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PMBP为载体的乳状液膜提取钪的研究 总被引:4,自引:0,他引:4
研究了以1-苯基-3-甲基-4-苯甲酰基吡唑酮-5(PMBP)为流动载体的乳状液膜(ELM)法提取钪,确定最佳液膜体系组成为0.4%PMBP-3%Span80-5%液体石蜡-煤油-3mol/LHCl,Roi=1:1(油内比).Rwe(水乳比)可达20:1.用该体系对钪与混合稀土进行分离,钪的回收率可达95.5%,分离系数β(SC/RE)=32.0。 相似文献
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彭天右 《高等学校化学学报》1998,19(5):699-702
报道了以1-苯基-3-甲基-4-苯甲酰基-吡唑酮「5」为化学改进剂的ETV-ICP-AES测定痕量钪的新方法。详细研究了属螯合在石墨炉内的形成、挥发及其影响因素;发现过量PMBP的存在有利于该螯合物的形成, 相似文献
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用钼酸盐和罗丹明B连续光度法测定铈和钪 总被引:4,自引:0,他引:4
聚乙烯醇存在下,铈或钪钼杂多酸与罗丹明B(RB)形成离子缔合物,最大吸收均位于570nm,摩尔吸光系数分别为1.16×10^6和5.62×10^5L.mol^-1.cm^-1,cm^-1,0-1.2μg/25mLCe和0-2.0μg/mLSc服从比耳定律,检测限1.5ng/mLCe(n=10)和1.1ng/mLSc(n=9)。缔合物的摩尔比为Ce:mO:RB=1:6:3和 Sc:Mo:RB=1:1 相似文献
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丁基罗丹明B—钼酸盐光度法连续测定铈和钪 总被引:4,自引:0,他引:4
在聚乙烯醇(PVA)存在下,丁基罗丹明B(BRB)分别与铈钼、钪钼杂多酸络阴离子形成离子缔合物,其最大吸收均位于570nm,表面摩尔吸光度分别为εCe=3.96×10^6L.mol^-1.cm^-1,εSc=4.71×10^5L.mol^-1.cm^-1,服从比耳定律范围分别为0-24μg/L Ce和0-60μg/LSc,测定极限为Ce1.0μg/L(n=12)和Sc1.9μg/L(n=10),对 相似文献
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聚乙烯醇存在下钼酸盐和罗丹明B光度法测定钪 总被引:4,自引:0,他引:4
在聚乙烯醇存在下,钪相杂多酸和罗丹明B(RB)形成离子缔合物,其最大吸收位于570nm,表观摩尔吸光系数ε值为5.62×10^5L.mol^-1.cm^-1,服从比耳定律范围0-1.0μgSc/25mL,检出限1.1ng/mL(n=9),考察了50多种外来离子影响,缔合物的摩尔组成为Sc:Mo:RB=1:12:6,方法用于地质样品中钪的分析,结果满意。 相似文献
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在pH=5.0的HAcNaAc介质中,Nb(Ⅴ)与1-苯基-3-甲基-4-苯甲酰基-吡唑啉酮-5(PMBP)生成络合物,于一0.96V(vs.SCE)出现一尖极谱波。在滴汞电极上用示波极谱仪或在悬汞电极上则吸附伏安曲线。峰电流与Nb(Ⅴ)浓度分别在0.0075-0.80μg/mL及0.000075-0.0075μg/mL范围内呈线性关系。实验 3 相似文献
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钪—水杨醛苯甲酰腙高灵敏度荧光反应及其应用 总被引:6,自引:0,他引:6
研究了水杨醛苯甲酰腙(SABH)与钪荧光反应新体系的最佳条件。在pH=6.4乙醇/水(6.2:3.8)溶液介质中,形成络合物的组成比1:3(钪、试剂),λex/λem=385nm/455nm,建立钪荧光分析法的线性范围为0 ̄100μg/L;相对标准偏差1.5%;检出下限为0.025μg/L。考察了30种共存离子的干扰情况,方法成功用于地质中样中痕量钪的测定。 相似文献
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镉(Ⅱ)—1—苯基—3—甲基—4—苯甲酰基—吡唑啉酮—5配合物吸附波的研究 总被引:4,自引:2,他引:4
在PH4.8的HAc-HN4Ac介质中,Cd(Ⅱ)与1-苯基-3-甲基-4-苯甲酰基-吡唑啉酮-5(PMBP)生成配合物,于-0.67V(vs.SCE)出现一尖锐、灵敏的极谱波。镉含量在0.001-1.0μg/mL范围内与峰高成线性关系。 相似文献
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镉(Ⅱ)-1-苯基-3-甲基-4-苯甲酰基-吡唑啉酮-5配合物吸附波的研究 总被引:1,自引:0,他引:1
在pH4.8的HAc-NH_(4)Ac介质中,Cd(Ⅱ)与1-苯基-3-甲基-4-苯甲酰基-吡唑啉酮-5(PMBP)生成配合物,于-0.67V(vs.SCE)出现一尖锐、灵敏的极谱波。镉含量在0.001~1.μg/mL范围内与峰高成线性关系。用多种电化学方法研究了极谱波的性质及电极反应机理,证明-0.67V处的极谱波为配合物吸附波,峰电流由中心离子Cd(Ⅱ)还原产生。配合物组成为Cd(Ⅱ):PMBP=1:1。试验了30多种离子对峰电流的影响,用SrSO_4共沉淀分离Pb(Ⅱ),再经巯基棉分离其它干扰离子。用于矿样中镉的测定,结果满意。 相似文献
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Two New Ammoniates of Scandium Trichloride, ScCl3(NH3) and ScCl3(NH3)2 Reactions of scandium with ammonium chloride in the presence of cupric chloride in sealed copper ampoules yield colorless single crystals of the two new ammoniates of scandium trichloride, ScCl3(NH3) und ScCl3(NH3)2. The crystal structures were determined from single crystal data; they both crystallize with the triclinic crystal system. In ScCl3(NH3)2 isolated unsymmetrical dimers of double octahedra, according to [Sc‐mer‐(NH3)3/1Cl1/1Cl(2/2)×2Sc(NH3)1/1Cl3/1] are the characteristic structural features. The crystal structure of ScCl3(NH3) also contains double octahedra, [Sc(NH3)2/1Cl2/1Cl2/2]2; these dimers are, however, connected via common edges forming infinite zig‐zag chains according to the formulation [Sc(NH3)1/1Cl1/1Cl4/2]. 相似文献
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IntroductionThe fluorescence of Sc(3+) itself in solution is not observed. After complexed with an organic ligand with a chromophore, Sc(3+) makes the ligand, which has no or has weak fluorescence, emit strong fluorescence. The fluorescence reagents of Sc~(3+) have been summarized inreferences[1,2], but the derivative of diacylated pyrazolone as a fluorescence reagent of Sc~(3+) hasnot been reported. The experiments indicated that the synthetic derivative of diacylated pyrazolone, 1, 6-bi (1… 相似文献
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本文系统研究了在阳离子表面活性剂存在下钪与溴邻苯三酚红及三乙烯四胺形成多元络合物的条件,测定了络合物的最大吸收波长和摩尔吸光系数,确定了络合物的组成。并初步探讨了反应机理。 相似文献
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《无机化学与普通化学杂志》2018,644(7):405-409
Acid‐base reaction of Sc(CH2C6H4NMe2‐o)3 with 1 equiv. of pyrrolyl‐substituted cyclopentadienyl ligand C4H2Me2NSiMe2C5Me4H in toluene gave the half‐sandwich scandium bis(aminobenzyl) complex (C4H2Me2NSiMe2C5Me4)Sc(CH2C6H4NMe2‐o)2 ( 2 ). Amine elimination between Sc[N(SiHMe2)2]3(THF) and one equivalent of C4H2Me2NSiMe2C5Me4H afforded the scandium bis(silylamide) complex (C4Me2H2NSiMe2C5Me4)Sc[(NSiHMe2)2SiMe2](THF) ( 3 ). Both scandium complexes 2 and 3 were characterized by elemental analysis, NMR spectroscopy, and single‐crystal X‐ray diffraction. 2 and 3 could serve as highly active precursors for styrene polymerization to give syndio‐tactic polystyrene (rrrrrr > 99 %). 相似文献
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Erick A. Juarez-Arellano Björn Winkler Alexandra Friedrich Daniel R. Kammler Jinyuan Yan Florian Schröder 《Journal of solid state chemistry》2010,183(5):975-5
Synchrotron diffraction experiments with in situ laser heated diamond anvil cells and multi-anvil press synthesis experiments have been performed in order to investigate the reaction of scandium and carbon from the elements at high-(P,T) conditions. It is shown that the reaction is very sensitive to the presence of oxygen. In an oxygen-rich environment the most stable phase is ScOxCy, where for these experiments x=0.39 and y=0.50-0.56. If only a small oxygen contamination is present, we have observed the formation of Sc3C4, Sc4C3 and a new orthorhombic ScCx phase. All the phases formed at high pressures and temperatures are quenchable. Experimentally determined elastic properties of the scandium carbides are compared to values obtained by density functional theory based calculations. 相似文献
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本文研究了钪—偶氮氯膦Ⅲ—铜—邻菲罗啉配合物的形成条件。在pH3.6醋酸钠—盐酸介质中配合物的最大吸收峰在606nm处,摩尔吸光系数ε_(606)=7.02×10~(-4)L·mol~(-1)·cm~(-1)。配合物各组分摩尔比Sc∶R ∶Cu∶Phen=1∶1∶1∶3。分子式为[ScOH·H_4R][Cu(Phen)_3]。应用于以铜基合金合成试样中钪的直接测定,结果较好。 相似文献