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1.
This Letter aimed to develop an efficient method for the determination of cyanide ion (CN −). A novel colorimetric chemosensor 4-[(1 E)-2-(4-hydroxyphenyl)ethenyl]-1-allylpyridinium bromide (HPEAPB) was synthesized. HPEAPB displayed good selectivity toward CN − over other competing anions in ethanol. A color change from yellow to red was immediately observed upon the addition of CN − and the limit of detection (LOD) was 3.4 × 10 −6 mol L −1. The sensing mechanism was discussed by UV–vis, 1H NMR titration, and a comparison study. Colorimetric test paper for CN − was prepared by attaching HPEAPB to a chromatography paper, which could be used to detect CN − in environmental samples as simply as a pH-indicator paper for pH value. The LOD of the test paper for CN − was 2.0 × 10 −4 mol L −1. This detection method for CN − has potential applications in cyanide ion containing fields by combination of rapid and real-time advantages. 相似文献
2.
A colorimetric and fluorescent chemosensor (chemosensor 2) for the detection of cyanide anions in aqueous solution has been designed and synthesized in high yield. The sensing mechanism of the chemosensor was verified via UV–vis, fluorimetric, and NMR titrations, and was theoretically explained using DFT and TD-DFT calculations. The chemosensor could optically discriminate the presence of fluoride ions over other anions by a color change from yellow to red with an enhancement of pink fluorescence in DMSO. However, it showed strong green fluorescence when CN ? was added to a mixture of DMSO/water (6:4 v/v). Thus, the chemosensor can be employed in selective detecting of CN ? besides other interference anions (F ?, AcO ? and H 2PO 4?) in aqueous solution. Moreover, 2 can be used to detect CN ? at a concentration as low as 0.32?μM, which is lower than the WHO guideline (2.7?μM) for cyanide. A low quantity of CN ? (1.08?μM) can be detected and quantified using the prepared chemosensor. Moreover, the UV–vis and fluorescence spectroscopy studies of the interactions between 2 and dublex DNA revealed intercalative binding of calf thymus DNA to the chemosensor. 相似文献
3.
A new fluorescent chemosensor based on bithiophene coupled dimesitylborane (BMB-1) was synthesized and characterized. BMB-1 was used for colorimetric and turn-on fluorescent sensing of cyanide (CN −) and fluoride (F −) ions, in the presence of other competitive anions in an aqueous (CH 3CN–H 2O) medium. BMB-1 showed a hypsochromic shift (blue shift) with addition of CN − and F − ions in absorption studies. The lower detection level of CN − and F − ions is 1.37 × 10 −9 and 1.75 × 10 −9 M, respectively. The BMB-1 binding mechanism is based on the nucleophilic addition of CN − and F − ions in the internal charge transfer transition of bithio moiety to the boranylmesitylene unit, and the color changes were observed under UV light. This result is further confirmed by Fourier transform infrared spectroscopy, mass spectrometry and density functional theory calculations. Also, the BMB-1 probe is found to be a good adsorbent for the removal of F − ions in real water samples using the adsorption technique. 相似文献
4.
The selective assay of cyanide ions with a thioamide compound (HNPTU) containing phenol and pyridine as a chemosensor is reported using absorbance changes in a buffered aqueous solution (50 mM HEPES, pH 7.4) containing ethanol. Upon treatment with cyanide ions, the colorless solution of HNPTU turned yellow. No significant changes were observed with other comparable anions, such as F −, Cl −, Br −, I −, and CH 3COO −. The color change of HNPTU upon treatment with CN − was maintained even in the presence of the comparable monovalent anions. The complex stability constant ( Ka = 2.6 × 10 3) for the stoichiometric 1:1 complexation of HNPTU with cyanide ions was obtained based on absorbance titrations. The interaction of HNPTU with cyanide ions was proposed to be deprotonation, as shown by NMR and Cu(II) treatment experiments. 相似文献
5.
Taking advantage of the special nucleophilicity of cyanide, a new simple colorimetric chemosensor has been synthesised. This allows a deprotonation reaction to monitoring the cyanide. With the addition of CN ? to the chemosensor aqueous solution, which could induce a change in the solution colour from yellowish to deep yellow, while no colour change could be observed in the presence of other hackneyed anions, by which CN ? can be distinguished from other anions immediate with the naked eye. At the same time, a fluorescence quenching was implemented upon adding cyanide into the chemosensor aqueous solution. The absorption spectra detection limits of the chemosensor for cyanide was 5.35 × 10 ?8 M and the fluorescence spectra detection limit was 2.63 × 10 ?8 M. The cyanide test strips based on the chemosensor could serve as a convenient cyanide test kits. Furthermore, the chemosensor was successfully applied to detect cyanide in sprouting potatoes. 相似文献
6.
Coumarinyl-benzothiazolyl Schiff base (HL) is spectroscopically (FTIR, UV–Vis, NMR, Mass) characterized and the Single Crystal X-Ray Diffraction measurement confirms the structure. The molecule is water insoluble and DMSO solution shows weak emission which may be due to ESIPT assisted H-transfer quenching process. The emission is significantly enhanced in presence of CN −, one of the most toxic anions, through ‘turn-on’ emission (λ em = 449 nm; λ ex = 350 nm) even in presence of many other anions. The mechanism of sensing towards CN − has been described by 1H NMR titration which reveals deprotonation of –OH group and nucleophilic attack to the imine (-CHN-) bond. Further, the Job's plot supports 1:1 molar binding ratio, [HL + CN −] ( Kd, 0.696 x 10 4 M −1) and has been confirmed by ESI-MS. The detection limit (LOD), 0.75 μM, is third best literature. MTT assay of HL shows no-toxicity up to 100 μM and Intracellular Imaging in MDA-MB 231 cell line has been performed for the sensing of CN −. 相似文献
7.
The cyanide ion was studied as an effecter of Jack bean urease at 300 K in 30 mmol⋅L −1 Tris buffer, pH=7. The inhibition was investigated by isothermal titration calorimetry (ITC). The extended solvation model
was used for CN −+JBU interaction over the whole range of CN − concentrations. The binding parameters recovered from the solvation model were attributed to the interaction with cyanide
ion. It was found that cyanide ion acted as a noncooperative inhibitor of urease, and there is a set of 12 identical and independent
binding sites for CN − ions. The dissociation equilibrium constant is 749.99 μmol⋅L −1. The molar enthalpy of binding is Δ H=−13.60 kJ⋅mol −1. 相似文献
8.
As a novel macrocyclic host, pillar[5]arene can selectively recognise guest molecules in organic solvents. In this study, a fluorescent chemosensor composed of a functionalised-pillar[5]arene and Cu 2+ metal complex (PN–Cu), which shows good selectivity for CN ? anions, has been designed and synthesised. Complexation between PN–Cu and anions has been probed by means of various fluorescence-based methods. PN–Cu, as a turn-on fluorescence chemosensor showed high selectivity towards CN ? ions in comparison to other anions, and its detection limit for CN ? was calculated as 9.03 × 10 ?7 M. The PN–Cu sensor can serve as a recyclable component in sensing materials. Moreover, the interaction between the singly functionalised pillar[5]arene and Cu 2+ has been probed through various tests. Based on the remarkable selectivity of the chemosensor PN–Cu, we propose that it might be used as a potential material for CN ? recognition. 相似文献
9.
One main source of cyanide (CN −) exposure for mammals is through the plant consumption; thus, the sensitive and selective cyanide detection in plant tissue is a significant and urgent work. Here, a simple sensor N′‐(2,4‐dihydroxybenzylidene)naphtha[2,1‐ b]furan‐2‐carbohydrazide ( Q1‐3 ) was designed and synthesized for selective and sensitive dual‐channel detection of cyanide in aqueous medium (DMSO/H 2O, 1:9, v/v). Acylhydrazone and phenolic hydroxyl groups on Q1‐3 are the recognition sites, and naphthofuran group is the signal report group. The intramolecular charge transfer between the benzene group and naphthofuran group was impeded because of the electron‐withdrawing groups (hydroxyl) on sensor Q1‐3 . Interestingly, the sensor Q1‐3 exhibited an intramolecular charge transfer absorption band at 400 nm and emission band at 500 nm, respectively, directly realizing an “OFF–ON” response after the deprotonation process induced by cyanide anions in aqueous medium (DMSO/H 2O, 1:9, v/v). Notably, this sensor was successfully applied to detect cyanide anions in food samples, which proves a very simple and selective platform for on‐site monitoring of cyanide in agriculture samples. In addition, the test strips and silica gel plates based on Q1‐3 were also fabricated, which could act as test kits and silica gel plates for convenient and efficient detection of cyanide anions. 相似文献
10.
Preconcentration followed by ultraviolet spectrophotometric determination of amoxicillin (Amox) in pharmaceuticals and water samples by using a three-phase hollow fiber microextraction technique based on carrier-mediated transport has been presented. Amox was extracted from an aqueous solution (source phase) at pH 9.0 into 1-octanol containing 5% (w/v) Aliquat-336 impregnated in the pores of a hollow fiber. It was then back-extracted into NaCl solution (pH = 4.0) which was already positioned as the receiving phase inside the lumen of the hollow fiber. The extraction took place due to the concentration gradient of the counterion between the source and the receiving phases. Under the optimized conditions, an enrichment factor of 240 and a limit of detection of 0.2 μmol L−1 were obtained. The calibration curve was linear (R2 = 0.9967) in the concentration range of 0.5–10.0 µmol L−1 Amox. The interday relative standard deviation (n = 9) and the intraday relative standard deviation (n = 3) for 1.0 × 10−6 mol L−1 Amox solution were 7.3 and 6.4%, respectively.
相似文献
11.
A tripodal receptor bearing phenol as a hydrogen bond donor site and azo dye as the signaling subunit was synthesized. The receptor had a high binding affinity for CN − as signaled by the change in the color of a solution of sensor 4 upon addition of CN −. Using UV-Vis spectroscopy, the system can be used to quantify 0-19 × 10 −5 mol L −1 of CN −, and the sensor was found to successfully function in the presence of other anions. 相似文献
12.
A Rhodamine based Schiff base, (E)-3′,6′-Bis(ethylamino)-2-(2-(((7-hydroxy-4-methyl-2-oxo-2H-chromen-8-yl)methyl-ene)amino)ethyl)-2′,7′-dimethylspiro[isoindoline-1,9′-xanthen]-3-one ( HL) has been synthesized and characterized by various spectroscopic data, viz. 1H and 13C NMR, ESI-MS, FT-IR and elemental analysis. It shows very weak fluorescence emission (9:1 (v/v) DMSO/H 2O, HEPES buffer at pH 7.4) while it is enhanced considerably upon addition of CN − ion selectively ( λem, 456 nm) in presence of nineteen other biologically important anions. The Limit of Detection (LOD) is 24 nM which is significantly lower than literature reported data. The binding interaction of the probe to CN − ion, 1:1 (HL:CN −) mole ratio has been confirmed by Job's plot, ESI-MS spectral data and 1H NMR spectral titration measurement. 相似文献
13.
A new benzimidazole‐spiropyran conjugate chemosensor molecule ( BISP ) has been synthesized and characterized by 1H NMR spectroscopy, mass spectrometry (ESI‐MS), and elemental analysis. The two isomeric forms ( BISP ? BIMC ) were shown to be highly selective and sensitive to CN ? among the ten anions studied in aqueous HEPES buffer, as shown by fluorescence and absorption spectroscopy and even by visual color changes, with a detection limit of 1.7 μM for BIMC . The reaction of CN ? with BIMC was monitored by 1H NMR spectroscopy, high‐resolution mass spectrometry (HRMS), UV/Vis measurements, and fluorescence spectroscopy in HEPES buffer of pH 7.4. TDDFT calculations were performed in order to correlate the electronic properties of the chemosensor with its cyanide complex. Further, titration against thiophilic metal ions like Au 3+, Cu 2+, Ag +, and Hg 2+ with [ BIMC‐CN ] in situ showed that it acts as a secondary recognition ensemble toward Au 3+ and Cu 2+ by switch‐on fluorescence. In addition, a reversible logic‐gate property of BIMC has been demonstrated through a feedback loop in the presence of CN ? and Au 3+ ions, respectively. Furthermore, the use of BIMC to detect CN ? in live cells by fluorescence imaging has also been demonstrated. Notably, test strips based on BIMC were fabricated, which could serve as convenient and efficient CN ? test kits. 相似文献
14.
We synthesized a new cyanide (CN −) chemosensor CX based on a nucleophilic addition reaction prompted by cyanide ion, which could be used for highly selective and sensitive fluorescence turn‐on detection of cyanide in aqueous media. The CX showed selective fluorescence recognition for CN −, the miscellaneous competitive anions (F −, Cl −, Br −, I −, AcO −, H 2PO 4−, HSO 4−, ClO 4−, S 2 −, PO 43−, CO 32− and SCN −) did not lead to any significant interference. The detection limit of the sensor towards CN − is 1.15 × 10 −7 mol•L −1. The sensor has been successfully applied to estimate the cyanide ion in seeds of cherries. Test strips based on CX were fabricated, which could be used as a convenient and efficient CN − test kit to detect CN − in aqueous solution for “in‐the‐field” measurement. 相似文献
15.
We have developed a FRET-based ratiometric fluorescent probe for the detection of CN − using a fluorescein–Zn–naphthalene ensemble (NFH·Zn 2+). The sensing mechanism was ascribed by displacement approach. The chemosensor exhibits high selectivity and sensibility for CN −. The speculation was supported by fluorescence emission spectra, UV–vis spectrum, 1H NMR titration experiments, and mass spectra. The interconversion of probe NFH and NFH·Zn 2+ via the complexation/decomplexation by the modulation of Zn 2+/CN − mimics INHIBIT gate. In addition, it also shows an excellent performance in ‘dip stick’ method. 相似文献
16.
Sodium diethyldithiocarbamate (DDTC-Na) was demonstrated to be a new colorimetric cyanide chemosensor by utilizing an indirect
trick. First, some copper ions were added to the colorless aqueous solution of DDTC-Na. Then, the resultant brown solution
was studied upon the addition of different anions, including Cl −, I −, IO 3−, SO 42−, NO 2−, Br −, H 2PO 4−, F −, SCN −, HSO 4−, ClO 4− and CN −. It was observed by naked eyes that the brown solution changed to colorless immediately after the addition of the trace cyanide,
but there were no changes towards other anions, making DDTC-Na a good selective cyanide chemosensor in pure water.
Supported by the National Natural Science Foundation of China (Grant Nos. 20674059 & 20402011) 相似文献
17.
Graphene oxide (GO) was chemically modified with a poly(propylene)imine Generation 3.0 dendrimer (DAB-Am-16). The characterization, structure and properties of hybrid graphene oxide/DAB-Am-16 dendrimer was studied by Raman spectroscopy, Fourier-Transforming Infrared Spectroscopy (FT-IR), X-Ray Photoelectron Spectroscopic (XPS), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Thermogravimetric analysis. After functionalized the hybrid material (GOD) can interact with copper and subsequently with hexacyanoferrate (III) ions (GODHCu). The GODHCu incorporated into a graphite paste electrode (20% w/w) was applied to an electrocatalytic detection of neurotransmitter l-dopamine using differential pulse voltammetry. The analytical curve showed a linear response in the concentration range from 1.0 × 10 −7 to 1.0 × 10 −5 mol L −1 with a corresponding equation Y(A) = 1.706 × 10 −5 + 0.862 [l-dopamine] and a correlation coefficient r 2 = 0.998. The detection limit was 6.36 × 10 −7 mol L −1 with a relative standard deviation of ±4% (n = 3) and an amperometric sensitivity of 0.862 A/mol L −1. 相似文献
18.
A novel thiazole-based Schiffbase chemosensor SB1 with N- and O- donor atoms was synthesized and characterized by different techniques (UV–vis, 13C NMR, 1H NMR, and FT-IR analysis). The chemosensor SB1 was used for the determination of Cu 2+ ions in various samples. The significant spectral changes in absorption spectra of chemosensor SB1 at 220 and 416 nm and the color change from light yellow to yellowish-brown indicate high selectivity and sensitivity towards Cu 2+ ions as compared to other cations (Na +, K +, Ag +, Zn 2+, Ni 2+, Pb 2+, Mn 2+, Mg 2+, Co 2+, Cd 2+, Sn 2+, Hg 2+, Cr 3+, Fe 3+, and Al 3+). The sensing mechanism of SB1 was investigated through various techniques such as FT-IR, UV–vis and 1H NMR titration experiment and further confirmed by DFT computational studies. The 2:1 binding mode between SB1 and Cu 2+ ions was confirmed by Job‘s plot using UV–vis spectrophotometry. The limit of detection (LOD) and limit of quantification (LOQ) were found to be 0.015 and 0.0471 µg mL ?1, respectively. The percent recovery of Cu 2+ from various environmental samples was found to be 95.00–103.33% at various levels. These obtained results demonstrate that chemosensor SB1 is a cost-effective, facile, selective, sensitive, and colorimetric sensing platform to detect trace amounts of Cu 2+ ions in variousenvironmental and agricultural samples. 相似文献
19.
Carbazole-based Schiff base chemosensor was synthesized in one-pot synthesis using 2-hydroxy-1-naphtaldehyde for fluorescent sensing of Al 3+ ions. Characterization of the ligand (L) was revealed through spectroscopic and physicochemical techniques. The fluorescence emission responses of L to various metal ions and anions were investigated. The chelation was studied by UV–vis, 1H NMR, LC-MS/MS, fluorescence titration and Job’s plot analysis. Bathochromic shift resulted from charge transfer from L to electrophilic Al 3+ ion was observed in the chelation of L with Al 3+. The potentiality of L to be a distinguished probe to detect Al 3+ ions was due to a chelation enhanced fluorescence (CHEF) effect, concomitant with noticeable fluorescent enhancement. A significant fluorescence enhancement at 533 nm was observed in ethanol–water (1:1, v/v) solution upon addition of Al 3+ along with a distinct color change from yellow to white. Non-fluorescent ligand exposed highly sensitive turn-on fluorescent sensor behavior for selectively sensing Al 3+ ions via 1:1 (ligand:metal) stoichiometry. The ligand’s specificity in the existence of other tested metal ions and anions indicated no observation in color change. The ligand-Al 3+ complex formation was reversible upon addition of chelating agent EDTA. The ligand interacted with Al 3+ ions with an association constant of K a = 5 × 10 4 M ?1. The limit of detection (LOD) was found to be 2.59 × 10 -7 M. The synthesized Schiff base could efficiently detect Al 3+ ions as a fluorescent sensor. 相似文献
20.
A water-soluble polymeric probe was designed and synthesized that can be used for the colorimetric selective detection of cyanide ions in pure aqueous media. In particular, P1, a water-soluble random terpolymer (P1) of N, N′-dimethylacrylamide, 2-(( E)-4-(( E)-(4-((2-(acryloyloxy)ethyl)(methyl)amino)phenyl)diazenyl)styryl)-1,3,3-trimethyl-3H-indol-1-ium (M1), and N-(4-benzoylphenyl)acrylamide was synthesized via traditional free-radical polymerization. Upon the addition of CN − ions to a P1 solution, a macroscopically detectable color change of the solution from brick red to light yellow took place, which was associated with a low limit of analyte detection (1.23 μM). Notably, P1 exhibited excellent selectivity toward CN − over other anions and biothiols, which may be present in the medium. Such highly selective colorimetric response to CN − by P1 originated from the nucleophilic attack of CN − anions onto the electron-deficient polarized CN bonds of P1's indolium moieties, resulting in the perturbation of the intramolecular charge transfer process occurring within the probe via destruction of the polymer's extended π-conjugation. P1 was also immobilized on a quartz slide by spin coating and then exposed to ultraviolet light. The resulting polymeric film displayed a rapid response to CN − consisting in a distinct color change, extending the scope of the usefulness of P1 as a cyanide-ion probe beyond the solution phase. © 2019 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 124–131 相似文献
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