共查询到17条相似文献,搜索用时 281 毫秒
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本实验测定了新型钼(钨)-铁-硫簇合物(1)(Et4N)[MoFe2(μ3-S)2(CO)8(S2CNEt2)和(2)(Et4N)[WFe2(μ3-S)2(CO)8(S2CNEt2]的穆斯堡尔谱和晶体结构。它们分子中的两个铁原子是等价的,所以都只的一组对称的四极分裂双峰。这个结果与单晶结构分析一致。经计算机拟合后的穆斯堡尔参数(77K时)为:对于(1),化学位移δ=0.08±0.004mm/s,四 相似文献
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本采用H2O的二个^1A1态的双值多体项展式(DMBE)势能函数,用Ehrenfest模型方法研究了反应(1)O(^1D)+H2→OH和(2)O(^1D)+H2→OH(A^2∑^+)+H的非绝热碰撞动力学过程。讨论了电子非绝热跃迁对反应(1)的影响及H2振动能对反应(2)的促进作用。并求得反应(1)的室温速度常数为0.944×10^-^1^0cm^3.molecule^-^1.s^-^1。 相似文献
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对下列含MoFe3S4单元的μ2-OR或μ2-SR桥联双类立方烷簇合物的红外光谱进行了研究:(Et4N)3「Mo2Fe6S8Cl6(OMe)3」(1),(Et4N)3「Mo2Fe6S8(SPh)6(OMe)3」(2),(Bu4N)3「Mo2Fe6S8(SPh)6(OMe)3」(3)(Et4N)3「Mo2Fe6S8(SBu^t)6(OMe03」(4)m,(Et4N)3「Mo2Fe6S8(SPh)9」 相似文献
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利用群的直乘分解公式,考虑U(N)群的[2a1b]表示按群链U(N)SP(N)O(3)的约化规则,给出了相应的比较简单的分支律递推公式.该公式在用计算机计算分支律时,不受秩和表示维数的限制.为求解这类问题的分支律提供了一种比较简单的算法.在简化同位旋1/2的单j费米子体系的母分系数计算中具有十分重要的意义.用同样的方法也可以求出群链U(N)O(N)O(3)的分支律. 相似文献
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在流体粒子概率密度函数输运方程中考虑颗粒对流体的反作用力,发展了考虑双向耦合效应的LB气固两相流模型,引入Smagorinsky亚格子模型模拟高雷诺数气相流场.对经典后台阶气固两相流动进行模拟,气相和颗粒相速度分布与实验结果进行比较,发现考虑双向耦合效应的LB气固两相流模型结果明显优于单向耦合结果.进一步研究不同惯性颗粒在流场中的弥散特性,小颗粒(St~O(0.1))对流体的跟随性较好,在流场中分布较为均匀;而St~O(1)的颗粒难被流场涡卷吸进入涡内,呈现倾向性弥散现象;大颗粒(St~O(10))由于自身惯性进入流场涡,在流场中分布较为均匀. 相似文献
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Ayyalasomayajula S Gylfason A Collins LR Bodenschatz E Warhaft Z 《Physical review letters》2006,97(14):144507
We describe Lagrangian measurements of water droplets in grid generated wind tunnel turbulence at a Taylor Reynolds number of R(lambda)=250 and an average Stokes number (St) of approximately 0.1. The inertial particles are tracked by a high speed camera moving along the side of the tunnel at the mean flow speed. The standardized acceleration probability density functions of the particles have spread exponential tails that are narrower than those of a fluid particles (St approximately 0) and there is a decrease in the acceleration variance with increasing Stokes number. A simple vortex model shows that the inertial particles selectively sample the fluid field and are less likely to experience regions of the fluid undergoing the largest accelerations. Recent direct numerical simulations compare favorably with these first measurements of Lagrangian statistics of inertial particles in highly turbulent flows. 相似文献
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The effects of different tracer particles used in the PTV technique on the velocity field are investigated. The measurements are taken in a water round jet at a Reynolds number equal to about 40000, a flow field widely examined in the literature, in which strong velocity differences are encountered. The interest is focused onto particles with different density. Although the mean and rms values are almost unaffected, both measurements obtained with light and heavy particles (in comparison to the density of the fluid) reveal a modified velocity field. The moments of velocity differences (structure functions) point out that such a modification is felt within each range of flow scales. Particles with density almost equal to that of the fluid reproduce the flow behaviour over all the scales. 相似文献
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The evolution of the vortex state in superconductors with anisotropic pairing is investigated on the basis of the time-dependent
Ginzburg-Landau equations.
Fiz. Tverd. Tela (St. Petersburg) 39, 35–38 (January 1997) 相似文献
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A. A. Bukharaev D. V. Ovchinnikov N. I. Nurgazizov E. F. Kukovitskii M. Klaiber R. Wiesendanger 《Physics of the Solid State》1998,40(7):1163-1168
Isolated Ni nanoparticles were studied in situ by atomic and magnetic force microscopy in the presence of an additional external field up to 300 Oe. By comparing topographic
and magnetic images, and also by computer modeling of magnetic images, it was established that particles smaller than 100
nm are single-domain and easily undergo magnetic reversal in the direction of the applied external magnetic field. For large
magnetic particles, the external magnetic field enhances the magnetization uniformity and the direction of total magnetization
of these particles is determined by their shape anisotropy. Characteristics of the magnetic images and magnetic reversal of
particles larger than 150 nm are attributed to the formation of a vortex magnetization structure in these particles.
Fiz. Tverd. Tela (St. Petersburg) 40, 1277–1283 (July 1998) 相似文献
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螺旋状尾迹涡是直升机悬停旋翼流场的主导特征之一,其时空演化特性对旋翼气动性能具有重要影响.为了揭示悬停状态下旋翼尾迹涡的演化特征,对两桨叶刚性旋翼在高雷诺数悬停状态下的双螺旋状尾迹涡开展数值研究,采用基于流场特征的网格自适应技术,结合低耗散迎风/中心混合格式以及延迟脱体涡模拟方法对Caradonna-Tung旋翼在桨尖马赫数为0.439、桨尖雷诺数为1.92×10~6的悬停流场进行了高分辨率计算.基于欧拉和拉格朗日两种描述方法对计算结果进行了分析,揭示了双螺旋尾涡系统的演化特性:后缘尾涡面在桨尖附近的反向卷起及其与下游桨尖涡的相互作用是影响涡系稳定性以及涡-涡相互作用的重要因素;涡龄小于720°时,在固连于桨叶上的旋转坐标系中观察,涡系具有时空稳定性,涡管中心处轴向涡量随涡龄按照幂函数规律衰减.在固连于漩涡中心的局部极坐标系中,周向速度分布以及涡核半径随涡龄的变化与理论涡模型相符合,环量随涡龄的变化显示了漩涡的生长、平衡及耗散等演化阶段;模态分析结果表明,除点涡模态外,来流与点涡的复合模态在漩涡演化过程中对流动特征的转变有重要影响;涡系轴截面速度场的拉格朗日拟序结构直观地显示了漩涡场的时空演化过程,揭示了漩涡配对和共旋穿越等流动特征,同时也展示了后缘尾涡面卷起现象在漩涡演化过程中的作用. 相似文献