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1.
激光烧蚀叠氮化钠产生的团簇离子及其分布   总被引:1,自引:0,他引:1  
用飞行时间质谱研究了激光烧蚀叠氮化钠固体产生的正负团簇离子的组成及其分布,产生的团簇系列包括:(Na(NaN3)n)^+,(Na3(NaN3)n)^+,(Na4N(NaN3)n)^+,(Na5(NaN3)n)^+,(NaN3)n)^+,(Nan)^+,(N3(NaN3)n)^-,(Na(NaN3)n)^-,(NaN3)n)^-,(N(NaN3)n)^-,提出正负团簇离子形成的可能机理,分析了影响因  相似文献   

2.
不同金属离子与色氨酸作用的荧光光谱研究   总被引:2,自引:0,他引:2  
研究了不同金属离子对色氨酸的荧光强度的影响。结果表明,在一定条件下当达到一定浓度时,Cu(Ⅱ),Fe(Ⅲ),Mo(Ⅵ)对色氨酸的荧光有猝灭作用,而此时Zn(Ⅱ),Mn(Ⅱ),Cr(Ⅲ),Co(Ⅱ),Ca(Ⅱ)和Na(Ⅰ)则对色氨酸的荧光几乎没有影响。  相似文献   

3.
用飞行时间质谱仪探测了直接激光气化碱式碳酸镁样品产生的质谱,结果表明:氧化镁团簇与同时产生的水分子发生了原位溶剂化反应并产生了各种尺寸的溶剂化氧化团簇离子,这些团簇离子包括:(Mg(H2O)m)^+(m=0,1,2,3),(Mg(MgO)H2O)m(m=1,2,3,4)(H(MgO)(H2O)m)^+(m=0,1,2,3,4,5,6),(H(MgO)2(H2O)m)^+(m=0,1,2,3,4,5  相似文献   

4.
本文成功地合成了一系列新型Pb-1222相层状铜氧化物(Pb0.5Cd0.5)(Sr0.9R0.1)2(R'0.7Ce0.3)2。Cu2Ox,R=R'=Y,Pr,Sm,Eu,Gd,Dy,Ho以及(R,R’)=(La,Eu),(Sm,Gd),(Sm,Eu),(La,Gd),(Eu,Gd),(Nd,Eu),(Nd,Dy),(Nd,Y),(Nd,Er).X-射线衍射和电子衍射表明它们属于四方晶系,其结构与(Pb,CU)-1222相结构相似.其中(R',R')=(Eu,Gd)的样品在氧气中成相得到23K的超导转变临界温度.  相似文献   

5.
本成功地合成了一系列新型Pb-1222相层状铜氧化物(Pb0.5Cd0.5)(Sr0.9R0.1)2(R‘0.7Ce0.3)2Cu2Oz,R=R’=Y,Pr,Sm,Eu,Gd,Dy,Ho以有(R,R‘)=(La,Eu),Sm,Gd),(Sm,Eu),(La,Gd),(Eu,Gd),(Nd,Dy),(Nd,Y),(Nd,Er)。  相似文献   

6.
AuthorIndextoVolumeB3,1994Alda,J.--(3),265GuoHong--(2),129,137;(4),317;(5),421;Bernabeu,E.--(3),265(6),529,533CatShangda--(4)...  相似文献   

7.
元素在探针表面上的原子化机理研究   总被引:3,自引:0,他引:3  
探针原子人经法是一种新技术,本文系统地总结了用探针原子化法研究Au(1B),Sr(ⅡA),Cd(ⅡB),Al(ⅢA),La,Sm,Fu(ⅢB),Ge,Sn,Pb(ⅣA),Sb,Bi(ⅤA),V(ⅤB),Cr,Mo(ⅥB),Mn(ⅦB),Fe,Co,Ni,Pt(Ⅷ)等20个元素的原子化机理了起源于卤化物分解的元素有Au与Pt,起源于氧化物分解的元素有Cd,Al,La,Sm,Eu,Ge,Mn与Fe。  相似文献   

8.
用紫外可见吸收光谱研究了二种新尾式卟啉:5-邻(4-(3-吡啶氧基)丁氧基)苯基10,15,20三苯在卟啉(O-PyTpp)和5-邻(4-(1-咪唑基)丁氧基)苯基10,15,20三苯基卟啉(O-ImTPP)的铁(Ⅲ)和锰(Ⅲ)配合物:O-PyTPPFe(Ⅲ),Cl,O-ImTPPFe(Ⅲ),Cl-PyTPPMn(Ⅲ),Cl,O-ImTPPMn(Ⅲ)Cl与含氮配体的轴向配位性质,结果表明,对于铁(  相似文献   

9.
为了真实削减核弹头,核查的健全措施必须保证:(1)除一致同意的数量外,不得在库存中增加任何核弹头(衡算);(2)对于行将拆卸的弹头,必须建立一套完整的库存保管措施(来源);(3)要拆卸的弹头,必须得到确认(认证);(4)拆卸过程尽可能做到不可逆(处置)。  相似文献   

10.
万钧  申三国 《物理学报》1997,46(6):1161-1167
利用角度修正的嵌入原子方法研究了Cu(100),(110),(111)和(311)等8个面的驰豫,得到了与实验符合较好的结果,然后研究了Cu(100)面上的自扩散机制,得到了与实验和局域密度近似计算相符合的结论,还计算了*(110)和(111)面的扩散势垒。  相似文献   

11.
A review of schemes for multiple access in fiber optic networks shows that a hybrid of wavelength and code division multiple access (WCDMA) combines the best features of both. In particular, the hybrid scheme retains the large information carrying capacity of wavelength division multiple access (WDMA) and flexibility of code division multiple access (CDMA). In this paper WDMA, optical CDMA (OCDMA), and WCDMA networks are discussed. In OCDMA networks, concept of incoherent and coherent coding including inverse decoding and matched filter is introduced. The delay performance of both WDMA and WCDMA networks, under the simple suboptimum access protocols based on cyclic search, is computed. It has been shown quantitatively that tuning delay significantly affects the delay performance of both WDMA and WCDMA networks. Futhermore, delay performance of WCDMA networks is always better than the WDMA networks for the same tuning delay, load, and number of users.  相似文献   

12.
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.  相似文献   

13.
A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output.  相似文献   

14.
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation (5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure crystals is analyzed (preliminarily). Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997.  相似文献   

15.
A multi-conjugate adaptive optics (MCAO) can offer a possibility of widening field of view (FOV) characterized by the isoplanatic angle, and the choose of conjugate height becomes a basic problem for MCAO, which influences the size of iosplanatic angle. Considering the application of lidar, the isoplanatic angle's expressions of two deformable mirrors (DMs) MCAO for uplink and downlink are deduced. The effects of conjugate heights for dual-conjugate AO are thoughtfully discussed, and the isoplanatic angles are further analyzed. The results show that the isopanatic angle varies with the conjugate height and reaches the maximum as the conjugate height is at the optimal altitude. Moreover, the optimal conjugate height changes with the propagation distance.  相似文献   

16.
Due to the limit of response speed of the present single-photon detector, the code rate is still too low to come into practical use for the present quantum key distribution (QKD) system.A new idea is put up to design a quick single-photon detector.This quick single-photon detector is composed of a multi-port optic-fiber splitter and many avalanche photo diodes (APDs).Au of the ports with APDs work on the time division and cooperate with a logic discriminating and deciding unit driven by the clock signal.The operation frequency lies on the number N of ports, and can reach N times of the conventional single-photon detector.The single-photon prompt detection can come true for high repetition-rate pulses.The applying of this detector will largely raise the code rate of the QKD, and boost the commercial use.  相似文献   

17.
18.
The performance of port/starboard discrimination of dual-line array will be seriously degraded when the space between the two line arrays of the dual-line array is mismatched. The directivity function of the delay-sum and delay-subtract beamforming is deduced and the port/starboard discrimination of the delay-sum and delay-subtract beamforming is also studied both under the ideal status and the status under which the space between the two line arrays of the dual-line array is mismatched. Analysis results show the delay-subtract beamforming has better performance of port/starboard discrimination. At last, the sea trial results demonstrate the theoretical results.  相似文献   

19.
The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper.  相似文献   

20.
With a novel light-weight and absolutely calibrated ultraviolet (UV) spectrometer, UV skylight radiances and O3 slant column densities are measured by balloon-borne limb measurements in Xinjiang area, China. UV skylight radiances measured at the height of 31 km are compared with the results from Modtran in the wavelength range from 290 to 420 nm. O3 slant column densities are derived from radiance spectra in the Huggins bands (320 - 335 nm) using differential optical absorption spectroscopy method. And the parameter exhibits a good correlation with the same value simulated by radiative transfer model (Tracy). The O3 profile simultaneously measured by an O3 sonde is used as input in Tracy calculations. The O3 sonde is launched on the same balloon.  相似文献   

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