser at 880 nm. Continuous wave (CW) 10.7 W output power at 1064 nm is obtained under 17.8 W of incident pump power; the slope efficiency with respect to the incident pump power was 71.2%. Moreover, intracavity frequency doubling with LiB₃O₅ (LBO) nonlinear crystal yielded 4.6 W of green light at 532 nm. An optical-to-optical efficiency with respect to the incident pump power was 25.8%.     

All-solid-state Nd:Gd<Subscript>0.18</Subscript>Y<Subscript>0.82</Subscript>VO<Subscript>4</Subscript>-LBO green laser at 532 nm

We report a continuous-wave (CW) coherent green radiation at 532 nm by intracavity frequency doubling generation of 1064 nm Nd:Gd_0.18Y_0.82VO₄ laser. With incident pump power of 18.2 W, output power of 1.08 W at 532 nm has been obtained using a 5 mm-long KTP crystal. The optical conversion efficiency was up to 5.9%. At the output power level of 1.08 W, the output stability is better than 5%. The beam quality M² values were equal to 1.26 and 1.12 in X and Y directions, respectively.     

Diode-pumped CW Nd:YAG laser at 1116 nm based on the <Superscript>4</Superscript><Emphasis Type="Italic">F</Emphasis><Subscript>3/2</Subscript>-<Superscript>4</Superscript><Emphasis Type="Italic">I</Emphasis><Subscript>11/2</Subscript> transition

We describe the output performances of the 1116 nm ⁴ F _3/2-⁴ I _11/2 transition (generally used for a 1064 nm transition) in Nd:YAG under in-band pumping with diode laser at the 809 nm wavelength. An end-pumped Nd:YAG crystal yielded 680 mW of continuous-wave (CW) output power for 18.2 W of incident pump power. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a power of 97 mW at 558 nm by using a LiB₃O₅ (LBO) nonlinear crystal. The yellow-green beam quality factor M ² was less than 1.21. The yellow-green power stability was less 2.5% in 4 h.     

Synthesis and characterization of mono-dispersed Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript>:Er<Superscript>3+</Superscript>-coated SiO<Subscript>2</Subscript> nanoparticles by co-precipitation process

In this paper, a facile co-precipitation process for preparing mono-dispersed core–shell structure nanoparticles is reported. The 110 nm SiO₂ cores coated with an yttrium aluminum garnet (Y₃Al₅O₁₂) layer doped with Er³⁺ were synthesized and the influence of the concentration ratio of [urea]/[metal ions] on the final product was investigated. The structure and morphology of samples were characterized by the X-ray powder diffraction, Fourier transform IR spectroscopy and transmission electron microscopy, respectively. The results indicate that a layer of well-crystallized garnet Y₃Al₅O₁₂:Er³⁺ were successfully coated on the silica particles with the thickness of 20 nm. The near infrared and upconversion luminescent spectra of the SiO₂@Y₃Al₅O₁₂:Er³⁺ powders further confirm that a Y₃Al₅O₁₂:Er³⁺ coating layer has formed on the surface of silica spherical particles.     

Optical properties and highly efficient laser oscillation of Nd:YAG ceramics

Optical absorption, emission spectra have been measured for polycrystalline Nd-doped Y₃Al₅O₁₂ ceramics. Fluorescence lifetimes of 257.6 μs, 237.6 μs, 184.2 μs and 95.6 μs have been obtained for 0.6%, 1%, 2% and 4% neodymium-doped YAG ceramics, respectively. For the first time, highly efficient laser oscillation at 1064 nm has been obtained with this kind of ceramics. Slope efficiency of 53% has been achieved on a uncoated 4.8-mm thick 1% Nd:YAG ceramics sample. Optical to optical conversion efficiency is 47.6%. Laser oscillation has also been obtained with a 2% Nd:YAG ceramics. The optical properties and laser output results have been compared with that of Nd:YAG single crystal grown by the Czochralski method. Almost identical results have been achieved including laser experiments results. But fabrication of Nd:YAG ceramics is much easier compared to the single-crystal growth method. And also large size (now of about 400 mm diameter×5 mm is available) and high-concentration (>1%) Nd:YAG ceramics can be fabricated. The results show that this kind of Nd:YAG ceramics is a very good alternative to Nd:YAG single crystal. Received: 20 April 2000 / Published online: 16 August 2000     

Quasi-three-level laser operation of Nd:Y<Subscript>0.53</Subscript>Gd<Subscript>0.47</Subscript>VO<Subscript>4</Subscript> mixed vanadate crystal oscillating at 913 nm

Efficient continuous-wave (CW) laser operation on the ⁴ F _3/2 → ⁴ I _9/2 transition of Nd:Y_0.53Gd_0.47VO₄, a mixed vanadate crystal, is demonstrated at room temperature employing a compact plano-concave resonator, generating a polarized output power of 0.39 W at 913.2 nm with 2.85 W of pump power absorbed, the optical-to-optical and slope efficiencies being 14 and 25%, respectively.     

The influence of the specific surface of grains on the luminescence properties of Nd<Superscript>3+</Superscript>-doped Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> nanopowders

Nd³⁺:Y₃Al₅O₁₂ (Nd:YAG) powders were prepared by the Pechini method in the temperature range of 800 to 1400 °C. The pure garnet phase of the obtained materials was confirmed by XRD studies. The size of the grains was controlled by the annealing temperature of the samples. Their morphologies were investigated by TEM and porosity measurements (BET). The effect of annealing temperature on the morphology and luminescence properties of Nd:YAG nanocrystallites was studied, and the results were compared to the properties of a Nd:YAG single crystal. A significant enhancement of the ⁴F_3/2→⁴I_9/2/⁴F_3/2→⁴I_11/2 intensity ratio with decreasing grain size was observed. It was found that the decay times of the Nd³⁺ luminescence depends on the specific surface and is significantly longer for well crystallized nanocrystalline grains than for single crystals having the same concentration of Nd³⁺ ions. The role of crystallinity and specific surface on the radiative processes is analyzed. PACS 78.55.-m; 78.20.Ci; 78.67.Bf; 78.68.+m     

Diode-pumped Yb:Y<Subscript>2</Subscript>SiO<Subscript>5</Subscript>-LiB<Subscript>3</Subscript>O<Subscript>5</Subscript> cyan laser at 501.7 nm

We describe the output performances of the 928 nm ⁴ F _3/2 → ⁴ I _9/2 transition in Nd:CLNGG under diode-laser pumping. An end-pumped Nd:CLNGG crystal yielded 1.3 W of continuous-wave output power for 17.8 W of absorbed pump power. The slope efficiency with respect to the absorbed pump power was 11.2%. Furthermore, with 17.8 W of diode pump power and the frequency-doubling crystal LiB₃O₅ (LBO), a maximum output power of 260 mW in the blue spectral range at 464 nm has been achieved. The blue output power stability over 4 h is better than 3.2%.     

Diode-pumped Nd:LuVO<Subscript>4</Subscript>-LBO green laser at 533 nm

We report a continuous-wave (CW) coherent green radiation at 533 nm by intracavity frequency doubling generation of 1066 nm Nd:LuVO₄ laser. With incident pump power of 18.2 W, output power of 4.3 W at 533 nm has been obtained using a 5 mm-long LBO crystal. The optical conversion efficiency was up to 23.6%. At the output power level of 4.3 W, the output stability is better than 3%. The beam quality M² values were equal to 1.13 and 1.21 in X and Y directions, respectively.     

Diode-pumped Nd:LuVO<Subscript>4</Subscript>-Nd:YVO<Subscript>4</Subscript> laser at 492 nm with intracavity sum-frequency-mixing in LiB<Subscript>3</Subscript>O<Subscript>6</Subscript>

We present for the first time a Nd:YVO₄ laser emitting at 1064 nm intracavity pumped by a 916 nm diode-pumped Nd:LuVO₄ laser. A 809 nm laser diode is used to pump the Nd:LuVO₄ crystal emitting at 916 nm, a Nd:YVO₄ laser crystal was pumped at 916 nm and lased at 1064 nm. Intracavity sum-frequency mixing at 916 and 1064 nm was then realized in a LiB₃O₆ (LBO) crystal to reach the blue range. We obtained a continuous-wave output power of 216 mW at 492 nm under 19.6 W of incident pump power at 809 nm.     

Efficient Nd:Y<Subscript>0.36</Subscript>Gd<Subscript>0.64</Subscript>VO<Subscript>4</Subscript>-GdCa<Subscript>4</Subscript>O(BO<Subscript>3</Subscript>)<Subscript>3</Subscript> red laser under diode pumping into the emitting level

We report a red laser at 671 nm generation by intracavity frequency doubling of a continuous wave (cw) laser operation of a 1342 nm Nd:Y_0.36Gd_0.64VO₄ laser under diode pumping into the emitting level ⁴ F _3/2. An GdCa₄O(BO₃)₃ (GdCOB) crystal, cut for critical type I phase matching at room temperature is used for second harmonic generation of the laser. At an incident pump power of 17.8 W, as high as 1.12 W of cw output power at 671 nm is achieved. The optical-to-optical conversion efficiency is up to 6.3%, and the fluctuation of the red output power was better than 3.5% in the given 30 min.     

Continuous-wave intracavity frequency-doubled Nd:Yag-KTiOPO<Subscript>4</Subscript> red laser

Efficient and compact red laser output at 669 nm is generated by intracavity frequency doubling of a continuous-wave (CW) diode-pumped Nd:YAG laser at 1338 nm. With 16.9 W of diode pump power and the frequency-doubling crystal KTiOPO₄ (KTP), a maximum output power of 582 mW in the red spectral range at 669 nm has been achieved, corresponding to an optical-to-optical conversion efficiency of 3.4%; the output power stability over 4 h is better than 3.6%. To the best of our knowledge, this is first work on intracavity frequency doubling of a diode pumped Nd:YAG laser at 669 nm.     

All-solid-state intracavity frequency-doubled Nd:Y<Subscript>0.36</Subscript>Gd<Subscript>0.64</Subscript>VO<Subscript>4</Subscript>-GdCa<Subscript>4</Subscript>O(BO<Subscript>3</Subscript>)<Subscript>3</Subscript> green laser under direct 880 nm pumping

We report a green laser at 532 nm generation by intracavity frequency doubling of a continuous wave (CW) laser operation of a 1064 nm Nd:Y_0.36Gd_0.64VO₄ laser under in-band diode pumping at 880 nm. An GdCa₄O(BO₃)₃ (GdCOB) crystal, cut for critical type I phase matching at room temperature is used for second harmonic generation of the laser. At an incident pump power of 17.8 W, as high as 2.92 W of CW output power at 532 nm is achieved. The optical-to-optical conversion efficiency is up to 16.4%, and the fluctuation of the green output power was better than 2.5% in the given 30 min.     

High-peak power,passively Q-switched,composite, all-poly-crystalline ceramics Nd:YAG/Cr<Superscript>4+</Superscript>:YAG laser and generation of 532-nm green light

Output performances of passively Q-switched, composite Nd:YAG/Cr⁴⁺:YAG lasers that consisted of bonded, all-poly-crystalline ceramics Nd:YAG and Cr⁴⁺:YAG are reported. Laser pulses at 1.06 μm with 2.5-mJ energy and 1.9-MW peak power are obtained from a 1.1-at % Nd:YAG/Cr⁴⁺:YAG ceramics that was quasi-continuous-wave (quasi-CW) pumped with a diode laser. Single-pass frequency doubling with LiB₃O₅ (LBO) nonlinear crystal at room temperature yielded green laser pulses at 532 nm of 0.36-mJ energy and 0.3-MW peak power, with a conversion efficiency of 0.27.     

Dual-wavelength oscillation at 1064 and 1342 nm in a passively Q-switched Nd:YVO<Subscript>4</Subscript> laser with V<Superscript>3+</Superscript>:YAG as saturable absorber

The efficient dual-wavelength oscillation at 1064 and 1342 nm in the passively Q-switched laser based on Nd:YVO₄/V³⁺:YAG is successfully obtained, as demonstrated in this paper. A total average output power of 2.2 W is obtained with 1.3 W for 1064 nm and 0.9 W for 1342 nm under the incident pump power of 7.7 W, corresponding to a total optical-optical conversion efficiency of 28.2%. The pulse widths are 58 and 54 ns for 1064 and 1342 nm, respectively, with the repetition rate of 89 kHz. Moreover, a rate equation model considering the Gaussian spatial distributions of the intracavity photon density and the initial population-inversion density is presented to characterize the dual-wavelength passive Q-switching operation.